CN1415205A - Insecticide compsn. and its method of application - Google Patents
Insecticide compsn. and its method of application Download PDFInfo
- Publication number
- CN1415205A CN1415205A CN 02146519 CN02146519A CN1415205A CN 1415205 A CN1415205 A CN 1415205A CN 02146519 CN02146519 CN 02146519 CN 02146519 A CN02146519 A CN 02146519A CN 1415205 A CN1415205 A CN 1415205A
- Authority
- CN
- China
- Prior art keywords
- compound
- imidaclothiz
- composition
- insecticide
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 238000000034 method Methods 0.000 title claims description 5
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 8
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- 150000001875 compounds Chemical class 0.000 claims description 20
- -1 chlopyrifos Chemical compound 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 11
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a composite insecticide for preventing and eliminating the pests with piercing-sucking mouth part of the lepidopterous pests with high effect.
Description
Background information
As everyone knows, existing nitro-methylene-type systemic insecticide such as Imidacloprid (imidacloprid), it is the acting body of nicotinic acid acetylcholinesterase acceptor, it is mainly used in the control sucking pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid, its insecticidal spectrum and insecticidal effect all have desirable not to the utmost part.
The purpose of a kind of insecticide of the present invention and other compound compositions: with some other pesticide compositional, produce synergistic effect and have broad spectrum activity, or the control resistant strain, or delaying drug resistance produces.
Technical field
The object of the present invention is to provide that a kind of cost is low, a kind of nitro-methylenes systemic insecticide and other compound compositions of good disinsection effect, thereby improve insecticidal effect.
Summary of the invention
The present invention relates to that a kind of nitro-methylenes systemic insecticide and other compound make composition and application thereof.
The present invention proposes the composition that a kind of nitro-methylenes systemic insecticide and other compound are made, this insecticide is a kind of nitro-methylene-type systemic insecticide (chemical name: 1-(2-chloro-5-thiazolyl methyl)-N-Nitroimidazoline-2-base amine with following structural formula, the Chinese adopted name: imidaclothiz), other compound also is an insecticide.
The composition that a kind of insecticide of the present invention and other compound are made is characterized in that: contain following composition by weight:
Imidaclothiz 0.5%～30%
Other pesticide compound 0.5%～50%
Surfactant 3～20%
Carrier 3～65%.
Other compound is meant Pesticidal compound in the above-mentioned composition, and they mainly comprise:
1. Avermectin (abamectin)
2. 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan)
3. dichlorvos (dichlorvos)
4. chlorophos (trichlorfon)
5. sumithion (fenitrothion)
6. Hostathion (triazophos)
7. chlopyrifos (chlorpyrifos)
8. diazinon (diazinon)
9. isocarbophos (isocarbophos)
10. phoxim (phoxim)
11. omethoate (omethoate)
12. Profenofos (profenofos)
Malathion 13. (malathion)
14. orthene (acephate)
15. Methomyl (methomyl)
16. Bassa (fenobucarb)
17. Aphox (pirimicarb)
18. carbosulfan (carbosulfan)
19. Mobucin (isoprocarb)
20. cypermethrin (cypermethrin)
21. efficient chlorine hydrocyanic ester (beta-cypermethrin)
22. sumicidin (fenvalerate)
23. Buprofezin (buprofezin)
24. cartap (cartap)
25. desinsection list (monosultap)
26. desinsection peace (profurite-aminium)
27. dimehypo (bisultap)
Surfactant is emulsifier, dispersant or wetting agent, can be nonionic and/or ionic surfactant.The sodium salt or the calcium salt that comprise polyacrylic acid and lignin sulfonic acid; The fatty acid or fatty amine or the acid amides that contain at least 12 carbon atoms in the molecule are with the polycondensation product of oxirane and/or expoxy propane; The fatty acid ester of glycerine, sorbierite, sucrose or pentaerythrite is with the condensation polymer of oxirane and/or expoxy propane; Fatty alcohol or alkyl phenol be for example right-octyl phenol or right-octyl cresol, with the condensation polymer of oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; At least contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid in the molecule, sodium salt and the sweet-smelling alkyl sulfonic acid sodium such as the neopelex of preferable is sodium salt such as lauryl sodium sulfate, Teepol, sulfonated castor oil; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Particularly following material can be used as emulsifier and/or wetting agent: nonionic surface active agent such as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, ethoxylated castor oil, anion surfactant such as acidity and alkylsulfonate neutrality, alkyl sulfate and arylsulphonate.Lignin-sulphonate's alkali lye and the cellulose of deriving also can be used as dispersant.
Carrier can be water or organic solvent, natural and synthetic clay and silicate, attapulgite, calcium carbonate, calcium sulphate, ammonium sulfate, ammonium nitrate, urea, sugar, potash (sodium), synthetic hydrated silica and synthetic calcium silicates or alumina silicate, white carbon, natural and synthetic resin, solid multi-chlorophenol, perphosphate.
Organic solvent is benzene,toluene,xylene, alkylbenzene, Fluhyzon, chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride, many chloroethanes, cyclohexane, machine oil, kerosene, paraffin wax, methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol, propane diols, phenmethylol, furfuryl alcohol and cyclohexanol, acetone, methylisobutylketone, cyclohexanone, butyrolactone, dimethyl formamide, dimethyl sulfoxide (DMSO) and N-methyl-pyrrolones.
Natural silica or talcum powder, active face soil, vermiculite, kaolinite, montmorillonite and mica on natural and synthetic clay and the silicate.
Natural and synthetic resin cumarone resin, polyvinyl chloride, styrene polymer and copolymer.
Contain bleeding agent 0～4%, adsorbent 0～5%, anti-decomposition agent 0～2%, disintegrant 0～8%, viscosity modifier 0～1%, preservative 0～0.2%, defoamer 0～6%, film forming agent, dyestuff 0～0.02% weight portion in the composition.Bleeding agent can be Laurocapram or fast penetrant T, adsorbent can be white carbon or diatomite, anti-decomposition agent can be urea or epoxidized vegetable oil, disintegrant can be starch or sodium bicarbonate, viscosity modifier can be xanthans or carboxymethyl cellulose, stabilizing agent can be phosphate or oxirane and propylene oxide adduct and derivative thereof, preservative can be Sodium Benzoate or Potassium Benzoate, defoamer can be the organosilicon or the propylene oxide block copolymer of emulsification, film forming agent can be polyvinyl alcohol or Filmmagent W-2, and dyestuff can be azo dyes or kiton colors.
The present invention can be effective to prevent and treat sucking pest and lepidoptera pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof; Because its good interior absorption, be specially adapted to seed treatment and Gen Shi, on wheat class, corn, paddy rice, potato, beet and cotton, can continue pest control in early days, but the insect foliar spray control in growth later stages such as above-mentioned crop and citrus, deciduous fruit tree, tea tree, vegetables.Foliar spray has excellent preventive effect to leafhopper class, plant hopper, Phytophthira, thrips class, striped rice borer, paddy stem borer, and is also effective to aleyrodid, rice borer, rice leaf beetles, Lissorhoptrus oryzophilus Kuschel.
A kind of Nitromethylene insecticides and other insecticide combination in the present composition, it improves effect and is considered to its synergistic effect and broad spectrum of activity, as imidaclothiz and Buprofezin combination, to water rice hopper performance synergistic effect.
The present invention is with following embodiment explanation.
The preparation of embodiment 1 microemulsion
| 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine (imidaclothiz) Hostathion emulsifier bleeding agent organic solvent and water | 10.0% (m/m) 30.0% (m/m), 15.0% (m/m) 2.0% (m/m) complements to 100% (m/m) |
Active component through stirring and dissolving, obtains light brown solution with organic solvent, adds the further stirring and dissolving of emulsifier and bleeding agent again, adds water at last and continues to be stirred to transparent.This combination can have obvious synergistic effect to rice-stem borer, double simultaneously harness the river rice fulgorid and striped rice borer etc.
Subjects: rice-stem borer, third-instar larvae, body weight 3mg～4mg.
Test method: reagent is diluted 5～7 concentration by irregular gradient ratio, fresh wild rice stem is immersed in the soup for preparing, through (general 3s～5s) taking-up is dried and put into the culture dish that diameter is 6cm behind the certain hour, every culture dish connects 5 larvas, each concentration is handled 50, and other establishes contrast.Larva is after treatment still put into receptacle, looks into death toll after 48 hours and calculates lethality, plants calculating virulence regression equation LC according to drug concentration logarithm value and dead probability
50(ppm).Calculate co-toxicity coefficient according to the abundant method of Sun Yun.See Table 1
Each concentration of treatment of table 1 is to the virulence of striped rice borer
| Medicament title and ratio | Virulence regression equation | ????LC 50(ppm) | Co-toxicity coefficient |
| Imidaclothiz (A) | ??Y＝2.0255+2.2068X | ????22.28 | |
| Hostathion (B) | ??Y＝6.1935+2.8299X | ????0.3787 | |
| ????A∶B＝1∶1 | ??Y＝5.4784+2.3043X | ????0.62 | ????120.15 |
| ????A∶B＝1∶2 | ??Y＝5.7219+1.9640X | ????0.429 | ????131.24 |
| ????A∶B＝1∶3 | ??Y＝5.9219+2.1464X | ????0.3720 | ????151.42 |
| ????A∶B＝1∶4 | ??Y＝5.8176+2.0340X | ????0.4473 | ????105.37 |
| ????A∶B＝2∶1 | ??Y＝5.0789+2.4416X | ????0.9283 | ????118.36 |
As can be seen from the table, imidaclothiz and Hostathion are the most obvious with 1: 3 proportioning synergy, and co-toxicity coefficient is 151.42.
The preparation of embodiment 2 water-dispersible granules
| 1-, (2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine, (imidaclothiz) desinsection list, (monosultap) dispersant wetting agent disintegrant bleeding agent carrier | 10%, (m/m) 5.0%, (m/m) 10.0%, (m/m) 0.2%%, (m/m) 5.0%, (m/m) 2.0%, (m/m) complement to 100%, (m/m) |
Imidaclothiz is prefabricated into suspending agent, adds desinsection list (＜200 order) and make thick slurry thing, water content is carried out extruder grain again or is waved granulation below 20%.This combination is obvious to rice-stem borer synergy, can doublely harness the river rice fulgorid and striped rice borer etc.
Subjects: rice-stem borer, third-instar larvae, body weight 3mg～4mg.
Test method: reagent is diluted 5～7 concentration by irregular gradient ratio, fresh wild rice stem is immersed in the soup for preparing, through (general 3s～5s) taking-up is dried and put into the culture dish that diameter is 6cm behind the certain hour, every culture dish connects 5 larvas, each concentration is handled 50, and other establishes contrast.Larva is after treatment still put into receptacle, looks into death toll after 48 hours and calculates lethality, plants calculating virulence regression equation LC according to drug concentration logarithm value and dead probability
50(ppm).Calculate co-toxicity coefficient according to the abundant method of Sun Yun.See Table 2
Each concentration of treatment of table 2 is to the virulence of striped rice borer
| Medicament title and ratio | Virulence regression equation | ????LC 50(ppm) | Co-toxicity coefficient |
| Imidaclothiz (A) | ??Y＝2.0255+2.2068X | ????22.28 | |
| Desinsection list (B) | ??Y＝1.8244+2.2884X | ????24.42 | |
| ????A∶B＝1∶1 | ??Y＝2.0454+2.2416X | ????20.80 | ????112.30 |
| ????A∶B＝1∶2 | ??Y＝1.6647+2.5143X | ????21.21 | ????108.23 |
| ????A∶B＝1∶3 | ??Y＝1.8727+2.3421X | ????21.64 | ????110.20 |
| ????A∶B＝1∶4 | ??Y＝2.3884+1.8924X | ????23.99 | ????98.30 |
| ????A∶B＝2∶1 | ??Y＝2.4684+1.9847X | ????18.86 | ????125.41 |
As can be seen from the table, imidaclothiz and desinsection list are the most obvious with 2: 1 proportioning synergy, and co-toxicity coefficient is 125.41.
Imidaclothiz 20% is added desinsection list 10%, and carrier is done corresponding minimizing, does not change the water-dispersible granules that other component proportioning is made, and is embodiment 3.
Imidaclothiz 30% is added desinsection list 15%, and carrier is done corresponding minimizing, does not change the water-dispersible granules that other component proportioning is made, and is embodiment 4.
Embodiment 5 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine is to the virulence effect of the red aphid of peach
| Concentration (ppm) | Concentration logarithm value (x) | 24 hours | 48 hours | ||
| Corrected mortality (%) | Lethality probit value (y) | Corrected mortality (%) | Lethality probit value (y) | ||
| ??25 | ?1.3979 | ????90 | ????6.2816 | ????98 | ????7.0537 |
| ??12.5 | ?1.0969 | ????82 | ????5.9154 | ????87 | ????6.1264 |
| ??6.25 | ?0.7959 | ????60 | ????5.2533 | ????65 | ????5.3853 |
| ??3.125 | ?0.4949 | ????32 | ????4.5323 | ????39 | ????4.7207 |
| ??1.5626 | ?0.1938 | ????18 | ????4.0846 | ????19 | ????4.1221 |
Embodiment 6 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the cabbage aphid field efficacy
| Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | ||
| 1 day | 3 days | 7 days | |
| ????0.5 | ????85.8 | ????88.4 | ????90.2 |
| ????1.0 | ????94.6 | ????94.4 | ????94.8 |
| ????1.5 | ????95.4 | ????95.2 | ????96.9 |
| CK (borer population/strain of on average living) | ????28.88 | ????34.56 | ????46038 |
Embodiment 7 contains the virulence effect of the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to brown back rice plant hopper
| Concentration of treatment (ppm) | Borer population alive | Dead borer population | Lethality | Corrected mortality |
| ????10 | ????17 | ????115 | ????87.12 | ????85.39 |
| ????5 | ????26 | ????107 | ????80.45 | ????77.83 |
| ????2.5 | ????45 | ????99 | ????68.75 | ????64.56 |
| ????1.25 | ????58 | ????75 | ????56.39 | ????50.54 |
| ????0.625 | ????78 | ????60 | ????43.48 | ????35.90 |
| ????CK | ????149 | ????20 | ????11.83 | ????/ |
Embodiment 8 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the brown planthopper field efficacy
| Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | |||
| 1 day | 3 days | 7 days | 30 days | |
| ??0.5 | ????82.0 | ?????88.8 | ????89.9 | ????93.8 |
| ??1.0 | ????79.1 | ????85.2 | ????85.8 | ????94.3 |
| ??1.5 | ????87.2 | ????93.4 | ????92.6 | ????97.3 |
| CK (hundred caves borer population alive) | ????678 | ????598 | ????558 | ????224 |
Embodiment 9 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the Trialeurodes vaporariorum Westwood preventive effect
| Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | ||
| 1 day | 3 days | 7 days | |
| ??1.0 | ????44.3 | ????61.2 | ????70.2 |
| ??1.5 | ????61.9 | ????83.3 | ????91.9 |
| ??2.0 | ????64.1 | ????85.5 | ????94.9 |
| CK (borer population/15 strains of living) | ????201 | ????217 | ????245 |
Claims (10)
1, the composition made of 1-(2-chloro-5-thiazolyl methyl)-N-Nitroimidazoline-2-base amine (to call imidaclothiz in the following text) and other compound is characterized in that: contain following composition by weight:
Imidaclothiz 0.5%～30%
Other pesticide compound 0.5%～50%
Surfactant 3%～20%
Carrier 3%～65%.
2, imidaclothiz according to claim 1 and other compound are made composition, it is characterized in that: other compound also is an insecticide.
3, imidaclothiz according to claim 2 and other compound are made composition, it is characterized in that: other insecticide can be following compound: Avermectin, 5a,6,9,9a-hexahydro-6,9-methano-2,4, dichlorvos, chlorophos, sumithion, Hostathion, chlopyrifos, diazinon, isocarbophos, phoxim, omethoate, Profenofos, malathion, orthene, Methomyl, Bassa, Aphox, carbosulfan, Mobucin, cypermethrin, efficient chlorine hydrocyanic ester, sumicidin, Buprofezin, cartap, desinsection list, desinsection peace, dimehypo etc.
4, imidaclothiz according to claim 3 and other compound are made composition, it is characterized in that: Hostathion in the insecticide and desinsection list are preferentially selected for use.
5, according to the composition of above-mentioned any one claim, can be mixed with granule and comprise that big granula, tablet comprise effervescent tablet, aqueous emulsion, microemulsion, micro-capsule suspension, dry suspending agent, water-dispersible granules, wherein water-dispersible granules and microemulsion are preferentially selected for use.
6, the composition made of imidaclothiz according to claim 1 and other compound, it is characterized in that: surfactant is ionic or nonionic surface active agent.
7, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: carrier is water or organic solvent, natural or synthetic clay and silicate, attapulgite, calcium carbonate, calcium sulphate, ammonium sulfate, ammonium nitrate, urea, sugar, potash, sodium carbonate, synthetic hydrated silica and synthetic calcium silicates or alumina silicate, white carbon, natural and synthetic resin, solid multi-chlorophenol, perphosphate.
8, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: organic solvent is benzene and toluene, dimethylbenzene, alkylbenzene, Fluhyzon, chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride, many chloroethanes, cyclohexane, machine oil, kerosene, paraffin wax, methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol, propane diols, phenmethylol, acetone, methylisobutylketone; Natural and synthetic clay and silicate, natural silica or talcum powder, active face soil, vermiculite, kaolin, montmorillonite, mica; Natural and synthetic resin is cumarone resin or polyvinyl chloride, styrene polymer and copolymer.
9, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: bleeding agent 0～4%, adsorbent 0～5%, anti-decomposition agent 0～2%, disintegrant 0～8%, viscosity modifier 0～1%, preservative 0～0.2%, defoamer 0～6%, film forming agent, dyestuff 0～0.02%.
10, according to the composition of above-mentioned any one claim, can adopt spread fertilizer over the fields, spread manuer in holes, method such as spraying, seed treatment uses, be used to prevent and treat sucking pest and lepidoptera pest, comprise Phytophthira, leafhopper class, plant hopper, thrips class, aleyrodid class, striped rice borer, paddy stem borer and resistant strain thereof.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146519 CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146519 CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
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| CN1415205A true CN1415205A (en) | 2003-05-07 |
| CN1247090C CN1247090C (en) | 2006-03-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 02146519 Expired - Lifetime CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
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| CN (1) | CN1247090C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7445791B2 (en) * | 2004-07-12 | 2008-11-04 | United Phosphorus, Ltd. | Synergistic insecticidal composition containing Chloronicotynyle and Organosphosphorus compounds |
| CN101953380A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
| CN101953382A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
| CN101953375A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite mosquito-killing powder |
| CN102349503A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing imidaclothiz |
| CN102405927A (en) * | 2011-11-21 | 2012-04-11 | 广东中迅农科股份有限公司 | Wheat seed coating agent |
| CN106942261A (en) * | 2017-04-13 | 2017-07-14 | 青岛瀚生生物科技股份有限公司 | Composition and its application with pesticide and miticide actility |
| CN107318878A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN109414013A (en) * | 2016-07-27 | 2019-03-01 | 巴斯夫欧洲公司 | With anion C6-C10It is divided into the agricultural formulations of the microcapsules of powder |
| CN110521678A (en) * | 2019-09-29 | 2019-12-03 | 重庆市农业科学院 | A method of utilizing ant aphid commensalism large-scale breeding aphid |
| CN111869674A (en) * | 2020-07-19 | 2020-11-03 | 南通江山农药化工股份有限公司 | Imidaclothiz and diazinon insecticidal composition |
-
2002
- 2002-10-21 CN CN 02146519 patent/CN1247090C/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7445791B2 (en) * | 2004-07-12 | 2008-11-04 | United Phosphorus, Ltd. | Synergistic insecticidal composition containing Chloronicotynyle and Organosphosphorus compounds |
| CN101953382B (en) * | 2010-05-27 | 2012-04-18 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
| CN101953375A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite mosquito-killing powder |
| CN101953380A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
| CN101953380B (en) * | 2010-05-27 | 2012-04-18 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
| CN101953382A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
| CN102349503A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing imidaclothiz |
| CN102405927A (en) * | 2011-11-21 | 2012-04-11 | 广东中迅农科股份有限公司 | Wheat seed coating agent |
| CN107318878A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN109414013B (en) * | 2016-07-27 | 2021-11-12 | 巴斯夫欧洲公司 | Having an anion C6-C10Agroformulation of co-dispersant microcapsules |
| CN109414013A (en) * | 2016-07-27 | 2019-03-01 | 巴斯夫欧洲公司 | With anion C6-C10It is divided into the agricultural formulations of the microcapsules of powder |
| CN106942261A (en) * | 2017-04-13 | 2017-07-14 | 青岛瀚生生物科技股份有限公司 | Composition and its application with pesticide and miticide actility |
| CN110521678A (en) * | 2019-09-29 | 2019-12-03 | 重庆市农业科学院 | A method of utilizing ant aphid commensalism large-scale breeding aphid |
| CN110521678B (en) * | 2019-09-29 | 2021-11-16 | 重庆市农业科学院 | Method for large-scale aphid feeding by utilizing co-inhabitation of ants and aphids |
| CN111869674A (en) * | 2020-07-19 | 2020-11-03 | 南通江山农药化工股份有限公司 | Imidaclothiz and diazinon insecticidal composition |
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| Publication number | Publication date |
|---|---|
| CN1247090C (en) | 2006-03-29 |
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