CN1541550A - Mineral iodine and selenium feed addictive - Google Patents

Mineral iodine and selenium feed addictive Download PDF

Info

Publication number
CN1541550A
CN1541550A CNA2003101050245A CN200310105024A CN1541550A CN 1541550 A CN1541550 A CN 1541550A CN A2003101050245 A CNA2003101050245 A CN A2003101050245A CN 200310105024 A CN200310105024 A CN 200310105024A CN 1541550 A CN1541550 A CN 1541550A
Authority
CN
China
Prior art keywords
feed
egg
mineral matter
feldspar
calcite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2003101050245A
Other languages
Chinese (zh)
Other versions
CN1218658C (en
Inventor
焦宝连
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNB2003101050245A priority Critical patent/CN1218658C/en
Publication of CN1541550A publication Critical patent/CN1541550A/en
Application granted granted Critical
Publication of CN1218658C publication Critical patent/CN1218658C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Fodder In General (AREA)
  • Feed For Specific Animals (AREA)

Abstract

The present invention is one kind of feed additive containing iodine, selenium and other mineral elements and no hormone, pigment and other harmful components. The additive can raise the disease resistance of farm animal and raise the yield of eggs and the quality of animal meat. It is produced with attapulgite, kaolin, calcite, zeolite and feldspar and through crushing to 30-60 mesh and mixing. It has simple production process, easy use, low cost and wide application range.

Description

The mineral matter iodine selenium multi-element feed supplement
Affiliated technical field
The invention belongs to technical field of feed additives, relate in particular to and a kind ofly be applicable to fowl, poultry, and contain a kind of mineral matter iodine selenium multi-element feed supplement the mineral matter of human body beneficial's various trace elements.
Background technology
At present, the various trace elements of contained needed by human body are few in fowl such as the egg of being sold in the market, egg meat, duck's egg, duck and pork, the poultry meat egg at home, the minority raiser is wherein also arranged in order to improve the nutritive value of birds, beasts and eggs, and the trace element of 1-2 kind needed by human body is added in the feed, as sodium selenate is dissolved in the drinking-water, cultivate " selenium rich of egg "; Iodine or sea-tangle are added in the feed, cultivate " iodine-enriched egg "; Even have the people that pimiento is added in the feed, cultivate what is called " reddish yellow nutrition egg " or the like.Can make relatively like this that contained trace element increases to some extent in fowl, the poultry meat egg, but this way can not improve the nutritive value of birds, beasts and eggs and meat.Therefore still can't satisfy the content of normal daily required various trace elements of human body and nutrition.
As chicken feed of the prior art, because egg and chicken are indispensable nutrition ticbits during people live, at present, because the develop rapidly of extensive cage bird industry, the output surge of egg can be satisfied people's living needs fully.But, because lack a lot of beneficial elements in the artificial feed prepared, thereby cause the nutritive value of egg and meat to reduce, mouthfeel is dull, no longer is the nutraceutical of favoring.Because formulating in China has forage health standard, so the product of each feed-processing plant is similar, an existing tame enterprise that produces 100000 tons of feeds per year with Shenyang is an example, the chicken concentrated feed that its is produced, the kind of macroelement and content (%) Ca 6-12Total P0.8, salt (us cl 39) 0.4~1.6, trace element (mg/kg), Cu 〉=15, Zn 〉=120, Mn 〉=75, Fe 〉=120 contain few like this beneficial element in the feed, be understood that the egg reasons for quality decrease; For improving the quality of egg, a lot of raisers recover " raising scattered " again, yet owing to feed does not change, so the quality of egg still can't be improved.
The necessary for human body nutrient, through Primary Study just have 20 surplus kind, contain so feed addictive of multielement, also can't manually synthesize at present, moreover the market price can not carry too high, otherwise common people can not accept.
Summary of the invention
At the technical problem of above-mentioned existence, the invention provides a kind of iodine selenium multi-element feed supplement that the multiple mineral matter that contains multielements such as iodine selenium is made that contains.It has solved in the past that feed can't be added into enough various trace elements, thereby makes contained trace element in the fowl poultry meat egg be not enough to satisfy the problem of human body average demand; And it does not contain hormone, pigment and oxious component, can also strengthen the resistance against diseases of fowl poultry, improves the quality of birds, beasts and eggs output and fowl poultry meat.
The present invention is achieved in that
A, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=(20~90): (5~20): (5~15): (5~15): (1~5).
The preparation method of B, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=(20~90): (5~20): (5~15): (5~15): (1~5);
Its preparation method is:
Choose attapulgite, Gao Cen, calcite, zeolite and feldspar by the above-mentioned raw materials weight ratio, be crushed to 30 orders-60 order then, fully stir, mix, promptly.
C, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=50: 20: 10: 15: 5;
The preparation method of D, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
It is made of by weight following raw material:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=50: 20: 10: 15: 5;
Its preparation method is:
Choose attapulgite, Gao Cen, calcite, zeolite and feldspar by the above-mentioned raw materials weight ratio, be crushed to 50 orders then, fully stir, mix, promptly.
E, described mineral matter iodine selenium multi-element feed supplement is characterized in that and can directly it be added in the feed that the weight ratio of its interpolation is: 4%~8%.
The invention has the beneficial effects as follows:
1, do not contain hormone, pigment and any oxious component.
2, can strengthen the resistance against diseases of fowl poultry, make its not apocleisis, and increase birds, beasts and eggs output, make the yolk projection, the egg white thickness, egg size can increase 8%--10%, and the tenderer aquatic foods of meat are good to eat, are rich in multiple nutrients again.
3, human body is being taken after the birds, beasts and eggs that this feed addictive is raised are " rich iodine selenium multi-element egg " and fowl poultry meat, and the people knows from experience the natural sufficient beneficial element that replenishes, thus the generation of minimizing disease, and physique also is enhanced.
4, because the present invention is synthetic by natural mineral matter, therefore cheap, with birds, beasts and eggs and fowl neat of animal product that it is cultivated, its price also can be corresponding cheap, and people can be accepted fully.
5, solved the bird of raising in cages on a large scale, thus the problem that poultry egg matter and meat are descended.
Advantage of the present invention is: draw materials easily, using method is easy, safe and reliable, and production technology is simple, invest little, instant effect, the output height, cost is low, and is applied widely, has vast market prospect and considerable social benefit and economic benefit.
The specific embodiment
Be the experiment of carrying out at the present invention below:
Experiment one, this feed addictive is added on contrast experiment in the chicken feed
The present invention can be used as chicken feed addictive, is example with the laying hen, and purpose is to cultivate laying hen to produce " rich iodine selenium multi-element egg ".
(1), process of the test
1, optional 800 laying hens in the chicken farm are divided four row's cages, 200 in every cage.
2, the chicken feed is common commercially available chicken feed, does not wherein contain hormone, pigment and micro-inorganic salts; Average every laying hen needs feeding chicken feed 100 ± 20 to restrain every day.
3, the first cage chicken: in the feed of feeding, add 2% mineral matter iodine selenium multi-element feed supplement, i.e. 2 grams.
The second cage chicken: in the feed of feeding, add 5% mineral matter iodine selenium multi-element feed supplement, i.e. 5 grams.
The 3rd cage chicken: in the feed of feeding, add 7% mineral matter iodine selenium multi-element feed supplement, i.e. 7 grams.
The 4th cage chicken: in the feed of feeding, add 10% mineral matter iodine selenium multi-element feed supplement, i.e. 10 grams.
4, feeding time: equal three times on the one average feedings routinely.
5, test period: 40 days.
(2), experimental observation and test item:
The overall process of sending the special messenger to be responsible for testing, tracing observation:
1, appetite of chicken and state have no change.
2, the variation of egg comprises eggshell, egg white, yolk and egg size.
3, the mouthfeel of ripe egg.
4, the variation of chicken manure.
5, get the egg sample in per 10 days and carry out chemical analysis.
(3), result of the test:
After testing, in " the rich iodine selenium multi-element egg " of above-mentioned four cage laying hen outputs, the amount of the trace element that contains in the egg that the first cage chicken produces is few, every index of the trace element that contains in the egg that the second cage chicken produces is suitable for the standard of human body requirements amount and absorption most, the amount of the trace element that contains in the egg that third and fourth cage chicken produces is higher, is unfavorable for human body and receipts.
Be the testing result of carrying out at the egg that the second cage chicken produces below, contained every beneficial element content is as follows in its egg: (mg/kg)
Iodine: 4.3 selenium: 0.026 calcium: 160 zinc: 8.2
Iron: 12 bronze medals: 0.57 manganese: 0.48 chromium: 0.18
Cobalt: 0.18 nickel: 0.16 vanadium: 0.01 strontium: 0.09
Lithium: 0.03 molybdenum: 0.01
The major physiological function:
Iodine is to constitute thyroxine and the amino acid whose fundamental component of thyroid gland, is of value to intelligence development.
Selenium is to participate in the fat metabolism, and immunologic function is regulated, heavy metal detoxification.
Calcium can be strengthened bone, tooth, prevent osteoporosis.
Zinc can promote regeneration, brain cell growth, reproductive development.
Iron is hemoglobin, myoglobins composition, oxidizing ferment, metalloenzyme activator.
Copper is oxidisability enzyme composition, and scarce copper can cause causing coronary heart disease.
Manganese is participate in protein, Cobastab, C, E synthetic, and can promote the formation of bone.
Chromium can participate in ester, glycometabolism, prevent and treat diabetes and artery sclerosis.
Cobalt is the component part of cobalamin, can play the effect of softening blood vessel.
Nickel is the coenzyme composition of insulin, can play the effect of softening blood vessel.
Vanadium helps the formation of glycometabolism and bone.
Strontium can softening blood vessel, promotes skeleton development.
Lithium can play the effect of softening blood vessel.
Molybdenum can promote nucleic acid and protein to form.
Because chicken is the crop animal of food mineral matter, therefore by this feed addictive of feeding, the resistance against diseases of chicken is strengthened, and make not apocleisis of chicken, the chicken manure stink also alleviates relatively.The yolk projection of egg, the egg white thickness, egg size can increase 8%-10%, and egg output also obtains increasing.The tenderer aquatic foods of chicken meat are good to eat, and are being rich in nutrition again, and mouthfeel is very good; And the beneficial element in the egg is increased to more than 14 kinds, and wherein the content of iodine and selenium is particularly outstanding, is human body necessary " wisdom element " and " anticancer king ".The family is very suitable to this feed addictive so raise chickens.It has also solved the problem of raise in cages on a large scale bird and the decline of birds, beasts and eggs quality, will effectively promote the development of bird animal husbandry, benefits the people, also can bring considerable economic benefit and social benefit.The experiment proved that dropping into optimum weight percentage is 5%~6%, this ratio can make the moon requirement of the suitable people of beneficial element content in egg and the meat, can satisfy the day requirement of people's iodine as an egg.
Experiment two, this feed addictive is added on contrast experiment in the duck feed
(1), process of the test
1, selects 200 ducks, divide four groups, 50 every group.
2, the duck feed is common commercially available duck feed, and average every duck needs greenfeeds 500 such as feeding duck feed 150 ± green vegetables, grass to restrain every day.
3, first group of duck: in the duck feed of feeding, add 2% mineral matter iodine selenium multi-element feed supplement, i.e. 3 grams.
Second group of duck: in the duck feed of feeding, add 5% mineral matter iodine selenium multi-element feed supplement, i.e. 7.5 grams.
The 3rd group of duck: in the duck feed of feeding, add 7% mineral matter iodine selenium multi-element feed supplement, i.e. 10.5 grams.
The 4th group of duck: in the duck feed of feeding, add 10% mineral matter iodine selenium multi-element feed supplement, i.e. 15 grams.
4, feeding time: the average feeding of a twice-daily routinely.
5, test period: 30 days.
(2), experimental observation and test item:
The overall process of sending the special messenger to be responsible for testing, tracing observation:
1, appetite of duck and state have no change.
2, the variation of duck's egg comprises eggshell, egg white, yolk and egg size.
3, the mouthfeel of ripe egg.
4, the variation of duck excrement.
5, get the egg sample in per 10 days and carry out chemical analysis.
(3), result of the test:
Above-mentioned duck has also reached with the same result of egg in the experiment one by this feed addictive of feeding.
Experiment three, this feed addictive is added on contrast experiment in the pig feed
(1), process of the test
1, optional 200 pigs, body weight 30-40 jin is equally divided into four groups.
2, pig feed is common commercially available pig feed, and average every pig needs feeding pig feed 1000 to restrain every day.
3, first group of pig: in the pig feed of feeding, add 2% mineral matter iodine selenium multi-element feed supplement, i.e. 20 grams.
Second group of pig: in the pig feed of feeding, add 5% mineral matter iodine selenium multi-element feed supplement, i.e. 50 grams.
The 3rd group of pig: in the pig feed of feeding, add 7% mineral matter iodine selenium multi-element feed supplement, i.e. 70 grams.
The 4th group of pig: in the pig feed of feeding, add 10% mineral matter iodine selenium multi-element feed supplement, i.e. 100 grams.
4, feeding time: three times on the one average feedings routinely.
5, test period: four months.
(2), experimental observation and test item:
The overall process of sending the special messenger to be responsible for testing, tracing observation:
1, appetite of pig and state have no change.
2, the mouthfeel of pork.
3, the color and luster of pork, texture variations.
(3), result of the test:
Find that by test trace element value contained in first group of pork is very few, does not satisfy human body requirements; Trace element value contained in the 4th group of pork is too high, has surpassed human body normal demand amount, and is also unfavorable with absorption of human body and digestion.Second group and the 3rd group of pork are most appropriate to absorption of human body, also can satisfy human body normal demand amount simultaneously.
By this feed addictive of feeding as can be seen, the resistance against diseases of pig strengthens to some extent, and makes not apocleisis of pig, and shredded meat delicacy, color and luster are pink, and the tenderer aquatic foods of pork are good to eat, and are being rich in nutrition again, and mouthfeel is very good.Only feed and to reach more than 200 jin in four months, and can deliver for sale; Through the pig that this feed addictive is fed, the beneficial element in its meat promptly rises to more than 14 kinds, and wherein the content of iodine and selenium is particularly outstanding, so the family of raising pigs is what to be suited very much with this feed addictive.It has also solved raises pigs and problem that the domestic animals meat quality descends on a large scale, will effectively promote the development of domestic animals animal husbandry, benefits the people, also can bring considerable economic benefit and social benefit.
Introduction:
The inventor in 1999 to 2003 successively in Lanzhou, several different cities such as Tai'an, Taiyuan, Dandong, Shenyang, Various Seasonal, do not wait the cycle, promptly in 40~120 days the test of many times, the conclusion that finally draws is: dropping into optimum weight percentage is 5%~6%.Raise through the fowl of this forage feed and to contain useful element in its egg and the meat and promptly rise to 14~19 kinds, wherein the content of iodine and selenium is particularly outstanding, can satisfy the normal day requirement of people, also is most appropriate to absorption of human body and digestion.
Embodiment 1:
The mineral matter iodine selenium multi-element feed supplement is made of by weight following raw material:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=50: 20: 10: 15: 5
Its preparation method is:
Choose attapulgite 500g, high Cen 200g, calcite 100g, zeolite 150g and feldspar 50g by the above-mentioned raw materials weight ratio, be crushed to 50 orders then, fully stir, mix, promptly.
During use, get this feed addictive and directly add in the common feed in 5% ratio and get final product.
Embodiment 2:
The mineral matter iodine selenium multi-element feed supplement is made of by weight following raw material:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=20: 5: 5: 5: 1
Its preparation method is:
Choose attapulgite 200g, high Cen 50g, calcite 50g, zeolite 50g and feldspar 10g by the above-mentioned raw materials weight ratio, be crushed to 30 orders then, fully stir, mix, promptly.
During use, get this feed addictive and directly add in the common feed in 8% ratio and get final product.
Embodiment 3:
The mineral matter iodine selenium multi-element feed supplement is made of by weight following raw material:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=70: 20: 10: 10: 1
Its preparation method is:
Choose attapulgite 700g, high Cen 200g, calcite 100g, zeolite 100g and feldspar 10g by above-mentioned weight ratio, be crushed to 60 orders then, fully stir, mix, promptly.
During use, get this feed addictive and directly add in the common feed in 6% ratio and get final product.
Embodiment 4:
The mineral matter iodine selenium multi-element feed supplement is made of by weight following raw material:
Attapulgite: Gao Cen: calcite: zeolite: feldspar=90: 20: 15: 15: 5;
Its preparation method is:
Choose attapulgite 900g, high Cen 200g, calcite 150g, zeolite 1508 and feldspar 50g by the above-mentioned raw materials weight ratio, be crushed to 60 orders then, fully stir, mix, promptly.
During use, get this feed addictive and directly add in the common feed in 4% ratio and get final product.

Claims (5)

1, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite:Gao : calcite:zeolite:feldspar=(20~90): (5~20): (5~15): (5~15): (1~5).
2, the preparation method of mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite:Gao : calcite:zeolite:feldspar=(20~90): (5~20): (5~15): (5~15): (1~5);
Its preparation method is:
Choose attapulgite, Gao , calcite, zeolite and feldspar by the above-mentioned raw materials weight ratio, be crushed to 30 orders-60 order then, fully stir, mix, promptly.
3, mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite:Gao : calcite:zeolite:feldspar=50:20:10:15:5.
4, the preparation method of mineral matter iodine selenium multi-element feed supplement, it is characterized in that it by following raw material by weight forming:
Attapulgite:Gao : calcite:zeolite:feldspar=50:20:10:15:5;
Its preparation method is:
Choose attapulgite, Gao , calcite, zeolite and feldspar by the above-mentioned raw materials weight ratio, be crushed to 50 orders then, fully stir, mix, promptly.
5, mineral matter iodine selenium multi-element feed supplement according to claim 1 is characterized in that and can directly it be added in the feed that the weight ratio of its interpolation is: 4%~8%.
CNB2003101050245A 2003-11-07 2003-11-07 Mineral iodine and selenium feed addictive Expired - Fee Related CN1218658C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2003101050245A CN1218658C (en) 2003-11-07 2003-11-07 Mineral iodine and selenium feed addictive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2003101050245A CN1218658C (en) 2003-11-07 2003-11-07 Mineral iodine and selenium feed addictive

Publications (2)

Publication Number Publication Date
CN1541550A true CN1541550A (en) 2004-11-03
CN1218658C CN1218658C (en) 2005-09-14

Family

ID=34333596

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2003101050245A Expired - Fee Related CN1218658C (en) 2003-11-07 2003-11-07 Mineral iodine and selenium feed addictive

Country Status (1)

Country Link
CN (1) CN1218658C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103519000A (en) * 2013-09-27 2014-01-22 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 Multifunctional aquatic feed with slow-release nanometer material carrier and preparation method of multifunctional aquatic feed
CN103519003A (en) * 2013-09-27 2014-01-22 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 Multi-element feed taking silicon hydroxyl apatite as carrier and preparation method thereof
CN108617857A (en) * 2018-06-21 2018-10-09 佛山市三水区嘉信农业技术研究院(普通合伙) A kind of natural calcite mineral feed and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103519000A (en) * 2013-09-27 2014-01-22 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 Multifunctional aquatic feed with slow-release nanometer material carrier and preparation method of multifunctional aquatic feed
CN103519003A (en) * 2013-09-27 2014-01-22 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 Multi-element feed taking silicon hydroxyl apatite as carrier and preparation method thereof
CN103519000B (en) * 2013-09-27 2015-08-19 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 Aquatic products multifunctional fertilizers of a kind of slow release nanometer material support and preparation method thereof
CN103519003B (en) * 2013-09-27 2015-08-19 苏州市阳澄湖现代农业产业园特种水产养殖有限公司 A kind of silicone hydroxyl apatite that utilizes is as the polynary feed of carrier and manufacture method thereof
CN108617857A (en) * 2018-06-21 2018-10-09 佛山市三水区嘉信农业技术研究院(普通合伙) A kind of natural calcite mineral feed and preparation method thereof

Also Published As

Publication number Publication date
CN1218658C (en) 2005-09-14

Similar Documents

Publication Publication Date Title
CN1640294A (en) Disease-resistant growth-promoting Chinese medicine fodder additive for aquatic and domestic animal, and its preparing method
CN106036181A (en) Meat duck compound feed for improving muscle quality and preparation method thereof
CN100337556C (en) Animal nutrient
CN1810147A (en) Feed for weaned piglet
CN107348244A (en) A kind of cray feed
CN113598281A (en) Production method of coated slow-release microelement premix for poultry
CN102342373A (en) Chick forage
CN107333999B (en) A kind of egg duck feed and preparation method thereof
Kirkendale et al. Review on the use and production of algae and manufactured diets as feed for sea-based abalone aquaculture in Victoria
CN107772135A (en) A kind of production method of selenium-rich chicken feed and Se-enriched egg
RU2425586C1 (en) Fodder mixture for growing quail birdlings
CN112806494A (en) Feed formula suitable for feeding young red birds
CN1218658C (en) Mineral iodine and selenium feed addictive
CN1194623C (en) Plant compound extract capable of modifying meat and promoting growth, preparing method and use thereof
CN102007884A (en) Method for producing eggs rich in multiple trace elements
CN1568746A (en) Alkali type zinc chloride feedstuff additive and preparation method thereof
CN103583461A (en) Production method capable of improving calcium content in eggs
CN102342374A (en) Middle broiler feedstuff
JP6795817B1 (en) Edible fish farming feed that enhances the edible fat content of edible fish, its production method, and the method of cultivating edible fish with high edible fat content using it.
CN105815571A (en) Feeding composition and application thereof to animal feed additive preparation
CN104222633B (en) A kind of double-colored eel elver stage powdery compound feed
CN103892101A (en) Refined feed for improving mutton sheep immunity
CN108522895A (en) A kind of Clarias fuscus ecological feed and preparation method thereof
CN115644324B (en) Aquatic feed additive and low-ammonia excretion feed
CN107307220A (en) A kind of novel environment friendly is without hormone free range chicken feed formula

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee