CN1572846A - Special silk-screen print ink and presswork - Google Patents
Special silk-screen print ink and presswork Download PDFInfo
- Publication number
- CN1572846A CN1572846A CNA2004100476974A CN200410047697A CN1572846A CN 1572846 A CN1572846 A CN 1572846A CN A2004100476974 A CNA2004100476974 A CN A2004100476974A CN 200410047697 A CN200410047697 A CN 200410047697A CN 1572846 A CN1572846 A CN 1572846A
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- Prior art keywords
- ether
- printed matter
- printing ink
- screen printing
- glycol
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- Granted
Links
- 239000002904 solvent Substances 0.000 claims abstract description 43
- 238000007639 printing Methods 0.000 claims abstract description 40
- 238000009835 boiling Methods 0.000 claims abstract description 38
- 239000000049 pigment Substances 0.000 claims abstract description 38
- 239000011230 binding agent Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 238000007650 screen-printing Methods 0.000 claims description 69
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 33
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 33
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 26
- 238000000637 aluminium metallisation Methods 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 17
- 238000000576 coating method Methods 0.000 claims description 17
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
- 235000019439 ethyl acetate Nutrition 0.000 claims description 11
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 11
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 11
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 9
- 239000004697 Polyetherimide Substances 0.000 claims description 9
- 239000004417 polycarbonate Substances 0.000 claims description 9
- 229920000515 polycarbonate Polymers 0.000 claims description 9
- 229920001601 polyetherimide Polymers 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000004381 surface treatment Methods 0.000 claims description 8
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 6
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 4
- QYGBYAQGBVHMDD-XQRVVYSFSA-N (z)-2-cyano-3-thiophen-2-ylprop-2-enoic acid Chemical compound OC(=O)C(\C#N)=C/C1=CC=CS1 QYGBYAQGBVHMDD-XQRVVYSFSA-N 0.000 claims description 3
- WGYZMNBUZFHYRX-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-ol Chemical compound COCC(C)OCC(C)O WGYZMNBUZFHYRX-UHFFFAOYSA-N 0.000 claims description 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 3
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 3
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims description 3
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 claims description 3
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 claims description 3
- RFQLTXOJXDPLFL-UHFFFAOYSA-N C(CCC)OCC(=S)OCCO Chemical compound C(CCC)OCC(=S)OCCO RFQLTXOJXDPLFL-UHFFFAOYSA-N 0.000 claims description 3
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims description 3
- UBPGILLNMDGSDS-UHFFFAOYSA-N diethylene glycol diacetate Chemical class CC(=O)OCCOCCOC(C)=O UBPGILLNMDGSDS-UHFFFAOYSA-N 0.000 claims description 3
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims description 3
- 229960005082 etohexadiol Drugs 0.000 claims description 3
- 229940051250 hexylene glycol Drugs 0.000 claims description 3
- -1 polyethylene terephthalate Polymers 0.000 claims description 3
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 claims description 3
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 claims description 3
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 claims description 2
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 19
- 229910052782 aluminium Inorganic materials 0.000 abstract description 19
- 230000007547 defect Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 230000002950 deficient Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000009738 saturating Methods 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 2
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 2
- YEJSPQZHMWGIGP-YFKPBYRVSA-N L-glutamic acid, dimethyl ester Chemical compound COC(=O)CC[C@H](N)C(=O)OC YEJSPQZHMWGIGP-YFKPBYRVSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YEJSPQZHMWGIGP-UHFFFAOYSA-N dl-glutamic acid dimethyl ester Natural products COC(=O)CCC(N)C(=O)OC YEJSPQZHMWGIGP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- DJQULQXOZQDEBV-UHFFFAOYSA-N 1-[2-(2-methoxyethoxy)ethoxy]-2-methylpropane Chemical compound COCCOCCOCC(C)C DJQULQXOZQDEBV-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
To provide a screen ink which exhibits stable printing properties enough to cause no defects in printed matter such as jaggedness, blur, pinholes or transparency and gives printed matter exhibiting high-grade specular gloss and color specular gloss. The special screen ink comprises 100 pts. wt. of a deposited aluminum pigment containing at least 75% of one having a thickness of at most 0.5 [mu]m and an area of 20-2,000 [mu]m<SP>2</SP>and, incorporated therewith at least, 10-1,000 pts. wt. of a binder polymer and 600-2,000 pts. wt. of one or more solvents having a boiling point of not lower than 112[deg.]C but not higher than 250[deg.]C, and has an ink viscosity of 100-2,500 cps (at 30[deg.]C).
Description
Technical field
The present invention relates to screen printing ink that in the manufacturing that possesses specular gloss, colour mirrorlike surface glossy printed matter, uses and the printed matter made from this screen printing ink.
Background technology
When manufacturing has the printed matter of specular gloss, the raw-material printing ink of various aluminium such as flakey aluminium, paper tinsel shape aluminium, AM aluminum metallization pigment have been added in use, this always knows for people, but use this printing ink to carry out under the situation of silk screen printing, printed matter generation hackle mark arranged, cut marks, the problem of defectives such as pinprick, saturating look, obtain stable specular gloss, colour mirrorlike surface gloss difficulty.
Therefore, wish to obtain printability good, can present stable specular gloss or colour mirrorlike surface glossy screen printing ink.Here the good screen printing ink of said printability means hackle mark on the printed matter, cuts marks, the considerably less screen printing ink of generation of defectives such as pinprick, saturating look.
Particularly, as the printing ink that has added as the raw-material flakey aluminium of aluminium, (strain) minot Gu Lupu (" rice draws (ミ ラ-) C " of the corporate system of ミ ノ グ Le-プ) etc. are for example arranged, but the surface smoothing of flakey aluminium is poorer than AM aluminum metallization pigment, and therefore the problem that can not obtain enough specularities is arranged.
In addition, having put down in writing the printing ink of printed matter that is used to make the specular gloss with height in patent documentation 1, as this printing ink, is to be that 0.5 μ m or following, paper tinsel area are 20 μ m with respect to containing thickness
2-2000 μ m
2Aluminium foil 75% or above aluminium foil 100 weight parts, contain that binder polymer 15-200 weight part and solvent 600-3000 weight part form.
[patent documentation 1]
No. 3151606 communique of patent
Distinguish that the printing ink printability that patent documentation 1 is put down in writing is also bad, be difficult to obtain possessing minute surface printed matter, the colour mirrorlike surface printed matter of specular gloss.
Summary of the invention
As printed matter generation hackle mark, cut marks, the essential factor of defectives such as pinprick, saturating look, be estimated as: in printing ink in the past, cooperation raw materials such as aluminium starting material, binder polymer, solvent such as flakey aluminium, paper tinsel shape aluminium, AM aluminum metallization pigment influence, these each raw materials each other give the base material of printed matter, applied the printed matter etc. of original printing ink and coating etc. on this base material influence is not thrown a flood of light on, be difficult to present simultaneously tack of filming and specularity after the printing, printability is poor.
In addition, in recent years, at by for improve tack etc. through surface treatment polyethylene terephthalate (PET), acrylic acid or the like, through hard coating processing the base material that forms such as acrylic acid or the like, polycarbonate, polyetherimide, hope obtains presenting stable specular gloss or colour mirrorlike surface glossy screen printing ink.
, use above-mentioned printing ink in the past to carry out under the situation of minute surface printing, because above-mentioned, existence can not obtain the specularity of height and the problem of tack.
Have again, when repeatedly printing above-mentioned in the past printing ink on the printed matter that has printed original printing ink or coating, the problem that exists the part of repeating print to impact by infringement and to tack, form and aspect.
The present invention finishes in view of so existing situation, as its purpose, and the 1st, provide and have stable printability and can make the specular gloss, the screen printing ink of colour mirrorlike surface glossy printed matter that presents height.
Again, the 2nd purpose of the present invention provides, even for as specularity that in silk screen printing, is difficult to simultaneously to satisfy height and tack raw-material, for improve tack etc. through surface treatment PET, acrylic acid or the like, through hard coating processing base materials such as acrylic acid or the like, polycarbonate, polyetherimide, also can make the screen printing ink of the printed matter of the specularity that presents height and tack.
Again, the 3rd purpose of the present invention provides, even printing repeatedly on the printed matter that has printed original printing ink or coating, can not encroach on the part of repeating print yet and tack, form and aspect are impacted, have stable printability and present specular gloss, the colour mirrorlike surface glossy screen printing ink of height.
In order to achieve the above object, aluminium starting material and solvent that the inventor is conceived to add, research with keen determination repeatedly, find: by at the AM aluminum metallization pigment of the smoothness excellence of using the surface as the raw-material while of aluminium of adding, use possesses the solvent of defined terms, and adjust in the scope that makes printing ink concentration reach regulation, can finish above-mentioned problem, to such an extent as to finish the present invention.
That is, relevant special screen printing ink of the present invention is characterized in that, with respect to containing pigment thickness 0.5 μ m or following, pigment area 20 μ m
2-2000 μ m
2AM aluminum metallization pigment 7 5% or above AM aluminum metallization pigment 100 weight parts, at least contain binder polymer 10-1000 weight part, boiling point and be 112 ℃ or above, less than a kind or more kinds of 600-2000 weight part of 250 ℃ solvents, ink viscosity is that 100-2500cps (is measuring 30 ℃ of temperature, adopting E type rotational viscosimeter " the VISCONIC EHD viscometer of (strain) Tokyo gauge corporate system " to measure under rotating speed 100r.p.m.In this manual, only souvenir is " 30 ℃ ".)。
The of the present invention special screen printing ink of such formation is owing in the AM aluminum metallization pigment of the smoothness excellence of using the surface, contain pigment thickness 0.5 μ m or following, pigment area 20 μ m
2-2000 μ m
2AM aluminum metallization pigment 75% or more than, therefore can access the printed matter of the specular gloss that embodies height.
The thickness of AM aluminum metallization pigment surpasses the situation of 0.5 μ m, the area of AM aluminum metallization pigment can not get having the printed matter of specular gloss highly less than the situation of 20 μ m2.
The area of AM aluminum metallization pigment surpasses 2000 μ m
2Situation under printed matter hackle mark takes place easily, cut marks, defectives such as pinprick, saturating look.
And, special screen printing ink of the present invention, since the boiling point that contains the 600-2000 weight part be 112 ℃ or above, less than 250 ℃ a kind or more kinds of solvents, therefore can printability make well and present stable specular gloss or colour mirrorlike surface glossy printed matter.
When to use boiling point be 250 ℃ or above solvent, after the silk screen printing film dry slow, the operability of printing operation is bad, simultaneously, can not get the specular gloss of height because of the influence of residual solvent.
When using boiling point less than 112 ℃ solvent, the fast drying of filming after the silk screen printing, ink viscosity be along with effluxion uprises, defectives such as printed matter hackle mark takes place easily, cuts marks, pinprick, saturating look, and printability reduces.
As boiling point be 112 ℃ or more than, solvent less than 250 ℃, for example can list the polyvalent alcohol butyl cellosolve acetate, the mixture of glutamic acid dimethyl ester and Succinic acid dimethylester and dimethyl adipate, gamma-butyrolactone, isophorone, butylacetate, propylene glycol, Pyranton, propylene glycol list ethyl ether acetic ester, cellosolve acetate, pimelinketone, propylene glycol monomethyl ether, the N-amino alcohol, the methyl-isobutyl carbitol, propyl carbinol, ethylene glycol, glycol diacetate, the ethylene glycol bisthioglycolate butyl ether, ethylene glycol acetate, the glycol monomethyl phenyl ether, ethylene glycol monobutyl ether, the ethylene glycol monobutyl ether acetic ester, ethylene glycol mono hexyl ether, glycol monomethyl methoxymethyl ether, 1, the 3-ethohexadiol, Diethylene Glycol, Diethylene Glycol ethyl-methyl ether, the Diethylene Glycol diacetate esters, diethylene glycol dimethyl ether, diethylene glycol dimethyl ether, TC, the TC acetic ester, the Diethylene Glycol single-butyl ether, Diethylene Glycol single-butyl ether acetic ester, diethylene glycol monomethyl ether, dipropylene glycol, dihydroxypropane single-ethyl ether, the dipropylene glycol single-butyl ether, DPGME, the triethylene glycol dimethyl ether, the triethylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, trimethylene, 1, the 2-butyleneglycol, 1, the 3-butyleneglycol, 1, the 4-butyleneglycol, Texacar PC (プ ロ ピ レ Application カ Le ボ Na-ト), propylene glycol, propylene glycol list ethyl ether, the propylene glycol single-butyl ether, propylene glycol monomethyl ether, hexylene glycol, 1, the 5-pentanediol, 3-methyl-3-methoxyl group-1-butanols.
Both can contain these solvents singlely, also can mix contain a plurality of.
In addition, special screen printing ink of the present invention owing to be adjusted to the scope that ink viscosity is 100-2500cps (30 ℃), therefore can printability be made well and is presented stable specular gloss or colour mirrorlike surface glossy printed matter.
Ink viscosity less than the situation of 100cps, surpass the situation of 2500cps, defectives such as printed matter hackle mark takes place easily, cuts marks, pinprick, saturating look, printability reduces.
In special screen printing ink of the present invention,, contain binder polymer 10-1000 weight part with respect to AM aluminum metallization pigment 100 weight parts.As binder polymer, if be used for silk screen printing, then do not limit especially, for example can use various resins such as vinylchlorid vinyl acetate copolymerized resin, butyral resin, vibrin, urethane resin.
With respect to above-mentioned basic cooperation, also can contain the aluminium powder form of particle diameter 1-45 μ m in 50 weight parts or following scope.In the case, can reduce the content of AM aluminum metallization pigment, seek cost and reduce.
With respect to above-mentioned basic cooperation, also can contain tinting pigment and/or pearly pigment at 150 weight parts or following scope again.In the case, has various colors, Yi Bian embody the printed matter of the specular gloss of height Yi Bian can make.
With respect to above-mentioned basic cooperation, also can contain the solvent of when making AM aluminum metallization pigment, sneaking into and/or the solvent of dissolved adhesive polymkeric substance in 150 weight parts or following scope again.
But,, preferably use boiling point comparison binder polymer not have solvent so-called solubility promoter or the high solvent of thinner as the solvent of dissolved adhesive polymkeric substance.When using boiling point than the low solvent of solubility promoter or thinner, along with the effluxion in the printing operation, ink viscosity surpasses 2500cps, and defectives such as printed matter hackle mark takes place easily, cuts marks, pinprick, saturating look have the sorrow of printability reduction.Should restriction during solvent (boiling point 112-250 ℃ solvent) the dissolved adhesive polymkeric substance that, in basic the cooperation, uses.
In addition, the base material as the printing object thing be for improve tack etc. through surface treatment PET (for example, the Cosmoshine A4100 of Japan's weaving (strain) corporate system, A4300 etc., the HK-31WF of Dongshan film (strain) corporate system, the hard coat of CHC), acrylic acid or the like, through hard coating processing acrylic acid or the like (for example, the Acree of mitsubishi rayon's (strain) corporate system comes special (ア Network リ ラ ィ ト) MR200 etc.), polycarbonate, transparent substrates such as polyetherimide, translucent base material, it is the situation that arrives the base material of specularity highly and tack scarcely ever, above-mentioned boiling point 112 or more than, among 250 ℃ solvent, special screen printing ink of the present invention, the single or multiple mixing of scope ground with the 600-2000 weight part contains ethylene glycol, glycol diacetate, the ethylene glycol bisthioglycolate butyl ether, ethylene glycol acetate, the glycol monomethyl phenyl ether, ethylene glycol monobutyl ether, the ethylene glycol monobutyl ether acetic ester, ethylene glycol mono hexyl ether, glycol monomethyl methoxymethyl ether, 1, the 3-ethohexadiol, Diethylene Glycol, Diethylene Glycol ethyl-methyl ether, the Diethylene Glycol diacetate esters, diethylene glycol diethyl ether, diethylene glycol dimethyl ether, TC, the TC acetic ester, the Diethylene Glycol single-butyl ether, Diethylene Glycol single-butyl ether acetic ester, diethylene glycol monomethyl ether, dipropylene glycol, dihydroxypropane single-ethyl ether, the dipropylene glycol single-butyl ether, DPGME, the triethylene glycol dimethyl ether, the triethylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, trimethylene, 1, the 2-butyleneglycol, 1, the 3-butyleneglycol, 1, the 4-butyleneglycol, Texacar PC (プ ロ ピ レ Application カ Le ボ Na-ト), propylene glycol, propylene glycol list ethyl ether, the propylene glycol single-butyl ether, propylene glycol monomethyl ether, hexylene glycol, 1, the 5-pentanediol, 3-methyl-3-methoxyl group-1-butanols is for well.
When using these solvents, for for improve tack etc. through surface treatment PET, acrylic acid or the like, through hard coating processing transparent substrate, translucent base materials such as acrylic acid or the like, polycarbonate, polyetherimide, can present the specularity of height and tack, printability and make well and have stable specular gloss or colour mirrorlike surface glossy printed matter.In addition, also bring into play same effect, can on these printed matters, print by a part of multiple mode for the printed matter that has applied original screen printing ink and coating etc.
Moreover, in special screen printing ink of the present invention, can add various additives such as the flow agent that can in screen printing ink, add and anti-settling agent as required, be used to adjust the lower boiling solvent of ink viscosity.
But, the various content of additive beyond the solvent wish for the total scale of construction of printing ink 1% or below.The various additives that add more than 1% have the sorrow that reduces specularity.
Description of drawings
Fig. 1 is the enlarged photograph that adopts printing surface * 450 times of the printed matter that relevant special screen printing ink of the present invention (embodiment 1) obtains.
Fig. 2 is the enlarged photograph that adopts printing surface * 450 times of the printed matter that relevant special screen printing ink of the present invention (embodiment 2) obtains.
Fig. 3 is the enlarged photograph that adopts printing surface * 450 times of the printed matter that screen printing ink (comparative example 1) as a comparative example obtains.
Embodiment
Followingly illustrate in greater detail the present invention with reference to embodiment, comparative example.
[embodiment 1]
With respect to thickness 0.5 μ m or following, area 20 μ m
2-2000 μ m
2AM aluminum metallization pigment contain 75% or above AM aluminum metallization pigment 100 weight parts, contain butyral resin 47 weight parts as binder polymer, ethylene glycol monobutyl ether (170 ℃ of boiling points) 181 weight parts as the solvent of 112 ℃-250 ℃ of boiling points, propylene glycol monomethyl ether (121 ℃ of boiling points) 869 weight parts, Diethylene Glycol single-butyl ether acetic ester (247 ℃ of boiling points) 42 weight parts, isophorone (215 ℃ of boiling points) 77 weight parts, as acetone (56 ℃ of boiling points) 31 weight parts of the solvent of sneaking into when making AM aluminum metallization pigment, obtaining ink viscosity is the special screen printing ink of 250cps (30 ℃).
Use this special screen printing ink, carried out silk screen printing at the back side as the transparent polyester film of base material.
The printed matter that obtains be have the specular gloss of height and do not have hackle mark at printing surface, cut marks, the printed matter (with reference to Fig. 1) of pinprick.
[embodiment 2]
With respect to AM aluminum metallization pigment 100 weight parts, contain 12 weight part C.I. pigment red 149s (C.I.Pigment Red149), 18 weight part Novoperm Yellow HR as tinting pigment, in addition, constitute the cooperation identical with embodiment 1, obtaining ink viscosity is the special screen printing ink of 350cps (30 ℃).
Use this special screen printing ink, carried out silk screen printing at the back side as the transparent polyester film of base material.
The printed matter that obtains be have the colour mirrorlike surface gloss of height and do not have hackle mark at printing surface, cut marks, the printed matter (with reference to Fig. 2) of pinprick.
[comparative example 1]
The solvent that replaces 112-250 ℃ of boiling point contains the toluene (111 ℃ of boiling points) of 1169 weight parts, in addition, constitutes the cooperation identical with embodiment 1, and obtaining ink viscosity is the special screen printing ink of 200cps (30 ℃).
Use this special screen printing ink, carried out silk screen printing at the back side as the transparent polyester film of base material.
There is hackle mark in the printed matter that obtains, cuts marks, pinprick on printing surface, and can see that specular gloss significantly reduces.
By contrast the foregoing description 1,2 and comparative example 1 susceptible of proof: with the printed matter ratio made from the of the present invention special screen printing ink of the solvent that has used 112 ℃-250 ℃ of boiling points, with the printed matter that has used boiling point to make less than the screen printing ink of the comparative example of 112 ℃ solvent, its printability is bad.
Promptly, enlarged photograph by printing surface * 450 of the printed matter that obtains in embodiment 1,2, comparative example 1 times can confirm clearly, the printing surface of embodiment 1 (Fig. 1), embodiment 2 (Fig. 2) be do not cut marks, pinprick, the printability excellence, the printing surface existence of comparative example 1 (Fig. 3) cuts marks, pinprick, and printability is poor.
[comparative example 2]
Thickness 0.5 μ m or following, area 20 μ m have been used
2-2000 μ m
2Flakey aluminium pigment contain 75% or above scale aluminium pigment 100 weight parts, in addition, constitute the cooperation identical with embodiment 1, obtaining ink viscosity is the special screen printing ink of 260cps (30 ℃).
Use this special screen printing ink, carried out silk screen printing at the back side as the transparent polyester film of base material.
There is hackle mark in the printed matter that obtains, cuts marks, pinprick on printing surface, and can see that specular gloss significantly reduces.
By contrasting the foregoing description 1,2 and comparative example 2 susceptible of proofs: used the printed matter ratio of making as the of the present invention special screen printing ink of the raw-material AM aluminum metallization pigment of aluminium with usefulness, with having used the printed matter of making as the screen printing ink of the comparative example of the raw-material flakey aluminium of aluminium, its printability is bad.
[embodiment 3]
Urethane resin 30 weight parts have been used as binder polymer, ethylene glycol monobutyl ether (170 ℃ of boiling points) 338 weight parts as the solvent of 112 ℃-250 ℃ of boiling points, propylene glycol monomethyl ether (121 ℃ of boiling points) 544 weight parts, 3-methyl-3-methoxyl group-1-butanols (174 ℃ of boiling points) 138 weight parts, methylethylketone (80 ℃ of boiling points) 46 weight parts of the solvent of using as the dissolved adhesive polymkeric substance, Virahol (83 ℃ of boiling points) 23 weight parts, acetone (56 ℃ of boiling points) 29 weight parts as the solvent of when making AM aluminum metallization pigment, sneaking into, in addition, constitute the cooperation identical with embodiment 1, obtaining ink viscosity is the special screen printing ink of 225cps (30 ℃).
Use this special screen printing ink, as base material, be prepared as the PET base material that improves tack etc. and the handled Cosmoshine A4100 of (Japan weave (strain) corporate system), propylene base material, propylene base material (AcrylitMR200E of mitsubishi rayon's (strain) corporate system), polycarbonate substrate, the polyetherimide base material crossed of coating processing firmly, carried out silk screen printing at the back side of each base material.
The printed matter that obtains is the same with embodiment 1, be have the specular gloss of height and do not have hackle mark at printing surface, cut marks, the printed matter of pinprick.
[comparative example 3]
Solvent as boiling point 112-250 ℃, mixture (210 ℃ of boiling points) 882 weight parts of ethylene glycol monobutyl ether (170 ℃ of boiling points) 104 weight parts, glutamic acid dimethyl ester and Succinic acid dimethylester and dimethyl adipate have been used, in addition, constitute the cooperation identical with embodiment 3, obtaining ink viscosity is the screen printing ink of 160cps (30 ℃).
Use this special screen printing ink, silk screen printing is carried out at the back side of similarly to Example 3 each base material.
There is hackle mark in the printed matter that obtains, cuts marks, pinprick on printing surface, and can see that specular gloss significantly reduces.
By contrast the foregoing description 3 and comparative example 3 susceptible of proofs: use and adopted under 112 ℃ of boiling points cited in the summary of the invention of front or above, the situation less than the special screen printing ink of 250 ℃ solvents, even for for improve tack etc. through surface treatment PET, acrylic acid or the like, through hard coating processing base materials such as acrylic acid or the like, polycarbonate, polyetherimide, also can carry out satisfying the specularity highly and the silk screen printing of tack simultaneously.
In contrast to this, susceptible of proof: used and adopted under 112 ℃ of boiling points cited in the summary of the invention of front or above, the situation less than the screen printing ink of the solvent beyond 250 ℃ the solvents, for for improve tack etc. through surface treatment PET, acrylic acid or the like, through hard coating processing base materials such as acrylic acid or the like, polycarbonate, polyetherimide, can not satisfy specularity and tack highly simultaneously.
[embodiment 4]
Use the special screen printing ink of embodiment 3, on the printed matter that has applied original screen printing ink and coating etc., implemented silk screen printing by a part of multiple mode.
The printed matter that obtains be the specular gloss of height is arranged on the part of repeating print and do not have hackle mark at printing surface, cut marks, the printed matter of pinprick.
[comparative example 4]
Use the screen printing ink of comparative example 3, on the printed matter that has applied original screen printing ink and coating etc., implemented silk screen printing by a part of multiple mode.
The printed matter that obtains is the printed matter that the part of repeating print is encroached on, impacted for tack, form and aspect.
By contrast the foregoing description 4 and comparative example 4 susceptible of proofs: used 112 ℃ of boiling points cited in the summary of the invention of front or above, less than the special screen printing ink of 250 ℃ solvents, even on the printed matter that has printed original printing ink or coating, repeat print, can not encroach on the part of repeating print yet and impact for tack, form and aspect, have stable printability, and present specular gloss, the colour mirrorlike surface gloss of height.
More than based on embodiment several examples about the embodiment of special screen printing ink of the present invention and printed matter have been described, but the present invention is not limited to these embodiment, the category of the technological thought of being put down in writing in the every claim of the present invention can carry out all changes.
The present invention as described above, be when using the AM aluminum metallization pigment of prescribed condition as the aluminium starting material, contain specified amount 112 ℃ of boiling points or above, less than 250 ℃ solvents, and ink viscosity is the special screen printing ink of 100-2500cps (30 ℃), therefore, adopt common silk screen printing can stably embody specular gloss, colour mirrorlike surface gloss.And, because hackle mark, cut marks, the generation of defectives such as pinprick, saturating look considerably less, printability might as well, so printing efficiency improves extraordinarily, can make cheapness thus and matter is measured has specular gloss, a colour mirrorlike surface glossy printed matter.
In addition, as 112 ℃ of boiling points or above, less than 250 ℃ solvents, use under the situation of solvent cited in the summary of the invention of front, even for for improve tack etc. through surface treatment PET, acrylic acid or the like, through hard coating processing base materials such as acrylic acid or the like, polycarbonate, polyetherimide, also can embody the specularity and the tack of height.
In addition, even on the printed matter that has printed original printing ink or coating, repeat print, can not encroach on the part of repeating print yet and impact for tack, form and aspect, obtain to have stable printability, and present a lot of effects such as specular gloss highly, colour mirrorlike surface gloss.
Claims (8)
1. special screen printing ink, it is with respect to containing thickness 0.5 μ m or following, area 20 μ m
2-2000 μ m
2AM aluminum metallization pigment 75% or above AM aluminum metallization pigment 100 weight parts, at least contain binder polymer 10-1000 weight part, boiling point and be 112 ℃ or above, less than 250 ℃ a kind or more kinds of solvent 600-2000 weight parts, and ink viscosity is the printing ink of 100-2500cps (30 ℃).
2. special screen printing ink according to claim 1 wherein, contains tinting pigment and/or pearly pigment 150 weight parts or following.
3. special screen printing ink according to claim 1 and 2 wherein, contains solvent 150 weight parts of the solvent of sneaking into and/or dissolved adhesive polymkeric substance or following when making AM aluminum metallization pigment.
4. according to wantonly 1 the described special screen printing ink among the claim 1-3, wherein, as above-mentioned boiling point be 112 ℃ or more than, solvent less than 250 ℃, use is selected from ethylene glycol, glycol diacetate, the ethylene glycol bisthioglycolate butyl ether, ethylene glycol acetate, the glycol monomethyl phenyl ether, ethylene glycol monobutyl ether, the ethylene glycol monobutyl ether acetic ester, ethylene glycol mono hexyl ether, glycol monomethyl methoxymethyl ether, 1, the 3-ethohexadiol, Diethylene Glycol, Diethylene Glycol ethyl-methyl ether, the Diethylene Glycol diacetate esters, diethylene glycol diethyl ether, diethylene glycol dimethyl ether, TC, the TC acetic ester, the Diethylene Glycol single-butyl ether, Diethylene Glycol single-butyl ether acetic ester, diethylene glycol monomethyl ether, dipropylene glycol, dihydroxypropane single-ethyl ether, the dipropylene glycol single-butyl ether, DPGME, the triethylene glycol dimethyl ether, the triethylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, trimethylene, 1, the 2-butyleneglycol, 1, the 3-butyleneglycol, 1, the 4-butyleneglycol, Texacar PC, propylene glycol, propylene glycol list ethyl ether, the propylene glycol single-butyl ether, propylene glycol monomethyl ether, hexylene glycol, 1, the 5-pentanediol, in 3-methyl-3-methoxyl group-1-butanols a kind or more.
5. printed matter, it is to use wantonly 1 described screen printing ink among the claim 1-4 base material to be implemented the printed matter of printing.
6. printed matter according to claim 5, above-mentioned base material be for improve tack etc. through surface treatment transparent substrate or translucent base materials such as polyethylene terephthalate (PET), acrylic acid or the like, polycarbonate, polyetherimide.
7. printed matter, it is to use wantonly 1 the described screen printing ink among the claim 1-4, the printed matter that prints by a part of multiple mode on the printed matter that has applied original screen printing ink and coating etc.
8. according to wantonly 1 the described printed matter among the claim 5-7, wherein, be that the surface is appreciated with the opposing face of the printing surface of transparent substrate or translucent base material.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP165196/03 | 2003-06-10 | ||
| JP165196/2003 | 2003-06-10 | ||
| JP2003165196A JP3556210B1 (en) | 2003-06-10 | 2003-06-10 | Special screen ink and printed matter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1572846A true CN1572846A (en) | 2005-02-02 |
| CN100497500C CN100497500C (en) | 2009-06-10 |
Family
ID=32959732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100476974A Expired - Lifetime CN100497500C (en) | 2003-06-10 | 2004-06-09 | Special silk-screen print ink and presswork |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3556210B1 (en) |
| CN (1) | CN100497500C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102140273A (en) * | 2010-01-29 | 2011-08-03 | 周湛文 | Color mirror ink |
| CN101050324B (en) * | 2006-10-19 | 2012-08-15 | 日本精工油墨股份有限公司 | Ink and decorative printed products |
| CN108329751A (en) * | 2018-01-30 | 2018-07-27 | 深圳市美丽华科技股份有限公司 | A kind of two-component glass-mirror silver ink and preparation method thereof |
| CN108728796A (en) * | 2017-04-19 | 2018-11-02 | 蓝思科技（长沙）有限公司 | The preparation method and revision board of color gradient film |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1881042B1 (en) * | 2005-04-12 | 2009-06-24 | Teikoku Printing Inks Mfg. Co., Ltd | Ink for specular print |
| JP4323505B2 (en) * | 2006-10-18 | 2009-09-02 | 株式会社セイコーアドバンス | Screen printing ink, decorative prints and decorative resin moldings |
| JP2010029408A (en) * | 2008-07-29 | 2010-02-12 | Universal Entertainment Corp | Game machine |
| JP2009030065A (en) * | 2008-09-16 | 2009-02-12 | Seiko Advance:Kk | Ink, decorated printed matter and decorated resin molded article |
| FR2974103B1 (en) * | 2011-04-12 | 2013-04-12 | Saint Gobain | SERIGRAPIABLE COMPOSITION ON POLYVINYLBUTYRAL |
| JP5787317B2 (en) * | 2011-12-08 | 2015-09-30 | 独立行政法人 国立印刷局 | An ultraviolet curable glitter ink composition for screen printing. |
| FR2994190B1 (en) * | 2012-07-31 | 2014-08-08 | Saint Gobain | COLORED SERIGRAPIABLE COMPOSITION ON A SHEET OF POLYMERIC MATERIAL |
-
2003
- 2003-06-10 JP JP2003165196A patent/JP3556210B1/en not_active Expired - Fee Related
-
2004
- 2004-06-09 CN CNB2004100476974A patent/CN100497500C/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050324B (en) * | 2006-10-19 | 2012-08-15 | 日本精工油墨股份有限公司 | Ink and decorative printed products |
| CN102140273A (en) * | 2010-01-29 | 2011-08-03 | 周湛文 | Color mirror ink |
| CN108728796A (en) * | 2017-04-19 | 2018-11-02 | 蓝思科技（长沙）有限公司 | The preparation method and revision board of color gradient film |
| CN108329751A (en) * | 2018-01-30 | 2018-07-27 | 深圳市美丽华科技股份有限公司 | A kind of two-component glass-mirror silver ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100497500C (en) | 2009-06-10 |
| JP3556210B1 (en) | 2004-08-18 |
| JP2005002168A (en) | 2005-01-06 |
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