CN1518497A - 包含抗静电模塑材料的多层体系 - Google Patents
包含抗静电模塑材料的多层体系 Download PDFInfo
- Publication number
- CN1518497A CN1518497A CNA028123794A CN02812379A CN1518497A CN 1518497 A CN1518497 A CN 1518497A CN A028123794 A CNA028123794 A CN A028123794A CN 02812379 A CN02812379 A CN 02812379A CN 1518497 A CN1518497 A CN 1518497A
- Authority
- CN
- China
- Prior art keywords
- acid
- polycarbonate
- ion
- preferred
- static inhibitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title abstract description 33
- 238000000465 moulding Methods 0.000 title description 2
- -1 phosphonium ion Chemical class 0.000 claims description 33
- 230000003068 static effect Effects 0.000 claims description 33
- 239000003112 inhibitor Substances 0.000 claims description 29
- 229920001169 thermoplastic Polymers 0.000 claims description 20
- 239000004416 thermosoftening plastic Substances 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 150000001721 carbon Chemical group 0.000 claims description 5
- 238000006254 arylation reaction Methods 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 230000029936 alkylation Effects 0.000 claims description 2
- 238000005804 alkylation reaction Methods 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 2
- 239000000428 dust Substances 0.000 abstract description 21
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000009757 thermoplastic moulding Methods 0.000 abstract description 2
- 229920000515 polycarbonate Polymers 0.000 description 36
- 239000004417 polycarbonate Substances 0.000 description 31
- 150000001875 compounds Chemical class 0.000 description 22
- 239000000654 additive Substances 0.000 description 20
- 239000000206 moulding compound Substances 0.000 description 18
- 230000000996 additive effect Effects 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 239000004033 plastic Substances 0.000 description 17
- 229920003023 plastic Polymers 0.000 description 17
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- 239000006096 absorbing agent Substances 0.000 description 14
- 150000002148 esters Chemical class 0.000 description 11
- 238000001125 extrusion Methods 0.000 description 11
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 10
- 229930185605 Bisphenol Natural products 0.000 description 9
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 9
- YFSUTJLHUFNCNZ-UHFFFAOYSA-M 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane-1-sulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-M 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 239000012964 benzotriazole Substances 0.000 description 6
- 238000013517 stratification Methods 0.000 description 6
- 239000004425 Makrolon Substances 0.000 description 5
- 239000004594 Masterbatch (MB) Substances 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000006085 branching agent Substances 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 229940059574 pentaerithrityl Drugs 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical class OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- GJZAMOYERKVOGF-UHFFFAOYSA-N dimethyl-di(propan-2-yl)azanium Chemical compound CC(C)[N+](C)(C)C(C)C GJZAMOYERKVOGF-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- VLHZUYUOEGBBJB-UHFFFAOYSA-N hydroxy stearic acid Natural products OCCCCCCCCCCCCCCCCCC(O)=O VLHZUYUOEGBBJB-UHFFFAOYSA-N 0.000 description 4
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 125000003003 spiro group Chemical group 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- CJWNFAKWHDOUKL-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 CJWNFAKWHDOUKL-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- HCKMSHYCAFVSGW-UHFFFAOYSA-N cyclohexyl(trimethyl)azanium Chemical compound C[N+](C)(C)C1CCCCC1 HCKMSHYCAFVSGW-UHFFFAOYSA-N 0.000 description 2
- ZPADAZTVSGCTNF-UHFFFAOYSA-N cyclohexyl-diethyl-methylazanium Chemical compound CC[N+](C)(CC)C1CCCCC1 ZPADAZTVSGCTNF-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FRNYKUYJIUPPPW-UHFFFAOYSA-N ethyl(tripropyl)azanium Chemical compound CCC[N+](CC)(CCC)CCC FRNYKUYJIUPPPW-UHFFFAOYSA-N 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 150000001261 hydroxy acids Chemical class 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VFOJFWOVDZGATC-UHFFFAOYSA-N methyl(tripropyl)azanium Chemical compound CCC[N+](C)(CCC)CCC VFOJFWOVDZGATC-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-O pentylazanium Chemical class CCCCC[NH3+] DPBLXKKOBLCELK-UHFFFAOYSA-O 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
- 229920006352 transparent thermoplastic Polymers 0.000 description 2
- HJHUXWBTVVFLQI-UHFFFAOYSA-N tributyl(methyl)azanium Chemical compound CCCC[N+](C)(CCCC)CCCC HJHUXWBTVVFLQI-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 1
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- ODNRTOSCFYDTKF-UHFFFAOYSA-N 1,3,5-Trimethyl-cyclohexan Natural products CC1CC(C)CC(C)C1 ODNRTOSCFYDTKF-UHFFFAOYSA-N 0.000 description 1
- LQWSBXWILISUST-UHFFFAOYSA-N 1,3,5-trimethylcyclohexane Chemical compound CC1[CH]C(C)CC(C)C1 LQWSBXWILISUST-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- CVSXFBFIOUYODT-UHFFFAOYSA-N 178671-58-4 Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)=C(C#N)C(=O)OCC(COC(=O)C(C#N)=C(C=1C=CC=CC=1)C=1C=CC=CC=1)(COC(=O)C(C#N)=C(C=1C=CC=CC=1)C=1C=CC=CC=1)COC(=O)C(C#N)=C(C=1C=CC=CC=1)C1=CC=CC=C1 CVSXFBFIOUYODT-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- DFOLZQISJZKWBT-UHFFFAOYSA-N 2,3-dihydro-1h-indene;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.C1=CC=C2CCCC2=C1 DFOLZQISJZKWBT-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical compound OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical compound OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- RTNVDKBRTXEWQE-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-butan-2-yl-4-tert-butylphenol Chemical compound CCC(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O RTNVDKBRTXEWQE-UHFFFAOYSA-N 0.000 description 1
- KYGLCUAXJICESS-UHFFFAOYSA-N 2-[2,3-di(propan-2-yl)phenyl]phenol Chemical compound CC(C)C1=CC=CC(C=2C(=CC=CC=2)O)=C1C(C)C KYGLCUAXJICESS-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- JMTMSDXUXJISAY-UHFFFAOYSA-N 2H-benzotriazol-4-ol Chemical compound OC1=CC=CC2=C1N=NN2 JMTMSDXUXJISAY-UHFFFAOYSA-N 0.000 description 1
- KTFJPMPXSYUEIP-UHFFFAOYSA-N 3-benzoylphthalic acid Chemical compound OC(=O)C1=CC=CC(C(=O)C=2C=CC=CC=2)=C1C(O)=O KTFJPMPXSYUEIP-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
- HJSPWKGEPDZNLK-UHFFFAOYSA-N 4-benzylphenol Chemical class C1=CC(O)=CC=C1CC1=CC=CC=C1 HJSPWKGEPDZNLK-UHFFFAOYSA-N 0.000 description 1
- KNDDEFBFJLKPFE-UHFFFAOYSA-N 4-n-Heptylphenol Chemical compound CCCCCCCC1=CC=C(O)C=C1 KNDDEFBFJLKPFE-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- MKYMTAIWSIHDNJ-UHFFFAOYSA-N C(CCC)N.C(CCC)S(=O)(=O)O Chemical class C(CCC)N.C(CCC)S(=O)(=O)O MKYMTAIWSIHDNJ-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 239000004262 Ethyl gallate Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- JVWLUVNSQYXYBE-UHFFFAOYSA-N Ribitol Natural products OCC(C)C(O)C(O)CO JVWLUVNSQYXYBE-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- JDZJVWAHZYIHFA-UHFFFAOYSA-N [Br].C1(=CC=CC=C1)O Chemical compound [Br].C1(=CC=CC=C1)O JDZJVWAHZYIHFA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- DBLXLXKFOUFHML-UHFFFAOYSA-M butane-1-sulfonate;tetraethylazanium Chemical class CCCCS([O-])(=O)=O.CC[N+](CC)(CC)CC DBLXLXKFOUFHML-UHFFFAOYSA-M 0.000 description 1
- YJQWSHNVTZZOMU-UHFFFAOYSA-M butane-1-sulfonate;tetrapropylazanium Chemical class CCCCS([O-])(=O)=O.CCC[N+](CCC)(CCC)CCC YJQWSHNVTZZOMU-UHFFFAOYSA-M 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical class CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- HDVRLUFGYQYLFJ-UHFFFAOYSA-N flamenol Chemical compound COC1=CC(O)=CC(O)=C1 HDVRLUFGYQYLFJ-UHFFFAOYSA-N 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- NPZTUJOABDZTLV-UHFFFAOYSA-N hydroxybenzotriazole Substances O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- ISRXMEYARGEVIU-UHFFFAOYSA-N n-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)N(C)C(C)C ISRXMEYARGEVIU-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- DTIFFPXSSXFQCJ-UHFFFAOYSA-N tetrahexylazanium Chemical compound CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC DTIFFPXSSXFQCJ-UHFFFAOYSA-N 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2325/00—Polymers of vinyl-aromatic compounds, e.g. polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2369/00—Polycarbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
本发明涉及热塑性模塑组合物制造的层体系以及按照所述层体系制造的产品,特别是板材,它具有较低吸灰倾向并且在其制造和使用期间不带上静电。
Description
技术领域
本发明涉及热塑性模塑组合物的层体系,特别是片材,它具有较低积灰倾向并且在制造和使用期间不带上静电。
热塑性挤出模塑件,例如,聚碳酸酯片材,可从,例如EP A 0 110221得知,被用于多领域。其制造采取热塑性塑料的挤塑和任选地共挤塑。
一般地说在塑料模塑件,具体地说聚碳酸酯片材的情况下,产生灰尘沉积的积灰现象是普遍性问题。有关这方面可参见,例如,Saechtling,《Kunststoff-Taschenbuch(塑料袖珍本)》第26版,Hanser出版社,1995,慕尼黑,p.140起。积灰源于制造期间模塑件的带静电。灰尘当沉积在透明、半透明热塑性模塑件以及着浅色或鲜亮颜色模塑件上时特别麻烦。而且,透明度可因积灰而降低,其功能因而受损。最后,静电荷本身可能构成危险,特别是在操作可燃材料或可燃粉尘期间。
一种减少静电荷,因此减少塑料件表面积灰的已知方法是采用抗静电剂。限制热塑性塑料积灰的抗静电剂在文献中已有描述(例如参见Gchter,Müller,《Plastic Additives(塑料添加剂)》,Hanser出版社,慕尼黑,1996,p.749起)。这些抗静电剂能改善塑料模塑组合物的导电性,并从而消除制造和使用期间形成的表面电荷。这样吸引灰尘颗粒的程度减轻,结果灰尘积累也就减少了。
关于抗静电剂,通常分为内用和外用抗静电剂两大类。外用抗静电剂在加工后施加到塑料模塑件上,而内用抗静电剂则加入到塑料模塑组合物中作为添加剂。由于经济的原因,通常希望使用内用抗静电剂,因为加工后不再需要施加抗静电剂的步骤。迄今,文献中很少见到也能形成完全透明模塑件的内用抗静电剂,特别是用在聚碳酸酯上。JP-A 06 228 420描述脂族磺酸铵盐在聚碳酸酯中作为抗静电剂的应用。然而,此种化合物却在聚碳酸酯熔体中导致其分子量降低和/或因不相容而浑浊。JP-A 62 230 835描述在聚碳酸酯中加入4%壬基苯基磺酸四丁基磷鎓。WO-A 01/12713描述四乙基铵的全氟辛烷磺酸盐作为抗静电剂在聚碳酸酯中的应用。此种化合物的缺点是挤塑后出现泛黄。
已知抗静电剂的缺点在于,它们必须以较高浓度使用才能达到抗静电效果。然而结果是,热塑性塑料的材料性能发生不可心的改变。
热塑性塑料的挤出模塑件,例如,聚碳酸酯片材主要用作透明、半透明或不透明性质的颜料着色片材。由于成本的原因,此种颜料着色片材的制造是通过在挤塑期间向未加颜料或略带蓝色调的聚碳酸酯中加入彩色母料实现的。
正如开头所描述的,许多抗静电剂在聚碳酸酯中造成泛黄或分子量降低。
如果在片材挤塑期间加入因抗静电剂而带有黄色调的母料,则片材的颜色效果将改变。为抵消此种颜色效果,必须用彩色颜料加以调节。另外,在颜料着色片材的情况下,颜色可因抗静电剂母料的加入而变浅。
由于抗静电剂引起聚碳酸酯分子量下降,在聚碳酸酯基质中抗静电剂的允许使用最大浓度受到限制。特别是在颜料着色片材的情况下,其颜色于是还因加入抗静电剂母料而变浅。
许多抗静电剂还导致聚碳酸酯的浑浊。
因此,本发明的目的是提供一种抗静电热塑性模塑组合物的模塑件和挤出物,不仅其光学品质而且其他性能如机械性能和热畸变温度,与无抗静电剂模塑组合物和模塑件均无显著差异。
令人惊奇的是,这一目的已通过制备含至少一种特殊抗静电剂的热塑性模塑组合物的层体系实现。该层体系的特征在于,它包含至少两层,其中至少一层包含至少一种本发明含至少一种特殊抗静电剂的热塑性模塑配混料。
就本发明内容而言,所述层体系包含一种或多种不同热塑性塑料的至少两层,其中至少一层包含含有至少一种本发明特殊抗静电剂的热塑性塑料。
整个层体系的厚度优选介于21μm~10cm,尤其优选40μm~15mm,更特别优选100μm~12mm。
层体系的各个层的厚度优选介于1μm~10cm。含有抗静电剂的一层或多层的厚度有利地介于1μm~200μm,优选20μm~100μm,尤其优选40μm~60μm。不含本发明抗静电剂的一层或多层的厚度介于20μm~10cm。在薄膜的情况下,优选的厚度介于20μm~600μm;在实心片材的情况下,600μm~15mm;而在多壁片材的情况下,0.4cm~10cm。
下面的两层结构尤其优选(按叙述的顺序排列):
1.层结构
●含本发明抗静电热塑性模塑配混料的层
●含不带本发明抗静电剂的热塑性模塑组合物的层
2.层结构
●含本发明抗静电热塑性模塑配混料的层
●含不带本发明抗静电剂的热塑性模塑组合物的层
●含本发明抗静电热塑性模塑配混料的层。
另外,各个层可各自独立地包含进一步的添加剂如紫外吸收剂、热稳定剂、抗氧化剂、脱模剂、阻燃剂、染料、颜料、增亮剂、玻璃纤维、发泡剂、成核剂、增塑剂、加工助剂、填料或其他热塑性塑料领域传统上使用的添加剂,其用量介于0.001wt%~30wt%。更具体地说,合适的添加剂类型及其用量乃是本领域技术人员已知的(例如,描述在Gchter;Müller,《Plastics additives》,Hanser出版社,慕尼黑1996或在EP 0 839 623 A1或EP 0 500 496 A1)中。
本发明意义范围内的适宜抗静电剂包括类型(I)的盐
RA-SO3X (I)
其中
R代表含1~30个碳原子,优选4~8个碳原子的全氟线型或支化碳链;
A代表直接键或芳核,例如并优选氟代或非氟代邻-、间-或对-亚苯基;
X代表烷基化和/或芳基化铵离子NR’R”RR””,磷鎓离子PR’R”RR””,锍离子SR’R”R,以及取代或未取代的咪唑啉鎓离子、吡啶鎓离子或鎓离子,其中
R’R”RR””,每种情况彼此独立地代表芳族、环状或线型、支化或未支化碳链,可以是未取代的或取代上卤素、羟基、环烷基或烷基,特别是C1~C3-烷基和C5~C7-环烷基并具有1~30个碳原子,优选1~10个碳原子,在环状基团的情况下,优选具有5~7个碳原子的那些,尤其优选甲基、乙基、丙基、1-丁基、1-戊基、己基、异丙基、异丁基、叔丁基、新戊基、2-戊基、异戊基、异己基、环己基、环己基甲基、环戊基、苯基或苄基。
优选季铵盐NR’R”RR””。
尤其优选的本发明意义范围内的季铵盐是:
全氟辛烷磺酸四乙基铵盐
全氟丁烷磺酸四乙基铵盐
全氟辛烷磺酸四丙基铵盐
全氟丁烷磺酸四丙基铵盐
全氟辛烷磺酸四丁基铵盐
全氟丁烷磺酸四丁基铵盐
全氟辛烷磺酸四戊基铵盐
全氟丁烷磺酸四戊基铵盐
全氟辛烷磺酸四己基铵盐
全氟丁烷磺酸四己基铵盐
N-甲基-三丙基铵的全氟丁基磺酸盐
N-甲基-三丙基铵的全氟辛烷磺酸盐
N-乙基-三丙基铵的全氟丁基磺酸盐
N-乙基-三丙基铵的全氟辛烷磺酸盐
二甲基二异丙基铵的全氟丁基磺酸盐
二甲基二异丙基铵的全氟辛烷磺酸盐
乙基二异丙基甲基铵的全氟丁基磺酸盐
乙基二异丙基甲基铵的全氟辛烷磺酸盐
N-甲基-三丁基铵的全氟丁基磺酸盐
N-甲基-三丁基铵的全氟辛烷磺酸盐
环己基二乙基甲基铵的全氟丁基磺酸盐
环己基二乙基甲基铵的全氟辛烷磺酸盐
环己基三甲基铵的全氟丁基磺酸盐
环己基三甲基铵的全氟辛烷磺酸盐
以及对应的三氟甲烷磺酸盐。
更具体地说,上述盐当中每一种也优选地适宜。
磺酸盐的混合物也是优选的,尤其是上述磺酸盐的混合物。
这些全氟烷基磺酸铵盐为已知或者可按已知方法制备。磺酸盐可通过在室温水中加入等摩尔数量的游离磺酸与氢氧化物形式的对应阳离子并浓缩该溶液来制备。其他制备方法描述在,例如,DE A 19 66 931和NL A 7 802 830或在Pomaville等人,《J.Chromatogr.(色谱学杂志)(1989)》卷日期1988,468,pp.261~278中。
全氟烷基磺酸铵盐优选以0.001wt%~2wt%,优选0.1wt%~1wt%的用量加入到塑料中。
本发明意义范围内的适宜热塑性塑料包括,特别是,透明热塑性塑料。优选烯属不饱和单体的聚合物和/或双官能活性化合物的缩聚物。
特别合适的塑料包括基于双酚的聚碳酸酯或共聚碳酸酯,聚-或共聚丙烯酸酯和聚-或共聚甲基丙烯酸酯,例如并优选聚甲基丙烯酸甲酯,具有苯乙烯的聚合物或共聚物例如并优选透明聚苯乙烯或聚苯乙烯丙烯腈(SAN),透明热塑性聚氨酯,以及聚烯烃,例如并优选透明聚丙烯类型或者基于环状烯烃的聚烯烃(例如,TOPAS,Hoechst),对苯二甲酸,带或不带间苯二甲酸,与乙二醇和/或环己烷二甲醇的聚-或共缩聚产物,例如并优选聚-或共聚对苯二甲酸乙二醇酯(PET或CoPET)或者环己烷二甲醇改性的PET(PETG)。
聚碳酸酯或共聚碳酸酯是尤其优选的,特别是非卤代的聚碳酸酯和/或共聚碳酸酯,其重均分子量
Mw介于5000~100,000,优选10,000~50,000,尤其优选15,000~40,000者。
均聚碳酸酯、共聚碳酸酯和热塑性聚酯碳酸酯是尤其适宜的。它们的重均分子量Mw介于18,000~40,000,优选26,000~36,000,特别是28,000~35,000,通过测定在二氯甲烷中或在等重量苯酚/邻二氯苯的混合物中的相对溶液粘度并以光散射校准来确定。
含抗静电剂的模塑组合物的熔体粘度优选应小于其他层的模塑配混料的熔体粘度。
关于本发明模塑组合物用聚碳酸酯的制备可参见,例如,“Schnell”,“聚碳酸酯化学与物理”,《聚合物评论》卷9,国际科学出版社,纽约、伦敦、悉尼1964;D.C.PREVORSEK,B.T.DEBONA和Y.KESTEN,公司研究中心,联合化学公司,Moristown,新泽西07960,“聚(酯)碳酸酯共聚物的合成”,《聚合物科学杂志,聚合物化学辑》,卷19,75~90(1980);D.Freitag,U Grigo,P.R.Müller,N.Nouvertne,拜尔公司,“聚碳酸酯”,《聚合物科学与工程大全》卷11,第二版,1988,pp.648~718;以及最后,Dres.U.Grigo,K.Kircher和P.R.Müller“聚碳酸酯”,Becher/Braun主编的《塑料手册》卷3/1,聚碳酸酯、聚缩醛、聚酯、纤维素酯,Carl Hanser出版社,慕尼黑,维也纳,1992,pp.117~299。其制备优选采用界面法或熔融-酯交换法实施,作为例子,将基于界面法来叙述。
优选用作原料化合物的化合物包括对应于通式HO-Z-OH的双酚,其中Z是6~30个碳原子、含有一个或多个芳基的二价有机基团。此类化合物的例子包括属于以下类别的双酚:二羟基联苯、双(羟苯基)链烷、茚满双酚、双(羟苯基)醚、双(羟苯基)砜、双(羟苯基)酮和α,α’-双(羟苯基)二异丙基苯。
属于上面提到的化合物类别当中尤其优选的双酚包括双酚-A(2,2-双(4-羟苯基)丙烷)、四烷基双酚-A、4,4-(间亚苯基二异丙基)二酚(双酚M)、4,4-(对亚苯基二异丙基)二酚、1,1-双(4-羟苯基)-3,3,5-三甲基环己烷(BP-TMC)以及任选地它们的混合物。
基于双酚A的均聚碳酸酯和基于单体双酚-A和1,1-双(4-羟苯基)-3,3,5-三甲基环己烷的共聚碳酸酯是尤其优选的。本发明使用的双酚化合物与碳酸化合物,特别是光气,起反应,或者在熔融酯交换方法中,与碳酸二苯酯或碳酸二甲酯起反应。
聚酯碳酸酯通过上面已提到的双酚、至少一种芳族二羧酸以及任选地碳酸等价物之间的反应制取。合适的芳族二羧酸包括,例如,邻苯二甲酸、对苯二甲酸、间苯二甲酸、3,3’-或4,4’-联苯二羧酸和二苯酮二羧酸。聚碳酸酯中的碳酸酯基团的一部分,最高80mol%,优选20mol%~50mol%,可由芳族二羧酸酯基团替代。
界面法中使用的惰性有机溶剂包括,例如,二氯甲烷、各种二氯乙烷和氯丙烷化合物,四氯甲烷、三氯甲烷、氯苯和氯甲苯;使用氯苯或二氯甲烷,或者二氯甲烷与氯苯的混合物是优选的。
界面反应可采用诸如叔胺,尤其是N-烷基哌啶或鎓盐之类的催化剂加速。优选使用三丁基胺、三乙胺和N-乙基哌啶。在熔融酯交换方法的情况下,使用DE A 42 38 123中提到的催化剂。
聚碳酸酯可按已知和控制的方式通过采用少量支化剂达到支化。某些合适的支化剂包括:均苯三酚、4,6-二甲基-2,4,6-三(4-羟苯基)-庚烯-2;4,6-二甲基-2,4,6-三(4-羟苯基)-庚烷;1,3,5-三(4-羟苯基)-苯;1,1,1-三(4-羟苯基)-乙烷;三(4-羟苯基)-苯甲烷;2,2-双[4,4-双(4-羟苯基)-环己基]-丙烷;2,4-双(4-羟苯基异丙基)-苯酚;2,6-双(2-羟基-5’-甲基苄基)-4-甲基苯酚;2-(4-羟苯基)-2-(2,4-二羟苯基)-丙烷;六(4-(4-羟苯基-异丙基)-苯基)-原对苯二甲酸酯;四(4-羟苯基)-甲烷;四(4-(4-羟苯基-异丙基)-苯氧基)-甲烷;ααα’,ααα”-三(4-羟苯基)-1,3,5-三异丙基苯;2,4-二羟基苯甲酸;1,3,5-苯三甲酸;氰脲酰氯;3,3-双(3-甲基-4-羟苯基)-2-氧代-2,3-二氢吲哚;1,4-双(4’,4”-二羟基三苯基)-甲基)-苯,特别是:1,1,1-三(4-羟苯基)-乙烷和3,3-双(3-甲基-4-羟苯基)-2-氧代-2,3-二氢吲哚。
0.05mol%~2mol%,以二酚用量为基准,任选加入的支化剂或支化剂的混合物可与二酚一起使用,但也可在合成的较晚阶段加入。
使用的链终止剂优选是酚类,例如,苯酚、烷基酚如甲酚和4-叔丁基苯酚、氯酚、溴酚、枯基苯酚或它们的混合物,其用量介于1~20mol%,优选2~10mol%每摩尔双酚。苯酚、4-叔丁基苯酚和枯基苯酚是优选的。
链终止剂和支化剂可分别地或者与双酚一起加入到合成中。
本发明模塑组合物用聚碳酸酯采用熔融酯交换法的制备描述在,例如,DE A 42 38 123中。
本发明意义范围内适合作为紫外吸收剂的添加剂描述在,例如,EP A 0 839 623(p.23起)和EP A 0 500 496(p.2,化合物I;和p.6起,第二章)。
苯并***的、二苯酮的、三嗪的衍生物,以及芳基化氰基丙烯酸酯以及其他传统紫外吸收剂特别合适。
特别适合本发明模塑组合物使用的紫外吸收剂包括,考虑到其400nm以下的吸收能力,能有效地保护聚碳酸酯免遭紫外线损伤的化合物。
合适的紫外吸收剂包括,特别是,WO 99/05205中描述的对应于下式(I)的化合物
其中R1和R2相同或不同,代表氢、卤素、C1~C10-烷基、C5~C10-环烷基、C7~C13-芳烷基、C6~C14-芳基,-OR5或-(CO)-O-R5,其中R5=H或C1~C4-烷基,
R3和R4同样也相同或不同,代表氢、C1~C4-烷基、C4~C6-环烷基、苄基或C6~C14-芳基,
m是1、2或3并且n是1、2、3或4,
以及对应于通式(II)的那些
其中桥连基团意指
R1、R2、m和n具有通式(II)中给出的含义,
其中,另外,p是0~3的整数,
q是1~10的整数,
Y是-CH2-CH2-、-(CH2)3-、-(CH2)4-、-(CH2)5-、-(CH2)6-或
CH(CH3)-CH2-并且
R3和R4具有通式(II)的含义。
其他适合本发明的紫外吸收剂包括代表取代的三嗪的那些,例如,2,4-双(2,4-二甲基苯基)-6-(2-羟基-4-正辛氧基苯基)-1,3,5-三嗪(CYASORBUV-1164)或2-(4,6-二苯基-1,3,5-三嗪-2-基)-5-(己基)氧基苯酚(Tinuvin1577)。特别优选的紫外吸收剂是2,2-亚甲基双(4-(1,1,3,3-四甲基丁基)-6-(2H-苯并***-2-基)苯酚),按商品名Tinuvin360或Adeka StabLA31商业销售。EP 0500496 A1中提到的紫外吸收剂也适合。BASF公司以WO 96/15102,实例1得到的紫外吸收剂Uvinul 3030,也可使用。
其他适合本发明的紫外吸收剂包括羟基苯并***,例如,2-(3’,5’-双(1,1-二甲基苄基)-2’-羟苯基)-苯并***(Tinuvin234,汽巴特殊化学品公司,Basel)、2-(2’-羟基-5’-(叔辛基)-苯基)-苯并***(Tinuvin329,汽巴特殊化学品公司)、2-(2’-羟基-3’-(2-丁基)-5’-(叔丁基)-苯基)-苯并***(Tinuvin350,汽巴特殊化学品公司)、双(3-(2H-苯并***基)-2-羟基-5-叔辛基)甲烷(Tinuvin360,汽巴特殊化学品公司)、2-(4-己氧基-2-羟苯基)-4,6-二苯基-1,3,5-三嗪(Tinuvin1577,汽巴特殊化学品公司)和2,4-二羟基-二苯酮(Chimasorb22,汽巴特殊化学品公司)和2-羟基-4-(辛氧基)-二苯酮(Chimasorb81,汽巴特殊化学品公司)。
紫外吸收剂的用量,每种情况优选介于0.001wt%~20wt%,优选0.01wt%~1wt%,有利地0.1wt%~1wt%,更特别优选0.2wt%~0.6wt%。作为室外用途,用量有利地介于2wt%~11wt%,优选3wt%~10wt%,更特别优选3wt%~7wt%。
适合本发明模塑组合物的聚碳酸酯使用的稳定剂包括,例如,膦、亚磷酸酯或含硅稳定剂以及EP-A 0 839 623(p.21,第1章)中描述的另外的化合物。例子包括亚磷酸三苯酯、亚磷酸二苯基烷基酯、亚磷酸苯基二烷基酯、亚磷酸三(壬基苯基)酯、四(2,4-二叔丁基苯基)-4,4’-亚联苯基的二亚膦酸酯和亚磷酸三芳基酯。特别优选三苯基膦和三(2,4-二叔丁基苯基)亚磷酸酯。
另外,本发明模塑配混料还可包含0.01wt%~0.5wt%单~六羟基醇的(偏)酯,尤其是甘油、季戊四醇或格尔伯特醇的酯。
单羟基醇的例子包括十八烷基醇、棕榈醇和格尔伯特醇。
二羟基醇的例子是乙二醇。
三羟基醇的例子是甘油。
四羟基醇的例子包括季戊四醇和内消旋(meso)赤藓醇。
五羟基醇的例子包括阿糖醇、核糖醇和木糖醇。
六羟基醇的例子包括甘露糖醇、山梨醇和卫矛醇。
酯是单酯、二酯、三酯、四酯,任选地五酯和六酯或其混合物,特别是饱和、脂族C10~C36一元羧酸和任选地羟基一元羧酸,优选与饱和脂族C14~C32一元羧酸和任选地羟基一元羧酸的任意混合物。
市售供应的脂肪酸酯,特别是季戊四醇的和甘化油的,由于生产的原因,可以含有小于60%不同的偏酯。
10~36个碳原子的饱和脂族一元羧酸的例子包括癸酸、月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、羟基硬脂酸、花生酸、二十二烷酸、二十四烷酸、二十六烷酸、二十九烷酸。
优选的14~22个碳原子的饱和脂族一元羧酸的例子包括肉豆蔻酸、棕榈酸、硬脂酸、羟基硬脂酸、花生酸和二十二烷酸。
特别优选饱和脂族一元羧酸如棕榈酸、硬脂酸和羟基硬脂酸。
可按照本发明使用的饱和脂族C10~C36羧酸和脂肪酸酯或者是本身从文献中已知,或者可按从文献已知的方法制备。季戊四醇的脂肪酸酯的例子包括上面提到的特别优选的一元羧酸的那些酯。
季戊四醇和甘油与硬脂酸和棕榈酸的酯是特别优选的。
格尔伯特醇和甘油与硬脂酸和棕榈酸以及任选地羟基硬脂酸的酯尤其优选。
另外,本发明模塑配混料可含有有机染料、无机彩色颜料、荧光染料,特别优选荧光增白剂。
所有本发明模塑组合物合成用的原材料和溶剂,由于可能在生产和贮存期间掺杂进对应杂质如颗粒、凝胶固体、离子、溶剂残余、单体或低聚物残余或者其他化合物,都应以尽可能纯净状态使用。
各个组分的混合可按已知方式顺序或同时地,在室温或提高的温度进行。
添加剂在本发明模塑组合物中的掺入,特别是抗静电剂和紫外吸收剂以及其他上面提到的添加剂的掺入,应按已知方式通过使聚合物粒料与添加剂在约200℃~350℃的温度,在传统设备中,例如在密炼机、单螺杆挤出机和双螺杆挤出机中混合,例如,通过熔融配混或熔融挤出,或者通过使聚合物的溶液与添加剂在适当溶剂如二氯甲烷、卤代链烷、卤代芳烃、氯苯和二甲苯中的溶液之间的混合,随后按已知方式蒸发掉溶剂来实施。添加剂在模塑配混料中的比例可在宽范围内变化并取决于所要求的模塑配混料性能。添加剂在模塑配混料中的总比例大约最高为30wt%,优选0.1wt%~12wt%,以模塑配混料的重量为基准。
因此,本发明提供结合本发明模塑组合物所制成的模塑件和挤出物。该模塑组合物可用于生产薄膜、实心塑料片材和多壁片材(例如,双壁片材、三壁片材等)以及瓦楞板片材。本发明层体系还包括在一侧或两侧具有采用有较高紫外吸收剂含量的本发明模塑组合物的附加外层的那些。
本发明层体系能制造长期不积灰的模塑件和挤出物,特别是由它生产的片材和模塑件如暖房用的玻璃、公共汽车棚、机器覆盖物、广告牌、标志牌、保护屏障、汽车玻璃、玻璃窗和屋顶。
对包覆本发明模塑组合物的挤出零件随后实施的机械加工操作,例如,热成形或表面机械加工操作,是可能的,并且由这些方法所生产的模塑件也构成本专利的主题。
共挤出技术本身可从文献中得知(例如参见EP A 0 110 221和EPA 0 110 238)。在当前的情况下,这些操作优选按如下所述实施:
生产芯层和外层的挤出机连接到共挤出模头接套上。模头接套被设计成,使形成外层的熔体以薄层施加粘附到芯层的熔体上。
如此生产的多层熔体线料随后在下游连接的模具中被赋予要求的形状(多壁或实心片材)。随后,熔体在控制的条件下按已知方式通过压延(实心片材)或真空定型冷却,然后切断为一定的长度。任选地,也可在定型后设置退火炉以消除应力。替代布置在模头前的模头接套,模具本身也可设计成供熔体汇合的样式。
实施例
本发明将通过下面的实施例进一步说明,但不限于这些实施例。
实例1(添加剂):
396.2g五氟丁烷磺酰氟(1.311mol,Aldrich)和78.8g(二甲基二甲氧基硅烷(0.655mol,Fluka)放入到叔丁基甲基醚(Aldrich)中,并在室温下慢慢加入151.1g N,N-二异丙基甲基胺(1.311mol,Fluka)。反应溶液随后在室温搅拌7h,直至气体释放消退,最后沉淀产物经过滤,以叔丁基甲基醚洗涤并进行干燥。收率:525g二甲基二异丙基铵的全氟丁基磺酸盐白色晶体。
实例2(含添加剂的聚合物)
Makrolon2808(线型双酚-A聚碳酸酯,拜尔公司出品,Leverkusen,熔体流动指数(MFR)10g/10min,在300℃和1.2kg载荷下测定)按如下所述与0.05%三苯基膦、0.3%2-(2’-羟基-3’-(2-丁基)-5’-(叔丁基)-苯基)-苯并***、0.1%十八烷基-3-(3’,5’-二叔丁基-4’-羟苯基)-丙酸酯和1.5%二甲基二异丙基铵的全氟丁基磺酸盐(实例1)进行配混。
实例3(片材的生产)
3mm实心片材A~G由下列模塑组合物制成。所用基础材料是Makrolon3103(线型双酚-A聚碳酸酯,拜尔公司出品,Leverkusen,熔体流动指数(MFR)6.5g/10min,在300℃和1.2kg载荷下测定)。该材料与基于Makrolon3103(线型双酚-A聚碳酸酯,拜尔公司出品,Leverkusen,熔体流动指数(MFR)6.5g/10min,在300℃和1.2kg载荷下测定)的表1给出的配混料共挤出。
该配混料按下列方式制备:紫外吸收剂和抗静电剂按照表1所示在310℃和80rpm条件下的双螺杆挤出机(ZSK 32,Werner &Pfleiderer)中结合到聚碳酸酯中,然后将所得挤出物造粒。
共挤出层的厚度每种情况为约50μm。
表1:共挤出层的配混料组成
配混料 | 抗静电剂 | UV-吸收剂 |
A(对比例) | 0% | 0% |
B(对比例) | 0% | 7%Tinuvin 360***) |
C(对比例)****) | 4%Clariant-MB*****)NCABRB 12909 | 0% |
D | 1%Bayowet FT 248*) | 0% |
E | 0.4%Bayowet FT 248*) | 0.25%Tinuvin 350**) |
F | 0.4%Bayowet FT 248*) | 7%Tinuvin 360***) |
G****) | 10%MB来自实例2 | 0% |
*)市售供应,全氟-1-辛烷磺酸,四乙基铵盐,拜尔公司(leverkusen)出品
**)市售供应,2-(2H-苯并***-2-基)-4-(1,1-二甲基乙基)-6-(2-甲基丙基)-苯酚,汽巴特殊化学品公司(Lampertheim)出品
***)市售供应,2,2’-亚甲基双[6-(2H-苯并***-2-基)-4-(1,1,3,3-四甲基丁基)苯酚],汽巴特殊化学品公司(Lampertheim)出品
****)通过将Makrolon 3103粒料和母粒混合制备
*****)市售供应,Clariant(Muttenz,瑞士)出品。抗静电母粒,基于非氟代脂族磺酸酯。
实例4(本发明模塑配混料,非共挤出的):
不含添加剂、未稳定化的聚碳酸酯(Makrolon2808,拜尔公司,Leverkusen,出品)在340℃、双螺杆挤出机中与表1给出数量的全氟辛烷磺酸四乙基铵盐和上面提到的其他添加剂一起进行配混,然后造粒。
随后,由这些粒料在300℃的熔体温度下挤塑成形矩形片材(155mm×75mm×2mm),然后进行防尘试验。
表2:塑料组成
实例 | 组成 |
4.1 | 1%Bayowet 248+0.025%三苯基膦+0.3%2-(2’-羟基-3’-(2-丁基)-5’-(叔丁基)-苯基)-苯并***(Tinuvin350,汽巴特殊化学品公司,Basel) |
4.2 | 0.6%Bayowet 248+0.025%三苯基膦+0.3%2-(2’-羟基-3’-(2-丁基)-5’-(叔丁基)-苯基)-苯并*** |
4.2 | 0.4%Bayowet 248+0.025%三苯基膦+0.3%2-(2’-羟基-3’-(2-丁基)-5’-(叔丁基)-苯基)-苯并*** |
用于生产多层实心片材的机器和设备的情况如下:
该装置包括:
主挤出机,螺杆长度33D,直径60mm,带有脱气装置,
共挤出模头接套(供料***),单层,双面
用于施加外层的共挤出机,螺杆长度25D,直径30mm
平片材模头,350mm宽
3-辊上光叠辊机,辊筒垂直排列
辊式传送机
保护膜层合
引出装置
定长切断装置(锯)
码放台。
基础材料聚碳酸酯粒料投入到主挤出机的进料斗,共挤出材料喂入到共挤出机的进料斗。相关材料在对应机筒/螺杆塑化***中熔融并输送。两种材料的熔体在共挤出模头接套处汇合并在离开模头后形成复合材料,然后在诸辊筒之间冷却。其他设施被用于输送、表面保护和切断成挤出片材的长度。
随后,所获得的片材接受比色评估。采用下列测定方法:
透射率(根据标准ASTM E 308/ASTM D 1003)
装置:Pye-Unicam(测定几何参数:0°/漫射,根据光类型C计算)
黄色指数YI,按照ASTM E 313。
拒尘效果按如下方式考察并采用以下实际评价法评估。为考察在实验室试验中的积灰,将注塑片材暴露于载有流态化灰尘的大气中。为此,21只放入了80mm长三角形断面磁搅拌子的玻璃烧杯中以灰尘充填至约1cm高度(木炭灰/20g活性炭,Riedel-de Haen,Seelze,德国,制品号18003)。灰尘借助磁搅拌子保持流态化。搅拌子停下后,让样品暴露于该灰尘气氛中达7s。视所用样品而定,灰尘在或大或小的程度上沉积在样品上。积灰(灰尘沉积物)的评估根据肉眼评定。
下表显示,以本发明模塑组合物共挤塑的片材在制成后具有与用不含添加剂的已知模塑组合物制的片材(1)大致相同的泛黄(黄色指数),但在透明度和灰尘样式上却明显优于用含非本发明添加剂的模塑组合物制成的片材(2和3)。与采用本发明模塑组合物和添加剂但不具有本发明层体系的片材(9~11)相比,本发明片材具有明显较低的黄色指数。
表3:
Sheet | 共挤出层: | 黄色指数 | 透明度 | 灰尘式样 |
1(对比例) | A | <2 | 透明 | 不够格 |
2(对比例) | B | <2 | 透明 | 不够格 |
3(对比例) | C | <2 | 浑浊 | 不够格 |
4 | D | <2 | 透明 | 非常好 |
5 | E | <2 | 透明 | 非常好 |
6 | F | <2 | 透明 | 非常好 |
7 | G | <2 | 透明 | 非常好 |
8(对比例) | None | <2 | 透明 | 不够格 |
9(对比例) | 4.1 | 10 | 透明 | 非常好 |
10(对比例) | 4.2 | 6.9 | 透明 | 非常好 |
11(对比例) | 4.3 | 5.9 | 透明 | 非常好 |
正如可从上表看出的,拒尘与很少损害光学性能的可心组合只有本发明的层体系可以达到。另外,本发明层体系还表现出优异耐天候老化性。
Claims (3)
1.一种或多种不同热塑性塑料的至少两层的层体系,其中至少一层包含含有至少一种对应于通式(I)的抗静电剂的热塑性塑料,
RA-SO3X (I)
其中
R代表含1~30个碳原子的全氟线型或支化碳链;
A代表直接键或芳核;
X代表烷基化和/或芳基化铵离子NR’R”RR””,磷鎓离子PR’R”RR””,锍离子SR’R”R,以及取代或未取代的咪唑啉鎓离子、吡啶鎓离子或鎓离子,其中
R’R”RR””,每种情况彼此独立地代表芳族、环状或线型、支化或未支化碳链,其可以是未取代的或取代上卤素、羟基、环烷基或烷基,并具有1~30个碳原子。
2.模塑件和挤出物,其特征在于,它们包含权利要求1的层体系。
3.采用共挤出制造权利要求1的层体系的方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10119416.1 | 2001-04-20 | ||
DE10119416A DE10119416A1 (de) | 2001-04-20 | 2001-04-20 | Mehrschichtsysteme enthaltend antistatische Formmassen |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1518497A true CN1518497A (zh) | 2004-08-04 |
Family
ID=7682111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA028123794A Pending CN1518497A (zh) | 2001-04-20 | 2002-04-08 | 包含抗静电模塑材料的多层体系 |
Country Status (13)
Country | Link |
---|---|
US (1) | US20030031844A1 (zh) |
EP (1) | EP1404520A2 (zh) |
JP (1) | JP2004525004A (zh) |
KR (1) | KR20030090757A (zh) |
CN (1) | CN1518497A (zh) |
BR (1) | BR0209044A (zh) |
CA (1) | CA2444606A1 (zh) |
DE (1) | DE10119416A1 (zh) |
IL (1) | IL158323A0 (zh) |
MX (1) | MXPA03009480A (zh) |
RU (1) | RU2003133922A (zh) |
TW (1) | TW584598B (zh) |
WO (1) | WO2002085613A2 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102639624A (zh) * | 2009-09-30 | 2012-08-15 | 拜尔材料科学股份公司 | 具有改善的性能的uv稳定的聚碳酸酯组合物 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040043234A1 (en) * | 2002-05-10 | 2004-03-04 | Grant Hay | Light management films and articles thereof |
US7341784B2 (en) * | 2004-09-10 | 2008-03-11 | General Electric Company | Light management film and its preparation and use |
DE102005040313A1 (de) * | 2005-08-24 | 2007-03-01 | Bayer Materialscience Ag | Lichtstreuende Formkörper mit hoher Lichttransmission und verbesserter Antistatik |
DE102005040315A1 (de) * | 2005-08-24 | 2007-03-01 | Bayer Materialscience Ag | Lichtstreuende antistatische Kunststoffzusammensetzung mit hoher Helligkeit und deren Verwendung in Flachbildschirmen |
DE102005047615A1 (de) * | 2005-10-05 | 2007-04-12 | Bayer Materialscience Ag | Lichtstreuende Kunststoffzusammensetzung mit hoher Helligkeit und deren Verwendung in Flachbildschirmen |
DE102005047614A1 (de) * | 2005-10-05 | 2007-04-12 | Bayer Materialscience Ag | Licht streuende Kunststoffzusammensetzung mit hoher Helligkeit und deren Verwendung in Flachbildschirmen |
US20070203271A1 (en) * | 2006-01-27 | 2007-08-30 | Alms Gregory R | Coating process for thermoplastics |
KR20110028600A (ko) * | 2008-06-03 | 2011-03-21 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 폴리알킬 질소 또는 인 오늄 플루오로알킬 설포닐 염을 포함하는 미세구조체 |
EP2133202A1 (de) * | 2008-06-11 | 2009-12-16 | Bayer MaterialScience AG | Mehrschichtige optische Folienaufbauten mit verbesserten Eigenschaften und deren Verwendung |
EP2157133A1 (de) * | 2008-08-19 | 2010-02-24 | Bayer MaterialScience AG | Folien mit verbesserten Eigenschaften |
US9570211B2 (en) * | 2008-08-27 | 2017-02-14 | Covestro Llc | Transparent thermoplastic composition with improved electrical conductivity in the melt |
DE102009043509A1 (de) | 2009-09-30 | 2011-03-31 | Bayer Materialscience Ag | Polycarbonatzusammensetzung mit verbesserter Thermostabilität |
BR112014032247A2 (pt) | 2012-06-21 | 2018-05-02 | 3M Innovative Properties Co | filme gravável a laser susceptível a dissipação estática: |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4613520A (en) * | 1983-07-14 | 1986-09-23 | Hercules Incorporated | Coating compositions |
US5032458A (en) * | 1985-01-15 | 1991-07-16 | Hoechst Aktiengesellschaft | Polyester film |
JPS61285232A (ja) * | 1985-06-13 | 1986-12-16 | Daikin Ind Ltd | 帯電防止剤組成物 |
US5145727A (en) * | 1990-11-26 | 1992-09-08 | Kimberly-Clark Corporation | Multilayer nonwoven composite structure |
DE4202282A1 (de) * | 1991-01-29 | 1992-08-20 | Fuji Photo Film Co Ltd | Lichtempfindliches uebertragungsmaterial und bilderzeugungsverfahren |
CA2094434A1 (en) * | 1992-04-30 | 1993-10-31 | Tomoyuki Kotani | Biaxially oriented laminated polyester film for magnetic recording media |
JP4003090B2 (ja) * | 1996-04-11 | 2007-11-07 | 東洋紡績株式会社 | 導電性組成物 |
US6194497B1 (en) * | 1997-07-23 | 2001-02-27 | General Electric Company | Anti-static resin composition containing fluorinated phosphonium sulfonates |
US6383641B1 (en) * | 1997-08-15 | 2002-05-07 | Asahi Glass Company Ltd. | Transparent coated molded product and method for producing the same |
DE19943637A1 (de) * | 1999-08-16 | 2001-02-22 | Bayer Ag | Antistatikum |
DE10159373A1 (de) * | 2001-12-04 | 2003-06-12 | Bayer Ag | Mehrschichtiges Erzeugnis |
-
2001
- 2001-04-20 DE DE10119416A patent/DE10119416A1/de not_active Withdrawn
-
2002
- 2002-04-08 CA CA002444606A patent/CA2444606A1/en not_active Abandoned
- 2002-04-08 WO PCT/EP2002/003853 patent/WO2002085613A2/de not_active Application Discontinuation
- 2002-04-08 EP EP02735232A patent/EP1404520A2/de not_active Withdrawn
- 2002-04-08 CN CNA028123794A patent/CN1518497A/zh active Pending
- 2002-04-08 IL IL15832302A patent/IL158323A0/xx unknown
- 2002-04-08 MX MXPA03009480A patent/MXPA03009480A/es unknown
- 2002-04-08 JP JP2002583172A patent/JP2004525004A/ja active Pending
- 2002-04-08 BR BR0209044-9A patent/BR0209044A/pt not_active IP Right Cessation
- 2002-04-08 KR KR10-2003-7013612A patent/KR20030090757A/ko not_active Application Discontinuation
- 2002-04-08 RU RU2003133922/04A patent/RU2003133922A/ru not_active Application Discontinuation
- 2002-04-16 US US10/123,384 patent/US20030031844A1/en not_active Abandoned
- 2002-04-19 TW TW091108020A patent/TW584598B/zh not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102639624A (zh) * | 2009-09-30 | 2012-08-15 | 拜尔材料科学股份公司 | 具有改善的性能的uv稳定的聚碳酸酯组合物 |
Also Published As
Publication number | Publication date |
---|---|
WO2002085613A2 (de) | 2002-10-31 |
KR20030090757A (ko) | 2003-11-28 |
DE10119416A1 (de) | 2002-10-24 |
IL158323A0 (en) | 2004-05-12 |
RU2003133922A (ru) | 2005-05-10 |
CA2444606A1 (en) | 2002-10-31 |
BR0209044A (pt) | 2004-08-10 |
MXPA03009480A (es) | 2004-05-24 |
EP1404520A2 (de) | 2004-04-07 |
TW584598B (en) | 2004-04-21 |
WO2002085613A3 (de) | 2003-02-13 |
JP2004525004A (ja) | 2004-08-19 |
US20030031844A1 (en) | 2003-02-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1518497A (zh) | 包含抗静电模塑材料的多层体系 | |
US6740697B1 (en) | Flame-resistant thermoplastic molding material | |
CN1470563A (zh) | 含有聚碳酸酯的多层产品 | |
CN1105738C (zh) | 聚碳酸酯模塑组合物及其作为共挤塑板材涂层的应用 | |
CN1772811A (zh) | 降低吸水性的热塑性模塑组合物 | |
US20110098386A1 (en) | Products having improved flame resistance | |
EP2134779A1 (de) | Polycarbonatzusammensetzung enthaltend uv-absorber | |
CN1320027C (zh) | 具有改善的抗水解性的熔体聚碳酸酯 | |
CN1207363C (zh) | 抗静电剂 | |
TW201033270A (en) | Method of modifying gloss with modified polymers and related products and uses | |
KR20150065774A (ko) | 향상된 폴리카보네이트 압출 등급 | |
CN1923893A (zh) | 包含聚碳酸酯和新紫外线吸收剂的组合物 | |
CN1191292C (zh) | 含有聚碳酸酯的组合物 | |
CN1192052C (zh) | 聚碳酸酯模塑组合物 | |
CN1599668A (zh) | 多层产品 | |
JP6807634B2 (ja) | 繊維強化ポリプロピレン樹脂組成物 | |
CN1503821A (zh) | 具有抗静电性能的阻燃聚碳酸酯模塑料 | |
CN100338128C (zh) | 含有热塑性聚合物的组合物 | |
CN1211423C (zh) | 透明的热塑性组合物 | |
US7256230B2 (en) | Polycarbonate resin compositions and articles therefrom | |
KR101948295B1 (ko) | 향상된 폴리카보네이트 압출 등급 | |
JP7208069B2 (ja) | 繊維強化ポリプロピレン樹脂組成物 | |
CN1646616A (zh) | 含聚碳酸酯的组合物 | |
JP2017209921A (ja) | 波型成形板 | |
CN1791502A (zh) | 没有三角效应的通过共挤出而涂覆的多壁片材 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |