CN1346429A - Ultralow expansion brake rubber hose and its production method - Google Patents

Ultralow expansion brake rubber hose and its production method Download PDF

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Publication number
CN1346429A
CN1346429A CN00805930A CN00805930A CN1346429A CN 1346429 A CN1346429 A CN 1346429A CN 00805930 A CN00805930 A CN 00805930A CN 00805930 A CN00805930 A CN 00805930A CN 1346429 A CN1346429 A CN 1346429A
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Prior art keywords
reinforced layer
thermosetting resin
layer
rubber pipe
reinforcing fibre
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Granted
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CN00805930A
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Chinese (zh)
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CN1185427C (en
Inventor
小野茂生
寺嶋隆史
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Meiji Rubber and Chemical Co Ltd
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Meiji Rubber and Chemical Co Ltd
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Priority claimed from PCT/JP2000/000623 external-priority patent/WO2001048412A1/en
Publication of CN1346429A publication Critical patent/CN1346429A/en
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Publication of CN1185427C publication Critical patent/CN1185427C/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D23/00Producing tubular articles
    • B29D23/001Pipes; Pipe joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60TVEHICLE BRAKE CONTROL SYSTEMS OR PARTS THEREOF; BRAKE CONTROL SYSTEMS OR PARTS THEREOF, IN GENERAL; ARRANGEMENT OF BRAKING ELEMENTS ON VEHICLES IN GENERAL; PORTABLE DEVICES FOR PREVENTING UNWANTED MOVEMENT OF VEHICLES; VEHICLE MODIFICATIONS TO FACILITATE COOLING OF BRAKES
    • B60T17/00Component parts, details, or accessories of power brake systems not covered by groups B60T8/00, B60T13/00 or B60T15/00, or presenting other characteristic features
    • B60T17/04Arrangements of piping, valves in the piping, e.g. cut-off valves, couplings or air hoses
    • B60T17/043Brake line couplings, air hoses and stopcocks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00Hoses, i.e. flexible pipes
    • F16L11/04Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L11/08Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
    • F16L11/085Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more braided layers
    • F16L11/086Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more braided layers two layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/151Coating hollow articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/10Cords, strands or rovings, e.g. oriented cords, strands or rovings
    • B29K2105/101Oriented
    • B29K2105/108Oriented arranged in parallel planes and crossing at substantial angles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/005Hoses, i.e. flexible

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Transportation (AREA)
  • Valves And Accessory Devices For Braking Systems (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

An ultralow expansion brake rubber hose is characterized in that the hose comprises an inner rubber tube, a first reinforcing layer, a second reinforcing layer, and an outer rubber tube, a thermosetting resin which is set at the vulcanizing temperature is penetrated through reinforcing fibers constituting the first layer and cured by vulcanization, and thereby the first layer is made an integral cured layer. Therefore, the slippage between the reinforcing fibers of the first layer is prevented because the first layer is thus a cured layer, providing a brake hose low in expansion and excellent in durability. Such a brake hose is produced by a method comprising the step of forming a first reinforcing layer on the inner rubber tube by stranding, the stap of penetrating a thermally curing resin liquid through reinforcing fibers constituting the first reinforcing layer by soaking the first reinforcing layer in the thermosetting resin liquid of low viscosity, the step of forming a second reinforcing layer by stranding, and the step of extrusion-molding an outer rubber tube on the second reinforcing layer.

Description

Ultralow expansion brake rubber hose and manufacture method thereof
Technical field
The present invention relates to be used for the brake rubber hose of brake device for car, specifically, ultralow expansion brake rubber hose that the swell increment when relating to initial pressure is minimum and manufacture method thereof.
Background technique
In the hydraulic brake system of automobile, the legpower of brake petal is transformed to hydraulic pressure, passes to each wheel cylinder by brake rubber hose by master cylinder.Brake rubber hose before is made of the reinforced layer of rubber pipe and braiding.Fig. 3 is the stereogram with the brake rubber hose biopsy cavity marker devices.Brake rubber hose is made of interior rubber pipe the 1, the 1st reinforced layer 2, intermediate rubber layer the 3, the 2nd reinforced layer 4 and outer rubber pipe 5.Interior rubber pipe 1 is by propylene diene rubber (EPDM), the styrene butadiene rubbers formations such as (SBR) of resistance to braking fluid.The 1st reinforced layer 2 is that the vinylon line braiding as reinforcing line is formed.Intermediate rubber layer 3 is by natural rubber (NR), EPDM, butyl rubber formations such as (IIR).The 2nd reinforced layer 4 forms the vinylon line braiding.Outer rubber pipe 5 is made of EPDM, neoprene (CR).
The manufacture method of above-mentioned brake rubber hose is as follows.First rubber pipe 1 in the periphery extrusion moulding of preprepared strip resin axle weaves the 1st reinforced layer 2 at the outer surface of interior rubber pipe 1.Then, on the outer circumferential face of the 1st reinforced layer 2, form intermediate rubber layer 3 with extrusion press extrusion moulding intermediate rubber layer 3 or coiling strip rubber tape.During coiling strip rubber tape, while the rubber tape of reeling weaves the 2nd reinforced layer 4 in the above.Then, extrusion moulding outer rubber pipe 5 on the periphery of the 2nd reinforced layer 4.These rubber hose are vulcanized with the strip axle, after the sulfuration, utilized hydraulic pressure to extract the strip axle, then, the strip rubber hose is cut into predetermined length use.
In recent years, along with the progress of engine technology and the improvement of road environment, the vehicle speed up is higher, stricter to the requirement of braking ability.Especially stopping power and braking sense there is higher requirement.Act among the pressure range of brake rubber hose, relevant with the braking sense is the low pressure range of 0~2.94MPa.Even under this low pressure, the reason that causes the flexible pipe internal volume to expand in hose construction, is not the elastic elongation because of the fiber of fabric reinforcement itself, but skid mutually between the reinforcing fibre that weaves or weave lax bigger influence arranged.
The factor that the domination internal volume expands is the 1st reinforced layer 2.For this reason, in order to suppress skidding between braided fiber, the reinforcing fibre (vinylon) on rubber pipe 1 outer circumferential face in being woven in is adhesively fixed before with binder.
But there is following problem in the method in binder reinforcing fibre being adhesively fixed on the rubber pipe outer circumferential face.That is, as binder, normally adopting rubber is solution-type sulfuration binder.At rubber is in the solution-type sulfuration binder, owing to contain solvent, so, after being coated on the interior rubber pipe 1, must need the certain hour drying, therefore, having applied rubber on the interior rubber pipe 1 is after solution-type vulcanizes binder, can not weave the 1st reinforced layer 2 immediately, so, can not carry out manufacturing process continuously.
In addition, in this method, though interior rubber pipe and reinforcing fibre are bonding, between the reinforcing fibre not necessarily by bonding.Therefore, the reinforcing fibre of the 1st reinforced layer 2 under the state bonding with interior rubber pipe 1 with the interior rubber pipe changing of the relative positions, can not suppress skidding mutually between the reinforcing fibre of the 1st reinforced layer 2 fully.So only the reinforcing fibre with the 1st reinforced layer 2 is bonded on the interior rubber pipe, can not get the little brake rubber hose of swell increment.
Goal of the invention
The present invention makes in view of the above problems, and its purpose is to provide a kind of brake rubber hose and manufacture method thereof of skidding mutually between the reinforcing fibre of the 1st reinforced layer of suppressing fully.
Another object of the present invention is by skidding mutually between the reinforcing fibre that suppresses the 1st reinforced layer fully, to provide ultralow expansion brake rubber hose and manufacture method thereof.
The summary of the invention summary
Technological scheme
To achieve these goals, adopt following solution.
Ultralow expansion brake rubber hose of the present invention, it is characterized in that, constitute by interior rubber pipe, the 1st reinforced layer, the 2nd reinforced layer, outer rubber pipe, form the reinforcing fibre of the 1st reinforced layer, the reinforcing fibre of the thermosetting resin that hardens has been soaked in employing under sulfurize temperature, make its sclerosis, the hardened layer that the 1st reinforced layer is formed as one by sulfuration.
Rubber pipe in above-mentioned can adopt the EPDM that is not easy to see through brake fluid, and the outer rubber pipe can adopt EPDM similarly.The reinforcing fibre that forms the 1st reinforced layer and the 2nd reinforced layer can adopt the vinylon silk.Thermosetting resin with reinforcing fibre soaks into can adopt melamine resin or phenolic resin.
The manufacture method of above-mentioned ultralow expansion brake rubber hose is characterized in that, carries out following the 1st to the 4th operation continuously;
In the 1st operation, braiding the 1st reinforced layer on interior rubber pipe;
In the 2nd operation, be impregnated in the low viscosity thermosetting resin liquid of reinforcing fibre of above-mentioned the 1st reinforced layer of saturable formation, thermosetting resin liquid is soaked in reinforcing fibre;
In the 3rd operation, weave the 2nd reinforced layer;
In the 4th operation, extrusion moulding outer rubber pipe on the outside of the 2nd reinforced layer.
In above-mentioned operation of soaking into thermosetting resin liquid, saturable low viscosity thermosetting resin liquid bath in reinforcing fibre is set, by being immersed in forcibly in the above-mentioned resin liquid bath, thermosetting resin liquid is soaked in reinforcing fibre.
In addition, preferably then in the operation of extrusion moulding outer rubber pipe, carry out making the operation of interior rubber pipe, thermosetting resin, the sclerosis of outer rubber pipe continuously by sulfuration.
Among the present invention, owing to the reinforcing fibre that makes the 1st inboard reinforced layer soaks into the hardened layer that thermosetting resin becomes one, so, in the time of can preventing to arrange the pressurization of the 1st reinforced layer that internal volume expands fully, skidding mutually between reinforcing fibre, swell increment can be suppressed very low.Therefore, can obtain braking the brake rubber hose of sense, good endurance.Before, after weaving the 1st reinforced layer on the interior rubber pipe, cover the 1st reinforced layer surface and fixing with thermosetting resin, not only can not be impregnated into fully between interior rubber pipe and the 1st reinforced layer, and the thickness of the resin layer that covers is also limited, and reinforcing fibre is hardened fully.Therefore, reinforcing fibre skids each other, the changing of the relative positions in the time of can not preventing to pressurize between reinforcing fibre.And make resin liquid be impregnated into reinforcing fibre inside among the present invention, so can make the 1st reinforced layer become hardened layer.
In addition, the outside of the 1st reinforced layer that is hardened by thermosetting resin has the wear resistance performance of height, does not need to prevent the intermediate rubber layer that weares and teares between the 1st reinforced layer and the 2nd reinforced layer.In addition, be solution-type sulfuration binder owing to do not use the rubber that contains solvent, so, can adopt the extrusion moulding of rubber pipe in carrying out continuously and the manufacturing process of the braiding of the 1st reinforced layer, simultaneously, also less than evaporation problem of environment pollution caused because of solvent.
The accompanying drawing simple declaration
Fig. 1 is the exploded perspective view of brake rubber hose of the present invention.
Fig. 2 is the explanatory drawing of expression manufacturing process.
Fig. 3 is the exploded perspective view of brake rubber hose of the prior art.
The optimal morphology that carries out an invention
Below, with reference to description of drawings example of the present invention.Among the figure, the 10th, interior rubber pipe is made of the EPDM that is not easy through brake fluid.The 11st, the 1st reinforced layer in being woven in vinylon line on rubber pipe 10 outer circumferential faces.The 13rd, be woven in the 2nd reinforced layer of the 1st reinforced layer 11 outer circumferential faces with vinylon line.The 15th, covering the outer rubber pipe that constitutes by EPDM.The thermosetting resin that the reinforcing fibre that forms above-mentioned the 1st reinforced layer 11 is hardened under sulfurize temperature is that melamine resin or phenolic resin soak into and is solidified into one.
That is, above-mentioned thermosetting resin not only covers the surface of reinforcing fibre, and is impregnated into the inside of reinforcing fibre itself, and reinforcing fibre itself is solidified.Therefore, form the thermosetting resin sclerosis that each reinforcing fibre of the 1st reinforced layer 11 is soaked into, also integrated between fiber, integral body forms hardened layer.The withstand voltage of brake rubber hose born by the 1st reinforced layer 11, and 13 of the 2nd reinforced layers play auxiliary effect, so the sclerosis of reinforcing fibre is only carried out just enough to the 1st reinforced layer 11.
The manufacture method of the brake rubber hose of above-mentioned structure as shown in Figure 2, with rubber pipe 10 in extrusion press 21 extrusion mouldings, weaves the 1st reinforced layer 11 with lacing machine 23 on the outside of rubber pipe 10 in this on strip axle 20.Then, the interior rubber pipe that has woven the 1st reinforced layer 11 is impregnated in the thermosetting resin liquid 25, thermosetting resin liquid 25 is soaked in reinforcing fibre.Above-mentioned thermosetting resin liquid 25 is adjusted to and is saturable low viscosity in reinforcing fibre, floods forcibly with the pushing roller 28,30 that is provided in the resin liquid bath 27, while be coated on the 1st reinforced layer 11 it is soaked into.
After the coating of thermosetting resin liquid, being impregnated on the 1st reinforced layer 11, with lacing machine 31 braidings the 2nd reinforced layer 13, then, with extrusion press 32 coating forming outer rubber pipes 15.Then, with similarly before, the thermosetting resin that soaks into the 1st reinforced layer is hardened with interior rubber pipe 10, outer rubber pipe 15 by sulfuration.
In the above-mentioned manufacture method, the 1st reinforced layer and the 2nd reinforced layer are set, last extrusion moulding outer rubber pipe, this point is identical with before manufacture method.With manufacture method difference before be, behind the knitting process of the 1st reinforced layer 11, the extrusion moulding of the intermediate rubber layer that does not have before to be carried out, but the operation of coating, heat of immersion hardening resin liquid is set, omitted the extrusion process of intermediate rubber layer.
Embodiment
Below, specific embodiment of the present invention is described.
Among the embodiment, interior rubber pipe 10 is to adopt EPDM, forms internal diameter 3.4mm, external diameter 5.0mm.The 1st reinforced layer 11 is the vinylon lines that adopt 1200 Denier, weaves with 2 * 20 weft yarns carriers (carrier).Then, make it soak into melamine resin,, the melamine resin that has soaked into is hardened with rubber by sulfuration.The 2nd reinforced layer 13 is the vinylon lines that adopt 1200 Denier, weaves with 3 * 24 weft yarns carriers.Outer rubber pipe 15 is to adopt EPDM, forms internal diameter 8.0mm, external diameter 10.4mm.
In the comparative example, the structure of interior rubber pipe, the 1st reinforced layer, the 2nd reinforced layer, outer rubber pipe is identical with embodiment, but, between the 1st reinforced layer and the 2nd reinforced layer with similarly being provided with 0.25mm before the thick intermediate rubber layer that constitutes by natural rubber, and, the outside of rubber pipe in the 1st reinforced layer is bonded in.
The test result of embodiment and comparative example is as follows.
The rubber hose of the foregoing description and comparative example has been done the test of swell increment and durability.Test conditions carries out according to JIS D2601.Durability has been carried out the towing test.Test result is as shown in table 1.
Table 1
Embodiment Comparative example
Flexible pipe swell increment (cc/m) Pressure 0.98Mpa ????0.04 ????0.10
Pressure 1.96Mpa ????0.09 ????0.13
Pressure 2.94Mpa ????0.11 ????0.16
The towing test More than 200 hours More than 200 hours
As known from Table 1, embodiment's rubber hose is compared with comparative example, and swell increment is little, and durability is not inferior yet.
Industrial applicibility
As mentioned above, ultralow expansion brake rubber hose of the present invention and manufacture method thereof are applicable to by master cylinder the pedal force of brake pedal is transformed to the hydraulic vehicle brake system of hydraulic pressure.

Claims (7)

1. ultralow expansion brake rubber hose, it is characterized in that, constitute by interior rubber pipe, the 1st reinforced layer, the 2nd reinforced layer, outer rubber pipe, the thermosetting resin that hardens under sulfurize temperature is impregnated in the reinforcing fibre that forms the 1st reinforced layer, make the sclerosis of above-mentioned thermosetting resin, the hardened layer that the 1st reinforced layer is formed as one.
2. ultralow expansion brake rubber hose as claimed in claim 1 is characterized in that above-mentioned thermosetting resin is a melamine resin.
3. ultralow expansion brake rubber hose as claimed in claim 1 is characterized in that above-mentioned thermosetting resin is a phenolic resin.
4. the manufacture method of ultralow expansion brake rubber hose is characterized in that, carries out following the 1st to the 4th operation continuously;
In the 1st operation, weaving the 1st reinforced layer on the interior rubber pipe;
In the 2nd operation, be impregnated in the saturable low viscosity thermosetting resin liquid in the reinforcing fibre that forms above-mentioned the 1st reinforced layer, thermosetting resin liquid is impregnated in the reinforcing fibre;
In the 3rd operation, weave the 2nd reinforced layer;
In the 4th operation, extrusion moulding outer rubber pipe on the outside of the 2nd reinforced layer.
5. the manufacture method of ultralow expansion brake rubber hose as claimed in claim 4, it is characterized in that, in above-mentioned operation of soaking into thermosetting resin liquid, saturable low viscosity thermosetting resin liquid bath in reinforcing fibre is set, by it is immersed in the above-mentioned resin liquid bath forcibly, thermosetting resin liquid is impregnated in the reinforcing fibre.
6. as the manufacture method of claim 4 or 5 described ultralow expansion brake rubber hoses, it is characterized in that above-mentioned thermosetting resin liquid is melamine resin or liquid phenolic resin.
7. as the manufacture method of each described ultralow expansion brake rubber hose in the claim 4 to 6, it is characterized in that, be connected on the vulcanization process that after the operation of extrusion moulding outer rubber pipe interior rubber pipe, thermosetting resin, outer rubber pipe is hardened.
CNB008059306A 2000-02-04 2000-02-04 Ultralow expansion brake rubber hose and its production method Expired - Lifetime CN1185427C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2000/000623 WO2001048412A1 (en) 1998-09-21 2000-02-04 Ultralow expansion brake rubber hose and its production method

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Publication Number Publication Date
CN1346429A true CN1346429A (en) 2002-04-24
CN1185427C CN1185427C (en) 2005-01-19

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1295457C (en) * 2003-10-10 2007-01-17 丰田合成株式会社 Reinforced hose
CN100467925C (en) * 2004-07-08 2009-03-11 株式会社电装 Pressure resistant vibration absorbing hose and mfg. method thereof
CN102003579A (en) * 2010-11-09 2011-04-06 蒋亨雷 Oil cooler pipe and manufacturing method thereof
CN102702625A (en) * 2012-05-07 2012-10-03 青岛三祥股份有限公司 Formula of inner rubber layer of braking pipe with braking fluid resistance and production process of inner rubber layer
CN103987515A (en) * 2011-12-14 2014-08-13 雷奥两合股份公司 Method for producing fibre-reinforced composite tube and the fibre-reinforced composite tube
CN104169070A (en) * 2012-03-29 2014-11-26 丰田合成株式会社 Method for producing reinforced hose
CN104235530A (en) * 2014-09-02 2014-12-24 中国人民解放军总后勤部油料研究所 Hose capable of being flattened and manufacturing method thereof
CN110202845A (en) * 2019-06-28 2019-09-06 安徽屹盛机电科技有限公司 A kind of double braiding layer high-pressure anti-wear hoses
CN111037945A (en) * 2019-12-31 2020-04-21 重庆泓通管业有限公司 Forming process of composite pipeline

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1295457C (en) * 2003-10-10 2007-01-17 丰田合成株式会社 Reinforced hose
CN100467925C (en) * 2004-07-08 2009-03-11 株式会社电装 Pressure resistant vibration absorbing hose and mfg. method thereof
CN102003579A (en) * 2010-11-09 2011-04-06 蒋亨雷 Oil cooler pipe and manufacturing method thereof
CN103987515A (en) * 2011-12-14 2014-08-13 雷奥两合股份公司 Method for producing fibre-reinforced composite tube and the fibre-reinforced composite tube
CN103987515B (en) * 2011-12-14 2017-04-12 雷奥两合股份公司 Method for producing fibre-reinforced composite tube and the fibre-reinforced composite tube
CN104169070A (en) * 2012-03-29 2014-11-26 丰田合成株式会社 Method for producing reinforced hose
CN102702625A (en) * 2012-05-07 2012-10-03 青岛三祥股份有限公司 Formula of inner rubber layer of braking pipe with braking fluid resistance and production process of inner rubber layer
CN104235530A (en) * 2014-09-02 2014-12-24 中国人民解放军总后勤部油料研究所 Hose capable of being flattened and manufacturing method thereof
CN110202845A (en) * 2019-06-28 2019-09-06 安徽屹盛机电科技有限公司 A kind of double braiding layer high-pressure anti-wear hoses
CN111037945A (en) * 2019-12-31 2020-04-21 重庆泓通管业有限公司 Forming process of composite pipeline

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