CN1415205A - Insecticide compsn. and its method of application - Google Patents
Insecticide compsn. and its method of application Download PDFInfo
- Publication number
- CN1415205A CN1415205A CN 02146519 CN02146519A CN1415205A CN 1415205 A CN1415205 A CN 1415205A CN 02146519 CN02146519 CN 02146519 CN 02146519 A CN02146519 A CN 02146519A CN 1415205 A CN1415205 A CN 1415205A
- Authority
- CN
- China
- Prior art keywords
- compound
- imidaclothiz
- composition
- insecticide
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002917 insecticide Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 5
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 20
- -1 chlopyrifos Chemical compound 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 11
- 241000426497 Chilo suppressalis Species 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 230000000740 bleeding effect Effects 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 241001498622 Cixius wagneri Species 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 239000005885 Buprofezin Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 241001414720 Cicadellidae Species 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 241001414989 Thysanoptera Species 0.000 claims description 4
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 239000007884 disintegrant Substances 0.000 claims description 4
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000000025 natural resin Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005660 Abamectin Substances 0.000 claims description 3
- 239000005946 Cypermethrin Substances 0.000 claims description 3
- 239000005949 Malathion Substances 0.000 claims description 3
- 239000005916 Methomyl Substances 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 claims description 3
- 239000003463 adsorbent Substances 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 claims description 3
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 3
- 229960005424 cypermethrin Drugs 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims description 3
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229950001327 dichlorvos Drugs 0.000 claims description 3
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 claims description 3
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 claims description 3
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 claims description 3
- 229960000453 malathion Drugs 0.000 claims description 3
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims description 3
- 229960001952 metrifonate Drugs 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- PZXOQEXFMJCDPG-UHFFFAOYSA-N omethoate Chemical compound CNC(=O)CSP(=O)(OC)OC PZXOQEXFMJCDPG-UHFFFAOYSA-N 0.000 claims description 3
- 239000000575 pesticide Substances 0.000 claims description 3
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 claims description 3
- 229950001664 phoxim Drugs 0.000 claims description 3
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims description 3
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 claims description 3
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims description 3
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 241000255777 Lepidoptera Species 0.000 claims description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- 235000012241 calcium silicate Nutrition 0.000 claims description 2
- 239000001175 calcium sulphate Substances 0.000 claims description 2
- 235000011132 calcium sulphate Nutrition 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 239000010721 machine oil Substances 0.000 claims description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 125000005342 perphosphate group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 229960004029 silicic acid Drugs 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 239000010455 vermiculite Substances 0.000 claims description 2
- 229910052902 vermiculite Inorganic materials 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 239000007938 effervescent tablet Substances 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 239000003337 fertilizer Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- 239000003094 microcapsule Substances 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 239000003826 tablet Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002131 composite material Substances 0.000 abstract 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 230000001018 virulence Effects 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 231100000225 lethality Toxicity 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 230000009885 systemic effect Effects 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 241001124076 Aphididae Species 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000005906 Imidacloprid Substances 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 241000176086 Sogatella furcifera Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000746966 Zizania Species 0.000 description 2
- 235000002636 Zizania aquatica Nutrition 0.000 description 2
- 230000037396 body weight Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 description 2
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
- VIETUFSZPCIVQL-UHFFFAOYSA-N 1-methyl-3h-pyrrol-2-one Chemical class CN1C=CCC1=O VIETUFSZPCIVQL-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 102000012440 Acetylcholinesterase Human genes 0.000 description 1
- 108010022752 Acetylcholinesterase Proteins 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000982105 Brevicoryne brassicae Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000162400 Dicladispa armigera Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 241000966204 Lissorhoptrus oryzophilus Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241001556089 Nilaparvata lugens Species 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000005923 Pirimicarb Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241001249129 Scirpophaga incertulas Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940022698 acetylcholinesterase Drugs 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229930188620 butyrolactone Natural products 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- RDYMFSUJUZBWLH-SVWSLYAFSA-N endosulfan Chemical compound C([C@@H]12)OS(=O)OC[C@@H]1[C@]1(Cl)C(Cl)=C(Cl)[C@@]2(Cl)C1(Cl)Cl RDYMFSUJUZBWLH-SVWSLYAFSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 1
- 229960003639 laurocapram Drugs 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a composite insecticide for preventing and eliminating the pests with piercing-sucking mouth part of the lepidopterous pests with high effect.
Description
Background information
As everyone knows, existing nitro-methylene-type systemic insecticide such as Imidacloprid (imidacloprid), it is the acting body of nicotinic acid acetylcholinesterase acceptor, it is mainly used in the control sucking pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid, its insecticidal spectrum and insecticidal effect all have desirable not to the utmost part.
The purpose of a kind of insecticide of the present invention and other compound compositions: with some other pesticide compositional, produce synergistic effect and have broad spectrum activity, or the control resistant strain, or delaying drug resistance produces.
Technical field
The object of the present invention is to provide that a kind of cost is low, a kind of nitro-methylenes systemic insecticide and other compound compositions of good disinsection effect, thereby improve insecticidal effect.
Summary of the invention
The present invention relates to that a kind of nitro-methylenes systemic insecticide and other compound make composition and application thereof.
The present invention proposes the composition that a kind of nitro-methylenes systemic insecticide and other compound are made, this insecticide is a kind of nitro-methylene-type systemic insecticide (chemical name: 1-(2-chloro-5-thiazolyl methyl)-N-Nitroimidazoline-2-base amine with following structural formula, the Chinese adopted name: imidaclothiz), other compound also is an insecticide.
The composition that a kind of insecticide of the present invention and other compound are made is characterized in that: contain following composition by weight:
Imidaclothiz 0.5%~30%
Other pesticide compound 0.5%~50%
Surfactant 3~20%
Carrier 3~65%.
Other compound is meant Pesticidal compound in the above-mentioned composition, and they mainly comprise:
1. Avermectin (abamectin)
2. 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan)
3. dichlorvos (dichlorvos)
4. chlorophos (trichlorfon)
5. sumithion (fenitrothion)
6. Hostathion (triazophos)
7. chlopyrifos (chlorpyrifos)
8. diazinon (diazinon)
9. isocarbophos (isocarbophos)
10. phoxim (phoxim)
11. omethoate (omethoate)
12. Profenofos (profenofos)
Malathion 13. (malathion)
14. orthene (acephate)
15. Methomyl (methomyl)
16. Bassa (fenobucarb)
17. Aphox (pirimicarb)
18. carbosulfan (carbosulfan)
19. Mobucin (isoprocarb)
20. cypermethrin (cypermethrin)
21. efficient chlorine hydrocyanic ester (beta-cypermethrin)
22. sumicidin (fenvalerate)
23. Buprofezin (buprofezin)
24. cartap (cartap)
25. desinsection list (monosultap)
26. desinsection peace (profurite-aminium)
27. dimehypo (bisultap)
Surfactant is emulsifier, dispersant or wetting agent, can be nonionic and/or ionic surfactant.The sodium salt or the calcium salt that comprise polyacrylic acid and lignin sulfonic acid; The fatty acid or fatty amine or the acid amides that contain at least 12 carbon atoms in the molecule are with the polycondensation product of oxirane and/or expoxy propane; The fatty acid ester of glycerine, sorbierite, sucrose or pentaerythrite is with the condensation polymer of oxirane and/or expoxy propane; Fatty alcohol or alkyl phenol be for example right-octyl phenol or right-octyl cresol, with the condensation polymer of oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; At least contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid in the molecule, sodium salt and the sweet-smelling alkyl sulfonic acid sodium such as the neopelex of preferable is sodium salt such as lauryl sodium sulfate, Teepol, sulfonated castor oil; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Particularly following material can be used as emulsifier and/or wetting agent: nonionic surface active agent such as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, ethoxylated castor oil, anion surfactant such as acidity and alkylsulfonate neutrality, alkyl sulfate and arylsulphonate.Lignin-sulphonate's alkali lye and the cellulose of deriving also can be used as dispersant.
Carrier can be water or organic solvent, natural and synthetic clay and silicate, attapulgite, calcium carbonate, calcium sulphate, ammonium sulfate, ammonium nitrate, urea, sugar, potash (sodium), synthetic hydrated silica and synthetic calcium silicates or alumina silicate, white carbon, natural and synthetic resin, solid multi-chlorophenol, perphosphate.
Organic solvent is benzene,toluene,xylene, alkylbenzene, Fluhyzon, chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride, many chloroethanes, cyclohexane, machine oil, kerosene, paraffin wax, methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol, propane diols, phenmethylol, furfuryl alcohol and cyclohexanol, acetone, methylisobutylketone, cyclohexanone, butyrolactone, dimethyl formamide, dimethyl sulfoxide (DMSO) and N-methyl-pyrrolones.
Natural silica or talcum powder, active face soil, vermiculite, kaolinite, montmorillonite and mica on natural and synthetic clay and the silicate.
Natural and synthetic resin cumarone resin, polyvinyl chloride, styrene polymer and copolymer.
Contain bleeding agent 0~4%, adsorbent 0~5%, anti-decomposition agent 0~2%, disintegrant 0~8%, viscosity modifier 0~1%, preservative 0~0.2%, defoamer 0~6%, film forming agent, dyestuff 0~0.02% weight portion in the composition.Bleeding agent can be Laurocapram or fast penetrant T, adsorbent can be white carbon or diatomite, anti-decomposition agent can be urea or epoxidized vegetable oil, disintegrant can be starch or sodium bicarbonate, viscosity modifier can be xanthans or carboxymethyl cellulose, stabilizing agent can be phosphate or oxirane and propylene oxide adduct and derivative thereof, preservative can be Sodium Benzoate or Potassium Benzoate, defoamer can be the organosilicon or the propylene oxide block copolymer of emulsification, film forming agent can be polyvinyl alcohol or Filmmagent W-2, and dyestuff can be azo dyes or kiton colors.
The present invention can be effective to prevent and treat sucking pest and lepidoptera pest, as aphid, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof; Because its good interior absorption, be specially adapted to seed treatment and Gen Shi, on wheat class, corn, paddy rice, potato, beet and cotton, can continue pest control in early days, but the insect foliar spray control in growth later stages such as above-mentioned crop and citrus, deciduous fruit tree, tea tree, vegetables.Foliar spray has excellent preventive effect to leafhopper class, plant hopper, Phytophthira, thrips class, striped rice borer, paddy stem borer, and is also effective to aleyrodid, rice borer, rice leaf beetles, Lissorhoptrus oryzophilus Kuschel.
A kind of Nitromethylene insecticides and other insecticide combination in the present composition, it improves effect and is considered to its synergistic effect and broad spectrum of activity, as imidaclothiz and Buprofezin combination, to water rice hopper performance synergistic effect.
The present invention is with following embodiment explanation.
The preparation of embodiment 1 microemulsion
1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine (imidaclothiz) Hostathion emulsifier bleeding agent organic solvent and water | 10.0% (m/m) 30.0% (m/m), 15.0% (m/m) 2.0% (m/m) complements to 100% (m/m) |
Active component through stirring and dissolving, obtains light brown solution with organic solvent, adds the further stirring and dissolving of emulsifier and bleeding agent again, adds water at last and continues to be stirred to transparent.This combination can have obvious synergistic effect to rice-stem borer, double simultaneously harness the river rice fulgorid and striped rice borer etc.
Subjects: rice-stem borer, third-instar larvae, body weight 3mg~4mg.
Test method: reagent is diluted 5~7 concentration by irregular gradient ratio, fresh wild rice stem is immersed in the soup for preparing, through (general 3s~5s) taking-up is dried and put into the culture dish that diameter is 6cm behind the certain hour, every culture dish connects 5 larvas, each concentration is handled 50, and other establishes contrast.Larva is after treatment still put into receptacle, looks into death toll after 48 hours and calculates lethality, plants calculating virulence regression equation LC according to drug concentration logarithm value and dead probability
50(ppm).Calculate co-toxicity coefficient according to the abundant method of Sun Yun.See Table 1
Each concentration of treatment of table 1 is to the virulence of striped rice borer
Medicament title and ratio | Virulence regression equation | ????LC 50(ppm) | Co-toxicity coefficient |
Imidaclothiz (A) | ??Y=2.0255+2.2068X | ????22.28 | |
Hostathion (B) | ??Y=6.1935+2.8299X | ????0.3787 | |
????A∶B=1∶1 | ??Y=5.4784+2.3043X | ????0.62 | ????120.15 |
????A∶B=1∶2 | ??Y=5.7219+1.9640X | ????0.429 | ????131.24 |
????A∶B=1∶3 | ??Y=5.9219+2.1464X | ????0.3720 | ????151.42 |
????A∶B=1∶4 | ??Y=5.8176+2.0340X | ????0.4473 | ????105.37 |
????A∶B=2∶1 | ??Y=5.0789+2.4416X | ????0.9283 | ????118.36 |
As can be seen from the table, imidaclothiz and Hostathion are the most obvious with 1: 3 proportioning synergy, and co-toxicity coefficient is 151.42.
The preparation of embodiment 2 water-dispersible granules
1-, (2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine, (imidaclothiz) desinsection list, (monosultap) dispersant wetting agent disintegrant bleeding agent carrier | 10%, (m/m) 5.0%, (m/m) 10.0%, (m/m) 0.2%%, (m/m) 5.0%, (m/m) 2.0%, (m/m) complement to 100%, (m/m) |
Imidaclothiz is prefabricated into suspending agent, adds desinsection list (<200 order) and make thick slurry thing, water content is carried out extruder grain again or is waved granulation below 20%.This combination is obvious to rice-stem borer synergy, can doublely harness the river rice fulgorid and striped rice borer etc.
Subjects: rice-stem borer, third-instar larvae, body weight 3mg~4mg.
Test method: reagent is diluted 5~7 concentration by irregular gradient ratio, fresh wild rice stem is immersed in the soup for preparing, through (general 3s~5s) taking-up is dried and put into the culture dish that diameter is 6cm behind the certain hour, every culture dish connects 5 larvas, each concentration is handled 50, and other establishes contrast.Larva is after treatment still put into receptacle, looks into death toll after 48 hours and calculates lethality, plants calculating virulence regression equation LC according to drug concentration logarithm value and dead probability
50(ppm).Calculate co-toxicity coefficient according to the abundant method of Sun Yun.See Table 2
Each concentration of treatment of table 2 is to the virulence of striped rice borer
Medicament title and ratio | Virulence regression equation | ????LC 50(ppm) | Co-toxicity coefficient |
Imidaclothiz (A) | ??Y=2.0255+2.2068X | ????22.28 | |
Desinsection list (B) | ??Y=1.8244+2.2884X | ????24.42 | |
????A∶B=1∶1 | ??Y=2.0454+2.2416X | ????20.80 | ????112.30 |
????A∶B=1∶2 | ??Y=1.6647+2.5143X | ????21.21 | ????108.23 |
????A∶B=1∶3 | ??Y=1.8727+2.3421X | ????21.64 | ????110.20 |
????A∶B=1∶4 | ??Y=2.3884+1.8924X | ????23.99 | ????98.30 |
????A∶B=2∶1 | ??Y=2.4684+1.9847X | ????18.86 | ????125.41 |
As can be seen from the table, imidaclothiz and desinsection list are the most obvious with 2: 1 proportioning synergy, and co-toxicity coefficient is 125.41.
Imidaclothiz 20% is added desinsection list 10%, and carrier is done corresponding minimizing, does not change the water-dispersible granules that other component proportioning is made, and is embodiment 3.
Imidaclothiz 30% is added desinsection list 15%, and carrier is done corresponding minimizing, does not change the water-dispersible granules that other component proportioning is made, and is embodiment 4.
Embodiment 5 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine is to the virulence effect of the red aphid of peach
Concentration (ppm) | Concentration logarithm value (x) | 24 hours | 48 hours | ||
Corrected mortality (%) | Lethality probit value (y) | Corrected mortality (%) | Lethality probit value (y) | ||
??25 | ?1.3979 | ????90 | ????6.2816 | ????98 | ????7.0537 |
??12.5 | ?1.0969 | ????82 | ????5.9154 | ????87 | ????6.1264 |
??6.25 | ?0.7959 | ????60 | ????5.2533 | ????65 | ????5.3853 |
??3.125 | ?0.4949 | ????32 | ????4.5323 | ????39 | ????4.7207 |
??1.5626 | ?0.1938 | ????18 | ????4.0846 | ????19 | ????4.1221 |
Embodiment 6 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the cabbage aphid field efficacy
Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | ||
1 day | 3 days | 7 days | |
????0.5 | ????85.8 | ????88.4 | ????90.2 |
????1.0 | ????94.6 | ????94.4 | ????94.8 |
????1.5 | ????95.4 | ????95.2 | ????96.9 |
CK (borer population/strain of on average living) | ????28.88 | ????34.56 | ????46038 |
Embodiment 7 contains the virulence effect of the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to brown back rice plant hopper
Concentration of treatment (ppm) | Borer population alive | Dead borer population | Lethality | Corrected mortality |
????10 | ????17 | ????115 | ????87.12 | ????85.39 |
????5 | ????26 | ????107 | ????80.45 | ????77.83 |
????2.5 | ????45 | ????99 | ????68.75 | ????64.56 |
????1.25 | ????58 | ????75 | ????56.39 | ????50.54 |
????0.625 | ????78 | ????60 | ????43.48 | ????35.90 |
????CK | ????149 | ????20 | ????11.83 | ????/ |
Embodiment 8 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the brown planthopper field efficacy
Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | |||
1 day | 3 days | 7 days | 30 days | |
??0.5 | ????82.0 | ?????88.8 | ????89.9 | ????93.8 |
??1.0 | ????79.1 | ????85.2 | ????85.8 | ????94.3 |
??1.5 | ????87.2 | ????93.4 | ????92.6 | ????97.3 |
CK (hundred caves borer population alive) | ????678 | ????598 | ????558 | ????224 |
Embodiment 9 contains the composition of 1-(2-chloro-5-thiazole methyl)-N-Nitroimidazoline-2-base amine to the Trialeurodes vaporariorum Westwood preventive effect
Treatment dosage (g ai/667m 2) | Proofread and correct preventive effect (%) | ||
1 day | 3 days | 7 days | |
??1.0 | ????44.3 | ????61.2 | ????70.2 |
??1.5 | ????61.9 | ????83.3 | ????91.9 |
??2.0 | ????64.1 | ????85.5 | ????94.9 |
CK (borer population/15 strains of living) | ????201 | ????217 | ????245 |
Claims (10)
1, the composition made of 1-(2-chloro-5-thiazolyl methyl)-N-Nitroimidazoline-2-base amine (to call imidaclothiz in the following text) and other compound is characterized in that: contain following composition by weight:
Imidaclothiz 0.5%~30%
Other pesticide compound 0.5%~50%
Surfactant 3%~20%
Carrier 3%~65%.
2, imidaclothiz according to claim 1 and other compound are made composition, it is characterized in that: other compound also is an insecticide.
3, imidaclothiz according to claim 2 and other compound are made composition, it is characterized in that: other insecticide can be following compound: Avermectin, 5a,6,9,9a-hexahydro-6,9-methano-2,4, dichlorvos, chlorophos, sumithion, Hostathion, chlopyrifos, diazinon, isocarbophos, phoxim, omethoate, Profenofos, malathion, orthene, Methomyl, Bassa, Aphox, carbosulfan, Mobucin, cypermethrin, efficient chlorine hydrocyanic ester, sumicidin, Buprofezin, cartap, desinsection list, desinsection peace, dimehypo etc.
4, imidaclothiz according to claim 3 and other compound are made composition, it is characterized in that: Hostathion in the insecticide and desinsection list are preferentially selected for use.
5, according to the composition of above-mentioned any one claim, can be mixed with granule and comprise that big granula, tablet comprise effervescent tablet, aqueous emulsion, microemulsion, micro-capsule suspension, dry suspending agent, water-dispersible granules, wherein water-dispersible granules and microemulsion are preferentially selected for use.
6, the composition made of imidaclothiz according to claim 1 and other compound, it is characterized in that: surfactant is ionic or nonionic surface active agent.
7, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: carrier is water or organic solvent, natural or synthetic clay and silicate, attapulgite, calcium carbonate, calcium sulphate, ammonium sulfate, ammonium nitrate, urea, sugar, potash, sodium carbonate, synthetic hydrated silica and synthetic calcium silicates or alumina silicate, white carbon, natural and synthetic resin, solid multi-chlorophenol, perphosphate.
8, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: organic solvent is benzene and toluene, dimethylbenzene, alkylbenzene, Fluhyzon, chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride, many chloroethanes, cyclohexane, machine oil, kerosene, paraffin wax, methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol, propane diols, phenmethylol, acetone, methylisobutylketone; Natural and synthetic clay and silicate, natural silica or talcum powder, active face soil, vermiculite, kaolin, montmorillonite, mica; Natural and synthetic resin is cumarone resin or polyvinyl chloride, styrene polymer and copolymer.
9, the composition made of imidaclothiz according to claim 1 and other compound is characterized in that: bleeding agent 0~4%, adsorbent 0~5%, anti-decomposition agent 0~2%, disintegrant 0~8%, viscosity modifier 0~1%, preservative 0~0.2%, defoamer 0~6%, film forming agent, dyestuff 0~0.02%.
10, according to the composition of above-mentioned any one claim, can adopt spread fertilizer over the fields, spread manuer in holes, method such as spraying, seed treatment uses, be used to prevent and treat sucking pest and lepidoptera pest, comprise Phytophthira, leafhopper class, plant hopper, thrips class, aleyrodid class, striped rice borer, paddy stem borer and resistant strain thereof.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02146519 CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02146519 CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1415205A true CN1415205A (en) | 2003-05-07 |
CN1247090C CN1247090C (en) | 2006-03-29 |
Family
ID=4751095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 02146519 Expired - Lifetime CN1247090C (en) | 2002-10-21 | 2002-10-21 | Insecticide compsn. and its method of application |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1247090C (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7445791B2 (en) * | 2004-07-12 | 2008-11-04 | United Phosphorus, Ltd. | Synergistic insecticidal composition containing Chloronicotynyle and Organosphosphorus compounds |
CN101953380A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
CN101953382A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
CN101953375A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite mosquito-killing powder |
CN102349503A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing imidaclothiz |
CN102405927A (en) * | 2011-11-21 | 2012-04-11 | 广东中迅农科股份有限公司 | Wheat seed coating agent |
CN106942261A (en) * | 2017-04-13 | 2017-07-14 | 青岛瀚生生物科技股份有限公司 | Composition and its application with pesticide and miticide actility |
CN107318878A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
CN109414013A (en) * | 2016-07-27 | 2019-03-01 | 巴斯夫欧洲公司 | With anion C6-C10It is divided into the agricultural formulations of the microcapsules of powder |
CN110521678A (en) * | 2019-09-29 | 2019-12-03 | 重庆市农业科学院 | A method of utilizing ant aphid commensalism large-scale breeding aphid |
CN111869674A (en) * | 2020-07-19 | 2020-11-03 | 南通江山农药化工股份有限公司 | Imidaclothiz and diazinon insecticidal composition |
-
2002
- 2002-10-21 CN CN 02146519 patent/CN1247090C/en not_active Expired - Lifetime
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7445791B2 (en) * | 2004-07-12 | 2008-11-04 | United Phosphorus, Ltd. | Synergistic insecticidal composition containing Chloronicotynyle and Organosphosphorus compounds |
CN101953382B (en) * | 2010-05-27 | 2012-04-18 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
CN101953375A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite mosquito-killing powder |
CN101953380A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
CN101953380B (en) * | 2010-05-27 | 2012-04-18 | 江苏点金石凹土研究开发有限公司 | Attapulgite maggot-killing powder |
CN101953382A (en) * | 2010-05-27 | 2011-01-26 | 江苏点金石凹土研究开发有限公司 | Attapulgite fly-killing powder |
CN102349503A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing imidaclothiz |
CN102405927A (en) * | 2011-11-21 | 2012-04-11 | 广东中迅农科股份有限公司 | Wheat seed coating agent |
CN107318878A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
CN109414013B (en) * | 2016-07-27 | 2021-11-12 | 巴斯夫欧洲公司 | Having an anion C6-C10Agroformulation of co-dispersant microcapsules |
CN109414013A (en) * | 2016-07-27 | 2019-03-01 | 巴斯夫欧洲公司 | With anion C6-C10It is divided into the agricultural formulations of the microcapsules of powder |
CN106942261A (en) * | 2017-04-13 | 2017-07-14 | 青岛瀚生生物科技股份有限公司 | Composition and its application with pesticide and miticide actility |
CN110521678A (en) * | 2019-09-29 | 2019-12-03 | 重庆市农业科学院 | A method of utilizing ant aphid commensalism large-scale breeding aphid |
CN110521678B (en) * | 2019-09-29 | 2021-11-16 | 重庆市农业科学院 | Method for large-scale aphid feeding by utilizing co-inhabitation of ants and aphids |
CN111869674A (en) * | 2020-07-19 | 2020-11-03 | 南通江山农药化工股份有限公司 | Imidaclothiz and diazinon insecticidal composition |
Also Published As
Publication number | Publication date |
---|---|
CN1247090C (en) | 2006-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Zhang et al. | Insecticidal and fungicidal activities of chitosan and oligo-chitosan | |
CN1415205A (en) | Insecticide compsn. and its method of application | |
AU2006237375A1 (en) | Biologically active formulation based on cyclodextrin supramolecular complexes | |
CN101422153A (en) | Insecticidal composition containing pymetrozine | |
CN102630691A (en) | Pesticide composition containing cyflumetofen | |
CN102342291A (en) | Pesticide composition containing spinetoram and pyrethroid compound | |
CN111513069A (en) | Pesticide composition for preventing and treating red pine cone pests and application thereof | |
CN106857581A (en) | A kind of nematicidal composition containing trifluoro miaow pyridine acid amides | |
CN109247340A (en) | A kind of composition pesticide and its preparation method and application compounded containing microbial bacteria | |
CN1418059A (en) | Inoulant tolerant fungicidal compositions | |
CN106857564A (en) | The method for controlling plant root disease | |
CN102812964A (en) | Pesticide composition containing thiacloprid and validamycin | |
CN115176805B (en) | Pesticide composition containing spiromesifen and application thereof | |
CN103314988A (en) | Insecticidal composition containing pyridalyl and synthetic pyrethroids | |
CN102626101B (en) | A kind of Efficient insecticidal composition containing cyflumetofen | |
CN108633892A (en) | Bactericidal composition containing psoralen and octyl trichlamide | |
CN108633893A (en) | Bactericidal composition containing psoralen and dimoxystrobin | |
CN110115268B (en) | Pesticide composition containing tolfenpyrad and fluopyram | |
CN112237194A (en) | Insecticidal composition containing cyclic bromoantraniliprole | |
CN108077264A (en) | A kind of Pesticidal combination containing ethyl pleocidin and bromine worm fluorobenzene bisamide | |
CN102027951A (en) | Clothianidin-containing pesticide composition | |
CN108293997A (en) | bactericidal composition containing bromothalonil and eugenol | |
CN115500354A (en) | Insecticidal composition and application thereof | |
CN108142418A (en) | Bactericidal composition containing bromothalonil and propamidine | |
CN104872159A (en) | 4-p-phenoxy phenoxy methyl structure-containing 1,3-dioxolane compound and carbamate insecticide composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20060329 |
|
DD01 | Delivery of document by public notice | ||
DD01 | Delivery of document by public notice |
Addressee: Ren Xinfeng Document name: Notice of Expiration and Termination of Patent Right |