CN1580144A - Environmenttally friendly water-based transparent putty for woodenware - Google Patents
Environmenttally friendly water-based transparent putty for woodenware Download PDFInfo
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- CN1580144A CN1580144A CN 03143963 CN03143963A CN1580144A CN 1580144 A CN1580144 A CN 1580144A CN 03143963 CN03143963 CN 03143963 CN 03143963 A CN03143963 A CN 03143963A CN 1580144 A CN1580144 A CN 1580144A
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- aqueous transparent
- transparent woodenware
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- woodenware putty
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Abstract
The invention relates to a kind of functional dope used to decorate architecture, in particular, it is a sort of transparent greasy molecule matey with water, which is used for wood fitment, wood clapboard and wood floor board. the combination is Muddy liquid of the benzene C milk(third-phenyl emulsion), filling 5%-20%, assistant menstruum 5%-20%, 0.1%-1.0% dispersant, 0.1%-1.0% wetting agent, 0.1%-1.0% removing forth menstruum, 1.0%-2.0% growing film assistant menstruum., 0.1%-1.0% hydroxyl-B cellulose aether, increasing thick menstruum, 0-2% antiseptic and 0.1%-1.0% P-H regulator adding 100% water winkled ion. The dope is advantageous to fill and level up the wood exterior, improve velvet and embonpoint.
Description
Technical field the present invention relates to functional architectural decoration coating material, particularly a kind of aqueous transparent putty that is used for woodenware surfaces such as wood furniture, wall dunnage and floor.
The enhancing of Background Art As people ' environmental consciousness, particularly the countries in the world environmental regulation is to the strictness of volatile organic compounds in the coating system (VOC) content restriction, and water-borne coatings becomes the important development direction of coating with the low pollution of himself, nontoxic or low toxicity, operational safety and advantage such as easy to use.And also there is the trend of hydrotropismsization development with putty as woodenware.But the research of relevant woodenware use putty report is also relatively more rare at present, and the aqueous transparent woodenware putty that is exclusively used in woodwork coating does not see that on market production marketing is arranged yet.
As the main coating process that wood furniture is decorated, wood lacquer not only can beautify living environment, can also play good provide protection to woodenware, and prolongs the work-ing life of wood furniture.And the used aqueous putty of present many woodenware factories mainly is to be base-material with polyvinyl acetate emulsion or 107 glue etc., is that stopping composition is allocated voluntarily and formed with talcum powder, chalk powder etc.; But there are some important disadvantages in the putty that adopts this simple method to make,, poor water resistance not high as transparency, dry slow, intensity is low and easily come off etc., thereby limited its application, particularly can't be used for application to the exigent wooden primary colors furniture of the transparency; And urethane (PU) wood lacquer of present usage quantity maximum, because of it contains in a large number to poisonous, the deleterious organic solvent of human body, in use easily environment is polluted, along with the appearance of country to building materials hazardous and noxious substances limit standard, the consumption of this polyurethane carpentry paint also progressively is restricted.
2002.04, " modern coating and application ", yellow plum is beautiful, it is base-material with the water-compatible amino resin that Ceng Xianwen has introduced a kind of in " development of aqueous transparent woodenware putty ", acid is catalytic curing agent, at the prescription that is equipped with the made aqueous transparent woodenware putty of corresponding weighting agent and auxiliary agent, find through overtesting, though it has overcome the wretched insufficiency of aqueous putty in the past to a certain extent, but wherein the dosage of weighting agent is bigger than normal, influenced transparency of products to a certain extent, with acid is solidifying agent, also may impact the product environmental-protecting performance, and be formed by two component allotments, it is also not too convenient to operate.
Summary of the invention on the basis of existing technology, the invention discloses a kind of prescription of environment-friendly type aqueous transparent woodenware putty, wherein do not contain poisonous, deleterious organic solvent, the transparency height, grinability is good, can be used for the woodenware surface local and fill and lead up and all fill and lead up, make object plane more smooth, and can save the finish paint consumption, can also improve the slickness of lacquer painting, increase the fullness ratio of object plane.
This environment-friendly type aqueous transparent woodenware putty of the present invention, it consists of: 10～80% benzene emulsion by weight percentage, 5～20% filler, 0～20% solubility promoter, 0.1～1.0 dispersion agent, 0.1～1.0% wetting agent, 0.1～1.0% defoamer, 1.0～2.0% film coalescence aid, 0.1～1.0% hydroxyethyl ether cellulose, 0.2～2.0% thickening material, 0～2.0% sanitas, 0.1～1.0% pH value conditioning agent and add 100% deionized water to.
Wherein, benzene emulsion of the present invention is vinylbenzene and acrylic polymer emulsion, and solids content is greater than 42%, second-order transition temperature is 46～47 ℃, and pH value is 6.0～7.0, and emulsion particle diameter is 0.1～0.5 μ m, polymericular weight is 60,000～100,000;
Dispersion agent is sodium polyacrylate, polyacrylic acid amine salt or polyacrylic acid and copolymer-maleic anhydride salt, and molecular weight is 5000～6000;
Wetting agent is a nonionogenic tenside, and its composition is polyether-modified polysiloxane or amber sulfonate, and the surface tension of the aqueous solution (0.5%) is 20 dynes per centimeter
2
Defoamer is mineral oil and surfactant mixture;
Thickening material is polyacrylic acid and polyurethane associative thickener;
Solubility promoter is both at least a kind of wherein of propylene glycol monomethyl ether or propylene glycol butyl ether;
The PH conditioning agent is both at least a kind of wherein of ammoniacal liquor or 2-amino-2-methyl-1-propanol;
Sanitas can be an isothiazolinone;
But film coalescence aid alcohol ester-12 or Filmer C40 (Shenzhen Haichuan Company).
This environment-friendly type aqueous transparent woodenware putty of the present invention, its preparation method is the defoamer that adds earlier solubility promoter, dispersion agent, wetting agent, filler and 0.4～0.5 times in an amount of water successively, high speed dispersion to fineness less than 20um, and then add film coalescence aid, emulsion, thickening material, sanitas and remaining defoamer etc. therein, regulate pH value between 8～9, adjust to agreeable viscosity again and get final product.
Compared with prior art, environment-friendly type aqueous transparent woodenware putty of the present invention, the part that can be used for the woodenware surface is filled and led up and is is all filled and led up, and makes that object plane is smooth, the slickness that can also improve lacquer painting, the fullness ratio that increases object plane; Compare with Oil putty, fast drying, coating is hard, bonding force is strong, and the transparency is good, and in particular for the wood furniture that transparency is had relatively high expectations, product wood look bright is naturally.
Embodiment is following illustrates beneficial effect of the present invention by specific embodiment.
Embodiment 1:
Utilize method for preparing 100g aqueous transparent woodenware putty:
Component title content (%) place of production
Dispersion agent
Hydropalat 100 0.5 COGNIS companies
Wetting agent
Hydropalat 3,204 0.2 COGNIS companies
Defoamer
Foamaster NXZ 0.4 COGNIS company
Talcum powder (1250 order) 20.0 Xuzhou powder factories
Filmer C40 1.5 Shenzhen Haichuan Companies
NeoCryl?XK61??????????50.0???????????????????AVECIA
Ammoniacal liquor (28%) 0.2 is commercially available
Thickening material
HAS 660 (10% aqueous solution) 15.0 Shenzhen Haichuan Companies
Thicklevelling 632 0.2 Shenzhen Haichuan Companies
Perenol 1097A 2.0 Shenzhen Haichuan Companies
Deionized water 10
Amount to 100
In 10 gram water, add 0.5g dispersion agent, 0.2g wetting agent, 0.2g defoamer and talcum powder (1250 order) 20.0g successively, high speed dispersion to fineness less than 20um, and then add film coalescence aid 1.5g, emulsion 50.0g, thickening material and remaining defoamer 0.2g etc. therein, regulating pH value is 8.5, through experiment, its every performance index are as follows:
| Sticking power | 1 grade |
| 60 ° of glossiness | ????6.1 |
| Contrast ratio | ????9.05％ |
| Stormer viscosity | ????＞120KU |
| Surface drying time/do solid work the time | ????15min/30min |
| Package stability (50 ℃) | There are not layering, precipitation and flocculation around storing |
Embodiment 2:
Component title content (%) place of production
Propylene glycol butyl ether 2.0
Dispersion agent
Dispersant 5,050 0.2 Shenzhen Haichuan Companies
Wetting agent
Hydropalat?875??????????0.1????????????COGNIS
Defoamer
Foamaster?NXZ???????????0.5????????????COGNIS
Process white (1250 order) 5.0 Guangzhou Holley
Talcum powder (1250 order) 5.0 Xuzhou powder factories
Filmer C40 2.0 Shenzhen Haichuan Companies
NeoCryl XK61 60.0 AVECIA companies
Ammoniacal liquor (28%) 0.3 is commercially available
Thickening material
HBR-250 (3% aqueous solution) 11.0 Aqualon companies
Thicklevelling 632 0.4 Shenzhen Haichuan Companies
Perenol 1097A 2.0 Shenzhen Haichuan Companies
Deionized water 11.5
Amount to 100
Method with above-mentioned embodiment 1 is similar, preparation 100g aqueous transparent woodenware putty, and through experiment, its every performance index are as follows:
| ????PVC | ????12.8％ |
| Sticking power | 1 grade |
| 60 ° of glossiness | ????24.0 |
| Contrast ratio | ????3.6％ |
| Stormer viscosity | ????100KU |
| Thixotropy index | ????5.0 |
| Surface drying time | ????15min |
| Do solid work the time | ????30min |
Claims (8)
1, a kind of environment-friendly type aqueous transparent woodenware putty is by by weight percentage 10～80% benzene emulsion, 5～20% filler, 0～20% solubility promoter, 0.1～1.0 dispersion agent, 0.1～1.0% wetting agent, 0.1～1.0% defoamer, 1.0～2.0% film coalescence aid, 0.1～1.0% hydroxyethyl ether cellulose, 0.2～2.0% thickening material, 0～2.0% sanitas, 0.1～1.0% pH value conditioning agent and add 100% deionized water to and form.
2, aqueous transparent woodenware putty according to claim 1 is characterized in that, described benzene emulsion is vinylbenzene and acrylic polymer emulsion, solids content is greater than 42%, and emulsion particle diameter is 0.1～0.5 μ m, and pH value is 6.0～7.0, polymericular weight is 60,000～100,000.
3, aqueous transparent woodenware putty according to claim 1 and 2 is characterized in that, described dispersion agent is sodium polyacrylate, polyacrylic acid amine salt or polyacrylic acid and copolymer-maleic anhydride salt, and molecular weight is 5000～6000.
4, aqueous transparent woodenware putty according to claim 3 is characterized in that, wetting agent can be nonionogenic tenside, and its composition is polyether-modified polysiloxane or amber sulfonate, and the surface tension of the aqueous solution (0.5%) is 20 dynes per centimeter
2
5, aqueous transparent woodenware putty according to claim 1 and 2 is characterized in that, described defoamer can be mineral oil and surfactant mixture.
6, aqueous transparent woodenware putty according to claim 1 and 2 is characterized in that, solubility promoter is both at least a kind of wherein of propylene glycol monomethyl ether or propylene glycol butyl ether.
7, aqueous transparent woodenware putty according to claim 1 and 2 is characterized in that, the PH conditioning agent is both at least a kind of wherein of ammoniacal liquor or 2-amino-2-methyl-1-propanol.
8, according to any aqueous transparent woodenware putty among the claim 1-7, it is characterized in that described filler can be selected talcum powder or process white.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN03143963A CN100577749C (en) | 2003-08-04 | 2003-08-04 | A kind of environment-friendly type aqueous transparent woodenware putty |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN03143963A CN100577749C (en) | 2003-08-04 | 2003-08-04 | A kind of environment-friendly type aqueous transparent woodenware putty |
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| Publication Number | Publication Date |
|---|---|
| CN1580144A true CN1580144A (en) | 2005-02-16 |
| CN100577749C CN100577749C (en) | 2010-01-06 |
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| CN03143963A Expired - Fee Related CN100577749C (en) | 2003-08-04 | 2003-08-04 | A kind of environment-friendly type aqueous transparent woodenware putty |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986652B (en) * | 2005-12-19 | 2010-11-17 | 深圳市海川实业股份有限公司 | Latex paint for outer wall |
| CN102134434A (en) * | 2011-03-08 | 2011-07-27 | 三棵树涂料股份有限公司 | High-performance water-based white sealing primer |
| CN102732075A (en) * | 2012-06-27 | 2012-10-17 | 深圳市联达顺实业有限公司 | Wood putty and preparation method thereof |
| WO2013067696A1 (en) * | 2011-11-09 | 2013-05-16 | Rhodia (China) Co., Ltd. | Additive mixture and composition and method for polishing glass substrates |
| CN103540182A (en) * | 2013-09-30 | 2014-01-29 | 安徽华印机电股份有限公司 | Novel waterproof putty powder with antibacterial function |
| CN104059462A (en) * | 2013-03-18 | 2014-09-24 | 福建省腾龙工业公司 | Waterborne coating for magnesite artworks and preparation method thereof |
| CN104098967A (en) * | 2013-04-10 | 2014-10-15 | 展辰涂料集团股份有限公司 | Water-based high-filling white paint |
| CN104530846A (en) * | 2014-12-25 | 2015-04-22 | 广州市诚美涂饰工程有限公司 | Water-borne environment-friendly crack lacquer and preparation method thereof |
| CN104789058A (en) * | 2015-05-08 | 2015-07-22 | 重庆发宇涂料有限公司 | Novel emulsion paint |
| CN105295495A (en) * | 2015-11-05 | 2016-02-03 | 山东拜尔建材有限公司 | Water-based environmentally friendly wood putty and preparation method |
| CN105331172A (en) * | 2014-08-06 | 2016-02-17 | 上海邑通道具设计制作有限公司 | Novel putty composition, and preparation method and application thereof |
| CN105623434A (en) * | 2016-04-09 | 2016-06-01 | 佛山市恒学科技服务有限公司 | High-performance water-based wood paint |
| CN106042086A (en) * | 2016-07-21 | 2016-10-26 | 和县薛氏木制品制造有限公司 | Plywood putty and preparation method thereof |
| CN106118553A (en) * | 2016-07-13 | 2016-11-16 | 阜南县猛发工艺品有限公司 | A kind of cracking reinforcing agent for wicker products |
| CN106147341A (en) * | 2016-08-01 | 2016-11-23 | 太仓顺如成建筑材料有限公司 | A kind of environment-friendly water-based Wood putty |
| CN106479243A (en) * | 2016-12-20 | 2017-03-08 | 钦州市星火计划办公室 | A kind of environmental protection Wood putty and preparation method thereof |
| CN107163663A (en) * | 2017-07-13 | 2017-09-15 | 合肥市龙阳节能新材料有限公司 | A kind of preparation method of the aqueous repairing paste putty of woodcare paint |
| CN107674590A (en) * | 2017-10-26 | 2018-02-09 | 北京宝力特建材有限公司 | A kind of water-based prime material for wood surface and preparation method thereof |
| CN107738328A (en) * | 2017-10-26 | 2018-02-27 | 北京宝力特建材有限公司 | A kind of water-based patching material for wood surface and preparation method thereof |
| CN108530971A (en) * | 2018-02-11 | 2018-09-14 | 河北晨阳工贸集团有限公司 | A kind of aqueous wooden ware spackling of high fillibility |
| CN116554722A (en) * | 2023-04-04 | 2023-08-08 | 中华制漆（深圳）有限公司 | Water-based wood inorganic transparent putty and preparation method thereof |
-
2003
- 2003-08-04 CN CN03143963A patent/CN100577749C/en not_active Expired - Fee Related
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986652B (en) * | 2005-12-19 | 2010-11-17 | 深圳市海川实业股份有限公司 | Latex paint for outer wall |
| CN102134434A (en) * | 2011-03-08 | 2011-07-27 | 三棵树涂料股份有限公司 | High-performance water-based white sealing primer |
| KR101925170B1 (en) | 2011-11-09 | 2018-12-04 | 로디아 오퍼레이션스 | Additive mixture and composition and method for polishing glass substrates |
| WO2013067696A1 (en) * | 2011-11-09 | 2013-05-16 | Rhodia (China) Co., Ltd. | Additive mixture and composition and method for polishing glass substrates |
| JP2015502993A (en) * | 2011-11-09 | 2015-01-29 | ローディア オペレーションズ | Additive mixture and composition and method for polishing glass substrates |
| CN104736651A (en) * | 2011-11-09 | 2015-06-24 | 罗地亚经营管理公司 | Additive mixture and composition and method for polishing glass substrates |
| EP2776523A4 (en) * | 2011-11-09 | 2015-07-08 | Rhodia Operations | Additive mixture and composition and method for polishing glass substrates |
| CN102732075B (en) * | 2012-06-27 | 2014-12-03 | 深圳市联达顺实业有限公司 | Wood putty and preparation method thereof |
| CN102732075A (en) * | 2012-06-27 | 2012-10-17 | 深圳市联达顺实业有限公司 | Wood putty and preparation method thereof |
| CN104059462A (en) * | 2013-03-18 | 2014-09-24 | 福建省腾龙工业公司 | Waterborne coating for magnesite artworks and preparation method thereof |
| CN104059462B (en) * | 2013-03-18 | 2016-06-29 | 福建省腾龙工业公司 | A kind of magnesite artware water paint and preparation method thereof |
| CN104098967A (en) * | 2013-04-10 | 2014-10-15 | 展辰涂料集团股份有限公司 | Water-based high-filling white paint |
| CN103540182A (en) * | 2013-09-30 | 2014-01-29 | 安徽华印机电股份有限公司 | Novel waterproof putty powder with antibacterial function |
| CN105331172A (en) * | 2014-08-06 | 2016-02-17 | 上海邑通道具设计制作有限公司 | Novel putty composition, and preparation method and application thereof |
| CN105331172B (en) * | 2014-08-06 | 2018-05-04 | 上海邑通道具股份有限公司 | A kind of new putty composition and its preparation method and application |
| CN104530846A (en) * | 2014-12-25 | 2015-04-22 | 广州市诚美涂饰工程有限公司 | Water-borne environment-friendly crack lacquer and preparation method thereof |
| CN104789058A (en) * | 2015-05-08 | 2015-07-22 | 重庆发宇涂料有限公司 | Novel emulsion paint |
| CN105295495A (en) * | 2015-11-05 | 2016-02-03 | 山东拜尔建材有限公司 | Water-based environmentally friendly wood putty and preparation method |
| CN105623434A (en) * | 2016-04-09 | 2016-06-01 | 佛山市恒学科技服务有限公司 | High-performance water-based wood paint |
| CN106118553A (en) * | 2016-07-13 | 2016-11-16 | 阜南县猛发工艺品有限公司 | A kind of cracking reinforcing agent for wicker products |
| CN106118553B (en) * | 2016-07-13 | 2018-08-24 | 阜南县猛发工艺品有限公司 | A kind of cracking reinforcing agent for wicker products |
| CN106042086A (en) * | 2016-07-21 | 2016-10-26 | 和县薛氏木制品制造有限公司 | Plywood putty and preparation method thereof |
| CN106147341A (en) * | 2016-08-01 | 2016-11-23 | 太仓顺如成建筑材料有限公司 | A kind of environment-friendly water-based Wood putty |
| CN106479243A (en) * | 2016-12-20 | 2017-03-08 | 钦州市星火计划办公室 | A kind of environmental protection Wood putty and preparation method thereof |
| CN107163663A (en) * | 2017-07-13 | 2017-09-15 | 合肥市龙阳节能新材料有限公司 | A kind of preparation method of the aqueous repairing paste putty of woodcare paint |
| CN107738328A (en) * | 2017-10-26 | 2018-02-27 | 北京宝力特建材有限公司 | A kind of water-based patching material for wood surface and preparation method thereof |
| CN107674590A (en) * | 2017-10-26 | 2018-02-09 | 北京宝力特建材有限公司 | A kind of water-based prime material for wood surface and preparation method thereof |
| CN108530971A (en) * | 2018-02-11 | 2018-09-14 | 河北晨阳工贸集团有限公司 | A kind of aqueous wooden ware spackling of high fillibility |
| CN116554722A (en) * | 2023-04-04 | 2023-08-08 | 中华制漆（深圳）有限公司 | Water-based wood inorganic transparent putty and preparation method thereof |
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| CN100577749C (en) | 2010-01-06 |
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