CN1607026A - Exhaust gas treating tower - Google Patents
Exhaust gas treating tower Download PDFInfo
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- CN1607026A CN1607026A CNA200410075225XA CN200410075225A CN1607026A CN 1607026 A CN1607026 A CN 1607026A CN A200410075225X A CNA200410075225X A CN A200410075225XA CN 200410075225 A CN200410075225 A CN 200410075225A CN 1607026 A CN1607026 A CN 1607026A
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- exhaust gas
- liquid
- drop
- waste gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
- B01D47/063—Spray cleaning with two or more jets impinging against each other
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- Treating Waste Gases (AREA)
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Abstract
Provided is an exhaust gas treating tower in which exhaust gas flow velocity is increased more than a prior art case so that exhaust gas treating efficiency can be enhanced or the exhaust gas treating tower can be made compact if equivalent performance is to be maintained. Also, an exhaust gas treating tower ensuring a liquid recovery is provided. In an exhaust gas treating tower 10A, liquid columns C are generated and also a liquid drop generating member 20 is provided to thereby generate liquid drops M therearound to be floated. Also, liquid is spouted from spray nozzles to thereby generate liquid films F in area different from the liquid columns C. In an exhaust gas treating tower 110, a liquid drop eliminator 120 is provided upstream of a mist eliminator 118. Interval P1 of collecting plates 121 of the liquid drop eliminator 120 is made larger than interval P2 of collecting plates 119 of the mist eliminator 118. Thereby, liquid drops having larger particle diameter contained in the exhaust gas are collected by the liquid drop eliminator 120.
Description
Technical field
The present invention relates to be provided to the exhaust gas treating tower of various device and boiler etc.
Background technology
For oxysulfide (SO contained in the waste gas of removing various device and boiler
2), adopted the exhaust gas treating tower of the gas-liquid way of contact.
As this exhaust gas treating tower, the treating column of so-called fluid column formula is arranged, with the absorption liquid of oxysulfide towards the top with column ejection (for example, with reference to patent documentation 1).As Figure 31 or shown in Figure 32, in the exhaust gas treating tower 1 of this fluid column formula, import waste gas from the introducing port 2 that is formed at lower side, and, oxysulfide contained in the waste gas is removed by contacting with the fluid column C that sprays with column during the outlet 3 above flowing at waste gas.
In the exhaust gas treating tower 1 of this fluid column formula, contact with fluid column C and from the waste gas that outlet 3 is discharged, contain fine liquid drops (generally it being called mist), in order to absorb this drop, on outlet 3, be provided with arrester 5 and mist arrester 6.
The patent documentation 1 real clear 59-53828 communique (Fig. 1) of opening
In this fluid column formula exhaust gas treating tower 1, for improving treatment of waste gas efficient (treating capacity of unit interval), device is maximized, or improve the flow velocity of waste gas.
But, do not wish that certainly the situation of equipment enlarging occurs.Therefore, if research is brought up to scheme more than the present situation with the flow velocity of waste gas, then as shown in Figure 9, in existing exhaust gas treating tower 1, bring up to the flow velocity more than a certain value, can occur can't eliminating oxysulfide by fluid column C, waste gas can directly penetrate, thereby is difficult to improve problem such as treatment effeciency.
In addition, for example in formation shown in Figure 32, can occur: can't fully reclaim drop in the waste gas by mist arrester 6, and drop and waste gas together pass mist arrester 6 and problems such as discharge.
Wherein, waste gas from below should carry out gas-liquid with fluid column C the process above flowing to and contact, but since this waste gas flow direction and near the drop that produces the fluid column C be subjected to towards above resistance.And, because the balance of the resistance (air drag) that causes with corresponding gravity of drop weight (diameter) and the waste gas that flows to the top, the drop of the weight (diameter) that certain certain degree is above is shifted to mist arrester 6 along with the flow direction of waste gas rises in the exhaust gas treating tower 1.
At this moment, if the flow velocity of waste gas is accelerated, corresponding therewith, the higher limit that rises to the diameter of the drop in the exhaust gas treating tower 1 also can become greatly, and the amount of the drop that rises as a whole also increases.So, in mist arrester 6, having increased the drop amount of necessary collection, the amount of liquid on surface that is adsorbed on the collecting board 6a of mist arrester 6 also increases to some extent.
On the other hand, because the flow velocity of waste gas improves gradually, dispersed out by waste gas once more so be adsorbed in the liquid on collecting board 6a surface, its result causes liquid to pass mist arrester 6.
In addition, during exhaust gas treating tower 1, set the flow velocity of the waste gas when running well in design, based on the flow velocity of the waste gas of this setting, obtain the diameter that together rises to the drop in the exhaust gas treating tower 1 with waste gas, mist arrester 6 is designed to positively to collect the drop of the diameter of asking.
But in exhaust gas treating tower 1, the flow direction of waste gas is also inhomogeneous, and because of a variety of causes forms the improper flow direction, flow velocity is also different along with the position.Flow velocity when therefore, in fact also having the normal operation that waste gas sets greater than when design with flow velocity and the zone flow through.Thus, in this zone greatly when designing the drop of the diameter more than the default together rise with waste gas and tend to mist arrester 6, its result, with above-mentioned the same, liquid can not be by 6 collections of mist arrester, and directly pass.
Summary of the invention
The present invention is based on this technical problem and propose, its purpose is, by the flow velocity of waste gas being brought up to more than the existing value raising treatment of waste gas efficient etc.
In addition, its purpose is, provides a kind of exhaust gas treating tower, positively withdrawal liquid.
For reaching this purpose, present inventors have carried out research diligently, obtain following result.
Be provided with the nozzle 4 of a plurality of ejection fluid column C in exhaust gas treating tower 1 inside, but from each nozzle 4 with the liquid of column ejection owing to fall from the summit to foreign side's diffusion, so between the fluid column C of a plurality of nozzles 4 ejections the density phenomenon of the liquid in the same plane of generation.The waste gas that flows to the top from the below ought to be removed oxysulfide by contacting with this fluid column C and the drop that floats thereof on every side, but by contacting with drop with this fluid column C, was subjected to and flowed to opposite resistance.Also infer: if the flow velocity of waste gas improves, the liquid existence that can appear between the nozzle 4,4 of mutual vicinity is that sparse part is subjected to the resistance deficiency from fluid column C and drop, its result, and waste gas can directly pass, and can't eliminate phenomenon such as oxysulfide.
So exhaust gas treating tower of the present invention that constitutes, possesses the tower main body, the waste gas that will import from the below is discharged upward, it is characterized in that, possess in the tower main body: first material is removed portion, by producing fluid column with the column ejection, contact with waste gas by fluid column and remove material contained in the waste gas from the below to the top; Remove portion with second material, be located at and be different from the zone that first material is removed the fluid column that produces in the portion, contact with waste gas, remove material contained in the waste gas by making fluid column.
In this exhaust gas treating tower, gas is imported from tower main body below, removes portion at first material, by contacting with fluid column, and removes material contained in the waste gas; And remove portion being located at second material that the first material portion of removing that is different from produces the zone of fluid column, by contacting, and remove material contained in the exhaust with liquid.
This exhaust gas treating tower is particularly suitable for, and in the side of tower main body, removes the introducing port type that the square on the lower side position of the portion and the second material portion of removing has formed waste gas than first material.
Wherein, the second material portion of removing should be located at and be different from first material and remove in the portion zone that produces fluid column, but specifically, in the tower main body, can be located at any place or two places up and down of top, the below of fluid column.
In addition, remove portion, can possess nozzle,, produce liquid film by with umbrella ejection liquid as second material.This nozzle preferably is equipped with a plurality of, and then preferred disposition becomes the liquid film that produces from nozzle seamlessly overlapping with the liquid film of adjacent other nozzles generations.And, can pressurize by pump from the liquid of nozzle ejection.
Yet the nozzle first material portion of removing that preferably is located at carries the pipe arrangement of the liquid be used to produce fluid column.Thus, can remove portion and second material is removed shared pipe arrangement in the portion at first material.Its result, can be with tower main body inner opening rate reduce to be suppressed to irreducible minimum.
Remove portion as second material, can possess the collision parts, make and remove the liquid that liquid film that the fluid column that produces the portion or nozzle produce falls from first material and produce drop by collision.Wherein, the collision parts should be able to make the liquid that falls from the liquid film of nozzle generation produce drop by collision, but just in this case, can possess nozzle and collide the parts both sides as the second material portion of removing.And, also can remove the liquid collision that the fluid column that produces the portion falls from first material and produce drop by only having, in this case, only possess the collision parts as the second material portion of removing.
In addition, the formation of collision parts also: have the wall that extends to tower main body above-below direction, make the drop that produces by the collision parts by means of and wall between frictional force remain near the wall.
Exhaust gas treating tower as above-mentioned is characterized in that, also can possess: the tower main body, and the waste gas that will import from the below is discharged upward; Fluid column generating unit in the tower main body is for removing material contained in this waste gas by contacting with waste gas, by liquid is produced fluid column with the column ejection upward from the below; And drop-liquid film generating unit, for removing material contained in this waste gas, produce drop and/or liquid film in the zone that is different from fluid column by contacting with waste gas.
In addition, exhaust gas treating tower of the present invention possesses the tower main body that the waste gas that imports from the below is discharged upward, it is characterized in that in the tower main body, possessing: the liquid supply unit, and feed fluid is removed material contained in the waste gas by contacting with waste gas; The first drop collection unit, be located at relative liquid supply unit waste gas flow to the downstream, collect with waste gas that liquid contacts in contained drop; And the second drop collection unit, be located at relative liquid supply unit waste gas flow to the downstream, and than first drop collection unit upstream side on the upper side, collect in the waste gas in the contained drop drop greater than the drop of collecting in the first drop collection unit.
This exhaust gas treating tower can be the formation of arbitrary form, but for example can preferably adopt so-called fluid column mode, promptly in the liquid supply unit by with liquid with column from below spray upward and produce fluid column, remove material contained in the waste gas by means of gas is contacted with fluid column.
Possess the second drop collection unit according to upstream side, collect drop greater than the collected drop of the first drop collection unit in the second drop collection unit of upstream side in the first drop collection unit.Thus, collect less than dripping the night of the collected drop of the second drop collection unit in the first drop collection unit in downstream.
As concrete formation, preferred: make the first drop collection unit possess many first collecting boaries, the flow direction of waste gas tilts relatively, arranges with prescribed distance; Make the second drop collection unit possess many second collecting boaries, the flow direction of waste gas tilts relatively, arranges with the prescribed distance greater than first collecting board.
Flow velocity when wherein, the spacing of second collecting board can be based on the common running of the waste gas in the tower main body and setting.For example, in the tower main body usually during running, the flow velocity of waste gas is made as under the situation of 5m/s, preferably the inclination angle with second collecting board is set as 28 °, and spacing is set as 100～150mm.In this case, can drip by the night that the second collecting board collection cut size is roughly more than the 3mm.And in this case, the spacing of first collecting board preferably is set to 40～60mm.
In addition, the spacing of second collecting board also can be based on the Peak Flow Rate of the waste gas in the tower main body and is set.Thus, also can be that the situation of improper grade is corresponding with the flow direction of waste gas in the tower main body.
According to the present invention, improve the contacting efficiency of gas-liquid and can improve treatment of waste gas efficient, by the flow velocity of waste gas being brought up to more than the existing value, can improve the performance of exhaust gas treating tower, can bring into play and be equal to performance and can carry out miniaturization to exhaust gas treating tower again.
In addition,,, can improve the flow velocity of waste gas, even or outside the imagination, have the very high situations such as zone of waste gas flow velocity, also withdrawal liquid positively by the drop arrester is set according to the present invention.
Description of drawings
Fig. 1 is the cutaway view of expression about the formation of the exhaust gas treating tower of first embodiment.
Fig. 2 is the perspective view of drop production part.
Fig. 3 is the cutaway view of the drop production process in the expression drop production part.
Fig. 4 is the cutaway view of expression about the variation of the exhaust gas treating tower of first embodiment.
Fig. 5 is the cutaway view of expression about the formation of the exhaust gas treating tower of second embodiment.
Fig. 6 is the cutaway view of expression about the variation of the exhaust gas treating tower of second embodiment.
Fig. 7 is the cutaway view of expression about the formation of the exhaust gas treating tower of the 3rd embodiment.
Fig. 8 is the cutaway view of expression about the variation of the exhaust gas treating tower of the 3rd embodiment.
Fig. 9 is expressed as the performance of estimating exhaust gas treating tower of the present invention and the result's of the test of carrying out figure, the figure of the relation between the sulfoxide concentration that expression gas flow rate and tower export.
Figure 10 is the figure of the relation of the specific discharge of express liquid and gas flow rate.
Figure 11 is the figure of the relation of the specific discharge of express liquid and desulfurization degree.
Figure 12 is the cutaway view of formation of the exhaust gas treating tower of expression the 4th embodiment.
Figure 13 is the figure that example is set of expression spray nozzle, (a) be front view, (b) be (a) to looking cutaway view.
Figure 14 is that another of expression spray nozzle is provided with the figure of example, (a) be front view, (b) be (a) to looking cutaway view.
Figure 15 is the another figure that example is set of expression spray nozzle, (a) be front view, (b) be (a) to looking cutaway view.
Figure 16 is expressed as the performance of exhaust gas treating tower in the comparison present embodiment and the exhaust gas treating tower in second embodiment and the result's of the test carried out figure, the relation between representation unit circular flow and the desulfurization degree.
Figure 17 is the figure that concerns between the expression gas flow rate and the pressure loss.
Figure 18 is near the example that is provided with the situation on inclined plane the introducing port of exhaust gas treating tower.
Figure 19 is the example that is provided with the situation of cowling panel in exhaust gas treating tower.
Figure 20 be expressed as evaluation when being provided with inclined plane and cowling panel performance and the result's of the test carried out figure (a) is the specific discharge of express liquid and the figure of the relation between the desulfurization degree, (b) be the figure that concerns between expression gas flow rate and the desulfurization degree.
Figure 21 is the cutaway view of the formation of expression exhaust gas treating tower.
Figure 22 is the figure of the formation of expression drop arrester, (a) is vertical view, (b) is longitudinal section.
Figure 23 is that express liquid adopts limewash and the figure of waste gas flow velocity when having changed the interval of collecting board and the relation of collecting critical liquid-drop diameter.
Figure 24 is the figure that is illustrated in the shape of collecting board used when obtaining the waste gas flow velocity and collecting the concerning of critical liquid-drop diameter.
Waste gas flow velocity when Figure 25 is express liquid when adopting water, the interval that changes collecting board and the figure of the relation of collecting critical liquid-drop diameter.
Figure 26 is illustrated under the situation that is set at the collecting board that is different from Figure 23 shape, and liquid adopts limewash and the figure of waste gas flow velocity when changing the interval of collection and the relation of collecting critical liquid-drop diameter.
Figure 27 is illustrated in liquid to adopt water and change the waste gas flow velocity of collecting board at interval time the and the figure of the relation of collecting critical liquid-drop diameter.
Figure 28 is the figure that concerns between liquid-drop diameter and the collection efficiency in expression mist arrester and the drop arrester.
Figure 29 is the figure of the experimental result in the formation shown in the expression present embodiment, and is expression inlet mist concentration and the figure that exports the mist concentration relationship.
Figure 30 is the figure of the expression pressure loss.
Figure 31 is the cutaway view that the existing exhaust gas treating tower of expression constitutes.
Figure 32 is the cutaway view of another formation of the existing exhaust gas treating tower of expression.
The specific embodiment
Below, the present invention is described in detail based on embodiment shown in the drawings.
(first embodiment)
Fig. 1 is the cutaway view of formation that is used for illustrating the exhaust gas treating tower 10A of present embodiment.
As shown in Figure 1, exhaust gas treating tower 10A, tower main body 11 for example for analysing and observe the tubular for rectangle, stopped up by base plate 12, formed peristome 13 on top by its bottom.And, at the lower side opening of tower main body 11 and formed introducing port 14, be used for waste gas is imported in the tower main body 11.
In tower main body 11, be provided with the pipe arrangement 16 that possesses a plurality of nozzles 15.Suct by pump 17 and to hold the liquid that stays in tower main body 11 bottoms, supplying tubing 16.Nozzle 15 is the parts that liquid is sprayed with column upward, and these a few nozzles 15 are configured with the interval of suitable setting, and feasible nozzle 15 from mutual vicinity makes progress and produces the gap between the fluid column C that sprays.
In the present embodiment, the ratio nozzle 15 of the tower main body 11 of exhaust gas treating tower 10A on the lower side the side and than introducing port 14 on the upper side the part of side be provided with drop production part 20.
As shown in Figures 2 and 3, this drop production part 20 is for being known as the parts of grid etc., have mutually orthogonal vertical piece (the collision parts) 21 and lateral piece (collision parts) 22 shapes that make up that dispose with predetermined distance respectively mutually orthogonally, formed clathrate as a whole.Vertical piece 21, lateral piece 22 have formed the plane that its upper surface 21a, 22a have Rack respectively.And the height that vertical piece 21, lateral piece 22 have regulation thus, has formed space S in the part that is surrounded by mutually contiguous vertical piece 21,21 and lateral piece 22,22.
Have among the exhaust gas treating tower 10A of above-mentioned formation, the liquid that upwards sprays from nozzle 15 forms fluid column C, drops to the below.And upper surface 21a, the 22a collision of the liquid of whereabouts and drop production part 20 forms fine liquid drops M.
Like this, if the drop M of generation should directly float usually and fall, but form on drop production part 20 in a plurality of space S, the frictional force by means of the wall of vertical piece 21, lateral piece 22 keeps than the state that flies at for more time usually in the space S.And this phenomenon and flow rate of fluid can be understood easily because of approaching more identical along near the phenomenon just more little wall that flows to the frictional force of wall.
Then, droplets fall is held and is stayed the bottom in exhaust gas treating tower 10A.
On the other hand, roughly in exhaust gas treating tower 10A, change direction, flow to the top along the waste gas that horizontal direction imports from introducing port 14.And, remove portion as first material, by contacting with the fluid column C that sprays upward from nozzle 15, the oxysulfide in the waste gas is absorbed by liquid, and discharges from the peristome 13 on top.Also, also produce, and remain in space S and showy fine liquid drops M contact, absorb the oxysulfide in the waste gas by colliding with upper surface 21a, 22a in the part of removing the drop production part 20 of portion as second material.
Moreover as shown in Figure 1, the top in exhaust gas treating tower 10A is provided with arrester 18, removes-reclaim the fine liquid drops M that remains in the waste gas by this arrester 18.
As mentioned above, in exhaust gas treating tower 10A, by being equipped with drop production part 20, can not only be to fluid column C, can also near drop production part 20, produce drop and float.Thus, can in exhaust gas treating tower 10A, not exist region of fluid to have drop M in the past.Its result can improve the performance of removing of oxysulfide.
In addition, waste gas should be subjected to resistance when contacting with drop M with fluid column C, but only has the situation of fluid column C to compare with existing, has increased again as a whole and the corresponding resistance of drop M amount, thereby can improve the contacting efficiency of gas-liquid.Its result even the flow velocity of waste gas is brought up to more than the existing value, also can improve the critical flow velocity that waste gas can directly pass.Therefore, can be increased sharply the desulfurization performance of exhaust gas treating tower 10A.And,, can what improve and made exhaust gas treating tower 10A by exhaust gas flow correspondingly than existing more miniaturization as long as can bring into play the performance that is equal to.
Moreover, in the above-described embodiment, drop production part 20 is disposed at the below of nozzle 15, but as shown in Figure 4, also can be disposed at from the top of the fluid column C of nozzle 15 generations.And, certainly, also drop production part 20 can be located at nozzle 15 on-two places down.
When above fluid column C, having disposed drop production part 20, by producing and because of waste gas flows to the space S that the drop M that flows through upward remains on drop production part 20, the oxysulfide that can bring into play in the waste gas is removed effect, flowed to waste gas and pay the resistance effect from fluid column C.
(second embodiment)
Then, be illustrated in the example of the situation of having added spray nozzle (nozzle) 30 on the exhaust gas treating tower 10B.And, for the basic comprising of exhaust gas treating tower 10B,,, omit its explanation so be marked with same numeral because of identical with above-mentioned first embodiment.
As shown in Figure 5, the ratio nozzle 15 of the tower main body 11 of exhaust gas treating tower 10B on the lower side the side and than introducing port 14 on the upper side the part of side be provided with the pipe arrangement 31 that possesses a plurality of spray nozzles 30.
On this pipe arrangement 31, connected booster (pump) 33, the liquid that drinks up from the bottom of tower main body 11 by pump 17 has been boosted.And, can also form following formation: pump 17 and booster 33 are not equipped to two-stage, and directly liquid are drunk up, but in this case, preferably liquid is boosted to the pressure that is higher than pump 17 with booster 33 from the bottom of tower main body 11 by booster 33.And, booster 33 can also be set, and only adopt the formation of pump 17.
Liquid from each spray nozzle 30 is boosted by booster 33 with umbrella (coniform) ejection forms the liquid film F that spreads all over full Zhou Lianxu.At this moment, a plurality of spray nozzles 30 are configured to: overlapping each other from the spray nozzle 30 of mutual vicinity with the liquid film F of umbrella ejection, so that in tower main body 11, do not produce the gap.
Adopt this exhaust gas treating tower 10B, in exhaust gas treating tower 10B, change direction with the gas that general horizontal direction imports, flow to the top from introducing port 14.And by contacting with the fluid column C that upwards sprays from the nozzle 15 of removing portion as first material, the oxysulfide in the waste gas is absorbed by liquid, discharges from the peristome 13 on top.And then, by with contact from the spray nozzle 30 of removing portion as second material fluid column F with the umbrella ejection, the oxysulfide in the waste gas is absorbed.
As mentioned above, in exhaust gas treating tower 10B, do not exist zones liquid, different with fluid column C to form liquid film F by being equipped with spray nozzle 30, can making in the past.Its result can improve the performance of removing of oxysulfide.
At this moment, by spray nozzle 30 is configured to: overlapping each other with the liquid film F of umbrella ejection from the spray nozzle 30 of mutual vicinity, thereby in tower main body 11, do not produce the gap, also there is liquid in the part that can make liquid annotate the sparse existence of liquid among the C, thus, but the oxysulfide in the homogenization exhaust gas treating tower 10B remove performance, also can obtain the rectification effect of gas.
In addition, waste gas should be subjected to resistance when contacting with liquid film F with fluid column C, but only has the situation of fluid column C to compare with existing, can improve the contacting efficiency of gas-liquid by the state that liquid film F exists accordingly, increases overall resistance.Its result even the flow velocity of waste gas is increased to more than the existing value, also can improve the critical flow velocity that waste gas directly penetrates.Therefore, can be increased sharply the desulfurization performance of exhaust gas treating tower 10B.And, be equal to performance as long as can bring into play, can make exhaust gas treating tower correspondingly than existing more miniaturization by the degree that exhaust gas flow improves.
Yet, except fluid column C, eject the liquid that boosted pump 33 boosts by spray nozzle 30.Also can consider following formation: do not adopt fluid column C, be equipped with multi-stage spray nozzle 30, only remove oxysulfide, but in this case, the whole liquid that spray must be boosted by booster 33 with multistage liquid film F.To this, as mentioned above, except fluid column C,, the liquid that supplies to spray nozzle 30 is boosted at 33 need of booster by from spray nozzle 30 ejection liquid film F.
Moreover, in the above-described embodiment, spray nozzle 30 has been configured to the below of nozzle 15, but as shown in Figure 6, can also be configured in from the top of the fluid column C of nozzle 15 generations.And, certainly, also spray nozzle 30 can be located at the top of nozzle 15, two places of below.
(the 3rd embodiment)
Then, be illustrated among the exhaust gas treating tower 10C example of the situation that drop production part 20 and spray nozzle 30 both sides combination are equipped with.And, then identical for the basic comprising of exhaust gas treating tower 10C with above-mentioned the one the second embodiments, therefore be marked with same numeral, omit its explanation.
As shown in Figure 7, the ratio nozzle 15 of the tower main body 11 of exhaust gas treating tower 10C on the lower side the side and than introducing port 14 on the upper side the part of side be provided with the pipe arrangement 31 that has possessed a plurality of spray nozzles 30.And then, below the spray nozzle 30 of exhaust gas treating tower 10C and than introducing port 14 on the upper side the part of side be provided with drop production part 20.
In this formation, the liquid that upwards sprays from nozzle 15 forms fluid column C, following track lowering below.So upper surface 21a, the 22a collision of the liquid of whereabouts and drop production part 20 becomes fine liquid drops M.
Have, the liquid that will boost through booster 33 from each spray nozzle 30 forms liquid film F with umbrella and coniform ejection again.And then the liquid that has formed liquid film F falls, and forms fine liquid drops M with top 21a, the 22a collision of the drop production part 20 of below.
So keeping showy state in a plurality of space S that the drop M that produces forms on drop production part 20.
And then, drop M falls in exhaust gas treating tower 10C, holds and stays the bottom.
In this exhaust gas treating tower 10C, in treating column 10C, change direction with the waste gas that general horizontal direction imports from introducing port 14, flow to the top.And, by with the part of removing the drop production part 20 of portion at second material remain in space S and showy fine liquid drops M, from the spray nozzle 30 of removing portion as second material equally with the liquid film F of umbrella ejection and also from the nozzle 15 of removing portion as first material upwards the fluid column C of ejection contact, oxysulfide in the waste gas is absorbed by liquid, discharges from the peristome 13 on top.
As mentioned above, owing to possess drop production part 20 and spray nozzle 30, can in exhaust gas treating tower 10C, not exist region of fluid to have drop M and liquid film F in the past.Its result can improve the performance of removing of oxysulfide.
In addition, when waste gas contacts with fluid column C, liquid film F and drop M, should be subjected to resistance, but only have the situation of fluid column C to compare, can correspondingly improve the contacting efficiency of gas-liquid, increase overall resistance by the degree of liquid film F and drop M existence with existing.Its result even the flow velocity of waste gas is brought up to more than the existing value, also can improve the critical flow velocity that waste gas directly penetrates.Therefore, can be increased sharply the desulfurization performance of exhaust gas treating tower 10C.And, be equal to performance as long as can bring into play, can how much make exhaust gas treating tower 10C correspondingly than existing more miniaturization by what exhaust gas flow improved.
Yet, compare with second embodiment that only possesses spray nozzle 30 with first embodiment that only possesses drop production part 20, in the formation that possesses both present embodiments of drop production part 20 and spray nozzle 30, liquid from the liquid film F of spray nozzle 30 produces drop M by upper surface 21a, the 22a collision with drop production part 20, so the generation of drop M will be more than the amount of simple combination.Therefore, the above-mentioned more remarkable effect of the exhaust gas treating tower 10C of present embodiment.
Moreover, in the above-described embodiment, drop production part 20 and spray nozzle 30 are configured in the below of nozzle 15, but as shown in Figure 8, also configurable above the fluid column C that produces from nozzle.And, certainly, can drop production part 20 and spray nozzle 30 be configured to the below of nozzle 15 yet, and only be located at the top of fluid column C.
Wherein, carried out test that the performance of exhaust gas treating tower 10A, the 10B shown in above-mentioned first～the 3rd embodiment, 10C is estimated, its result is expressed as follows.
Except the exhaust gas treating tower 10C of the exhaust gas treating tower 10B of the exhaust gas treating tower 10A of first embodiment shown in Figure 1, second embodiment shown in Figure 5 and the 3rd embodiment shown in Figure 7, in order to compare, in existing exhaust gas treating tower 1 shown in Figure 31, establish the SO of tower inlet (introducing port 14) respectively
2Concentration is 2700ppmD, establish be used for desulfurization liquid with NH
3Concentration be 270mmol/l, the concentration of establishing calcium carbonate is 115mmol/l, and studied the SO in the outlet (peristome 13) of gas flow rate and exhaust gas treating tower 10
2The relation of concentration.At this moment, at existing exhaust gas treating tower 1 with only possess among the exhaust gas treating tower 10A of first embodiment of drop production part 20, the circular flow of establishing liquid is 304m
3/ (m
2* h); The exhaust gas treating tower 10B of the 2nd embodiment that only is equipped with spray nozzle 30 and be equipped with drop production part 20 and the exhaust gas treating tower 10C of both the 3rd embodiments of spray nozzle 30 in, the liquid circulation flow amount that is used to produce fluid column C is made as 274m
3/ (m
2* h), the flow of sending into the liquid of spray nozzle 30 is made as 59m
3/ (m
2* h).
Its result as shown in Figure 9, compares with existing exhaust gas treating tower 1, and exhaust gas treating tower 10A, 10B, 10C are at the SO in exit
2The flow velocity (this is called critical flow velocity) in the moment that concentration raises rises significantly.Particularly compare, in the exhaust gas treating tower 10C that possesses both the 3rd embodiments of drop production part 20 and spray nozzle 30, improved critical flow velocity with the exhaust gas treating tower 10A of first embodiment that only possesses drop production part 20 and the exhaust gas treating tower 10B of second embodiment that only possesses spray nozzle 30.
In addition, studied the relation of falling liquid measure (below, be called specific discharge) and gas flow rate (critical flow velocity) of (being equivalent to) fluid column C unit cross-sectional area.
Its result, learn: as shown in figure 10, as long as the specific discharge of liquid is the same terms, compare with existing exhaust gas treating tower 1, exhaust gas treating tower 10A, 10B, 10C have just increased substantially critical flow velocity.
And then, studied the specific discharge of fluid column C and the relation of desulfurization degree.
Its result, learn: as shown in figure 11, as long as the specific discharge of liquid is the same terms, compare with existing exhaust gas treating tower 1, exhaust gas treating tower 10A, 10B, 10C have just increased substantially desulfurization degree, under same flow, the absorptive capacity coefficient has improved 10% (situation of exhaust gas treating tower 10B)～30% (situation of exhaust gas treating tower 10A, 10C).Thus, compare with existing exhaust gas treating tower 1, desulfurization performance has improved 1.1～1.3 times.
(the 4th embodiment)
Then, illustrate the same with aforementioned second embodiment, the example of the situation of additional spray nozzle (nozzle) 30 on exhaust gas treating tower 10D.And, because of the basic comprising of exhaust gas treating tower 10D is identical with above-mentioned first embodiment, therefore be marked with same numeral, omit its explanation.
As shown in figure 12, the ratio nozzle 11 of the tower main body 11 of exhaust gas treating tower 10D on the lower side the side and than introducing port 14 on the upper side the part of side be provided with a plurality of spray nozzles 30.
Wherein, be with the difference of the formation of the exhaust gas treating tower 10B shown in aforementioned second embodiment: in exhaust gas treating tower 10B, a plurality of spray nozzles 30 are separated being located at individually on the pipe arrangement 31 with the pipe arrangement 16 that is provided with nozzle 15, but among the exhaust gas treating tower 10D of present embodiment a plurality of spray nozzles 30 are located on the pipe arrangement 16 that is provided with nozzle 15.
At Figure 13～Figure 15 a plurality of detailed examples that spray nozzle 30 are installed to the structure of pipe arrangement 16 are shown.
Among the exhaust gas treating tower 10D-1 shown in Figure 13, be provided with the flange components 40 that is used to install each nozzle 15, so that outstanding upward at pipe arrangement 16.And, on this pipe arrangement 16, be provided with to the outstanding flange components 41 of general horizontal direction, on this flange components 41, spray nozzle 30 has been installed, liquid is sprayed downwards with umbrella and form liquid film F.Wherein, flange components 41 can suitably be configured to: for example to 2～3 nozzles 15, dispose 1.
Establish spray nozzle 30 and when realizing exhaust gas treating tower 10D-1, flange components 41 is set on pipe arrangement 16 when on the exhaust gas treating tower of having established, chasing after, spray nozzle 30 is installed on this flange components 41.
In exhaust gas treating tower 10D-2 shown in Figure 14,, also be provided with outstanding equally upward flange components 42 being arranged to be provided with the flange components 40 that is used to install each nozzle 15 on the outstanding upward pipe arrangement 16.And, installed at this flange components 42 and to have prolonged pipe 43, manage 43 leading section in this prolongations and be provided with spray nozzle 30.Prolong pipe 43 liquid is sprayed downwards from spray nozzle 30, and make the liquid that is sprayed not disturb pipe arrangement 16, carried out bending process for spray nozzle 30 keeps posture-position.
Wherein, flange components 41 configurable pars intermedias at 21 group contiguous mutually nozzle 15 are so that for example be equipped with 1 to 2 nozzles 15.
Establish spray nozzle 30 and when realizing exhaust gas treating tower 10D-2, flange components 42 is set on pipe arrangement 16 when on the exhaust gas treating tower of having established, chasing after, on this flange components 42, install and prolong pipe 43 and spray nozzle 30.
In exhaust gas treating tower 10D-3 shown in Figure 15, be located on the pipe arrangement 16, for installing on the outstanding upward flange components 40 that is provided with of each nozzle 15, be provided with spray nozzle 30 by fairlead 45.
Wherein, this fairlead 45 is configured to: for example per 2 nozzles are placed 1.
Establish spray nozzle 30 and when realizing exhaust gas treating tower 10D-3 when on the exhaust gas treating tower of having established, chasing after, after the nozzle of having established 15 is removed from flange components 40, installation fairlead 45, assembling nozzle 15 again on this fairlead 45.And, spray nozzle 30 has been installed at the leading section of fairlead 45.
In formation as Figure 13～shown in Figure 15, through the liquid of pump 17 pressurizations by pipe arrangement 16 from nozzle 15 and spray nozzle 30 ejections, form fluid column C and liquid film F.Thus, identical with the exhaust gas treating tower 10B shown in above-mentioned second embodiment, owing to be equipped with spray nozzle 30, that can improve oxysulfide removes performance and desulfurization performance.
And then, in exhaust gas treating tower 10A, the 10B shown in above-mentioned first～Third Way, 10C, be provided with drop production part 20 and be used to install the pipe arrangement 31 of spray nozzle 30, therefore correspondingly reduce the aperture opening ratio of the gas flow path among exhaust gas treating tower 10A, 10B, the 10C therewith, strengthened the pressure loss of gas.
To this, in the gas exhaust gas treating tower 10D of present embodiment (10D-1,10D-2,10D-3), on the pipe arrangement 16 that is provided with the nozzle 15 that produces fluid column C, spray nozzle 30 can be set, therefore can control the minimizing aperture opening ratio, reduce the pressure loss.
Wherein, the exhaust gas treating tower 10B of exhaust gas treating tower 10D-1, the 10D-2 of present embodiment, 10D-3 and second embodiment shown in Figure 5 is compared, therefore its result is shown.
In exhaust gas treating tower 10B, exhaust gas treating tower 10D-1,10D-2,10D-3, establishing in the tower temperature respectively and be 30 ℃, gas flow rate is the SO of 2.5～4.5m/s, tower inlet (introducing port 14)
2The liquid that concentration is 500ppmD, be used for desulfurization then is 160mmol/l with the concentration of calcium carbonate, be that the circular flow of 1～5m, liquid is 150～600m from the spray height of the fluid column C of nozzle 15 ejections
3/ (m
2* h).
Unit circular flow and the relation of desulfurization degree, the relation of the relative gas flow rate of the pressure loss to this moment are studied.
Figure 16 and Figure 17 show its result.
As shown in figure 16, learn: in the exhaust gas treating tower 10B of the tower exhaust gas treating tower 10D-1 of present embodiment, 10D-2,10D-3 and second embodiment shown in Figure 5, can obtain desulfurization performance about equally.And, as shown in figure 17, learn: in the exhaust gas treating tower 10B of exhaust gas treating tower 10D-1, the 10D-2 of present embodiment, 10D-3 and second embodiment shown in Figure 5, exhaust gas treating tower 10D-1, the 10D-2 of present embodiment, 10D-3 can reduce the pressure loss significantly.That is, compare, can keep in exhaust gas treating tower 10D-1, the 10D-2 of present embodiment, 10D-3 that desulfurization degree is constant to reduce the pressure loss again significantly with the exhaust gas treating tower 10B of second embodiment.
Yet, do not have the directly part of contact at liquid, because contained SO in the liquid
2Composition and adhere to incrustation scale easily.For example, in exhaust gas treating tower 10A, the 10B shown in above-mentioned first～Third Way, 10C, owing to be provided with drop production part 20 and the pipe arrangement 31 that is used to install spray nozzle 30, so it is very big that the surface area of the part that liquid does not directly contact is compared with exhaust gas treating tower 10D (10D-1,10D-2,10D-3), adheres to incrustation scale easily.If the incrustation scale that adheres to falls, might damage the nozzle that is positioned at its below and pipe arrangement etc.In exhaust gas treating tower 10D-1, the 10D-2 of present embodiment, 10D-3, by spray nozzle 30 is located on the pipe arrangement 16, the position that might adhere to incrustation scale can be suppressed to Min., also can suppress to produce damage.
In addition, establish spray nozzle 30 and when realizing exhaust gas treating tower 10D-1,10D-2,10D-3 when on the exhaust gas treating tower of having established, chasing after, preferably on the pipe arrangement of having established 16 mounting flange parts 41, prolong pipe 43, fairlead 45, and on these parts assembling nozzle 15.And, spray nozzle 30 is installed at the leading section of fairlead 45.Compare with exhaust gas treating tower 10A, 10B, 10C shown in above-mentioned first～Third Way, reduced components number, and it is provided with and also is easy to and has realized cost degradation.Drop production part 20 and pipe arrangement 31 must be set in exhaust gas treating tower 10A, the 10B shown in above-mentioned first～Third Way, 10C, and need carry out large-scale operation.
Particularly, when being exhaust gas treating tower 10D-3 shown in Figure 15, install in being used to of having established and on the flange components 40 of nozzle 15 fairlead 45 only is installed and is got final product, with for mounting flange parts 41 with prolong pipe 43 and need exhaust gas treating tower 10D-1,10D-2, the 10D-3 of operations such as welding to compare, also carry out operation easily, can obtain above-mentioned effect with low cost.
In exhaust gas treating tower 10D-2 shown in Figure 14, install on also can be similarly the flange components 40 of nozzle 15 being installed and prolong pipe 43 and spray nozzle 30 in being used to of having established, but in this case, because of the number that reduces the nozzle 15 that forms fluid column C not quite is fit to.
Moreover, in the above-described 4th embodiment, enumerated by with the relation that the position is set of nozzle 15 determine exhaust gas treating tower 10D-1,10D-2,10D-3 flange components 41, prolong the example that position (number) etc. is set of pipe 43, but be not limited to illustrative mode.Particularly, the exhaust gas treating tower of having established is not being transformed, and newly established under the situation of exhaust gas treating tower 10D-1,10D-2, preferably flange components 41 and prolongation pipe 43 are being located at the optimized position of the position-number that can make spray nozzle 30.
Yet, exhaust gas treating tower 10A, the 10B that illustrates in the respective embodiments described above, 10C, 10D (below, when need not to distinguish especially, abbreviate exhaust gas treating tower 10 as) going up combination formation as follows can be very effective.
As shown in figure 18, in the part of the introducing port 14 of exhaust gas treating tower 10, between the inside upper surface 14a of the inner vertical walls face 10a of exhaust gas treating tower 10 and introducing port 14, formed the inclined plane 48 that is inclined to predetermined angular.According to this inclined plane 48, the sectional area of introducing port 14 enlarges gradually upward along with the inner vertical walls face 10a near exhaust gas treating tower 10.
By forming this inclined plane 48, change over upward part in the flow direction of the waste gas that imports from introducing port 14, the flow velocity of all sides in can improving can be alleviated the bias current in the tower main body 11 of exhaust gas treating tower 10 thus.
By this inclined plane 48 is combined in the respective embodiments described above, can makes the flow direction of waste gas even, thereby can make above-mentioned effect more remarkable.
Figure 19 is provided with many cowling panels 50 for the front portion of introducing port 14 in the tower main body 11 of exhaust gas treating tower 10, is the roughly direction of quadrature with the flow direction of the waste gas of sending into from introducing port 14.At this moment, many cowling panels 50 are configured to differing heights, so that be positioned at the top near introducing port 14 1 sides.And, be provided with air flap 51, prolong to oblique below from the inside upper surface 14a of introducing port 14 and the cross section of inner vertical walls face 10a.
Since this cowling panel 50 and air flap 51 the flow direction of the waste gas that imports from introducing port 14 be changed into above part, waste gas is directed to each cowling panel 50 by air flap 51, touches each cowling panel 50 and changes direction.When this cowling panel 50 not, the flow velocity of waste gas is fast more, and waste gas just directly enters the inner vertical walls face 10b in the front of introducing port 14, contacts with inner vertical walls face 10b and to change the composition of direction just many more.To this, changes direction by making waste gas flow to each cowling panel 50 of contact as mentioned above, can alleviate the interior bias current of tower main body 11 of exhaust gas treating tower 10.This cowling panel 50 is combined in the respective embodiments described above, also can makes the flow direction equilibrium of waste gas, thereby make above-mentioned effect more remarkable.
Wherein, for verification setting the effect of situation of above-mentioned inclined plane 48 and cowling panel 50, test, its result is expressed as follows.
Except the exhaust gas treating tower 10 that is provided with inclined plane shown in Figure 180 48, the exhaust gas treating tower 10 that is provided with cowling panel shown in Figure 19 50 are studied, for comparing, in existing exhaust gas treating tower 1 shown in Figure 31, under condition as hereinbefore, test, the relation (with reference to Figure 20 (b)) of relation (with reference to Figure 20 (a)), gas flow rate and the desulfurization degree of the specific discharge and the desulfurization degree of liquid is studied.
Its result, shown in Figure 20 (a) and (b), learn: as long as the specific discharge of liquid or gas flow are under the same conditions, compare with existing exhaust gas treating tower 1, the desulfurization degree that is provided with the exhaust gas treating tower 10 of inclined plane 48 and cowling panel 50 increases.
So,, can further improve the performance of exhaust gas treating tower 10A, 10B, 10C, 10D by inclined plane 48 and cowling panel 50 are set.
(the 5th embodiment)
Figure 21 is the figure that is used to illustrate that the exhaust gas treating tower 100 of present embodiment constitutes.
As shown in Figure 21, the tower main body 11 of exhaust gas treating tower 100 for example for analysing and observe the tubular of rectangle, sealed by base plate 112 by its bottom, and peristome 113 has been formed at top.And, at the lower side opening of tower main body 111 and formed the introducing port 114 that is used for waste gas imported in the tower main body 111.
In tower main body 111, be provided with the pipe arrangement 116 that possesses a plurality of nozzles 115.Hold to stay to be sucted by pump 117 and supply to pipe arrangement 116 in the liquid of the bottom of tower main body 111.Nozzle 115 sprays this liquid with column upward as the liquid supply unit, and in tower main body 111, form fluid column C, this a few nozzle 115 is configured with proper spacing, so that upwards do not producing the gap on the fluid column C of ejection from the nozzle 115 of mutual vicinity.
In this exhaust gas treating tower, the gas of showing the horizontal direction importing from introducing port 114 greatly changes direction in exhaust gas treating tower 100, upwards flow.So by contacting with the fluid column C that upwards sprays from nozzle 15, the oxysulfide in the waste gas is absorbed by liquid, discharges from the peristome 113 on top.
In the present embodiment, exhaust gas treating tower 100 possesses at the peristome 113 that becomes outlet port: mist arrester (first drop collection unit) 118 and drop arrester (the second drop collection unit) 120.
Mist arrester 118 just is provided on the exhaust gas treating tower 100 all the time, therefore for remove fine liquid drops contained in the waste gas by fluid column C (below, this suitably is called mist), have the collecting board (first collecting board) 119 at the predefined inclination angle flow direction of waste gas (relatively tilt) with predetermined distance being provided with.Wherein, as long as collecting board 119 has the inclined plane of the flow direction inclination predetermined angular of relative waste gas, can make zigzag fashion cross section, can also make the cross section of "＜" shape that only has a joggling part or not have other shapes such as plate that only tilt of joggling part with a plurality of joggling part 119a.
On the other hand, drop arrester 120 is located at the below of mist arrester 118, i.e. the upstream side of the waste gas flow direction.This drop arrester 120 has a plurality of collecting boaries (second collecting board) 121 equally with mist arrester 118, but this drop arrester 120 is used for the drop of collection cut size greater than the particle diameter of the mist that will be collected by mist arrester 118, so the interval greater than the collecting board 119 of mist arrester 118 is set at the interval of these collecting boaries 121 for.
As shown in figure 22, drop arrester 120 has been installed the collecting board 121 of regulation number with predetermined distance (spacing) P1 on the attaching parts 122,123 of the bar-shaped or tubulose that disposes up and down.Each collecting board 121 makes the part 121a, the 121b that are fixed in attaching parts 122,123 and axis direction (flow direction of the waste gas) almost parallel of tower main body 111, has formed the rake 121c of the axis direction inclination predetermined angular α of relative tower main body 111 between it.
Wherein, in the exhaust gas treating tower 100 of present embodiment, for example, collect the drop of the above particle diameter of 3mm by drop elimination portion 120, in mist arrester 118, for the drop (mist) of collecting the following particle diameter of this value, preferably the interval P1 of the collecting board 121 of drop arrester 120 is set at 100～150mm, the interval (spacing) of the collecting board 119 of mist arrester 118 is set at 40～60mm.
The interval P1 of the collecting board 121 of this drop arrester 120 can obtain (list of references: put quick U.S., " the bubble drop disperses engineering ", hardwood bookstore, October 30 nineteen eighty-two day) by mode as follows.
The collection principle of the drop in the drop arrester 120 (containing mist) is: by changed the direction of the waste gas that flows to a side by collecting board 121, make proportion be different from the motion of waste gas by inertia force greater than the drop of waste gas, stick on the collecting board 121.
More detailed saying, by flowing through the part that changes the flow direction of waste gas between the collecting board 121,121 with uniformly-spaced assortment, when the drop in the waste gas moved with the track with radius of curvature r, this drop was subjected to the resistance from the viscosity of centrifugal force (inertia force) and waste gas.In this state, the equation of motion of the radial direction of drop is approximately formula (1).
Wherein, m: the quality of drop, u: the grain direction speed of waste gas, υ: the radial direction translational speed of drop, μ: the viscosity of waste gas.
In formula (1), when with small drop during as object, because of ignoring the acceleration item, so the mist translational speed υ of radial direction becomes the form of formula (2).
In the formula, ρ
L: the density of drop.
Then, the time of establishing the angle [alpha] of waste gas deflection is t, and then the distance, delta S that moves along radial direction during this period of drop just becomes the form of formula (3).
Therefore, the collection efficiency η that collects owing to 121 collisions of drop and collecting board becomes the form of formula (4).
In the formula, S: the flow path width of the deflector of collecting board 121.
And, the 100% minimum liquid-drop diameter of collecting (below, this is called the critical liquid-drop diameter of collection) d
MinBecause of η=1, and become the form of formula 5.
The viscosity, mu of waste gas, the density p of drop
L, determine based on the waste gas of handling in the exhaust gas treating tower 100, used class of liquids.Therefore, the critical liquid-drop diameter d of collection that will collect in the operating condition of grain direction speed u, the exhaust gas treating tower 100 by decision waste gas, the drop arrester 120
Min, change among the flow path width S of deflector of the angle [alpha] of the flow direction of waste gas and collecting board 121 each, can determine all the other parameters.
Figure 23 is expression flow velocity that obtain based on above-mentioned theory, waste gas and the critical liquid-drop diameter d of collection
MinRelation.Figure 24 (a) is for to obtain this relation corresponding, and schematically shows drop arrester 120 shown in Figure 22.
Wherein, in Figure 24 (a), if change angle (being the angle of inclination of the collecting board 121) α of exhaust gas direction and be 28 °, the interval P1 of collecting board 121 and be 25,50,75,100,125,150,175, during 200mm, obtain waste gas flow velocity u respectively and be 2.0,3.0,4.0,5.0,6.0,7.0,8.0,9.0,10.0, the critical liquid-drop diameter dmin of collection during 11.0m/s.
Moreover, the temperature of waste gas is made as 30 ℃, the viscosity, mu of waste gas is made as 1.83 * 10
-5Adopt limewash in kg/m/s, the liquid, with the density p of its liquid (drop)
LBe made as 998kg/m
3
Have, Figure 25 is illustrated under the condition same as described above again, the flow velocity of the waste gas when liquid adopts water and the critical liquid-drop diameter d of collection
MinThe figure of relation.Here, density of liquid ρ
LBe 998kg/m
3
By also learning among these Figure 23 and Figure 25, (collect critical liquid-drop diameter d if set the particle diameter of the drop that will collect
Min) and the flow velocity u of the waste gas of exhaust gas treating tower 100, can select the interval P1 of best collecting board 121.
Certainly, when having changed the tilt angle alpha of collecting board 121, also can select the interval P1 of best collecting board 121 by obtaining same relation.
In addition, shown in Figure 24 (b), when collecting board 121 being made cross section, similarly also can obtain and collect critical liquid-drop diameter d for "＜" shape with a joggling part 121d
MinWith the relation of the flow velocity of the waste gas of exhaust gas treating tower 100,, can select the interval P1 of best collecting board 121 based on this.
Figure 26 is illustrated in the cross section in the collecting board 121 of "＜" shape, the relation when adopting water in the situation when liquid adopts limewash, Figure 27 express liquid.Wherein, the tilt angle alpha of collecting board 121 is 45 °, and promptly collecting board 121 is 90 ° of the front and back of joggling part 121d warpages.
When collecting board 121 being made the cross section, if, (collect critical liquid-drop diameter d if set the particle diameter of the drop that will collect based on Figure 26 and these relations shown in Figure 27 for "＜" shape
Min) and the flow velocity u of exhaust gas treating tower 100 waste gas, also can select the interval P1 of best collecting board 121.
In the present embodiment, adopt as shown in figure 22 drop arrester 120, promptly have a formation (shape) of Figure 23 and Figure 25 relation, the interval P1 of collecting board 121 is made the tilt angle alpha of 200mm, collecting board 121 and make 28 °.On the other hand, mist arrester 118 adopts the formation (shape) of the relation with Figure 26 and Figure 27, and the interval P2 of collecting board 119 is made 20mm, and the tilt angle alpha that will have the collecting board 119 of 3 joggling part 119a is done at 45.
And the temperature that is made as 5m/s, waste gas at the flow velocity u that establishes waste gas is that 30 ℃, the viscosity, mu of waste gas are 1.83 * 10
-5Kg/m/s, use under the situation of limewash water at liquid to drop arrester 120 and mist arrester 118, obtained the relation (for mist arrester 118, the drop that directly has been suitable for aforesaid drop arrester 120 is collected theoretical) of liquid-drop diameter and collection efficiency.
Figure 28 is the liquid-drop diameter asked of expression and the relation of collection efficiency.As shown in Figure 28, having adopted on the liquid under any situation of limewash or water, in mist arrester 118, also can make liquid-drop diameter be roughly 3.00 * 10
-5M (30 μ m) and reach collection efficiency η=1.0 only is provided with under the situation of mist arrester 118 in that drop arrester 120 is not set, and can all collect the drops of the above liquid-drop diameters of this value by mist arrester 118.
To this, drop arrester 120 has adopted under any situation of limewash or water at liquid, also makes liquid-drop diameter be roughly 1.40 * 10
-4～1.50 * 10
-4M (140～150 μ m) and reach collection efficiency η=1.0.
That is, thus, drop arrester 120 is set, collects liquid-drop diameter by drop arrester 120 and be roughly 1.40 * 10 by upstream side at mist arrester 118
-4～1.50 * 10
-4The drop that m (140～150 μ m) is above is collected liquid-drop diameter and is roughly 1.40 * 10 in the mist arrester 118 of level thereafter
-4～1.50 * 10
-4The fine liquid drops that m (140～150 μ m) is following.
As mentioned above, in exhaust gas treating tower 100,, can collect the drop of big particle diameter contained in the waste gas by drop arrester 120 by upstream side configuration drop arrester 120 at mist arrester 118.Drop arrester 120 has the collecting board 121 that is configured with the interval P1 greater than the interval P2 of the collecting board 119 of mist arrester 118.
Thus, in mist arrester 118, by the flow velocity of waste gas being brought up to more than the existing value, though greater than the drop of existing value under the situation that mist arrester 118 and waste gas together rise, also can collect it by the drop arrester 120 of its preceding-stage side.Its result, therefore the load that can alleviate mist arrester 118 needn't collect whole mists by mist arrester 118, can suppress liquid and directly pass mist arrester 118.
In addition, the relative flow velocity of the waste gas of supposing during the design of exhaust gas treating tower 100, when existing than local high flow velocity regional, in this zone, the drop and the waste gas of the big diameter during design more than the hypothesis together rise, also can collect it, in this case, also can suppress liquid and pass mist arrester 118 by drop arrester 120.
Thus, by drop arrester 120, positively withdrawal liquid are set.
Wherein, test for the effect of confirming the drop arrester 120 shown in the above-mentioned embodiment, its result is expressed as follows.
(device condition)
Embodiment: at upstream side drop arrester 120 is set, 2 grades of mist arresters 118 are set in the downstream.Drop arrester 120 is made shape shown in Figure 22, and the interval P1 of collecting board 121 is made 100mm, and the tilt angle alpha of collecting board 121 is made 28 °.On the other hand, mist arrester 118 is made shape as shown in figure 21, and the interval P2 of collecting board 119 is made 40mm, and the tilt angle alpha with collecting board 119 of 3 joggling part 119a is done at 45.
Comparative example: will be made as 2 grades with the identical shaped mist arrester 118 of embodiment.The interval P2 of collecting board 119 is made 40mm, and the tilt angle alpha with collecting board 119 of 3 joggling part 119a is done at 45.
(operating condition)
Exhaust gas flow: 17250m
3N/h
Oxidation air amount: 493m
3N/h
EGT: 10 ℃
Waste gas flow velocity: 5m/s
Liquid: limewash
(measuring condition)
At upstream side (entrance side) and downstream (outlet side) of drop arrester 120 and mist arrester 118 (situation of embodiment), mist arrester 118 (situation of comparative example), mist concentration and pressure have been measured respectively.
Figure 29 is the relation of expression entrance side mist concentration and outlet side mist concentration.
As shown in Figure 29, be not equipped with the comparative example of drop arrester 120 relatively, in the embodiment that is equipped with drop arrester 120, even entrance side mist concentration rises, outlet side mist concentration can remarkable rising as comparative example yet, can suppress liquid by drop arrester 120 and spill outside exhaust gas treating tower 100.
In addition, Figure 30 has compared the pressure loss of embodiment and comparative example, and is therefore irrelevant with entrance side mist concentration, by possessing the big drop arrester 120 of spacing (P1 at interval), can suppress the pressure loss.
Moreover, in the above-described embodiment, set the interval P1 of drop arrester 120 according to the flow velocity of waste gas, but this moment used waste gas the flow velocity of the waste gas of flow velocity u can be for the common running in the king-post body 111 time, and can also set based on the Peak Flow Rate of the waste gas in the tower main body 111.Thus, also can be that improper situation etc. is corresponding with the flow direction of waste gas in tower main body 111.
In addition, only otherwise break away from purport of the present invention, can suitably select the formation enumerated in the respective embodiments described above, or suitably change to other formations.
Claims (12)
1. an exhaust gas treating tower possesses the tower main body that the waste gas that imports from the below is discharged upward, it is characterized in that possessing:
First material is removed portion, in described tower main body, by producing fluid column from the below to the top with column ejection liquid, contacts with described waste gas by described fluid column and removes material contained in this waste gas; With
Second material is removed portion, is arranged on to be different from the zone that described first material is removed the described fluid column that produces in the portion, by contacting with described waste gas, removes material contained in this waste gas.
2. exhaust gas treating tower as claimed in claim 1 wherein, in the side of described tower main body, is removed the introducing port that the square on the lower side position of portion and the described second material portion of removing has formed described waste gas than described first material.
3. exhaust gas treating tower as claimed in claim 1 wherein, is removed portion as described second material, can possess a plurality of nozzles, by with umbrella ejection liquid, produces liquid film,
Described nozzle is configured to, and the liquid film that produces from this nozzle is seamlessly overlapping with the liquid film of other adjacent described nozzles generations.
4. exhaust gas treating tower as claimed in claim 3, wherein, described nozzle is set at described first material and removes in the portion pipe arrangement of carrying the liquid that is used to produce described fluid column.
5. exhaust gas treating tower as claimed in claim 3 wherein, also possesses pump, to pressurizeing from the liquid of described nozzle ejection.
6. exhaust gas treating tower as claimed in claim 3 wherein, is removed portion as described second material, can possess the collision parts, makes to remove the liquid that liquid film that the fluid column that produces the portion or described nozzle produce falls from described first material and produce drop by collision.
7. exhaust gas treating tower as claimed in claim 6, wherein, described collision parts have the wall that extends to described tower main body above-below direction, and the drop that produces by described collision parts is remained near this wall by means of the frictional force with described wall.
8. an exhaust gas treating tower possesses the tower main body that the waste gas that imports from the below is discharged upward, it is characterized in that possessing:
The liquid supply unit, in described tower main body, feed fluid is removed material contained in the described waste gas by contacting with described waste gas;
The first drop collection unit, be located at described relatively liquid supply unit described waste gas flow to the downstream, collect with described waste gas that described liquid contacts in contained drop; And
The second drop collection unit, be located at described relatively liquid supply unit described waste gas flow to the downstream, and than described first drop collection unit upstream side on the upper side, collect in the described waste gas in the contained drop drop greater than the drop of collecting in this first drop collection unit.
9. exhaust gas treating tower as claimed in claim 8, wherein, described liquid supply unit produces fluid column by liquid is sprayed from the below upward with column, and described waste gas is contacted with this fluid column.
10. exhaust gas treating tower as claimed in claim 8, wherein, the described first drop collection unit possesses many first collecting boaries, and the flow direction of described relatively waste gas tilts, arranges with prescribed distance,
The described second drop collection unit possesses many second collecting boaries, and the flow direction of described relatively waste gas tilts, and arranges with the prescribed distance greater than described first collecting board.
11. exhaust gas treating tower as claimed in claim 10, wherein, the spacing of described second collecting board flow velocity and setting during based on the common running of the described waste gas in the described tower main body.
12. exhaust gas treating tower as claimed in claim 10, wherein, the spacing of described second collecting board is based on the Peak Flow Rate of the described waste gas in the described tower main body and set.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP356562/2003 | 2003-10-16 | ||
| JP2003356562A JP4088578B2 (en) | 2003-07-11 | 2003-10-16 | Exhaust gas treatment tower |
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|---|---|
| CN1607026A true CN1607026A (en) | 2005-04-20 |
| CN1308057C CN1308057C (en) | 2007-04-04 |
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| CNB200410075225XA Expired - Fee Related CN1308057C (en) | 2003-10-16 | 2004-09-13 | Exhaust gas treating tower |
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| KR (1) | KR100583930B1 (en) |
| CN (1) | CN1308057C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102166469A (en) * | 2010-02-25 | 2011-08-31 | 阿尔斯托姆科技有限公司 | A wet scrubber and a method of cleaning a process gas |
| CN111375354A (en) * | 2018-12-31 | 2020-07-07 | 中国石油化工股份有限公司 | Gas-liquid mass transfer equipment |
| TWI802860B (en) * | 2020-03-31 | 2023-05-21 | 日商三菱動力股份有限公司 | Absorption tower of desulfurization unit |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102080570B1 (en) * | 2018-01-25 | 2020-02-24 | 두산중공업 주식회사 | Wet flue gas desulfurization apparatus |
| US11110391B2 (en) | 2018-01-25 | 2021-09-07 | Doosan Heavy Industries & Construction Co., Ltd. | System for simultaneously removing nitrogen oxides (NOx) and sulfur oxides (SOx) from exhaust gas |
| KR102130840B1 (en) * | 2019-12-23 | 2020-07-07 | 두산중공업 주식회사 | Wet flue gas desulfurization apparatus |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5840263A (en) * | 1996-05-30 | 1998-11-24 | Mitsubishi Heavy Industries, Ltd. | Flue gas treating process and system |
| EP1366796A3 (en) * | 1997-11-11 | 2004-01-07 | Mitsubishi Heavy Industries, Ltd. | A wet gas processing method and the apparatus using the same |
| CN2440164Y (en) * | 2000-07-21 | 2001-07-25 | 北京西山除尘器厂 | Shower foam desulfurizing duster |
| CN1337276A (en) * | 2000-08-05 | 2002-02-27 | 张延民 | Tempering mechanism for flue gas of electric dust remover of cement shaft kiln |
| CN1108180C (en) * | 2000-08-18 | 2003-05-14 | 清华大学 | Process and system for desulfurizing fume by two-stage liquid column spray |
-
2004
- 2004-07-30 KR KR1020040060457A patent/KR100583930B1/en active IP Right Grant
- 2004-09-13 CN CNB200410075225XA patent/CN1308057C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102166469A (en) * | 2010-02-25 | 2011-08-31 | 阿尔斯托姆科技有限公司 | A wet scrubber and a method of cleaning a process gas |
| CN102166469B (en) * | 2010-02-25 | 2015-07-08 | 阿尔斯托姆科技有限公司 | A wet scrubber and a method of cleaning a process gas |
| CN111375354A (en) * | 2018-12-31 | 2020-07-07 | 中国石油化工股份有限公司 | Gas-liquid mass transfer equipment |
| CN111375354B (en) * | 2018-12-31 | 2022-06-07 | 中国石油化工股份有限公司 | Gas-liquid mass transfer equipment |
| TWI802860B (en) * | 2020-03-31 | 2023-05-21 | 日商三菱動力股份有限公司 | Absorption tower of desulfurization unit |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050036696A (en) | 2005-04-20 |
| KR100583930B1 (en) | 2006-05-26 |
| CN1308057C (en) | 2007-04-04 |
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