CN1477990A - 具有改进的机械性能的新型膜及其在燃料电池中的用途 - Google Patents
具有改进的机械性能的新型膜及其在燃料电池中的用途 Download PDFInfo
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- CN1477990A CN1477990A CNA018197779A CN01819777A CN1477990A CN 1477990 A CN1477990 A CN 1477990A CN A018197779 A CNA018197779 A CN A018197779A CN 01819777 A CN01819777 A CN 01819777A CN 1477990 A CN1477990 A CN 1477990A
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- polymer film
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- polysulfones
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- 229920002492 poly(sulfone) Polymers 0.000 claims abstract description 39
- 229920000642 polymer Polymers 0.000 claims abstract description 26
- 229920002959 polymer blend Polymers 0.000 claims abstract description 22
- 125000003118 aryl group Chemical group 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- -1 1,2-phenylene, 1,3-phenylene, 1,4-phenylene, 4,4'-biphenyl Chemical group 0.000 claims abstract description 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 4
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- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
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- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
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- 239000007787 solid Substances 0.000 description 2
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- 238000004448 titration Methods 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical group C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical group C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- MILSYCKGLDDVLM-UHFFFAOYSA-N 2-phenylpropan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 MILSYCKGLDDVLM-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
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- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
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- 238000005147 X-ray Weissenberg Methods 0.000 description 1
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- 239000007864 aqueous solution Substances 0.000 description 1
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- 125000004429 atom Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
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- 239000003054 catalyst Substances 0.000 description 1
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- 238000012512 characterization method Methods 0.000 description 1
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- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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Classifications
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- Y02E60/50—Fuel cells
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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Abstract
Description
实施例 | 掺混组分(%) | H3PO4/聚合物的重复单元 |
E1 | 5%PES | 9.26 |
E2 | 10%PES | 8.75 |
E3 | 20%PES | 8.44 |
E4 | 5%PSU | 9.29 |
E5 | 10%PSU | 8.92 |
E6 | 20%PSU | 7.75 |
CE1 | 0% | 9.35 |
CE2 | 5%sPEK | 9.85 |
CE3 | 10%sPEK | 9.51 |
CE4 | 20%sPEK | 8.76 |
实施例 | 掺混组分 | 配合结果 | 膜 | 传导率[S/cm] | ||||||
电阻(R)[欧姆] | 误差(%) | 平均电容(Cpar)[pF] | 误差(%) | 厚度(cm) | 误差(%) | 宽度(cm) | 误差(%) | |||
E1 | 5%PES | 2004 | 2.67 | 102.2 | 23.16 | 3.2E-03 | 1.0 | 3.5 | 3.0 | 0.0891 |
E2 | 10%PES | 2293 | 2.45 | 119.7 | 17.39 | 3.1E-03 | 1.0 | 3.5 | 3.0 | 0.0804 |
E3 | 20%PES | 2756 | 3.21 | 131.4 | 23.31 | 2.8E-03 | 1.0 | 3.5 | 3.0 | 0.074 |
E4 | 5%PSU | 2395 | 1.58 | 120.5 | 18.21 | 3.3E-03 | 1.0 | 3.5 | 3.0 | 0.072 |
E5 | 10%PSU | 2392 | 2.77 | 127.9 | 10.64 | 3.3E-03 | 1.0 | 3.5 | 3.0 | 0.072 |
E6 | 20%PSU | 2923 | 2.06 | 126.5 | 18.40 | 3.0E-03 | 1.0 | 3.5 | 3.0 | 0.065 |
CE1 | 0 | 2091 | 2.72 | 115.9 | 27.52 | 2.9E-03 | 1.0 | 3.5 | 3.0 | 0.094 |
CE2 | 05%sPEK | 2485 | 1.29 | 122.8 | 20.37 | 2.9E-03 | 1.0 | 3.5 | 3.0 | 0.079 |
CE3 | 10%sPEK | 2797 | 0.72 | 123.0 | 15.90 | 2.7E-03 | 1.0 | 3.5 | 3.0 | 0.076 |
CE4 | 20%sPEK | 3191 | 2.64 | 129.1 | 16.21 | 3.2E-03 | 1.0 | 3.5 | 3.0 | 0.056 |
实施例 | E模数[MPa] | 断裂韧度[J/m2] | 在Fmax的伸长率(%) | 最大抗张强度(Rmax)[N/mm2] |
E1 | 8.67 | 37733 | 24.41 | 1.75 |
E2 | 8.32 | 32590 | 27.80 | 1.67 |
E3 | 8.04 | 47931 | 33.14 | 1.99 |
E4 | 7.21 | 41715 | 27.25 | 1.60 |
E5 | 9.81 | 22473 | 20.22 | 1.62 |
E6 | 22.59 | 190428 | 55.90 | 4.66 |
E1 | 7.71 | 23263 | 22.06 | 1.51 |
CE2 | 8.27 | 47650 | 33.08 | 1.97 |
E3 | 7.52 | 37561 | 27.87 | 1.93 |
CE4 | 6.65 | 47483 | 38.68 | 1.72 |
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10052242.4 | 2000-10-21 | ||
DE10052242A DE10052242A1 (de) | 2000-10-21 | 2000-10-21 | Mit Säure dotierte, ein- oder mehrschichtige Kunststoffmembran mit Schichten aufweisend Polymerblends umfassend Polymere mit wiederkehrenden Azoleinheiten, Verfahren zur Herstellung solche Kunststoffmembranen sowie deren Verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1477990A true CN1477990A (zh) | 2004-02-25 |
CN100528310C CN100528310C (zh) | 2009-08-19 |
Family
ID=7660573
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB018197779A Expired - Fee Related CN100528310C (zh) | 2000-10-21 | 2001-10-20 | 具有改进的机械性能的新型膜及其在燃料电池中的用途 |
Country Status (9)
Country | Link |
---|---|
US (1) | US7285325B2 (zh) |
EP (1) | EP1337319B1 (zh) |
KR (1) | KR100774227B1 (zh) |
CN (1) | CN100528310C (zh) |
AT (1) | ATE349269T1 (zh) |
BR (1) | BR0114764A (zh) |
CA (1) | CA2425683C (zh) |
DE (2) | DE10052242A1 (zh) |
WO (1) | WO2002036249A1 (zh) |
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-
2000
- 2000-10-21 DE DE10052242A patent/DE10052242A1/de not_active Withdrawn
-
2001
- 2001-10-20 BR BR0114764-1A patent/BR0114764A/pt not_active Application Discontinuation
- 2001-10-20 CN CNB018197779A patent/CN100528310C/zh not_active Expired - Fee Related
- 2001-10-20 AT AT01978444T patent/ATE349269T1/de not_active IP Right Cessation
- 2001-10-20 DE DE50111749T patent/DE50111749D1/de not_active Expired - Lifetime
- 2001-10-20 EP EP01978444A patent/EP1337319B1/de not_active Expired - Lifetime
- 2001-10-20 CA CA002425683A patent/CA2425683C/en not_active Expired - Fee Related
- 2001-10-20 US US10/399,514 patent/US7285325B2/en not_active Expired - Fee Related
- 2001-10-20 WO PCT/EP2001/012147 patent/WO2002036249A1/de active IP Right Grant
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- 2003-04-18 KR KR1020037005434A patent/KR100774227B1/ko not_active IP Right Cessation
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101685867B (zh) * | 2008-07-22 | 2011-09-28 | 山东东岳神舟新材料有限公司 | 一种微孔膜增强的多层含氟交联掺杂离子膜及其制备方法 |
CN101685865B (zh) * | 2008-07-29 | 2011-08-17 | 山东东岳神舟新材料有限公司 | 一种多层含氟交联离子膜及其制备方法 |
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CN101685866B (zh) * | 2008-07-29 | 2012-07-04 | 山东华夏神舟新材料有限公司 | 一种多层含氟交联离子膜及其制备方法 |
CN101692496B (zh) * | 2008-07-29 | 2013-09-25 | 山东华夏神舟新材料有限公司 | 一种多层含氟交联离子膜及其制备方法 |
CN112275146A (zh) * | 2020-09-01 | 2021-01-29 | 中国科学院山西煤炭化学研究所 | 一种经磷酸处理的Tr*ger`s Base聚合物气体分离膜及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
EP1337319B1 (de) | 2006-12-27 |
KR20030036938A (ko) | 2003-05-09 |
WO2002036249A1 (de) | 2002-05-10 |
CA2425683C (en) | 2008-02-12 |
KR100774227B1 (ko) | 2007-11-07 |
BR0114764A (pt) | 2003-10-07 |
DE10052242A1 (de) | 2002-05-02 |
US7285325B2 (en) | 2007-10-23 |
DE50111749D1 (de) | 2007-02-08 |
EP1337319A1 (de) | 2003-08-27 |
US20040131909A1 (en) | 2004-07-08 |
ATE349269T1 (de) | 2007-01-15 |
WO2002036249A9 (de) | 2002-09-19 |
CA2425683A1 (en) | 2003-04-17 |
CN100528310C (zh) | 2009-08-19 |
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