CN1559444A - Oral liquid contg. extration of sturgeon and sturgeon active protein capsule, prepn. method therefor - Google Patents
Oral liquid contg. extration of sturgeon and sturgeon active protein capsule, prepn. method therefor Download PDFInfo
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- CN1559444A CN1559444A CNA2004100127954A CN200410012795A CN1559444A CN 1559444 A CN1559444 A CN 1559444A CN A2004100127954 A CNA2004100127954 A CN A2004100127954A CN 200410012795 A CN200410012795 A CN 200410012795A CN 1559444 A CN1559444 A CN 1559444A
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- acipenser sinensis
- sturgeon
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- oral liquid
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- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 25
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 25
- 241000881711 Acipenser sturio Species 0.000 title claims abstract description 24
- 239000007788 liquid Substances 0.000 title claims abstract description 19
- 239000002775 capsule Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 3
- 239000006228 supernatant Substances 0.000 claims abstract description 16
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 238000001291 vacuum drying Methods 0.000 claims abstract description 5
- 241000883303 Acipenser sinensis Species 0.000 claims description 54
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 30
- 239000002244 precipitate Substances 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002671 adjuvant Substances 0.000 claims description 8
- 239000011265 semifinished product Substances 0.000 claims description 8
- 102000057297 Pepsin A Human genes 0.000 claims description 6
- 108090000284 Pepsin A Proteins 0.000 claims description 6
- 102000004142 Trypsin Human genes 0.000 claims description 6
- 108090000631 Trypsin Proteins 0.000 claims description 6
- 235000011194 food seasoning agent Nutrition 0.000 claims description 6
- 229940111202 pepsin Drugs 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000012588 trypsin Substances 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 claims description 4
- 241000195474 Sargassum Species 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 239000000796 flavoring agent Substances 0.000 claims description 4
- 235000013373 food additive Nutrition 0.000 claims description 4
- 239000002778 food additive Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002386 leaching Methods 0.000 claims description 4
- 229940043353 maltol Drugs 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000003531 protein hydrolysate Substances 0.000 claims description 4
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 4
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims description 4
- 235000012141 vanillin Nutrition 0.000 claims description 4
- 229920000388 Polyphosphate Polymers 0.000 claims description 2
- 235000013355 food flavoring agent Nutrition 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 abstract description 3
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000001502 supplementing effect Effects 0.000 abstract 1
- 235000018102 proteins Nutrition 0.000 description 16
- 235000013305 food Nutrition 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229940088598 enzyme Drugs 0.000 description 4
- 239000002994 raw material Substances 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 235000019449 other food additives Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000252335 Acipenser Species 0.000 description 1
- 241000252344 Acipenser gueldenstaedtii Species 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 241000556189 Huso Species 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000002980 postoperative effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
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- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
An oral liquid of sturgeon extract and an active protein capsule for improving intelligence andendurance, delaying sanility and supplementing protein to patient are prepared from sturgeon through enzymolyzing, filtering to obtain supernatant and deposit, flavouring the supernatant to obtain said oral liquid, freezing said deposit, deodoring, defatting, dissolving, neutralizing, filter, concentating, vacuum drying, pulverizing to obtain said active protein powder, and loading in capsules.
Description
Technical field
The invention belongs to field of food, being specifically related to a kind of is the protein food and preparation method thereof of primary raw material with the Acipenser Sinensis.
Background technology
Acipenser Sinensis has another name called the sturgeon dragon, have the good reputation of " soft gold, living fossil ", is ancient, the most rare in the world Fish, and its life-span reaches 150-250, and body weight can reach more than 1000 kilograms.The principal item of Acipenser Sinensis has sturgeon sturgeon classes such as acipenser schrencki, Siberia sturgeon, Acipenser gueldenstaedti Brandt, Da Shi huso sturgeon.In recent years, gorge, sky, Yichang City, Hubei Province sturgeon industry company limited has been broken through Acipenser Sinensis whole artificial propagation seed and has been closed, for the large-scale cultivation of Acipenser Sinensis has been established material guarantee.200,000 hectares Three Gorges Reservoir group natural environmental condition is superior, is fit to the breed of Acipenser Sinensis.Reservoir area intensification net cage is supported the fast development of sturgeon industry, and " company+base+peasant household " industrialization management pattern can furnish ample material for the dark polish of Acipenser Sinensis endlessly.The development of Acipenser Sinensis processing industry can be converted into resources advantage huge economic advantages, is the shortcut of realizing that regional economy rapid development, relocation of people from reservoir areas are got rich and striven for a relatively comfortable life.
Show according to Chinese invention patent document Investigation data: the at present domestic report that yet there are no preparation Acipenser Sinensis protein food.
Summary of the invention
The object of the present invention is to provide a kind of is that primary raw material contains the sturgeon essence oral liquid of high protein and activated protein capsule and preparation method thereof with the Acipenser Sinensis.
To achieve these goals, technical scheme of the present invention is: sturgeon essence oral liquid and activated protein capsule, it is characterized in that: rotten 1 part of Acipenser Sinensis, water be the rotten weight of Acipenser Sinensis 1-2 doubly, trypsin is that 1%-2%, the 4molNaOH of the rotten weight of Acipenser Sinensis is that 1-2%, the pepsin of the rotten weight of Acipenser Sinensis is that 2-2.5%, the acetic acid of the rotten weight of Acipenser Sinensis is the 5-10% of the rotten weight of Acipenser Sinensis, gets supernatant and precipitate through enzymolysis, centrifugal or fine straining; Getting supernatant adds appropriate amount of auxiliary materials seasoning preparation and is sturgeon essence oral liquid, the treated capsule that is processed into of precipitate.
The capsular preparation method of sturgeon essence oral liquid and activated protein is characterized in that being realized by following steps:
1), Acipenser Sinensis through dissect, clear water is cleaned, smash into the Acipenser Sinensis gruel to pieces pours in the reactor, add and account for the rotten gross weight 1-2 of Acipenser Sinensis water doubly, add the trypsin that accounts for the rotten gross weight 1%-2% of Acipenser Sinensis again, regulate pH value to 7-9 with 4mol NaOH, temperature control 40-60 ℃, stir hydrolysis 2-3 hour, reuse accounts for the pepsin of the rotten gross weight 2-2.5% of Acipenser Sinensis, add the acetic acid that accounts for the rotten gross weight 5-10% of Acipenser Sinensis and regulate PH3-5, temperature control 30-45 ℃, hydrolysis 1-2 hour; Acipenser Sinensis gruel this moment hydrolysis is finished, and is warmed up to 80-100 ℃, is incubated 10-20 minute, makes enzyme deactivation; Discard filtering residue (making feedstuff) through coarse filtration (14 order), must be than the dun Acipenser Sinensis protein hydrolyzate of thickness.
2), the Acipenser Sinensis protein hydrolyzate through high speed centrifuge centrifugal or fine straining (more than 100 orders) supernatant and precipitate (can make active protein powder), get supernatant and add adjuvant seasoning preparation and be sturgeon essence oral liquid, adjuvant is sweeting agent, food additive.
3), precipitate behind centrifugal filtration or the fine straining contains the not nutrient substance such as activated protein of complete hydrolysis, after-10 ℃ of freezers freeze 15-20 hour, reagent concentration with precipitate equivalent is the smart Rong Ye of a 5-10% ethyl acetate Jiu rotation stream eliminating sargassum smell, the ether reagent defat that reuse precipitate 2-3 doubly measures promptly gets semi-finished product, after semi-finished product are added precipitate gross weight 6-8 and doubly measure the NaOH solution heating dissolving in 1 hour that concentration is 1-2%, with concentration is that the acetic acid of 5-10% is neutralized to PH7, cross leaching filtrate concentrating, vacuum drying promptly gets the Acipenser Sinensis active protein powder, with this powder routinely processes become capsule or electuary.
Above-mentioned adjuvant is that every 1000ml supernatant adds the 80-100g white sugar and makes sweeting agent, and also available 20-40g white sugar adds the combination of 1-2% protein sugar, or novel sweetener such as aspartame; Other adds food additive, and 2-4g polyphosphate, the different basic maltol of 30-60ppm, 20-30g beta-schardinger dextrin-and an amount of vanillin or other flavouring agent etc. are arranged.
The present invention is to be raw material with the Acipenser Sinensis, adopts above-mentioned preparation technology, is equipped with refining sturgeon essence oral liquid and the Acipenser Sinensis activated protein capsule of forming of adjuvant.It is a kind ofly collect nourishing, health care, treatment is the fully natural green treasure of one.The present invention uses modern compound enzyme engineering and protein molecule improving technology, forms with its advanced technologies, scientific formula refine.It can not only keep inherent nutritional labeling of Acipenser Sinensis and various bioactive substance, comprehensive nutrition and abundant, and wound healing, the tonify deficiency QI invigorating of promotion arranged, improve immunity, control remarkable efficacy such as stranguria with blood; Improve intelligence, appetite stimulator in addition, the effect of building body, endurance, defying age, qi and blood tonifying, skin moist.Especially postoperative rehabilitation, tumor, the cancer patient of surgical patient replenished the specific function food of animal protein source, aminoacid, trace element and vitamin.It satisfies people's gourmandism " nature, healthy, easily, high-grade " food fashion.
The specific embodiment
Embodiment 1: Acipenser Sinensis through dissect, clear water is cleaned, smash into the Acipenser Sinensis gruel to pieces, getting the gruel of 1000g Acipenser Sinensis pours in the reactor, add 1000g water mixed after, add the 10g trypsin, stir to 7-9 with the 4molNaOH adjustment pH value of the rotten weight 1-2% of Acipenser Sinensis, 50 ℃ of temperature controls, stirring reaction 3 hours, reuse 25g pepsin adds 100g acetic acid and regulates PH3,30 ℃ of temperature controls, hydrolysis 2 hours.Be warmed up to 100 ℃ again, be incubated 10 minutes and kill enzyme, get fish albumen hydrolysis solution through 14 mesh sieve coarse filtration.This liquid gets supernatant and precipitate through centrifugal (8000 rev/mins) again.Get supernatant 1000ml with white sugar 20g, protein sugar 2g, and other food additive,, promptly get sturgeon essence oral liquid as adjuvant seasonings such as sodium tripolyphosphate 2-4g, different basic maltol 30-60ppm, beta-schardinger dextrin-20-30g, vanillin 0.3g preparation.
Precipitate after centrifugal through-10 ℃ freeze 20h after, be that 5% the smart Rong Ye of ethyl acetate Jiu rotation stream eliminating sargassum smell is smelly with the concentration of precipitate equivalent, till can hearing stench the flavor, the ether reagent defat that reuse precipitate 2-3 doubly measures promptly gets semi-finished product.After semi-finished product are added 8 times of precipitate amount concentration and be 2% NaOH solution heating dissolving in 1 hour, be that 10% acetic acid is neutralized to PH7 with concentration, cross leaching filtrate concentrating, vacuum drying, pulverizing promptly get the Acipenser Sinensis active protein powder.Can be made into capsule or electuary with this powder.
Embodiment 2: Acipenser Sinensis through dissect, clear water is cleaned, smash into the Acipenser Sinensis gruel to pieces, getting 1000 gram Acipenser Sinensis gruels pours in the reactor, add 2000 gram water mixed after, add 20 gram trypsin, stir to 7-9 with the 4molNaOH adjustment pH value of the rotten weight 1-2% of Acipenser Sinensis, 60 ℃ of temperature controls, stirring reaction 2 hours, reuse 10 gram pepsin add 50 gram acetic acid and regulate PH5,45 ℃ of temperature controls, hydrolysis 1 hour.Be warmed up to 80 ℃ again, be incubated 20 minutes and kill enzyme, get fish albumen hydrolysis solution through 14 mesh sieve coarse filtration.This liquid through fine straining (100-200 order) filter supernatant and precipitate.Get supernatant 1000ml and restrain, reach other food additive,, promptly get sturgeon essence oral liquid as adjuvant seasonings such as sodium tripolyphosphate 2-4g, different basic maltol 30-60ppm, beta-schardinger dextrin-20-30g, vanillin 0.3 gram preparation with white sugar 80.
Precipitate after centrifugal through-10 ℃ freeze 15h after, be that the smart Rong Ye of 10% ethyl acetate Jiu rotation stream eliminating sargassum smell is smelly with the concentration of precipitate equivalent, till can hearing stench the flavor, the ether reagent defat that reuse precipitate 2-3 doubly measures promptly gets semi-finished product.After semi-finished product are added 6 times of precipitate amount concentration and be 1% NaOH solution heating dissolving in 1 hour, be that 5% acetic acid is neutralized to PH7 with concentration, cross leaching filtrate concentrating, vacuum drying, pulverizing promptly get the Acipenser Sinensis active protein powder.Can be made into capsule or electuary with this powder.
Claims (3)
1. sturgeon essence oral liquid and activated protein capsule, it is characterized in that: rotten 1 part of Acipenser Sinensis, water be the rotten weight of Acipenser Sinensis 1-2 doubly, trypsin is that 1%-2%, the 4molNaOH of the rotten weight of Acipenser Sinensis is that 1-2%, the pepsin of the rotten weight of Acipenser Sinensis is that 2-2.5%, the acetic acid of the rotten weight of Acipenser Sinensis is the 5-10% of the rotten weight of Acipenser Sinensis, gets supernatant and precipitate through enzymolysis, centrifugal or fine straining; Getting supernatant adds appropriate amount of auxiliary materials seasoning preparation and is sturgeon essence oral liquid, the treated capsule that is processed into of precipitate.
2. the capsular preparation method of sturgeon essence oral liquid and activated protein is characterized in that being realized by following steps:
1), Acipenser Sinensis through dissect, clear water is cleaned, smash into the Acipenser Sinensis gruel to pieces pours in the reactor, add and account for the rotten gross weight 1-2 of Acipenser Sinensis water doubly, add the trypsin that accounts for the rotten gross weight 1%-2% of Acipenser Sinensis again, regulate pH value to 7-9 with 4molNaOH, temperature control 40-60 ℃, stir hydrolysis 2-3 hour, reuse accounts for the pepsin of the rotten gross weight 2-2.5% of Acipenser Sinensis, add the acetic acid that accounts for the rotten gross weight 5-10% of Acipenser Sinensis and regulate PH3-5, temperature control 30-45 ℃, hydrolysis 1-2 hour; Be warmed up to 80-100 ℃, be incubated 10-20 minute, discard filtering residue through coarse filtration, must be than the dun Acipenser Sinensis protein hydrolyzate of thickness;
2), centrifugal or fine straining gets supernatant and precipitate to the Acipenser Sinensis protein hydrolyzate through high speed centrifuge, gets supernatant and adds adjuvant seasoning preparation and be sturgeon essence oral liquid, is sweeting agent, food additive;
3), the precipitate behind centrifugal filtration or the fine straining is after-10 ℃ of freezers freeze 15-20 hour, concentration with precipitate equivalent is the smart Rong Ye of 5-10% ethyl acetate Jiu rotation stream eliminating sargassum smell, the ether reagent defat that reuse precipitate 2-3 doubly measures promptly gets semi-finished product, after semi-finished product are added precipitate gross weight 6-8 and doubly measure the NaOH solution heating dissolving in 1 hour that concentration is 1-2%, with concentration is that the acetic acid of 5-10% is neutralized to PH7, cross that leaching filtrate concentrates, vacuum drying promptly gets the Acipenser Sinensis active protein powder, processes becomes capsule routinely again.
3. sturgeon essence oral liquid according to claim 2 and the capsular preparation method of activated protein, it is characterized in that described adjuvant is sweeting agent and food additive, its proportioning is: the supernatant of every 1000ml adds protein sugar 1-2g, white sugar 20-40g, polyphosphate 2-4g, and different basic maltol 30-60PPm, beta-schardinger dextrin-20-30g, vanillin or other flavouring agent are an amount of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100127954A CN1245214C (en) | 2004-03-01 | 2004-03-01 | Oral liquid contg. extration of sturgeon and sturgeon active protein capsule, prepn. method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100127954A CN1245214C (en) | 2004-03-01 | 2004-03-01 | Oral liquid contg. extration of sturgeon and sturgeon active protein capsule, prepn. method therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1559444A true CN1559444A (en) | 2005-01-05 |
| CN1245214C CN1245214C (en) | 2006-03-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100127954A Expired - Fee Related CN1245214C (en) | 2004-03-01 | 2004-03-01 | Oral liquid contg. extration of sturgeon and sturgeon active protein capsule, prepn. method therefor |
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| Country | Link |
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| CN (1) | CN1245214C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105192701A (en) * | 2015-10-19 | 2015-12-30 | 宜都宏济科技有限公司 | Sturgeon compound preparation and preparation process thereof |
| CN107467674A (en) * | 2017-06-22 | 2017-12-15 | 乐清瑞耀食品技术有限公司 | Compound based on duckbilled fish active peptides |
-
2004
- 2004-03-01 CN CNB2004100127954A patent/CN1245214C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105192701A (en) * | 2015-10-19 | 2015-12-30 | 宜都宏济科技有限公司 | Sturgeon compound preparation and preparation process thereof |
| CN107467674A (en) * | 2017-06-22 | 2017-12-15 | 乐清瑞耀食品技术有限公司 | Compound based on duckbilled fish active peptides |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1245214C (en) | 2006-03-15 |
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