CN1544499A - Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof - Google Patents
Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof Download PDFInfo
- Publication number
- CN1544499A CN1544499A CNA2003101063137A CN200310106313A CN1544499A CN 1544499 A CN1544499 A CN 1544499A CN A2003101063137 A CNA2003101063137 A CN A2003101063137A CN 200310106313 A CN200310106313 A CN 200310106313A CN 1544499 A CN1544499 A CN 1544499A
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- Prior art keywords
- water dispersion
- initiator
- copolymerization
- water
- acrylic ester
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Material name | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 |
Polyether glycol N330 N210 | ??72.36 ??- | ??33.5 ??- | ??72.36 ??- | ??72.36 ??- | ??72.36 ??- | ??- ??39.41 |
Carboxylic polyvalent alcohol DMPA | ??7.00 | ??3.80 | ??7.00 | ??7.00 | ??7.00 | ??4.20 |
Polyisocyanates TDI | ??20.00 | ??14.25 | ??20.00 | ??20.00 | ??20.00 | ??24.00 |
Crylic acid hydroxy ester class HEMA HPA | ??6.89 ??- | ??9.55 ??- | ??6.89 ??- | ??6.89 ??- | ??- ??6.89 | ??14.77 ??- |
Neutralizing agent TEA | ??4.48 | ??2.43 | ??4.48 | ??4.48 | ??4.48 | ??2.57 |
Solvent NMP | ??32.00 | ??17.60 | ??32.00 | ??32.00 | ??32.00 | ??11.60 |
-NCO/-OH equivalence ratio | ??1.30 | ??1.82 | ??1.30 | ??1.30 | ??1.30 | ??1.95 |
Degree of neutralization, % | ??85 | ??85 | ??85 | ??85 | ??85 | ??81.18 |
Material name | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 |
Polyether polyurethane prepolymer | ??110.69 ??(82.03) | ??63.44 ??(88.05) | ??110.69 ??(82.03) | ??110.73 ??(82.07) | ??110.69 ??(82.03) | ??84.45 ??(91.02) |
Acrylic ester monomer MMA | ??22.40 ??(16.60) | ??8.00 ??(11.10) | ??11.20 ??(8.30) | ??22.40 ??(16.60) | ??22.40 ??(16.60) | ??7.58 ??(8.17) |
??St | ??- | ??- | ??11.20 ??(8.30) | ??- | ??- | ??- |
The organosilane monomer KH570 A151 that contains unsaturated double-bond | ??0.23 ??(0.17) | ???- ??0.10 ??(0.14) | ??0.23 ??(0.17) | ??0.23 ??(0.17) | ??0.23 ??(0.17) | ??0.23 ??(0.25) |
Oil-soluble initiator AIBN BPO | ??0.96 ??(0.71) | ??0.11 ??(0.15) | ??0.96 ??(0.71) | ??- ??0.91 ??(0.67) | ??0.96 ??(0.71) | ??0.04 ??(0.04) |
The chain-transfer agent lauryl mercaptan | ??0.66 ??(0.49) | ??0.40 ??(0.56) | ??0.66 ??(0.49) | ??0.66 ??(0.49) | ??0.66 ??(0.49) | ??0.48 ??(0.52) |
Water | ??272.26 | ??146.00 | ??272.26 | ??272.26 | ??272.26 | ??192.18 |
The shared percentage ratio of water in water dispersion, % | ??66.86 | ??66.96 | ??66.86 | ??66.85 | ??66.86 | ??67.44 |
The shared percentage ratio of solid part in water dispersion, % | ??33.14 | ??33.04 | ??33.14 | ??33.15 | ??33.14 | ??32.56 |
Test item | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 |
Time of drying surface drying, min≤do solid work, h≤ | ?32 ?4 | ?45 ?3.5 | ?48 ?4.5 | ?50 ?5.0 | ?36 ?4.5 | ?28 ?6.0 |
Sticking power, level | ?2 | ?1 | ?1 | ?1 | ?1 | ?2 |
Hardness | ?0.495 | ?0.489 | ?0.475 | ?0.478 | ?0.502 | ?0.546 |
Snappiness, mm | ?1 | ?1 | ?1 | ?1 | ?1 | ?1 |
Water tolerance, d 〉= | ?10 | ?15 | ?10 | ?10 | ?10 | ?5 |
Gloss, 60 ° of % | ?87 | ?88 | ?90 | ?88 | ?87 | ?86 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200310106313 CN1257199C (en) | 2003-11-13 | 2003-11-13 | Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200310106313 CN1257199C (en) | 2003-11-13 | 2003-11-13 | Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN1544499A true CN1544499A (en) | 2004-11-10 |
CN1257199C CN1257199C (en) | 2006-05-24 |
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Application Number | Title | Priority Date | Filing Date |
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CN 200310106313 Expired - Fee Related CN1257199C (en) | 2003-11-13 | 2003-11-13 | Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof |
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CN (1) | CN1257199C (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100351289C (en) * | 2005-07-13 | 2007-11-28 | 安徽大学 | Radiation polymerization method for aqueous polyurethane-siliceous acrylic resin fabric coating |
CN102010558A (en) * | 2010-10-11 | 2011-04-13 | 中国海洋石油总公司 | Acrylic acid non-aqueous dispersoid containing amino ester bonds and siloxy groups and preparation method thereof |
CN103467667A (en) * | 2013-09-10 | 2013-12-25 | 合肥乐凯科技产业有限公司 | Acrylate modified polyurethane emulsion and preparation method thereof |
CN105199051A (en) * | 2015-11-02 | 2015-12-30 | 宋介珍 | Transparent organosilicon material and preparation method thereof |
-
2003
- 2003-11-13 CN CN 200310106313 patent/CN1257199C/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100351289C (en) * | 2005-07-13 | 2007-11-28 | 安徽大学 | Radiation polymerization method for aqueous polyurethane-siliceous acrylic resin fabric coating |
CN102010558A (en) * | 2010-10-11 | 2011-04-13 | 中国海洋石油总公司 | Acrylic acid non-aqueous dispersoid containing amino ester bonds and siloxy groups and preparation method thereof |
CN102010558B (en) * | 2010-10-11 | 2012-07-04 | 中国海洋石油总公司 | Acrylic acid non-aqueous dispersoid containing amino ester bonds and siloxy groups and preparation method thereof |
CN103467667A (en) * | 2013-09-10 | 2013-12-25 | 合肥乐凯科技产业有限公司 | Acrylate modified polyurethane emulsion and preparation method thereof |
CN103467667B (en) * | 2013-09-10 | 2017-01-11 | 合肥乐凯科技产业有限公司 | Acrylate modified polyurethane emulsion and preparation method thereof |
CN105199051A (en) * | 2015-11-02 | 2015-12-30 | 宋介珍 | Transparent organosilicon material and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN1257199C (en) | 2006-05-24 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Anhui Province Jindun Paint Co., Ltd. Assignor: Changzhou Inst of Paint Chemical, Chinese Chemical Building Corp. Contract fulfillment period: 2008.10.16 to 2013.10.16 contract change Contract record no.: 2009340000146 Denomination of invention: Acrylic ester organic silicon composite modified polyether polyurethane aqueous dispersion and preparation method thereof Granted publication date: 20060524 License type: Exclusive license Record date: 2009.7.31 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.10.16 TO 2013.10.16; CHANGE OF CONTRACT Name of requester: ANHUI PROVINCE JINDUN COATING LIMITED LIABILITY CO Effective date: 20090731 |
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EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Anhui Province Jindun Paint Co., Ltd. Assignor: Changzhou Inst of Paint Chemical, Chinese Chemical Building Corp. Contract record no.: 2009340000146 Date of cancellation: 20110325 |
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Owner name: CNOOC CHANGZHOU PAINT + COATINGS INDUSTRY RESEARCH Free format text: FORMER OWNER: CHANGZHOU INST OF PAINT CHEMICAL, CHINESE CHEMICAL BUILDING CORP. Effective date: 20120910 |
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Effective date of registration: 20120910 Address after: 213016 Changzhou Zhong Road, Jiangsu Province, No. 22 Longjiang Road Patentee after: CNOOC Changzhou Paint & Coatings Industry Research Institute Address before: 213016, Jiangsu, Changzhou Province West Ring Road North intersection Patentee before: Changzhou Inst of Paint Chemical, Chinese Chemical Building Corp. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060524 Termination date: 20141113 |
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