CN107384155A - A kind of novel aqueous PE woodcare paints and preparation method thereof - Google Patents
A kind of novel aqueous PE woodcare paints and preparation method thereof Download PDFInfo
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- CN107384155A CN107384155A CN201710659847.4A CN201710659847A CN107384155A CN 107384155 A CN107384155 A CN 107384155A CN 201710659847 A CN201710659847 A CN 201710659847A CN 107384155 A CN107384155 A CN 107384155A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention relates to a kind of novel aqueous PE woodcare paints, by first component, second component and trigger accelerator to form；Described first component：Second component：The proportioning for triggering accelerator is 100:40:3~5；A kind of water-based PE woodcare paints of the present invention, first prepare first component, second component respectively by the formula of first, second component；The proportioning 100 of the first and second components is pressed in container:40 add first component, second component, and are well mixed；Then accelerator is added by proportioning, initiator is added after stirring, stirred 0.5h, filtering, obtain described water-based PE woodcare paints；Water-based PE woodcare paints produced by the present invention, its performance is suitable with solvent-borne type PE woodcare paints, has excellent adhesive force, stain resistance, water resistance, alkali resistance, and paint film has the characteristics that high richness, high rigidity, high light.
Description
Technical field
The present invention relates to a kind of aqueous woodware paint, more particularly to a kind of novel aqueous PE woodcare paints and preparation method thereof,
Belong to technical field of aqueous paint.
Technical background
Severe environmental regulation has been formulated in succession both at home and abroad has been discharged to limit VOC (VOC) to air,
High-performance, environmental protection have turned into the direction of paint development.
Aqueous woodware paint is a kind of special coating using water as decentralized medium, and it is without benzene, dimethylbenzene, free TDI etc.
Harmful substance, it is a kind of ecological environment-friendly type coating truly, has environment-protecting and non-poisonous, odorlessness, volatile matter few, non-ignitable
The advantages that being moved on the day of not quick-fried, non yellowing, brushing surface are big, the same day brushes.With the continuous enhancing of people's environmental consciousness,
Aqueous woodware paint is increasingly by the welcome in market and favoring for consumer.
At present, the main species of water-borne wood coating have aqueous alcoholic acids, polyurethane aqueous dispersion body, acrylic emulsion, poly-
Urethane-acrylic acid hybridisation emulsion etc..Although alcohol acids water-borne wood coating good film-forming property, glossiness are high, good decorative property, film
Dryness is slow, hardness is low, yellowing resistance is poor, and coating easily hydrolyzes during storage, poor storage stability；Polyurethane water
Although dispersion class woodwork coating richness height, good toughness, good decorative property, hardness of film is low, poor water resistance, and price is held high
It is expensive；Acrylic emulsion class woodwork coating has the advantages that hardness is good, price is more cheap, but acrylic emulsion class woodwork coating is also
Have that film is partially soft, grinability is poor, coating is to the poor permeability of ground, the water resistance of film and solvent resistance is poor, film
The shortcomings of glossiness is low, richness is poor.Therefore in the market largely uses acrylic acid hybridisation polyaminoester emulsion or polyurethane chemistry
Modified acrylic acid emulsion, but the performance such as its hardness, richness differs larger compared with solvent-borne type woodcare paint, therefore in the market aqueous wooden ware
It is smaller to paint occupation rate of market, under government policy environmental protection, the overall background of coating Water-borne modification, in the market is plentiful to high rigidity, height
The requirement for spending aqueous woodware paint is more and more urgent.
Chinese patent CN201510369898.4 discloses a kind of aqueous woodware paint and preparation method thereof, the aqueous wooden ware
Paint is by aqueous polyurethane acrylate resin, aminomethyl phenyl acid esters-butyl acrylate copolymer, thickener, light trigger, defoaming
Agent part, dispersant, levelling agent, inserts, cosolvent, water configure form by weight.The aqueous woodware paint of the invention has hard
The characteristics of degree is high, film formation time is short, and manufacture craft is simple, environmental protection.But the importance such as the hardness of the aqueous woodware paint, richness
There can be certain distance compared with solvent-borne type woodcare paint.
The features such as solvent-borne type unsaturated polyester resin (PE) woodcare paint is because of high richness, high rigidity, high light applies in woodenware
Material field has higher occupation rate of market, and due to environmental protection, aqueous polyester resin arises at the historic moment；But aqueous polyester resin is all
It is to be configured to baking vanish as the component containing hydroxyl and amino resins or be configured to two component polyurethane with polyurethane curing agent apply
Expect say it is not also waterborne polyester coating on stricti jurise.Waterborne polyester woodwork coating was reported currently without open source information, was developed
A kind of performance and waterborne polyester woodcare paint similar in solvent-borne type PE woodcare paints are necessary.
The content of the invention
The shortcomings that to overcome prior art and deficiency, primary and foremost purpose of the invention aim to provide a kind of novel aqueous PE woodenware
Paint.
Another object of the present invention provides a kind of preparation method of novel aqueous PE woodcare paints.
A kind of novel aqueous PE woodcare paints of the present invention, it is characterised in that described water-based PE woodcare paints are by first component, second
Component and initiation-accelerator composition；Described first component：Second component：The proportioning of initiation-accelerator is 100:40:3~5.
Described first component, by weight, consisting of：35.0~65.0 parts of modified unsaturated polyester resin emulsion,
2.0~5.0 parts of antifreezing agent, 0~40.0 part of color stuffing, 0~5.0 part of wetting dispersing agent, 0.2~1.0 part of pH adjusting agent, defoamer
0.2~0.5 part, 0.2~0.5 part of thickener rheology agent, 2.0~12.0 parts of coalescents, 0~5.0 part of aqueous color paste, function additive
0~10.0 part, 0.1~0.3 part of bactericide, 15.0~30.0 parts of deionized water；
Described second component, by weight, consisting of：20.0~30.0 parts of unsaturated monomer, deionized water and second
15.0~20.0 parts of alcohol liquid, 0.5~2.0 part of emulsifying agent；
Described initiation-accelerator, by weight, consisting of：1.5~2.5 parts of initiator, accelerator 1.5~3.0
Part.
Described modified unsaturated polyester resin emulsion, it is to introduce unsaturated monomer on traditional polyester molecule chain to carry out
Modified obtained modified unsaturated polyester, after reaching 20~80mgKOH/g of defined acid number, solvent removed by vacuum, then by anti-phase
Modified unsaturated polyester emulsion is made in emulsion process；The polyester emulsion is translucent nanometer micro-emulsion, its particle diameter is 60~
100nm；" a kind of waterborne polyester coating is poly- with modified unsaturation in the patent of application for described modified unsaturated polyester resin emulsion
Had been described in ester emulsion and preparation method thereof ".
Wherein, described color stuffing is titanium dioxide, superfine talcum powder, dicalcium powder, light calcium carbonate powder, mica powder, kaolin, precipitation
One or more of combinations in barium sulfate, silicon calcium powder, glass dust, stearic acid.
Described wetting dispersing agent is one in polyocarboxy acid type anionic dispersing agents, nonionic polymer waterborne dispersant
Kind or several combinations.
Described defoamer is organic silicon, polyacrylic, phosphoric acid ester, silylated polyether class, acetylenic diols defoamer
In one or more of combinations.
Described thickener rheology agent is modified cellulose class thickener, hydrophobically-modified alkali swelling acrylic acid, the poly- ammonia of association type
One or more of combinations of ester, modified alta-mud.
Described coalescents are polyethylene glycol -200, polyethylene glycol -300, alcohol ester-12, propane diols phenylate, DPG
One or more of combinations in methyl ether, dipropylene, butyl.
Described function additive is substrate wetting agents, anti-wear agent, delustering agent, scratching resistant, hand feeling agent, ultraviolet radiation absorption
Agent, one or more of combinations of nanometer additive.
Described unsaturated monomer be hydroxyethyl methacrylate, hydroxy propyl methacrylate, methacrylate,
It is more than one or both of hydroxy-ethyl acrylate, hydroxypropyl acrylate, hy-droxybutyl, vinylphenol, styrene.
Described emulsifying agent is APES, alkylphenol-polyethenoxy-polyethenoxy ether, aliphatic acid polyoxy second
One or both of alkene ether, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy ether with
On.
Described initiator is ammonium persulfate, azodiisobutyronitrile, benzoyl peroxide, hydrogen peroxide, potassium peroxydisulfate, over cure
It is more than one or both of sour sodium, perbenzoic acid, cyclohexanone peroxide.
Described accelerator is more than one or both of mercaptopropionic acid, TGA, ferrous sulfate, frerrous chloride.
A kind of preparation method of novel aqueous PE woodcare paints of the present invention, step are as follows：First by the formula point of first, second component
First component, second component are not prepared；The proportioning 100 of the first and second components is pressed in container:40 add first component, second component, and mix
Uniformly；Then accelerator is added by proportioning, initiator is added after stirring, stirred 0.5h, filtering, obtain described water-based PE
Woodcare paint.
Water-based PE woodcare paints of the present invention, its performance is suitable with solvent-borne type PE woodcare paints, have excellent adhesive force,
Stain resistance, water resistance, alkali resistance, paint film have the characteristics that high richness, high rigidity, high light.
Embodiment
A kind of waterborne polyester coating of the present invention is made further of modified unsaturated polyester emulsion with reference to embodiment
Description.It is understood that specific embodiment described herein is used only for explaining related invention, rather than to the invention
Limit.
Embodiment 1
A kind of novel aqueous PE woodware white primers：
First component forms：45 parts of modified unsaturated polyester resin emulsion, 2 parts of antifreezing agent, 10 parts of talcum powder, 5 parts of titanium dioxide,
8 parts of dicalcium powder, 3 parts of barium sulfate, 2.5 parts of stearic acid, 2 parts of anionic dispersing agents, 0.5 part of pH adjusting agent, organic silicon defoamer 0.3
Part, 0.4 part of acrylic emulsion of hydrophobically-modified alkali swelling, 6 parts of alcohol ester-12 coalescents, 0.2 part of substrate wetting agents, bactericide 0.3
Part, 20 parts of deionized water；
Second component forms：15 parts of hydroxyethyl methacrylate, 10 parts of hydroxy propyl methacrylate, 10 parts of ethanol, deionization
8 parts of water, 1 part of alkylphenol-polyethenoxy-polyethenoxy ether；
Preparation process is as follows：First first component, second component are prepared respectively by the formula of first, second component；First is pressed in container
The proportioning 100 of second component:40 add first component, second component, and are well mixed；Then 2.5 parts of accelerator TGA is added, is stirred
1 part of 1 part of initiator benzoyl peroxide and hydrogen peroxide are added after mixing uniformly, 0.5h is stirred, filtering, obtains described water-based PE wood
Device based white primer.
Performance test：Appropriate deionized water, even application to woodenware table are added in described water-based PE woodware white primers
Face, easily polish after drying time 24h, paint film is without dark bubble, high compactness.
Embodiment 2
A kind of novel aqueous PE woodenware white finish paint：
First component forms：55 parts of modified unsaturated polyester resin emulsion, 3 parts of antifreezing agent, 15 parts of titanium dioxide, macromolecule disperse
3 parts of agent, 0.3 part of pH adjusting agent, 0.3 part of silylated polyether defoamer, association 0.3 part of type polyurethane, 4.6 parts of dipropylene,
0.2 part of scratching resistant, 0.2 part of substrate wetting agents, 0.3 part of bactericide, 21 parts of deionized water；
Second component forms：15 parts of hydroxyethyl methacrylate, 12 parts of hydroxypropyl acrylate, 10 parts of ethanol, deionized water 8
Part, 1.2 parts of alkylphenol-polyethenoxy-polyethenoxy ether；
Preparation process is as follows：First first component, second component are prepared respectively by the formula of first, second component；First is pressed in container
The proportioning 100 of second component:40 add first component, second component, and are well mixed；Then 2.6 parts of accelerator TGA is added, is stirred
1 part of 1 part of initiator benzoyl peroxide and cyclohexanone peroxide are added after mixing uniformly, 0.5h is stirred, filtering, obtains described water
Property PE woodenware white finish paints.
Performance test：Appropriate deionized water, even application to woodenware table are added in described water-based PE woodenware white finish paint
Face, after drying time 24h, hardness of paint film 1H, hardness of paint film 2H after 7 days；Paint film is without dark bubble, high light, high richness.
Embodiment 3
A kind of novel aqueous PE woodenware coating varnish：
First component forms：60 parts of modified unsaturated polyester resin emulsion, 3 parts of antifreezing agent, 0.3 part of pH adjusting agent, silane gather
0.3 part of ether defoaming agent, 0.1 part of type polyurethane of association, 5 parts of dipropylene, 0.2 part of scratching resistant, substrate wetting agents 0.2
Part, 0.3 part of bactericide, 25 parts of deionized water；
Second component forms：15 parts of hydroxyethyl methacrylate, 10 parts of methacrylate, 2 parts of styrene, ethanol 10
Part, 8 parts of deionized water, 1.2 parts of alkylphenol-polyethenoxy-polyethenoxy ether；
Preparation process is as follows：First first component, second component are prepared respectively by the formula of first, second component；First is pressed in container
The proportioning 100 of second component:40 add first component, second component, and are well mixed；Then 2.5 parts of accelerator TGA is added, is stirred
1 part of 1 part of initiator benzoyl peroxide and cyclohexanone peroxide are added after mixing uniformly, 0.5h is stirred, filtering, obtains described water
Property PE woodenware coating varnishes.
Performance test：Appropriate deionized water, even application to woodenware are added in described water-based PE woodenware coating varnish
Surface, after drying time 24h, hardness of paint film 1H, hardness of paint film 2H after 7 days；Paint film is without dark bubble, high light, high transparency, Gao Feng
Full scale.
Although the present invention has been explained in detail and has been cited embodiment, for one of ordinary skill in the art, show
Various schemes, modification and the change that can so make as specified above, should be construed as being included within the scope of claim.
Claims (8)
1. a kind of novel aqueous PE woodcare paints, it is characterised in that described water-based PE woodcare paints by first component, second component and draw
Hair-accelerator composition；Described first component：Second component：The proportioning of initiation-accelerator is 100:40:3~5；
Described first component, by weight, consisting of：It is 35.0~65.0 parts of modified unsaturated polyester resin emulsion, antifreeze
2.0~5.0 parts of agent, 0~40.0 part of color stuffing, 0~5.0 part of wetting dispersing agent, 0.2~1.0 part of pH adjusting agent, defoamer 0.2
~0.5 part, 0.2~0.5 part of thickener rheology agent, 2.0~12.0 parts of coalescents, 0~5.0 part of aqueous color paste, function additive 0~
10.0 parts, 0.1~0.3 part of bactericide, 15.0~30.0 parts of deionized water；Wherein, described modified unsaturated polyester resin breast
Liquid, it is to introduce unsaturated monomer on traditional polyester molecule chain to be modified obtained modified unsaturated polyester, reaches defined
After 20~80mgKOH/g of acid number, solvent removed by vacuum, then pass through modified unsaturated polyester emulsion made from inversed phase emulsification；Institute
The polyester emulsion stated is translucent nanometer micro-emulsion, and its particle diameter is 60~100nm；
Described second component, by weight, consisting of：20.0~30.0 parts of unsaturated monomer, deionized water and ethanol
15.0~20.0 parts, 0.5~2.0 part of emulsifying agent；Wherein, described unsaturated monomer is hydroxyethyl methacrylate, methyl-prop
Olefin(e) acid hydroxypropyl acrylate, methacrylate, hydroxy-ethyl acrylate, hydroxypropyl acrylate, hy-droxybutyl, vinyl benzene
It is more than one or both of phenol, styrene；Described emulsifying agent is APES, alkylphenol-polyethenoxy-poly-
Oxypropylene ether, aliphatic acid polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxy second
It is more than one or both of alkene ether；
Described initiation-accelerator, by weight, consisting of：1.5~2.5 parts of initiator, 1.5~3.0 parts of accelerator；
Wherein, described initiator is ammonium persulfate, azodiisobutyronitrile, benzoyl peroxide, hydrogen peroxide, potassium peroxydisulfate, persulfuric acid
It is more than one or both of sodium, perbenzoic acid, cyclohexanone peroxide；Described accelerator is mercaptopropionic acid, sulfydryl second
It is more than one or both of acid, ferrous sulfate, frerrous chloride.
2. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described color stuffing is titanium dioxide, surpassed
One kind in fine and smooth stone flour, dicalcium powder, light calcium carbonate powder, mica powder, kaolin, blanc fixe, silicon calcium powder, glass dust, stearic acid
Or several combination.
3. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described wetting dispersing agent is polycarboxylic acids
One or more of combinations in type anionic dispersing agents, nonionic polymer waterborne dispersant.
4. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described defoamer be organic silicon,
One or more of combinations in polyacrylic, phosphoric acid ester, silylated polyether class, acetylenic diols defoamer.
5. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described thickener rheology agent is modified fine
Tie up one or more of combinations of plain class thickener, hydrophobically-modified alkali swelling acrylic acid, associate type polyurethane, modified alta-mud.
6. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described coalescents are poly- second two
Alcohol -200, polyethylene glycol -300, alcohol ester-12, propane diols phenylate, dipropylene glycol methyl ether, dipropylene, butyl
In one or more of combinations.
7. novel aqueous PE woodcare paints according to claim 1, it is characterised in that described function additive soaks for base material
Agent, anti-wear agent, delustering agent, scratching resistant, hand feeling agent, ultra-violet absorber, one or more of combinations of nanometer additive.
A kind of 8. preparation method of novel aqueous PE woodcare paints as claimed in claim 1, it is characterised in that：Its step is as follows：
First first component, second component are prepared respectively by the formula of first, second component；The proportioning 100 of the first and second components is pressed in container:40 add
First component, second component, and be well mixed；Then accelerator is added by proportioning, initiator is added after stirring, stirred
0.5h, filtering, obtain described water-based PE woodcare paints.
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| CN201710659847.4A CN107384155A (en) | 2017-08-04 | 2017-08-04 | A kind of novel aqueous PE woodcare paints and preparation method thereof |
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Cited By (5)
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| CN108753127A (en) * | 2018-05-08 | 2018-11-06 | 安徽名士达新材料有限公司 | A kind of novel aqueous PE woodcare paints and preparation method thereof |
| CN108948929A (en) * | 2018-06-08 | 2018-12-07 | 阜南县星光工艺品有限公司 | A kind of preparation method of cool feeling wicker products |
| CN109679473A (en) * | 2018-12-12 | 2019-04-26 | 苏州马培德办公用品制造有限公司 | Environment-friendly water-based pencil colored paint and its preparation method and application suitable for wood pencils |
| CN112646443A (en) * | 2020-12-24 | 2021-04-13 | 华南理工大学 | Thermal transfer printing roller coating woodware coating composition and preparation method thereof |
| CN116656214A (en) * | 2023-07-03 | 2023-08-29 | 聚涂科技(东莞)有限公司 | Water-based two-component epoxy primer and preparation method and application thereof |
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| CN1807531A (en) * | 2004-12-28 | 2006-07-26 | 关西涂料株式会社 | Paint composition |
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753127A (en) * | 2018-05-08 | 2018-11-06 | 安徽名士达新材料有限公司 | A kind of novel aqueous PE woodcare paints and preparation method thereof |
| CN108948929A (en) * | 2018-06-08 | 2018-12-07 | 阜南县星光工艺品有限公司 | A kind of preparation method of cool feeling wicker products |
| CN108948929B (en) * | 2018-06-08 | 2020-09-29 | 临沭青源工艺品有限公司 | Preparation method of cool wicker product |
| CN109679473A (en) * | 2018-12-12 | 2019-04-26 | 苏州马培德办公用品制造有限公司 | Environment-friendly water-based pencil colored paint and its preparation method and application suitable for wood pencils |
| CN112646443A (en) * | 2020-12-24 | 2021-04-13 | 华南理工大学 | Thermal transfer printing roller coating woodware coating composition and preparation method thereof |
| CN112646443B (en) * | 2020-12-24 | 2022-04-22 | 华南理工大学 | Thermal transfer printing roller coating woodware coating composition and preparation method thereof |
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Application publication date: 20171124 |