CN1651559A - 一种无泡无磷消毒洗涤剂 - Google Patents
一种无泡无磷消毒洗涤剂 Download PDFInfo
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- CN1651559A CN1651559A CN 200410077722 CN200410077722A CN1651559A CN 1651559 A CN1651559 A CN 1651559A CN 200410077722 CN200410077722 CN 200410077722 CN 200410077722 A CN200410077722 A CN 200410077722A CN 1651559 A CN1651559 A CN 1651559A
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- 239000011574 phosphorus Substances 0.000 title claims abstract description 18
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 18
- 239000012459 cleaning agent Substances 0.000 title claims description 17
- 229920000570 polyether Polymers 0.000 claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 10
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- 102220601533 Transforming growth factor-beta-induced protein ig-h3_A92R_mutation Human genes 0.000 claims abstract description 6
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- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 14
- 229960003500 triclosan Drugs 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
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- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
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Abstract
本发明公开了一种无泡无磷消毒洗涤剂。该洗涤剂按重量百分比计算，含有AEO－9 0.5～3.0％，聚醚L－62 1.0～4.0％，A92R 0.05～0.5％，丙烯酸－马来酸共聚物0.2～2.5％，三氯生0.2～2.0％，纯碱1.0～5.0％，聚醚改性有机硅消泡剂0.1～1.0％，水为余量。本发明的消毒洗涤剂同时兼具消毒和洗涤两种功能，消毒洗涤效果好，高效无毒，无污染。
Description
技术领域
本发明涉及一种组合物，具体的说涉及一种消毒洗涤剂。
背景技术
目前，应用于工业生产和日常使用的消毒和洗涤产品种类繁多，但同时兼具消毒和洗涤功能且作用效果显著又安全环保的产品极少。现有的消毒洗涤剂大多含有不同程度毒性的化学成份，其对环境和人畜有很大危害。大多消毒洗涤剂含磷，泡沫丰富，限制了其使用范围，市场呼唤高性能环保型消毒洗涤剂面世。
三氯生(克力恩)，化学名称为2.4.4′-三氯-2′-羟基二苯醚，结构式：
三氯生微溶于水，能溶于多种有机溶剂及表面活性剂，对强酸强碱及热具有高度稳定性，对引起感染或病原性革兰氏阳性及阴性菌、真菌、酵母及病毒(如甲、乙肝炎病毒、狂犬病毒、艾滋病毒HIV)等都具有广泛的杀灭及抑制作用；对皮肤无刺激性；对抗抗生素菌和非抗生素菌同样有效。
三氯生与人体皮肤有很好的相容性，长期广泛的动物毒理实验也证明了三氯生在建议使用范围及用量下，能够达到当今世界对化学品毒性的国际标准，是目前国际上推崇的安全高效广谱抗菌剂。
发明内容
本发明的目的在于克服现有消毒洗涤剂的环保问题，提供一种无色、无味、无毒、安全性好的高性能消毒洗涤剂。
本发明的无泡无磷消毒洗涤剂，按重量百分比计算，由如下组分组成：
AEO-9 0.5～3.0％
聚醚L-62 1.0～4.0％
A92R 0.05～0.5％
丙烯酸-马来酸共聚物 0.2～2.5％
三氯生 0.2～2.0％
聚醚改性有机硅消泡剂 0.1～1.0％
纯碱 1.0％～5.0％
水 余量。
上述无泡无磷消毒洗涤剂，其特征在于用NaOH调节无泡无磷消毒洗涤剂的pH＝13。
上述无泡无磷消毒洗涤剂，其特征在于用柠檬酸调节无泡无磷消毒洗涤剂的pH＝7.0～7.5。
本发明的无泡无磷消毒洗涤剂制备方法简单，将各个组分按比例混合均匀即可。
本发明的无泡无磷消毒洗涤剂使用方便，用水稀释30～50倍后，可室温下使用，也可以在30～40℃水中使用，消毒和洗涤时间为2～5分钟。
本发明的产品为无色透明溶液，稀释50倍后，1分钟杀灭大肠杆菌达到为100％。
本发明的有益效果：
1、本发明的无泡无磷消毒洗涤剂配方中，采用了消毒杀菌剂三氯生。三氯生为国际上流行的高效安全抗菌消毒剂，可以杀死大肠杆菌，金黄色葡萄球菌，白色念株菌，具有对化脓性球菌，肠道致病菌，和真菌的消毒作用，经实验测得其有效杀菌浓度为80ppm，广泛应用于化妆品，卫生洗液，洗涤用品，医疗器械，食品器具的杀菌消毒，对细菌无抗药性，目前其市场价格为140元/kg，而同样是杀菌剂的洗必泰(氯己定)的市场价格为460/kg。因此，本发明的无泡无磷消毒洗涤剂成本低，具有很好的性价比。
2、三氯生能被表面活性剂的胶束分散和包围在配方体系中，从而使微溶于水的三氯生能和较高浓度(1.5％以上)的表面活性剂形成均一透明溶液。选用L-62具有良好的乳化性能和分散性能，良好的除油污性能，作为洗涤剂的活性成份，无色、无味、无毒、安全性好。而AEO-9与L-62复配，使配方体系的HLB值达到了净洗所要求的值，从而使产品具有良好的洗涤功能。同时三氯生在液体水溶液中稳定性好，耐酸碱性好，适合于产品配方的无泡性能。
3、本配方使用了NTA和丙烯酸、马来酸共聚物作为金属离子螯合剂，其络合性能和分散能力很好，并且能完全生物降解，不含磷，从而不会对环境造成污染，是一种很好的环保型产品。
具体实施方式
实施例1
AEO-9 2.3克，A92R(Na3-NTA)0.7克，聚醚L-62 2.5克，丙烯酸-马来酸共聚物1.2克，三氯生0.5克，聚醚改性有机硅消泡剂0.3克，纯碱3克，用NaOH调节pH＝13，水余量。均匀混合制得100克无泡无磷消毒洗涤剂。本发明的无泡无磷消毒洗涤剂无色、无味、无毒、无泡。取10ml稀释50倍液于30ml比色管中，剧烈振荡10次，泡沫高度为25mm，3～4秒钟后泡沫全部消失，泡沫高度为0。
实施例2
AEO-9 3克，A92R(Na3-NTA)0.4克，聚醚L-62 3.5克，丙烯酸-马来酸共聚物2.4克，三氯生0.5克，聚醚改性有机硅消泡剂0.3克，用柠檬酸调节pH为7.0～7.5，水余量。均匀混合制得100无泡无磷消毒洗涤剂。本发明无泡无磷消毒洗涤剂无色、无味、无毒、无泡。取10ml稀释50倍液于30ml比色管中，剧烈振荡10次，泡沫高度为25mm，3～4秒钟后泡沫全部消失，泡沫高度为0。
Claims (2)
1、一种无泡无磷消毒洗涤剂，其特征在于按重量百分比计算，由如下组分组成：
AEO-9 0.5～3.0％
聚醚L-62 1.0～4.0％
A92R 0.05～0.5％
丙烯酸-马来酸共聚物 0.2～2.5％
三氯生 0.2～2.0％
聚醚改性有机硅消泡剂 0.1～1.0％
纯碱 1.0％～5.0％
NaOH 用于调节pH＝13
水 余量。
2、如权利要求1所述的无泡无磷消毒洗涤剂，其特征在于按重量百分比计算，由如下组分组成：
AEO-9 0.5～3.0％
聚醚L-62 1.0～4.0％
A92R 0.05～0.5％
丙烯酸-马来酸共聚物 0.2～2.5％
三氯生 0.2～2.0％
聚醚改性有机硅消泡剂 0.1～1.0％
纯碱 1.0％～5.0％
柠檬酸 用于调节pH＝7.0～7.5
水 余量。
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2004100777223A CN100340646C (zh) | 2004-12-29 | 2004-12-29 | 一种无泡无磷消毒洗涤剂 |
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| CNB2004100777223A CN100340646C (zh) | 2004-12-29 | 2004-12-29 | 一种无泡无磷消毒洗涤剂 |
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| Publication Number | Publication Date |
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| CN1651559A true CN1651559A (zh) | 2005-08-10 |
| CN100340646C CN100340646C (zh) | 2007-10-03 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820800A (zh) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | 一种低温脱脂清洗剂 |
| CN106577650A (zh) * | 2016-12-14 | 2017-04-26 | 广州泰晟生物科技有限公司 | 一种玉洁新泡腾制剂及其制备方法 |
| CN107254370A (zh) * | 2017-07-31 | 2017-10-17 | 王瑜琳 | 一种节能洗衣粉 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW430560B (en) * | 1996-11-15 | 2001-04-21 | Kao Corp | Detergent composition |
| US6488943B1 (en) * | 1999-04-13 | 2002-12-03 | The Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820800A (zh) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | 一种低温脱脂清洗剂 |
| CN106577650A (zh) * | 2016-12-14 | 2017-04-26 | 广州泰晟生物科技有限公司 | 一种玉洁新泡腾制剂及其制备方法 |
| CN106577650B (zh) * | 2016-12-14 | 2021-06-25 | 广州泰晟生物科技股份有限公司 | 一种玉洁新泡腾制剂及其制备方法 |
| CN107254370A (zh) * | 2017-07-31 | 2017-10-17 | 王瑜琳 | 一种节能洗衣粉 |
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Assignee: GUANGDONG BIOMAX SI&F NEW MATERIAL Co.,Ltd. Assignor: GUANGZHOU TAICHENG BIOCHEMICAL TECHNOLOGY CO.,LTD. Contract fulfillment period: 2009.11.23 to 2015.11.22 Contract record no.: 2009440001900 Denomination of invention: Foamless phosphorus less disinfactant cleaning agent Granted publication date: 20071003 License type: Exclusive license Record date: 20091218 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.11.23 TO 2015.11.22; CHANGE OF CONTRACT Name of requester: GUANGDONG BIOMAX SI+F NEW MATERIALS CO., LTD. Effective date: 20091218 |
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Effective date of registration: 20170126 Address after: 511455 Guangzhou Province, Nansha District, Dagang Town, high sand village street, No. 23 Patentee after: GUANGZHOU TAISHENG BIOTECHNOLOGY Co.,Ltd. Address before: Three good village Panyu District Shawan Town Guangzhou city Guangdong province 511487 Lok Wai (Shawan Institute) Patentee before: GUANGZHOU TAICHENG BIOCHEMICAL TECHNOLOGY CO.,LTD. |
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Address after: 511455 No. 23 Xincun Street, Gaosha Village, Dagang Town, Nansha District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Taisheng Biotechnology Co.,Ltd. Address before: 23 Xincun Street, Gaosha Village, Dagang Town, Nansha District, Guangzhou Patentee before: GUANGZHOU TAISHENG BIOTECHNOLOGY Co.,Ltd. |
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Granted publication date: 20071003 Termination date: 20211229 |
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| CF01 | Termination of patent right due to non-payment of annual fee |