CN1563132A - 基于聚(ε-己内酯)的形状记忆材料及其制备和使用方法 - Google Patents
基于聚(ε-己内酯)的形状记忆材料及其制备和使用方法 Download PDFInfo
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- CN1563132A CN1563132A CN 200410010734 CN200410010734A CN1563132A CN 1563132 A CN1563132 A CN 1563132A CN 200410010734 CN200410010734 CN 200410010734 CN 200410010734 A CN200410010734 A CN 200410010734A CN 1563132 A CN1563132 A CN 1563132A
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- temperature
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- pcl
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Abstract
Description
PCL-PU | 硬段(wt%) | 熔点Tm(℃) | 结晶温度Tc(℃) | 最低恢复温度LRT(℃) |
PCL-500 | - | 19.0 | -2.9 | |
PCL-1000 | - | 45.8 | 11.2 | |
PCL1000-PU132 | 39.3 | - | ||
PCL1000-PU154 | 52.8 | - | ||
PCL1000-PU176 | 61.4 | - | ||
PCL-2000 | - | 54.3 | 20.8 | |
PCL2000-PU132 | 24.4 | 43.0 | 23 | |
PCL2000-PU154 | 35.9 | - | ||
PCL2000-PU176 | 44.3 | - | ||
PCL-2500 | - | 55.6 | ||
PCL2500-PU132 | 20.5 | 44.0 | 27 | |
PCL-3000 | - | 56.9 | ||
PCL3000-PU132 | 17.7 | 46.5 | 30 | |
PCL-3500 | - | 60.3 | 27.1 | |
PCL3500-PU132 | 15.6 | 52.3 | ||
PCL3500-PU154 | 24.2 | 51.1 | ||
PCL3500-PU176 | 31.2 | 49.4 | 37 | |
PCL-5000 | - | 62.0 | 27.9 | |
PCL5000-PU132 | 11.4 | 55.5 | -1.1 | |
PCL5000-PU154 | 18.3 | 54.5 | - | |
PCL5000-PU176 | 24.1 | 52.2 | - | |
PCL-8000 | - | 62.8 | 36.7 | |
PCL8000-PU132 | 7.5 | 56.9 | 16.8 | |
PCL8000-PU154 | 12.3 | 57.9 | 11.7 | |
PCL8000-PU176 | 16.6 | 56.4 | -0.4 | 45 |
PCL-10000 | - | 61.7 | 26.3 | |
PCL10000-PU132 | 6.1 | 57.9 | 20.7 | |
PCL10000-PU154 | 10.1 | 58.8 | 19.6 | |
PCL10000-PU176 | 13.7 | 58.1 | 19.4 | 48 |
Claims (7)
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CN 200410010734 CN1279077C (zh) | 2004-03-19 | 2004-03-19 | 基于聚(ε-己内酯)的形状记忆材料及其制备和使用方法 |
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CN 200410010734 CN1279077C (zh) | 2004-03-19 | 2004-03-19 | 基于聚(ε-己内酯)的形状记忆材料及其制备和使用方法 |
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CN1563132A true CN1563132A (zh) | 2005-01-12 |
CN1279077C CN1279077C (zh) | 2006-10-11 |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1324174C (zh) * | 2004-06-09 | 2007-07-04 | 香港理工大学 | 一种由形状记忆聚氨酯制备的形状记忆纤维及其制备方法 |
CN101443383B (zh) * | 2006-05-15 | 2011-04-20 | Gkss研究中心盖斯特哈赫特有限公司 | 具有形状记忆性能的多嵌段共聚物 |
CN101496758B (zh) * | 2008-12-08 | 2011-04-27 | 中国人民解放军第三军医大学 | 实现避孕的形状记忆输卵管避孕装置 |
CN105820301A (zh) * | 2016-04-22 | 2016-08-03 | 哈尔滨工业大学 | 形状记忆聚合物塑料钱币基片的制作方法 |
WO2017012560A1 (zh) * | 2015-07-23 | 2017-01-26 | 浙江大学 | 基于酯交换的可塑性形状记忆聚合物的应用方法 |
CN107033304A (zh) * | 2017-05-09 | 2017-08-11 | 东南大学 | 具有可自修复功能的形状记忆嵌段热塑性高分子材料 |
CN108264623A (zh) * | 2018-01-23 | 2018-07-10 | 中国科学院长春应用化学研究所 | 一种聚酯型聚氨酯形状记忆材料及其制备方法 |
CN108976383A (zh) * | 2018-06-27 | 2018-12-11 | 西北民族大学 | 一种医用高分子夹板 |
CN109880054A (zh) * | 2019-03-29 | 2019-06-14 | 中国科学院宁波材料技术与工程研究所 | 具有形状记忆功能的聚氨酯及其制备方法 |
CN110041503A (zh) * | 2019-04-02 | 2019-07-23 | 镇江利德尔复合材料有限公司 | 一种可用于仿生4d打印的新型形状记忆聚氨酯材料 |
CN110982037A (zh) * | 2019-12-26 | 2020-04-10 | 郑州大学 | 体温响应形状记忆聚氨酯材料及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101906472B1 (ko) | 2017-04-04 | 2018-10-10 | 연세대학교 산학협력단 | 광가교가 가능한 형상기억고분자 및 이의 제조방법 |
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2004
- 2004-03-19 CN CN 200410010734 patent/CN1279077C/zh not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1324174C (zh) * | 2004-06-09 | 2007-07-04 | 香港理工大学 | 一种由形状记忆聚氨酯制备的形状记忆纤维及其制备方法 |
CN101443383B (zh) * | 2006-05-15 | 2011-04-20 | Gkss研究中心盖斯特哈赫特有限公司 | 具有形状记忆性能的多嵌段共聚物 |
CN101496758B (zh) * | 2008-12-08 | 2011-04-27 | 中国人民解放军第三军医大学 | 实现避孕的形状记忆输卵管避孕装置 |
WO2017012560A1 (zh) * | 2015-07-23 | 2017-01-26 | 浙江大学 | 基于酯交换的可塑性形状记忆聚合物的应用方法 |
US10449709B2 (en) | 2015-07-23 | 2019-10-22 | Zhejiang University | Fabrication and application of shape memory polymer possessing transesterification induced permanent reshaping property |
CN105820301A (zh) * | 2016-04-22 | 2016-08-03 | 哈尔滨工业大学 | 形状记忆聚合物塑料钱币基片的制作方法 |
CN107033304A (zh) * | 2017-05-09 | 2017-08-11 | 东南大学 | 具有可自修复功能的形状记忆嵌段热塑性高分子材料 |
CN108264623A (zh) * | 2018-01-23 | 2018-07-10 | 中国科学院长春应用化学研究所 | 一种聚酯型聚氨酯形状记忆材料及其制备方法 |
CN108976383A (zh) * | 2018-06-27 | 2018-12-11 | 西北民族大学 | 一种医用高分子夹板 |
CN109880054A (zh) * | 2019-03-29 | 2019-06-14 | 中国科学院宁波材料技术与工程研究所 | 具有形状记忆功能的聚氨酯及其制备方法 |
CN110041503A (zh) * | 2019-04-02 | 2019-07-23 | 镇江利德尔复合材料有限公司 | 一种可用于仿生4d打印的新型形状记忆聚氨酯材料 |
CN110982037A (zh) * | 2019-12-26 | 2020-04-10 | 郑州大学 | 体温响应形状记忆聚氨酯材料及其制备方法 |
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CN1279077C (zh) | 2006-10-11 |
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