CN1449275A - Pre-shampoo conditioning composition - Google Patents

Pre-shampoo conditioning composition Download PDF

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Publication number
CN1449275A
CN1449275A CN01814951.0A CN01814951A CN1449275A CN 1449275 A CN1449275 A CN 1449275A CN 01814951 A CN01814951 A CN 01814951A CN 1449275 A CN1449275 A CN 1449275A
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Prior art keywords
hair
oil
acid
present
ester
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Inventor
小军夏生
乌尔皮亚诺·B·杜尔吉姆第二
迈克尔·A·斯奈德
长雄美和
笠川由美
守田直广
原田辉郎
路易丝·G·斯科特
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Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
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Publication of CN1449275A publication Critical patent/CN1449275A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
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  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Disclosed are a hair conditioning composition having an oil-continuous phase for applying to the dry hair prior to shampooing, comprising: (a) a conditioning oil which is in liquid form at 25 DEG C; and (b) a nonionic surfactant in an amount which provides phase inversion when the composition is in contact with an abundant amount of water, a method of conditioning the hair and a method of increasing the bulk hair volume by applying the composition to dry hair before shampooing it.

Description

The care composition of pre-shampoo
Technical field
The present invention relates to the care composition of pre-shampoo (pre-shampoo), by being administered on the hair and using shampoo washing hair subsequently, this care composition provides conditioning benefit to hair.More particularly, the present invention relates to have the care composition of the pre-shampoo of inversion of phases performance.
Background technology
Owing to contact with surrounding and owing to the scalp sebum secreted, people's hair is understood dirty.Hair is dirty to make it have dirty sense, and from outside watch not attractive in appearance yet.Dirty hair necessitates shampooing with frequent regularity.
Hair washing is by removing dirt and excess sebum cleans hair.But hair washing can make hair be in humidity, the fluffy and disorderly and difficult usually state of putting in order.In case after the hair drying, owing to removed natural oil and other the natural conditioning and the moist composition of hair, hair is in drying, coarse, the matt or state of curling (frizzy) usually.Because it is dry, the static content of hair can further can increase, and this may disturb combing, and causes hair to be in being commonly referred to the state of " hair that disperses (flyaway hair) ", perhaps cause unfavorable " bifurcated " (split ends) phenomenon, especially for long hair.
Develop the whole bag of tricks and alleviated these hair washings problem of (after-shampoo) afterwards.Such method is used conditioner for hair such as leave (leave-on) and rinsing type (rinse-off) product after being included in hair washing, and attempts to clean hair conditioning shampoo with conditioning hair simultaneously by a kind of product.
Although some consumers like comprising conditioner shampoo easily and convenient, most consumer like as and the hair washing step of separating and be administered to more conventional conditioner composition on the hair.Usually the product form that has two types consumer preferably to use.A kind of form is a rinsing type conditioner, and it is normally used in the bathing after hair washing (bathing) process, and rinses from hair usually.Another kind of form is the leave conditioner, and it is administered on the hair of drying or part wetting state as the part of setting scheme usually, and makes the hair drying.
With being at room temperature that the oil of liquid such as Oleum Cocois be administered on the hair is known in the art.This class oil is difficult to effectively be transported on the hair.When described oil was included in the rinsing type care composition and be administered on the hair of wetting state after hair washing, described oil can not be deposited on the hair and/or is penetrated in the hair with effective and efficient manner, thereby is washed off easily in rinse cycle.When described oil is included in the leave care composition and uses and when dry with the state of relatively dry, hair had be clamminess sense (sticky feel) and bad outward appearance.Therefore, with the using method of this conventional class oil, can not realize the conditioning benefit of described oil.
Some consumers with thin hair wish to make its hair full (volume-up).Term used herein " hair is full " is not equal to the hair that disperses.The hair that disperses is because due to electrostatic charge increases, and the expression hair generally has only the volume of very a spot of hair to increase as one, and is unfavorable.On the other hand, the full increase that relates to the body of hair volume of term hair used herein.Consumer with thin hair wishes to make hair full, controls unfavorable hair simultaneously and disperses.Contained opsonic activity material comprises the effect that the amount of oil provides full effect or still less reduces volume (volume-down) to the hair conditioning product that designs for this class consumer in the compositions by reducing.Think that this forces down the design of (weigh down) hair from the opsonic activity material.Therefore, for making the hair conditioning product of this full class consumer design of hair, hope only has compromise conditioning effect.
According to above, Wo 2008069000 need be provided, said composition provides arrangement to hair and has made hair full (volume up), returns hair simultaneously smooth, softness and moisture feeling are provided.Also need to provide during use with use after be not clamminess sense or thick and heavy sense (heavy feel) or the Wo 2008069000 of above-mentioned beneficial effect is provided under the situation that does not have bad outward appearance after the use.Also need to provide Wo 2008069000, said composition to provide and have the described benefit of transparent appearance.
There is not one piece of file that benefit of the present invention and beneficial effect are provided in the prior art.
Summary of the invention
The present invention relates to be administered to before hair washing the Wo 2008069000 on the hair, it comprises following component by weight:
(a) at 25 ℃ of conditioning oil that are liquid form; With
(b) non-ionic surface active agent, its amount is for producing the amount of inversion of phases (phase inversion) when compositions contacts with the water of fully measuring.
To those skilled in the art, by reading the application's disclosure, these and other feature of the present invention, aspect and benefit will be tangible.
Detailed Description Of The Invention
Although claims of the application are specifically noted and have been spelt out protection scope of the present invention, according to following description, will be better understood the present invention.
The all references document is all introduced the present invention with for referencial use in full.Quoting and not meaning that of any document admits that it is with respect to any decision of the present invention as previous invention existence.
Be meant " comprising " herein and can add other step and other component that does not influence final result.This term comprise term " by ... form " and " basically by ... composition ".
In this article, except as otherwise noted, all percentage ratios, ratio and ratio all are by the gross weight of compositions of the present invention.Therefore all wt that relates to listed component does not comprise the carrier or the by-product that may be included in the commercially available material based on activity substance content.
Conditioning oil
Compositions of the present invention is included in the conditioning oil that is liquid form under 25 ℃, preferably accounts for about 99.9%, 30-99% more preferably from about of being up to of composition weight.
Be applicable to that the conditioning oil among the present invention is deposited on the surface of hair when hair is done.Preferably, thus be applicable to that conditioning oil among the present invention is those conditioning oil that can be penetrated in the hair to a certain extent and be not easy to be washed off after hair washing subsequently.More preferably, be applicable to conditioning oil among the present invention be those behind inversion of phases, can control those conditioning oil to the spreadability of hair surface.
Be applicable to that the conditioning oil among the present invention comprises that those are from natural source that comprises multiple chemical compound and the conditioning oil that is extracted or derived and obtain by the artificial oil that unification compound is more or less formed.Although do not get rid of volatility conditioning oil among the present invention, make this class oil remain under the high relatively boiling point or under the low content, thereby can not make hair, scalp and hands drying.
Be applicable to that conditioning oil among the present invention comprises vegetable oil, animal oil and derives from oil, artificial oil of other natural origin and composition thereof.Select described oil according to the required characteristic of conditioner composition.Preferably comprise a certain amount of molecular weight less than about 1500 oil.Be not wishing to be bound by theory, think that the oil with described molecular weight can be penetrated in the hair.
In a preferred embodiment, the consumption of paraffin oil account for compositions at least about 50%.The compositions that it is believed that described high paraffin oil provides bright feeling of freshness to hair, has controlled the spreadability to hair simultaneously.
Be applicable to that the vegetable oil among the present invention is Canola oil (canola oil), Camellia oil (camelliaoil), olive oil, Oleum Helianthi, Oleum Gossypii semen, soybean oil, Oleum Arachidis hypogaeae semen, olive oil, Petiolus Trachycarpi oil, Semen Maydis oil, Oleum Brassicae campestris (rapeseed oil), Oleum sesami, safflower oil, Oleum Cocois, palm kernel oil, American Avocado Tree oil, macadamia oil, Semen Maydis oil, peach kernel oil, wheat germ oil, pasanqua oil, Semen Lini oil, perillic oil, Oleum Camelliae (teaseed oil), kaya oil, Testa oryzae oil, China's Paulownia oil, Japan's Paulownia oil, Jojoba oil (jojoba oil), rice embryo oil (rice germ oil), and composition thereof.Particularly preferably be Canola oil (canola oil), Camellia oil (camellia oil), olive oil, safflower oil and composition thereof.
Be applicable to the animal oil among the present invention and be pilchard oil, Adeps Sus domestica, Adeps Bovis seu Bubali, turtle oil, egg oil (eggyolk oil), ermine oil, squalane, lanoline, liquid lanolin, liquid paraffin, vaseline from the oil of other natural origin, and composition thereof.
The commercially available oil that is applicable to the natural origin among the present invention comprises: the commodity that derive from Ajinomoto are called Canola Salad Oil, derive from the commodity Cropure Almond by name of Croda, Cropure ApricotKemel, the Canola oil of Cropure Avocado and Cropure Peanut (canola oil).
Comprise that as the aliphatic alcohol of conditioning oil carbon number is about 10-30, is preferably about 12-22, those aliphatic alcohol of about 16-22 more preferably in the present invention.These aliphatic alcohol can be the alcohol of straight or branched, and preferably undersaturated alcohol.The example of the indefiniteness of these chemical compounds comprises: oleyl alcohol (oleylalcohol), Palmitoleyl alcohol (palmitoleic alcohol), inferior oleyl alcohol (linoleyl alcohol) and ricinoleyl alcohol (recinoleyl alcohol).
Comprise that as the fatty acid of conditioning oil carbon number is about 10-30, is preferably about 12-22, those fatty acids of about 16-22 more preferably in the present invention.These fatty acids can be the acid of straight or branched, and preferably undersaturated acid.Suitable fatty acids for example comprises: oleic acid, linoleic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid and castor oil acid (ricinolic acid).
Be defined as the ester oil of the alkyl ether of the ester that comprises aliphatic alcohol for example, oxyalkylated aliphatic alcohol, the alkyl ether of aliphatic alcohol, oxyalkylated aliphatic alcohol and volume big (bulky) such as pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil, glyceride oil and composition thereof in the present invention as the derivative of fatty acid of conditioning oil and fatty alcohol derivative in the present invention.The example of the indefiniteness of derivative of fatty acid and fatty alcohol derivative comprises for example methyl linoleate, Ethyl linoleate, the linoleic acid isopropyl ester, Ceraphyl 140A, acid isopropyl, ethyl oleate, oleic acid octyl group dodecyl ester, oleic acid oleic alcohol ester, decyl oleate, butyl oleate, methyl oleate, stearic acid octyl group dodecyl ester, isostearic acid octyl group dodecyl ester, different Palmic acid octyl group dodecyl ester, different octyl pelargonate, octyl pelargonate, the own ester of isostearic acid, the isostearic acid isopropyl ester, different isodecyl pelargonate, the isostearic acid isopropyl ester, the isostearic acid ethyl ester, isostearic acid methyl ester and Oleth-2.The molecular weight that is applicable to bulky ester oil among the present invention such as pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil and glyceride oil less than about 800, preferably less than about 500.
Hydrocarbon as conditioning oil comprises straight chain, ring-type and branched-chain hydrocarbons in the present invention, and described hydrocarbon can be saturated or undersaturated, as long as its fusing point is not more than about 25 ℃.These hydrocarbon have about 12-40 carbon atom, preferably about 12-30 carbon atom, 12-22 carbon atom more preferably from about.Also comprise in the present invention be the polymer hydrocarbon of alkenyl monomer, as C 2-6The polymer of alkenyl monomer.These polymer can be the polymer of straight or branched.The length of straight chain polymer is shorter usually, and it has the total number of carbon atoms mentioned above.Branch polymer can have sizable chain length.The number-average molecular weight of described material can change on a large scale, but common about 500, preferably about 200-400, more preferably from about 300-350 of as many as.Various other mineral oil of level also are applicable among the present invention.Mineral oil is the liquid mixture that derives from the hydrocarbon of oil.The instantiation of suitable hydrocarbon materials comprises paraffin oil, mineral oil, dodecane, Fancol ID, hexadecane, 2-Methylpentadecane, eicosylene (eicosene), different eicosylene (isoeicosene), tridecane, the tetradecane, polybutene, polyisobutylene and composition thereof.
The commercially available aliphatic alcohol and the derivant thereof that are used for the present invention comprise: derive from the oleyl alcohol of the commodity UNJECOL 90BHR by name of Shin Nihon Rika, the various liquid ester that derive from the commodity SCHERCEMOL series by name of Scher, the own ester of isostearic acid of commodity HIS by name that derives from Kokyu Alcohol and the isostearic acid isopropyl ester of commodity ZPIS by name.The commercially available hydrocarbon that is used for the present invention comprises: the molecular weight that derives from the commodity CARNATION by name of Witco is about 330 the isoparaffin and the mixture of cycloalkane, derive from Presperse (South Plainfield New Jersey, USA) trade name is respectively PERMETHYL99A, PERMETHYL 101A, the Fancol ID of PERMETHYL 1082,2-Methylpentadecane and different eicosylene, derive from Amoco Chemicals (Chicago Illinois, USA) isobutene. of commodity INDOPOL H-100 by name and the copolymer of n-butene, derive from the mineral oil of the commodity BENOL by name of Witco, derive from the MARCOL series of Witco, derive from the DRAKEOL series of Penreco, derive from the MARCOL series of Esso and derive from Exxon Chemical Co. (Houston Texas, the isoparaffin of the ISOPAR by name of commodity USA).
The poly ﹠ Alpha ,-olefin oil that is used for the present invention derive from have about 6-16 carbon atom, the preferred 1-olefinic monomer of about 6-12 carbon atom.The example of indefiniteness that is used to prepare the 1-olefinic monomer of poly ﹠ Alpha ,-olefin oil comprises 1-hexene, 1-octene, 1-decene, 1-laurylene, 1-tetradecylene, 1-hexadecylene, branched chain isomer such as 4-methyl-1-pentene, and composition thereof.The preferred 1-olefinic monomer that is used to prepare poly ﹠ Alpha ,-olefin oil is 1-octene, 1-decene, 1-laurylene, 1-tetradecylene, 1-hexadecylene and composition thereof.The poly ﹠ Alpha ,-olefin oil that is used for the present invention also have the viscosity of about 1-35000 centistoke, about 200-60000, preferably less than about 6000, be more preferably less than about 800 molecular weight; With and polydispersity be not more than about 3.
Commercially available poly ﹠ Alpha ,-olefin oil of the present invention comprises that the number-average molecular weight that derives from Mobil Chemical Co. is the poly decene (polydecenes) of about 500 commodity PURESYN 6 by name.
High-molecular weight ester oil as conditioning oil comprises pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil, glyceride oil and composition thereof in the present invention.High-molecular weight ester oil of the present invention is " water-insoluble ".Term used herein " water-insoluble " is meant at 25 ℃ of following chemical compounds goes up the water fast substantially; When chemical compound when mixing with water greater than the concentration of 1.0% weight, the concentration that is preferably greater than 0.5% weight, this mixture becomes biphase with separated form water rapidly then to form unsettled colloid in water temporary transient the dispersion.
Be used for pentaerythritol ester oil of the present invention and have following formula: R wherein 1, R 2, R 3And R 4Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 30 carbon atoms of 1-.Preferably, R 1, R 2, R 3And R 4Independently for having side chain, straight chain, the saturated or unsaturated alkyl of about 22 carbon atoms of about 8-.More preferably, limit R 1, R 2, R 3And R 4Make that the molecular weight of this chemical compound is about 500-about 1,200.
Be used for trihydroxy methyl ester oil of the present invention and have following formula:
Figure A0181495100082
R wherein 11Be alkyl with about 30 carbon atoms of 1-, and R 12, R 13And R 14Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 30 carbon atoms of 1-.Preferably, R 11Be ethyl, and R 12, R 13And R 14Independently for having side chain, straight chain, the saturated or unsaturated alkyl of about 22 carbon atoms of 8-.More preferably, limit R 11, R 12, R 13And R 14Make that the molecular weight of this chemical compound is about 500-about 1,200.
Particularly preferred pentaerythritol ester oil and trihydroxy methyl ester oil comprise pentaerythritol tetraoctyl stearate, tetramethylolmethane four oleates, trimethylolpropane tris isostearate, trimethylolpropane tris oleate and their mixture among the present invention.Such chemical compound with trade name KAKPTI and KAKTTI available from Kokyo Alcohol, with trade name PTO and ENUJERUBU TP3SO available from Shin-nihon Rika.
Can be used for citric acid ester oil of the present invention is that molecular weight is at least about 500 following formula: compound:
Figure A0181495100091
R wherein 21Be OH or CH 3COO, and R 22, R 23And R 24Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 30 carbon atoms of 1-.Preferably, R 21Be OH, and R 22, R 23And R 24Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 22 carbon atoms of 8-.
The useful especially citric acid ester oil of the present invention comprises: with the citric acid three different cetyl esters of trade name CITMOL 316 available from Bernel, with trade name PELEMOL TISC available from the citric acid three iso stearyl esters of Phoenix with citric acid three (octyl group dodecyl) ester of trade name CITMOL 320 available from Bernel.
Can be used for glyceride oil of the present invention is that molecular weight is at least about 500 following formula: compound:
Figure A0181495100092
R wherein 41, R 42And R 43Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 30 carbon atoms of 1-.Preferably, R 41, R 42And R 43Independently for having side chain, straight chain, saturated or unsaturated alkyl, aryl and the alkylaryl of about 22 carbon atoms of 8-.
The useful especially glyceride oil of the present invention comprises: with the glycerol tristearate of trade name SUN ESPOL G-318 available from Taiyo Kagaku, with trade name CITHROL GTO available from Croda, Inc. triolein, with trade name EFADERMA-F available from Vevy or with the linolein of trade name EFA-GLYCERIDES available from Brooks.
Non-ionic surface active agent
Compositions of the present invention comprises non-ionic surface active agent, and its amount is for providing the amount of inversion of phases when compositions contacts with the water of fully measuring.But, with before the water of abundant amount contacts, can or can there be water in the compositions, compositions of the present invention has oily continuous phase.The type and the amount that depend on used non-ionic surface active agent, water can be used as the cosolvent of non-ionic surface active agent and help inversion of phases.Can use the combination of surfactant.When compositions being coated on the dried hair and use water rinse, generation inversion of phases and generate water continuous phase, normally oil-in-water phase.Control the type of non-ionic surface active agent contained in the compositions of the present invention and amount so that described inversion of phases to be provided, yet can not bubble or have one's hair wash when under drying condition, applying.
Ionic surfactant pack is drawn together those chemical compounds that produce by hydrophilic alkylene oxides and the condensation that can be the hydrophobic organic compound of aliphatic or alkyl aromatic.
The unrestricted example that preferably is used for the non-ionic surface active agent of the present composition comprises:
(1) polyethylene oxide condensation compound of alkyl phenol, comprise about 6-20 carbon atom and be the alkyl phenol of straight or branched configuration and the condensation product of oxirane as alkyl group, the consumption of described oxirane is about 60 moles of ethylene oxide of about 10-/mole alkyl phenol;
(2) oxirane carries out the material that condensation obtains with the product that is formed by expoxy propane and reacting ethylenediamine;
(3) have about 18 carbon atoms of about 8-and be the aliphatic alcohol of straight or branched configuration and the condensation product of oxirane, as the cocoanut oil alcohol ethylene oxide condensate that every mole of coco alcohol has about 30 moles of ethylene oxide of about 10-, cocoanut oil alcohol partly has about 14 carbon atoms of about 10-;
(4) formula [R 1R 2R 3N → O] the long chain tertiary amine oxide, wherein, R 1The alkyl, alkenyl or the monohydroxy alkyl that comprise about 18 carbon atoms of about 8-, about 10 ethylene oxides part of 0-and about 1 the glyceryl part of 0-, R 2And R 3Comprise about 3 carbon atoms of about 1-and about 1 hydroxyl of 0-, as methyl, ethyl, propyl group, ethoxy or hydroxypropyl;
(5) the long chain tertiary phosphine oxide of formula [RR ' R " P → O]; wherein; R comprises and has alkyl, alkenyl or the monohydroxy alkyl that chain is about about 18 carbon atoms of 8-; about 10 the ethylene oxide parts of 0-; and about 1 the glyceryl part of 0-, R ' and R " are alkyl or the monohydroxy alkyl that contains about 3 carbon atoms of the 1-that has an appointment;
(6) long-chain dialkyl sulphoxide, it comprises short-chain alkyl or a hydroxy alkyl (normally methyl) and a long hydrophobic chain with about 3 carbon atoms of 1-, this long hydrophobic chain comprises alkyl, alkenyl, hydroxy alkyl or the ketone group alkyl that contains about 20 carbon atoms of the 8-that has an appointment, about 10 ethylene oxide parts of 0-and about 1 the glyceryl part of 0-;
(7) alkyl polysaccharide (APS) surfactant (as alkyl polyglucoside), the example be at US 4,565, states in 647, and the document is incorporated herein by reference; The document discloses the APS surfactant, and it has the hydrophobic group of about 30 carbon atoms of about 6-and as the polysaccharide group (as poly glucoside) of hydrophilic group; Randomly, exist the polyalkylene oxide group that hydrophobic parts is connected with hydrophilic parts; And that alkyl group (being hydrophobic parts) can be is saturated or undersaturated, side chain or (for example replacing with hydroxyl or ring) non-side chain, that do not replace or replace; Preferred material is an alkyl polyglucoside, and it is commercially available from Henkel, ICI Americas, and Seppic; With
(8) suc as formula RO (CH 2CH 2) nThose polyoxyethylene alkyl ethers of H and suc as formula R (O) OCH 2CH (OH) CH 2(OCH 2CH 2) nThose Polyethylene Glycol (PEG) fatty acid glyceride of OH, wherein, n is that 1-is about 200, and preferably about 20-is about 100, and R is the alkyl with about 22 carbon atoms of about 8-.
(9) epoxyethane derivative of other hydrophilic surfactant active such as alkyl androstanediol, poly-glycerine fatty acid ester, poly-glycerine alkyl ether, polyoxyethylene sorbitan fatty acid esters, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, cithrol, polypropylene glycol fatty acid ester, trimethyl propane fatty acid ester, the hardened Castor Oil Fatty Acid ester of polyoxyethylene, polyoxyethylene glyceryl pyroglutamic acid ester, and composition thereof.
Can be used for commercially available ionic surfactant pack among the present invention draws together and has the C12-C13 aliphatic alcohol that meansigma methods is 7 mole ethylene oxides, it with trade name Neodol 23-6.5 available from Shell and with trade name Dobanol 23-6.5 available from Mitsubishi, with trade name Elfapur LT 65 SLN available from Akzo; With sorbeth-40 four oleates of trade name Nikkol GO-440 available from Nikko Chemicals; The anhydro sorbitol isostearate, its with trade name Crill 6 available from Croda, with trade name Arlacel 987 available from ICIAmericas, with trade name Montane-70 available from Seppic, with trade name Nikkol SI-10T available from NikkoChemicals; Oleth-5, with trade name Volpo 5 available from Croda, with trade name Brox OL-5 available from Brooks, with trade name Ethoxol-5 available from Lanaetex and with trade name Eumulgin 05 available from Henkel.
In a preferred embodiment, can comprise low amounts of water in the compositions.Not bound by theory, think that low amounts of water helps the surfactant in the stable composition, and when compositions contacts with the water of fully measuring, further help inversion of phases.Surprisingly, for having only a small amount of thickening agent or not containing the product of thickening agent, use low amounts of water to provide as clear as crystal outward appearance to compositions.Limpid and/or transparent is the aesthetic effect that can attract some consumer, and it is pure and soft that this class consumer thinks that this class outward appearance means.
The amount of water should be remained on the incomplete emulsive degree of compositions that makes.Preferably, the amount of water is remained on be not more than about 0.5%, more preferably about 0.1% to about 0.5%.
Thickening agent
Compositions of the present invention can further comprise thickening agent, the amount of thickening agent be the viscosity that makes compositions for about 100mPa.s to about 200,000mPas, it is extremely about 100 to be preferably about 500mPa.s, 000mPa.s, more preferably about 1,000mPa.s is extremely about 100,000mPa.s.Such viscosity is suitable for providing the product that has shear-thinning property, has good spreadability on hair, thereby it is simultaneously not too sticking to improve the deposition of conditioning oil on hair.In a preferred embodiment, using provides viscosity for about 1, and 000mPa.s is to about 100, and the thickening agent of 000mPas is to obtain good especially spreadability.
Measure viscosity of the present invention by Brookfield DV-II+ viscometer.When viscosity is higher than approximately 1, during 000Pa.s, adopt the #52 spindle and under the condition of using 0.5 ml sample under the 1rpm, measure after following 1 minute at 27 ℃.When viscosity is lower than approximately 10, during 000mPa.s, adopt the #41 spindle and under the condition of using 2 ml samples under the 1rpm, measure after following 3 minutes at 27 ℃.
Thickening agent of the present invention is selected from fatty compound, waxy compound, gellant, inorganic thickening agent, oil-soluble polymers and composition thereof.Amount and the type of selecting thickening agent according to the required viscosity and the characteristic of product.Preferably, use the combination of thickening agent.A preferred combination is to use Olestra and 12-hydroxy stearic acid or its ester.Preferably, the total amount of employed thickening agent is about 0.1% to about 60%.
In a preferred embodiment, use and to comprise about 0.1% to about 10% aliphatic alcohol and about 0.1% thickening agent to the combination of the waxy compound of about 50%, preferred as many as about 30%.In another preferred embodiment, use about 0.1% to about 10% gellant.In another preferred embodiment, use the thickening agent comprise about 0.1% to about 10% inorganic thickening agent.
Fatty compound
Can be used for fatty compound of the present invention and have 25 ℃ or higher fusing point, and be selected from aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid and their mixture.It will be understood by those skilled in the art that number and position according to two keys, and the length of side chain and position, some chemical compounds with certain required carbon atom may have and are lower than 25 ℃ fusing point.Fatty compound as thickening agent of the present invention only is that those fusing points are 25 ℃ or higher fatty compound.Should be understood that fatty compound thickening agent of the present invention also can provide the conditioning benefit.
Can be used for aliphatic alcohol of the present invention and be to have about 30 carbon atoms of about 14-, the aliphatic alcohol of about 22 carbon atoms of 16-more preferably from about.These aliphatic alcohol are saturated, and can be straight or branched alcohol.Nonlimiting examples of fatty alcohols comprises pure and mild their mixture of spermol, stearyl alcohol, docosane.
Can be used for fatty acid of the present invention and be to have about 30 carbon atoms of about 10-, preferably about 22 carbon atoms of about 12-, the fatty acid of about 22 carbon atoms of 16-more preferably from about.These fatty acids are saturated, and can be straight or branched acid.Also comprise the binary acid, ternary acid and other polyprotic acid that satisfy requirement of the present invention.The present invention also comprises the salt of these fatty acids.Nonlimiting examples of fatty acids comprises lauric acid, Palmic acid, stearic acid, behenic acid, decanedioic acid and their mixture.Fatty acid soaps also is applicable among the present invention.The non-limiting example of fatty acid soaps comprise have lithium, the natural soap of sodium, calcium, barium and aluminum, comprise aluminum oleate and Aluminum trilaurate.
But can be used for alkyl ether, the aliphatic alcohol of the alkyl ether that fatty alcohol derivative among the present invention and derivative of fatty acid comprise aliphatic alcohol, oxyalkylated aliphatic alcohol, oxyalkylated aliphatic alcohol ester, have the fatty acid ester, the fatty acid that hydroxyl replaces of chemical compound of the hydroxyl of esterification, and composition thereof.The limiting examples of fatty alcohol derivative and derivative of fatty acid comprises following material, as methyl octadecyl ether; Ceteth (ceteth) series compound such as ceteth-1 to ceteth-45, they are glycol ethers of cetyl alcohol, wherein figure notation is represented the number of existing ethylene glycol part; Octadecyl polyoxyethylene ether (steareth) series compound such as tsteareth-1 to steareth-10, they are glycol ethers of stearyl alcohol, wherein figure notation is represented the number of existing ethylene glycol part; 16/octadecyl polyoxyethylene ether (ceteareth) series compound such as ceteareth-1 to ceteareth-10, they be 16/stearyl alcohol (promptly, the mixture that mainly comprises the aliphatic alcohol of the pure and mild stearyl alcohol of cetyl) glycol ether, wherein figure notation is represented the number of existing ethylene glycol part; The C of above-described ceteth, steareth and ceteareth chemical compound 1-C 30Alkyl ether; The polyoxyethylene ether of docosanol; Ethyl stearte, the stearic acid cetyl ester, the Palmic acid cetyl ester, the stearic acid stearyl, myristyl myristate, the Polyoxyethylene cetyl ether stearate, polyoxyethylene octadecyl ether stearate, the polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, the polyoxyethylene distearate, propylene glycolmonostearate, the distearyl acid propylene glycol ester, distearyl acid trihydroxymethylpropanyl ester, the stearic acid Isosorbide Dinitrate, the stearic acid polyglycerol esters, glyceryl monostearate, distearin, glyceryl tristearate and composition thereof.
Can be used for commercially available high melting solid fatty compound of the present invention comprises: with trade name CrodamolMM series available from the myristyl myristate of Croda, with trade name KONOL series available from ShinNihon Rika (Osaka, Japan) with trade name NAA series available from NOF (Tokyo, spermol Japan), stearyl alcohol and docosanol; With trade name 1-DOCOSANOL available from Wako (Osaka, Japan) pure docosanol, with trade name NEO-FAT available from Akzo (Chicago, Illinois, USA), with trade name HYSTRENE available from Witco Corp. (Dublin, Ohio, USA) with trade name DERMA available from Vevy (Genova, various fatty acids Italy).
The fatty compound that can be used among the present invention comprises having fatty acid cane sugar ester, wherein has the C of sucrose and one or more carboxylic moiety 1-C 30Monoesters or polyester, sucrose polyfatty acid esters preferably, wherein esterification degree is that 7-8 and fatty acid part are that the mol ratio of unsaturates and behenic acid is 1: 7 to 3: 5 C 18Single-and/or two-unsaturates and behenic acid; Be more preferably the sucrose octaester, wherein have an appointment in the molecule 7 behenic acid fatty acid parts and about 1 oleic acid part are as the sucrose ester of cottonseed oil fatty acid.By in compositions, adding the lower alcohol of about 1-3% such as the thickening properties that ethanol has further strengthened these chemical compounds.The preferred chemical compound of this apoplexy due to endogenous wind comprises with deriving from fatty acid-esterified sucrose hardened, high erucic acid rapeseed oil, has bought with SEFA docosane acid esters from P﹠G.
Waxy compound
Waxy compound (waxy compounds) is as thickening agent of the present invention.What be used for the present invention is vaseline, it is to derive from the mixture of hydrocarbon of oil and it is at room temperature for semi-solid, paraffin (paraffinwax), microwax, ceresine (ozokerite wax), ceresin (ceresin wax), Brazil wax, candelilla wax (candellila wax), behenic acid eicosyl ester, and composition thereof.Vaseline is particularly preferred.The commercially available waxy compound that can be used among the present invention comprises that commodity are called the vaseline that derives from Witco of Super WhiteProtopet, derives from the Candelilla wax NC-1630 of Noda wax, derives from Strahl; The Ozokerite wax SP-1021 of Pitsh and the behenic acid eicosyl ester that derives from Cas Chemical.
Gellant
The ester and amide, hydroxy acid, hydroxy fatty acid, cholesterol material (cholesterolic materials), lanolin alcohols material (lanolinolic materials), other amide gellant and the crystal gellant that comprise the fatty acid gellant as the gellant of thickening agent of the present invention.
Can be used among the present invention just-acylamino acid prepares by glutamic acid, lysine, glutamate, Glu, aspartic acid and composition thereof.Particularly preferably be N-acyl glutamic acid corresponding to following general formula:
R 2-NH-CO-(CH 2) 2-CH-(NH-CO-R 1)-CO-NH-R 2
R wherein 1Be aliphatic group with about 12-22 carbon atom, R 2It is aliphatic group with about 4-12 carbon atom.The non-limiting example of these materials comprises N-lauroyl-L-glutamic acid dibutyl amide, N-stearyl-L-glutamic acid diheptyl amide, and composition thereof.Most preferably N-lauroyl-L-glutamic acid dibutyl amide is also referred to as dibutyl lauroyl glutamine.This material has been bought from Ajinomoto with trade name Gelling agent GP-1.
The amidoamines of following general formula is applicable among the present invention:
R 1-CO-NH(CH 2) m-N-(R 2) 2
R wherein 1Be C 11-C 24The residue of fatty acid, R 2Be C 1-C 4Alkyl, m are the integers of 1-4.The amidoamines that is preferred among the present invention comprises the amino propyl-dimethyl amine of stearoyl, the amino propyl group diethylamide of stearoyl, the amino ethyl diethylamide of stearoyl, the amino ethyl dimethyl amine of stearoyl, palmityl aminopropyl dimethyl amine, palmityl aminopropyl diethylamide, palmityl amino-ethyl diethylamide, palmityl amino-ethyl dimethyl amine, docosyl acylamino-propyl-dimethyl amine, docosyl acylamino-propyl group diethylamide, docosyl acylamino-ethyl diethylamide, docosyl acylamino-ethyl dimethyl amine, eicosyl acylamino-propyl-dimethyl amine, eicosyl acylamino-propyl group diethylamide, eicosyl acylamino-ethyl diethylamide, eicosyl acylamino-ethyl dimethyl amine and composition thereof; The more preferably amino propyl-dimethyl amine of stearoyl, the amino ethyl diethylamide of stearoyl and composition thereof.
Be applicable to that other gellant in the compositions comprises the ester of 12-hydroxy stearic acid, 12-hydroxy stearic acid, the amide and the combination thereof of 12-hydroxy stearic acid.These preferred gellant comprise those that meet following general formula:
R 1-CO-(CH 2) 10-CH-(OH)-CO-(CH 2) 5-CH 3
R wherein 1Be R 2Or NR 2R 3R 2And R 3Be hydrogen or straight chain, side chain or ring-type and have about 1-22 carbon atom, preferably alkyl, the aryl or aralkyl of about 1-18 carbon atom.R 2And R 3Can be identical or different; But at least one is hydrogen atom preferably.Preferably be selected from those following gellant in these gellant: the 12-hydroxy stearic acid, the 12-methyl hydroxystearate, 12-hydroxy stearic acid ethyl ester, 12-hydroxy stearic acid stearyl, 12-hydroxy stearic acid benzyl ester, 12-hydroxy stearic acid amide, 12-hydroxy stearic acid isopropyl amide, 12-hydroxy stearic acid butyl amide, 12-hydroxy stearic acid benzyl amide, 12-hydroxy stearic acid phenyl amide, 12-hydroxy stearic acid tert-butylamides, 12-hydroxy stearic acid cyclohexyl amide, 12-hydroxy stearic acid 1-adamantyl amide, 12-hydroxy stearic acid 2-adamantyl amide, 12-hydroxy stearic acid diisopropylamide, three esters of glycerol and hydroxy stearic acid, be also referred to as the trihydroxy stearin, and composition thereof; More preferably, 12-hydroxy stearic acid, 12-hydroxy stearic acid isopropyl amide and combination thereof.
Can be used for commercially available Oxystearin chemical compound among the present invention and comprise 12-hydroxy stearic acid (cosmetics-stage) available from Kawaken and Caschem; With trade name Thixcin R available from Rheox, with trade name Flowtone R available from ECC America with the trihydroxy stearin of trade name Rheocin available from UnitedCatalysts.
The suitable amide gellant comprises the monamide gellant of dibasic or side chain, diamides gellant, Disnalon (Ferrer). gellant and the combination thereof of monobasic or side chain; get rid of and be selected from following N-acyl amino acid derivative; be selected from by the N-acyl amino-acid amide of glutamic acid, lysine, glutamate, Glu, aspartic acid preparation, N-acyl amino acid ester and composition thereof; described material specifically is disclosed in US5; in 429,816.
Be applicable to that the binary in the compositions or the alkylamide of tricarboxylic acid or anhydride comprise that the alkylamide in citric acid, tricarballylic acid, equisetic acid, nitrilotriacetic acid, succinic acid and itaconic acid is as 1,2,3-propane tributyl amide, 2-hydroxyl-1,2,3-propane tributyl amide, 1-propylene-1,2,3-propane trioctylphosphine amide (trictylamide), N, N ', N " three (acetyl decyl amide) amine, 2-dodecyl-N; N '-dihexyl succinamide and 2-dodecyl-N, N '-dibutyl succinamide.The diamides of the alkylamide of dicarboxylic acids such as dialkyl succinylsuccinate, alkenyl succinic acid, dialkyl succinylsuccinate acid anhydride and enetutanedioic acid anhydride preferably, 2-dodecyl-N more preferably, N '-dibutyl succinamide.
Other gellant that can be used among the present invention comprises that anthryl derivative is as 2, the two n-decyloxy anthracenes of 3-, the hybrid of steroid and anthryl derivative such as cholesterol anthraquinone-2-carboxylic acid ester, a-amino acid oligomer such as N-benzyl oxygen carbonyl-I-valyl-L-valine-n-octadecane base amide, organo-metallic compound such as monokaryon copper beta-diketon hydrochlorate and two nuclear Cu and Rh tetracarboxylic acid hydrochlorates, dextrin derivative such as dextrin cetylate and dextrin myristinate and ten glycerol the five kinds of stiffness in infant fat acids.
Inorganic thickening agent
The inorganic thickening agent that can be used among the present invention comprises silicon dioxide, oil-soluble clay and composition thereof.Useful especially be have the submicron particle diameter high degree of dispersion, amorphous silica, be also referred to as pyrogenic silica.These materials can be used as Aerosil series (200,300,200CF and 300CF) and have bought from Degussa.
Oil-soluble polymers
Oil-soluble polymers is as thickening agent of the present invention.The oil-soluble polymers that can be used among the present invention comprises guar gum, and it is the resinae material that derives from Guar beans (cyanopsis tetragonaloba) and close relative's basic endosperm (ground endosperm).
Sensitizer
Wo 2008069000 of the present invention can further comprise sensitizer (sensate).When term used herein " sensitizer " is meant on being coated to skin, cause situation is changed the material can produce appreciable sensation, described situation Change Example as but be not limited to: heating, cooling, sensation frank (refreshing) etc.In addition, sensitizer can make the oily between the operating period and/or the sense of being clamminess reduces.
The preferable amount of sensitizer is about 0.001% to about 10%, more preferably from about 0.005% to about 5%, further preferred about 0.01% to about 1% of a total composition weight.
Can use any sensitizer that is applicable in the Haircare composition among the present invention.The sensitizer that is preferred in the present composition is Camphora, menthol, 1-isopulegol, ethyl menthane formamide and trimethyl isopropyl butanamide.
Annexing ingredient
Wide variety of other additional components can be formulated in the compositions of the present invention.These components comprise: other conditioner such as Salcare SC96, it is Polyquatemium 37, the mixture of propylene glycol two sad dicaprates and PPG-1 trideceth-6, bought from Ciba Specialty Chemicals, with the hydrolytic collagen of trade name Peptein2000 available from Hormel, with the vitamin E of trade name Emix-d available from Eisai, pantothenylol available from Roche, general benzyl ethyl ether available from Roche, with trade name Polawax NF available from the Polysorbate 60 of CrodaChemicals and the mixture of 16/stearyl alcohol, glyceryl monostearate available from StepanChemicals, hydrolysis of keratin, albumen, plant extract and nutrient; Antiseptic is benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea for example; The pH regulator agent is citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate for example; Salt is potassium acetate and sodium chloride for example; Coloring agent is FD﹠amp for example; C or D﹠amp; In the C dyestuff any; Spice; Chelating agen is disodiumedetate for example; Ultraviolet and infrared ray intercept and absorbent, for example ethylhexyl salicylate; Dandruff removing agent is Zinc Pyrithione (zinc pyrithione) for example; Fluorescent whitening agent is as polystyrene stibene, triazine stibene, Hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazoles and composition thereof.
Compositions and using method
Care composition of the present invention is to be used for being coated to dried hair before with shampoo washing hair.Be surprisingly found out that now when using by this way, care composition has brought conditioning effect as arrangement property with make hair full to hair.Term used herein " hair is full " is not equal to the hair that disperses.The hair that disperses is because due to electrostatic charge increases, and the expression hair generally has only the volume of very a spot of hair to increase as one, and is unfavorable.On the other hand, the full increase that relates to the body of hair volume of term hair used herein.Consumer with thin hair wishes to make hair full, controls unfavorable hair simultaneously and disperses.Be surprisingly found out that now in the time of on being coated to hair, Haircare composition as herein described can increase piles up hair volume (bulk hair volume), and can reduce the hair volume that disperses (flyaway hair volume).
Use the appropriate method of the present composition to comprise the following steps:
(a) on dried hair, apply Wo 2008069000 mentioned above; And
(b) with the shampoo composite hair washing that comprises detersive surfactant.
By compositions of the present invention is coated on the dried hair, think that oil will deposit and cover on the surface of hair, perhaps to a certain extent, be penetrated in the hair, thereby and stay on the hair, even also be like this in the hair washing process.Because the emulsifying of compositions if compositions is coated on the wet hair, took place in the inversion of phases performance of the present composition before depositing and/or being penetrated in the hair.Therefore, a feature of the inventive method is that compositions of the present invention is coated on the dried hair, rather than after with water-wet.Not bound by theory, think that by treatment of hair before with shampoo washing hair, the booty on the hair has been removed in hair washing then, simultaneously a certain amount of conditioning oil of the present invention is stayed on the hair.Think and need not compositions of the present invention hair is carried out pretreatment and compare when having one's hair wash, stay in the hair or on conditioning oil provide obvious good arrangement and appearance to hair.
The shampoo composite that uses in step (b) can be to comprise any compositions of detersive surfactant and be applicable to the booty of washing off on the hair.Detersive surfactant used herein is that intention distinguishes the surfactant that the latter promptly provides emulsifying effectiveness and has the low cleaning performance with these surfactants and the surfactant that mainly is emulsifying surfactant.Will be appreciated that most of surfactants have decontamination and emulsifiability simultaneously.Do not wish emulsifying surfactant is got rid of outside the present invention, as long as described surfactant also has and is enough to detergency ability used in this invention.Detersive surfactant is selected from anion surfactant, amphoteric surfactant, non-ionic surface active agent and composition thereof usually.It is can or can be not identical with contained detersive surfactant in the care composition of the present invention to be included in detersive surfactant in the shampoo composite.In a preferred embodiment, comprise at least a anion surfactant in the employed shampoo composite in the step (b).
The amount that is used for the present composition of treatment of hair before with shampoo washing hair depends on the volume of hair and required conditioning effect.Usually use about 2 milliliters to about 40 milliliters, preferred about 5 milliliters of about 20 milliliters compositionss of the present invention extremely.
The present invention needn't get rid of wherein after the hair washing or behind hair washing and dry hair, and additional rinses type and/or leave care composition are coated to whole hair processing scheme on the hair.
Embodiment
Embodiment has hereinafter further described and has illustrated the embodiment in the scope of the invention.These embodiment only are used for illustrative purposes and are not construed as limiting the invention, because can do various changes to it on the basis that does not deviate from essence of the present invention and scope.Each composition is represented with chemical name or CTFA title, or following the definition.
Embodiment 1-8 is coated to before with shampoo washing hair on the dried hair and the Wo 2008069000 of the present invention that uses.
The compositions of embodiment 1-5
Component Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Paraffin oil * 1 Be used to make 100% Be used to make 100% Be used to make 100% Be used to make 100% Be used to make 100%
Canola oil * 2 20 20 20 20 20
Sorbeth-40 four oleate * 5 4 4 ?4 ?4 ?4
Anhydro sorbitol isostearate * 6 1 1 ?1 ?1 ?1
?Oleth-5*7 4 4 ?4 ?4 ?4
SEFA docosane acid esters * 8 5 ?1
12-hydroxy stearic acid * 9 ?1.5
Dibutyl lauroyl glutamine * 10 ?0.5
Trihydroxy stearin * 11 ?5
P-Hydroxybenzoate 0.1 0.1 ?0.1 ?0.1 ?0.1
Vitamin E 0.2 0.2 ?0.2 ?0.2 ?0.2
Glycerol 0.1 0.1 ?0.1 ?0.1 ?0.1
Deionized water 0.3 0.3 ?0.3 ?0.3 ?0.3
Spice 0.3 0.3 ?0.3 ?0.3 ?0.3
Ethanol 3
The compositions of embodiment 6-8
Component Embodiment 6 Embodiment 7 Embodiment 8
Paraffin oil * 1 Be used to make 100% Be used to make 100% Be used to make 100%
Canola oil * 2 28 ?28 ?28
Myristyl myristate * 3 7 ?6 ?6
C12-13AE(6-7EO)*4 4 ?4
Sorbeth-40 four oleate * 5 ?3
Anhydro sorbitol isostearate * 6 ?1
Oleth-5*7 ?1 ?0.5
Deionized water 0.15 ?0.15 ?0.15
Menthol 0.1 ?0.5 ?0.1
Spice 0.3 ?0.3 ?0.3
Salcare?SC96*12 2
The component definition
*1 paraffin oil: be about 330 the isoparaffin and the blend of cycloalkane available from the molecular weight of Witco with trade name Camation
*2 Canola oils: available from the Canola Salad Oil of Ajinomoto
*3 myristyl myristates: available from the Crodamol MM of Croda
*4 C12-13AE (6-7EO): available from the Neodol 23-6.5 of Shell
*5 Sorbeth-40, four oleates: available from the Nikkol GO-440 of Nikko Chemicals
*6 anhydro sorbitol isostearates: available from the Crill6 of Nikko Chemicals
*7 Oleth-5: available from the Volpo 5 of Croda
*8 SEFA docosane acid esters: the sucrose that derives from the long-chain fatty acid esterification of hardened, high erucic acid rapeseed oil available from the usefulness of P﹠G
*9 12-hydroxy stearic acids: available from Kawaken
*10 dibutyl lauroyl glutamine: available from the GP-1 of Ajinomoto
*11 trihydroxy stearins: available from the Thixcin R of Rheox
*12 Salcare SC96: available from the mixture of Polyquatemium 37, propylene glycol two sad dicaprates and the PPG-1 trideceth-6 of Ciba Specialty Chemicals.
The preparation of compositions method
The compositions of embodiment 1-8 above can be by any conventional method preparation.Suitable method is as described below:
Paraffin oil is heated to about more than 50 ℃, adds non-ionic surface active agent and stir, add all the other conditioning oil.Can be with before other component be mixed, with antiseptic and antioxidant (if present) and the oily premix of a kind of conditioning.Add all the other components and other temperature-sensitive component such as spice and menthol outside dewatering.At last, product is being cooled to after about 35 ℃, if add water, spice and the menthol that exists.
The preparation of compositions of embodiment 2 is by paraffin oil being heated to about 75 ℃, adds SEFA docosane acid esters, and carry out according to above-mentioned same procedure.After being cooled to 35 ℃, product adds ethanol.
The preparation of compositions of embodiment 3 is by paraffin oil being heated to about 75 ℃, adds 12-hydroxy stearic acid and SEFA docosane acid esters, and carry out according to above-mentioned same procedure.In about 10 minutes, compositions is cooled to about 30 ℃ from 75 ℃.
The preparation of compositions of embodiment 4 is by paraffin oil being heated to about 160 ℃, adds dibutyl lauroyl glutamine, and carry out according to above-mentioned same procedure.
Previous embodiment embodiment disclosed and representative has many benefits.For example, embodiment 1-8 can provide the conditioning beneficial effect to pile up hair volume as increasing; Whole full weight (body fullness); Combing easily, arrangement and shaping hair; Provide smooth, softness and moisture feeling to hair, and bring gloss to hair.It is about 1 that embodiment 2-5 also has, and 000mPas is to about 100, the viscosity of 000mPas and have good spreadability on hair.Embodiment 1 and 6-8 also have at least about the viscosity of 100mPas and have limpid outward appearance.
Should be understood that, embodiment of the present invention and embodiment only are used for illustrative purposes, without departing from the spirit and scope of the present invention down, those of ordinary skill in the art can make multiple change or variation on the basis of disclosed embodiment of the present invention and embodiment.

Claims (11)

1. one kind is used for being coated to Wo 2008069000 on the dried hair before hair washing, and it comprises following component by weight:
(a) at 25 ℃ of conditioning oil that are liquid form; With
(b) non-ionic surface active agent, its amount is for producing the amount of inversion of phases when compositions contacts with the water of fully measuring.
2. the Wo 2008069000 of claim 1 also comprises thickening agent.
3. the Wo 2008069000 of claim 2, wherein thickening agent is a sucrose polyfatty acid esters.
4. the Wo 2008069000 of claim 2, wherein thickening agent is the gellant that is selected from N-acyl amino-acid amide, 12-hydroxy stearic acid and ester thereof and their mixture.
5. the Wo 2008069000 of claim 2, wherein thickening agent comprises sucrose polyfatty acid esters and 12-hydroxy stearic acid or its ester.
6. claim 1 or 2 Wo 2008069000 also comprise sensitizer.
7. the Wo 2008069000 of claim 1, wherein conditioning oil comprise account for whole composition weight at least about 50% paraffin oil.
8. the Wo 2008069000 of claim 1 also comprises and is not more than about 0.5% water.
9. the method for a conditioning hair comprises the following step:
(a) on dried hair, apply the Wo 2008069000 of claim 1 or 2; With
(b) with the shampoo composite hair washing that comprises detersive surfactant.
10. method that increases the accumulation hair volume of hair comprises the following step:
(a) on dried hair, apply the Wo 2008069000 of claim 1 or 2; With
(b) with the shampoo composite hair washing that comprises detersive surfactant.
11. the method for claim 9 or 10 wherein is coated on the hair to about 40 milliliters Wo 2008069000 about 2 milliliters in step (a).
CN01814951.0A 2000-08-31 2001-02-23 Pre-shampoo conditioning composition Pending CN1449275A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101959492B (en) * 2008-02-25 2013-10-23 宝洁公司 Hair care compositions comprising sucrose polyesters
CN108699491A (en) * 2016-02-26 2018-10-23 赢创德固赛有限公司 The thickener blend composition that the amide and lipase of aliphatic polyamine and 12- hydroxyoctadecanoic acids are stablized
CN110709051A (en) * 2017-06-05 2020-01-17 宝洁公司 Pre-wash composition for cleaning benefits

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8318187B2 (en) 2004-04-30 2012-11-27 The Procter & Gamble Company Long-wearing cosmetic compositions with improved shine
US9308397B2 (en) * 2004-04-30 2016-04-12 The Procter & Gamble Company Long-wearing cosmetic compositions
GB0621993D0 (en) * 2006-11-04 2006-12-13 Unilever Plc Make-up remover cosmetic compositions
ES2816774T3 (en) 2014-03-11 2021-04-05 Doc Japan Co Ltd Oily cosmetic conditioning composition and cosmetic product
WO2015155046A1 (en) * 2014-04-10 2015-10-15 Unilever Plc Method of treating damaged hair
WO2015155047A1 (en) * 2014-04-10 2015-10-15 Unilever Plc Method of shaping hair
FR3022775B1 (en) * 2014-06-30 2018-03-02 L'oreal ANHYDROUS COMPOSITION COMPRISING A LIPOPHILIC GELIFIER, AT LEAST TWO SEPARATE LOADS OF ANOTHER AND A FATTY PHASE
US20160095809A1 (en) * 2014-10-03 2016-04-07 The Procter & Gamble Company Method of improved volume and combability using personal care composition comprising a pre-emulsified formulation

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH272709A (en) * 1950-08-22 1950-12-31 Tempia Caliera Pierre Product for hair care.
CA876102A (en) * 1968-10-09 1971-07-20 Martonfi Joseph Hair restorer
FR2167407A1 (en) * 1972-01-14 1973-08-24 Braquart Rosa Scalp treating prepn - of vegetable oils and animal fats mixt
JPS5421416B2 (en) * 1973-04-09 1979-07-30
JPS542345A (en) * 1977-06-02 1979-01-09 Lion Dentifrice Co Ltd Hair conditioner composition
GB8519426D0 (en) * 1985-08-01 1985-09-04 Ici Plc Composition for personal care products
LU86268A1 (en) * 1986-01-27 1988-01-20 Oreal NOVEL POLYGLYCEROL ETHERS AND THEIR USE IN COSMETICS AND PHARMACY
US5116607A (en) * 1990-02-27 1992-05-26 Jones Alma L Hair dressing
DE69121976T2 (en) * 1990-06-11 1997-02-06 Kao Corp Hair cleaners
US5407675A (en) * 1990-08-10 1995-04-18 Etemad-Moghadam; Parviz Method and composition for use on the scalp and eyebrow region of a subject
FR2668927B1 (en) * 1990-11-09 1993-01-08 Oreal COSMETIC ANHYDROUS COMPOSITION IN AEROSOL FORM FOR THE FORMATION OF A FOAM.
GB9113484D0 (en) * 1991-06-21 1991-08-07 Unilever Plc Cosmetic composition
DE4202964A1 (en) * 1992-02-01 1993-08-05 Wella Ag HAIR AND BODY TREATMENT
BR9306360A (en) * 1992-05-12 1998-06-30 Procter & Gamble Composition in antiperspirant gel stick
US5380455A (en) * 1992-06-01 1995-01-10 Kao Corporation Detergent composition
JP3356313B2 (en) * 1992-09-29 2002-12-16 サンスター株式会社 Hair cleaning composition
GB9223604D0 (en) * 1992-11-11 1992-12-23 Unilever Plc Cosmetic composition
GB9223603D0 (en) * 1992-11-11 1992-12-23 Unilever Plc Cosmetic composition
FR2725364B1 (en) * 1994-10-06 1997-01-03 Oreal ANHYDROUS COSMETIC COMPOSITION IN THE FORM OF FLEXIBLE PASTE AND PREPARATION METHOD
JP3195557B2 (en) * 1996-03-16 2001-08-06 ウエラ アクチェンゲゼルシャフト Mixed wax and cosmetics containing it
DE19835239A1 (en) * 1998-08-04 2000-02-24 Johnson & Johnson Gmbh Foaming oil preparation and its use

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101959492B (en) * 2008-02-25 2013-10-23 宝洁公司 Hair care compositions comprising sucrose polyesters
CN108699491A (en) * 2016-02-26 2018-10-23 赢创德固赛有限公司 The thickener blend composition that the amide and lipase of aliphatic polyamine and 12- hydroxyoctadecanoic acids are stablized
CN110709051A (en) * 2017-06-05 2020-01-17 宝洁公司 Pre-wash composition for cleaning benefits
CN110709051B (en) * 2017-06-05 2023-07-04 宝洁公司 Pre-wash composition for cleaning benefit

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MXPA03001802A (en) 2003-06-04
EP1313430A1 (en) 2003-05-28
AU2000270997A1 (en) 2002-03-13
MXPA03001801A (en) 2003-06-04
AU2001241677A1 (en) 2002-03-13
JP2004517812A (en) 2004-06-17
CN1454073A (en) 2003-11-05
WO2002017864A1 (en) 2002-03-07
EP1313429A1 (en) 2003-05-28
JP2004518619A (en) 2004-06-24
WO2002017865A1 (en) 2002-03-07

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