CN1338918A - Sheet-type packs - Google Patents
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- CN1338918A CN1338918A CN00803247A CN00803247A CN1338918A CN 1338918 A CN1338918 A CN 1338918A CN 00803247 A CN00803247 A CN 00803247A CN 00803247 A CN00803247 A CN 00803247A CN 1338918 A CN1338918 A CN 1338918A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9755—Gymnosperms [Coniferophyta]
- A61K8/9761—Cupressaceae [Cypress family], e.g. juniper or cypress
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- Life Sciences & Earth Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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- Biotechnology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
Sheet-type packs which exert a skin cleaning effect while maintaining an effect of appropriately moistening the skin and are excellent in the feel in using and safety to the skin. In particular, sheet-type packs containing fruit extracts.
Description
Technical field
The present invention relates to sheet-type packs (packs).In more detail, the present invention relates to give the skin moist feeling, be applicable to conditioning skin and the cosmetics of beauty treatment or the sheet-type packs that health product are used.
Background technology
As packs, open the spy that to have put down in writing with polyacrylate, polynary alcohol and water in the clear 54-49334 communique be main component, water-retaining property is good, the packs that peeling force is low.In addition, in the fair 1-46485 communique of spy, disclose and to have used the sheet-type packs of cross-linking type aqueous gel as base material, and special open to disclose in the flat 5-295004 communique to cooperate derive from the packs of natural semi-synthetic composition as wetting agent and viscosifier.
But existing packs has shortage to keep the skin wet to skin and moistening effect or the composition of preserving moisture lack the suspicion of release property, and there is the inadequate problem of dressing effect to skin in the result.
Disclosure of the Invention
Therefore, problem to be solved by this invention is to solve above-mentioned existing issue, provides a kind of skin is kept appropriate moisture retention, shows the skin Caring effect simultaneously, and usability and good to the safety of skin, has the sheet-type packs of dressing effect.
The inventor has found its solution in order to solve the concentrated repeatedly research of above-mentioned problem.
That is to say, the present invention relates to contain the sheet-type packs of fruit extract.
Sheet-type packs of the present invention is made of substrate and base cloth basically, and substrate contains wetting agent, water soluble polymer, cross-linking agent, water usually.And, wherein can suitably contain an amount of antiseptic, skin Caring auxiliary element (for example glycyrrhizic acid dipotassium, Aesculus chinensis Bunge extract, allantoin, water solublity intacellin, Oleum Caryophylli, Salvia farinacea extract etc.), antioxidant, viscosifier, lytic agent, pigment, spice, surfactant, UV absorbent, inorganic filler and pH regulator agent etc.
In addition, in the sheet-type packs of the present invention, the proportion of preferred water berry extract is 0.95~1.20, and pH is 3.3~5.0, and pol is 19~23 weight %.
And in the sheet-type packs of the present invention, the proportioning of preferred water berry extract accounts for 0.0003~33.87 weight % of substrate total amount, and the ratio of preferred water berry extract accounts for 0.03~96.77 weight % of wetting agent total amount.Matrix optimization contains wetting agent 1~35 weight %, water soluble polymer 3~25 weight %, cross-linking agent 0.05~20 weight % and water 60~95 weight %.Can further contain antiseptic 0.005~10 weight % in the substrate.
In addition, sheet-type packs of the present invention also can further contain glycols except that fruit extract.At this moment, the proportion optimization of glycols and fruit extract is 1~35: 0.01~30, in addition, and preferred Polyethylene Glycol of glycols and/or polypropylene glycol.
Among the present invention, fruit extract preferably is selected from the fruit extract more than a kind or 2 kinds in Rosehips extract, mandarin orange extract, citrus fruit juice, blackberry extract, Fructus actinidiae chinensis extract, Semen Cucumidis sativi extract, Fructus Gardeniae extract, grapefruit extract, Fructus Crataegi extract, Pericarpium Zanthoxyli extract, whitethorn extract, juniperus communis extract, Fructus Jujubae extract, デ ュ-Network extract, Fructus Lycopersici esculenti extract, Fructus Vitis viniferae extract, Fructus Luffae extract, pears certain kind of berries fruit juice, Fructus Mali pumilae extract, apple juice, citron extract, the lemon juice.
According to the present invention, also provide and use the skin Caring of above-mentioned sheet-type packs to apply some make up or health product.The working of an invention mode
Below, illustrate in greater detail the embodiment of sheet-type packs of the present invention, but the present invention is not limited to this.
In the present invention, containing fruit extract in the wetting agent, is the material that any one or the mixed liquor more than 2 kinds extract from fruit and/or peel in water, ethanol, propylene glycol, 1,3 butylene glycol and the Polyethylene Glycol.Preferably from the Rosehips extract, the mandarin orange extract, citrus fruit juice, the blackberry extract, Fructus actinidiae chinensis extract, the Semen Cucumidis sativi extract, Fructus Gardeniae extract, grapefruit extract, Fructus Crataegi extract, the Pericarpium Zanthoxyli extract, the whitethorn extract, the juniperus communis extract, Fructus Jujubae extract, デ ュ-Network extract, Fructus Lycopersici esculenti extract, Fructus Vitis viniferae extract, Fructus Luffae extract, pears certain kind of berries fruit juice, Fructus Mali pumilae extract, apple juice, citron extract, select in the lemon juice to be used more than a kind or 2 kinds.As the use level of these fruit extracts, can suitably cooperate in right amount, but preferably cooperate 0.0003~33.87 weight %, more preferably 0.0025~20 weight %.In the case, the ratio that fruit extract is accounted for the wetting agent total amount is adjusted to 0.03~96.77 weight %, preferred 0.04~83.33 weight %, more preferably 0.05~80.00 weight %; In addition the proportion of the fruit extract that cooperates more than a kind or 2 kinds is adjusted to 0.95~1.20, preferred 0.98~1.10, be 3.3~5.0, preferred 3.5~4.0 in addition with pH regulator; And making it to contain pol is 19~23 weight %, preferred 20~22 weight %; Kinematic viscosity (25 ℃) is 2.3~2.8mm in addition
2/ S, preferred 2.5~2.7mm
2/ S, and the content that contains vitamin C (ascorbic acid) is the above fruit extracts of 10.0 μ g, can further relax the zest to skin thus, and certainly significantly improve the relaxing effect that soft fragrance brings, and significantly improve the skin Caring action effect, therefore more effective.In addition, fruit extract is because the distinctive armaticity of various extracts also has the effect as spice.
Secondly, preferably Polyethylene Glycol and/or polypropylene glycol of same glycols as wetting agent among the present invention, particularly having polyether structure and mean molecule quantity and be 200~600 Polyethylene Glycol, mean molecule quantity is polypropylene glycol of 500~3000 etc., can use wherein to be used more than a kind or 2 kinds.
Decisions such as usability when the use level that these wetting agents account for the substrate total amount can be considered homogeneity, operability, the use of water-retaining type before the cohesiveness of preparation or compendency, the use and shape-retaining ability, gel, preferred 1~35 weight %, more preferably 5~30 weight %, further preferred 5~25 weight %.
On the other hand, usability when the proportioning of the wetting agent that these 2 kinds of compositions of glycols and fruit extract constitute can be considered homogenization, operability, the use of water-retaining type before the cohesiveness of preparation or compendency, the use and shape-retaining ability, gel, and the skin Caring effect that produces of the vitamin C that contains in the fruit extract or 'alpha '-hydroxy acids, the decisions such as salubrious action effect that faint fruit extract fragrance produces, preferred 1~35: 0.01~30, more preferably 5~25: 0.01~25, further preferred 5~20: 0.01~20.
Preferably this wetting agent is with the use level of 5~25 weight % to contain the packs of the wetting agent that is made of glycols and fruit extract, and the wherein contained glycols and the proportioning of fruit extract are 5~20: the packs of preparation in 0.01~20 scope.In the case, the ratio that glycols accounts for the wetting agent total amount is 3.23~99.97 weight %, preferred 16.67~99.96 weight %, more preferably 20.00~99.95 weight %.
Water soluble polymer is gelatin, polyacrylic acid or its salt or part corrective etc. for example, can use separately respectively or be used more than 2 kinds.The salt of polyacrylate preferably uses slaines such as sodium, lithium, potassium, and preferably its average degree of polymerization is 1000~100000.The use level of these water soluble polymers can be considered cohesiveness and compendency, shape-retaining ability, water absorbing properties, the heterogeneityization of mastic, the reduction of operability and the decisions such as reduction of usability of preparation, can use 3~25 weight %, preferred 5~20 weight %, more preferably 5~10 weight %.
Cross-linking agent can use slightly water-soluble aluminium compound or multi-functional epoxide separately, or is used more than 2 kinds.The slightly water-soluble aluminium compound is aluminium hydroxide, hydrated aluminium silicate, synthetic aluminium silicate, Kaolin, aluminum acetate, aluctyl., aluminium stearate, Aluminium Hydroxide, metasilicic acid magnesium aluminate, silicic acid magnesium aluminate, dihydroxyaluminum aminoacetate aluminum, synthetic hydrotalcite, Magnesiumaluminumsilicate etc. for example, can use wherein to be used more than a kind or 2 kinds.By using the slightly water-soluble aluminium compound, except the inhibition effect that presses down the skin irritation that the acid effect brings and skin contraction effect that the Trace Aluminum ion produces, can also present following function on the rerum natura in the early stage, promptly give gel suitable intensity as filler, simultaneously change the aluminium ion stripping in time in preparation, the compensation macromolecule through the time decompose and macromolecule between covalently cross-linked position through the time fracture gel strength that causes reduce.And, also can control its aluminum ions dissolution rate by the pH adjustment.
Above-mentioned multi-functional epoxide can use polyethyleneglycol diglycidylether, Ethylene glycol diglycidyl ether, glycerin diglycidyl ether, T 55, propylene glycol diglycidylether, the polyglycereol polyglycidyl ether, the sorbitol polyglycidyl ether, the anhydro sorbitol polyglycidyl ether, the trimethylolpropane polyglycidyl ether, five erithritol polyglycidyl ethers, resorcinolformaldehyde resin, being used more than a kind or 2 kinds in the neopentylglycol diglycidyl ether.By using multi-functional epoxide, can obtain good water absorbing properties and shape-retaining ability, and can form covalent bond effectively with water soluble polymer with carboxyl, amino or hydroxyl etc., improve the intensity of gel.
The use level of these cross-linking agent can consider that the coherency of preparation and shape-retaining ability, the reduction of water absorbing properties, the uneven first-class of mastic that ageing stability reduces, reduction, the safety reduction to skin, usability reduction, cohesiveness, the transition increase of manufacturing medium viscosity and the gelation of operability cause of preparation rerum natura determine, can use 0.05~20 weight %, preferred 0.5~15 weight %, more preferably 1~10 weight %.In addition, from the complex equilibrium of wetting agent, on preparation, preferably use slightly water-soluble aluminium compound and multi-functional epoxide simultaneously.
Water uses distilled water, aquesterilisa, natural water.Water plays a role as dispersion, the lytic agent of water soluble polymer, the composition of preserving moisture, cross-linking agent, antiseptic etc., particularly in order to make glycols and fruit extract as wetting agent disperse equably, be dissolved in that it is very important in the preparation.And water itself also can produce and significantly improve when using and the usability after using, and with wetting agent one in the same way skin divide a word with a hyphen at the end of a line, give the effect of moistening and tension force etc.Therefore, the use level of water can be considered the cohesiveness of preparation and use the reduction of preceding water-retaining property, the reduction of operability.The decisions such as reduction of shape-retaining ability before the inhibition of the reduction of usability, cohesiveness and compendency and the use can be added 60~95 weight %, preferred 65~90 weight %, more preferably 70~85 weight % during use.Contain a large amount of water in the preparation by making, can improve the relative humidity of preparation self, can in use big water gaging be discharged to the outside effectively in addition, it is moistening that the result gives skin, further volatilize to the outside, take away heat of gasification, give comfortable refrigerant sense by water.
Antiseptic for example is a p-Hydroxybenzoate (methyl parahydroxybenzoate for example, ethylparaben, propyl p-hydroxybenzoate), 1, the 2-pentanediol, benzoic acid, benzoate, salicylic acid, sorbic acid, sorbate, dehydroacetic acid, 4-isopropyl-3-methylphenol, 2-isopropyl-5-methylphenol, phenol, hinokitol, cresol, 2,4,4 '-three chloro-2 '-hydroxy diphenyl ether, 3,4,4 '-neko, methaform, benzalkonium chloride, benzethonium chloride and the material that well known to a person skilled in the art that is used for this purpose can use wherein to be used more than a kind or 2 kinds.Wherein preferred p-Hydroxybenzoate.The preparation that mould and generation bacterium caused during use level can be considered to preserve addles, when using and the decisions such as sense of discomfort that the usability after using reduces, cohesiveness, compendency and the stimulation of preparation and antiseptic flavor bring, can use 0.005~10 weight %, preferred 0.01~5 weight %, more preferably 0.01~1 weight %.As freshener and cool agent, can suitably cooperate L-menthol, d1-menthol, d1-Camphora, eucalyptus oil, Oleum menthae, isopulegol, 3-L- oxygen base propane-1,2-glycol, base ketopyrrolidine formic acid esters, L- base-3-butyric ester etc.
As antioxidant, can cooperate sodium ethylene diamine tetracetate, ascorbic acid, propyl gallate, butylated hydroxyanisole (BHA), dibenzylatiooluene, nordihydroguaiaretic acid, tocopherol, tocopheryl acetate etc.
As viscosifier, can cooperate casein, the enzyme polysaccharide of growing sturdily, agar, glucosan, sodium alginate, soluble starch, carboxyl starch, dextrin, carboxymethyl cellulose, sodium carboxymethyl cellulose, methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, polyvinyl alcohol, poly(ethylene oxide), polyacrylamide, polyacrylic acid, polyvinylpyrrolidone, carboxyl ethylene polymer, polyvinylether, poly copolymer, methoxy-ethylene copolymer-maleic anhydride, isobutene. copolymer-maleic anhydride, polymine etc.
As lytic agent, can cooperate benzyl alcohol, Oleum menthae, isopropyl myristate, its rice grain pattern of Crow etc.
Pigment preferably to the preparation outward appearance do not have too much influence and with the relevant material of activation sense that improves usability and skin, for example red No. 2 (amaranth), red No. 3 (erythrosines), red No. 102 (new coccines), red No. 104 they (1) (Phloxin Bs), red No. 105 they (1) (rose-red), red No. 106 (Xylene Reds), yellow No. 4 (tartrazines), yellow No. 5 (xanthates Huangs), green No. 3 (fast green FCFs), blue No. 1 (Brilliant Blue FCF), blue No. 2 legal pigments such as (indigo carmine), but there is no particular limitation.
As surfactant, can cooperate dioctyl sodium sulphosuccinate, alkyl sulfate salt, 2-ethylhexyl alkylsurfuric acid ester sodium salt, anion surfactants such as dodecyl benzene sulfonic acid sodium salt, hexadecyltrimethylammonium chloride, stearyl dimethyl benzyl ammonium chloride, cationic surfactants such as polyoxyethylene dodecyl-ammonio methacrylate, polyoxyethylene stearyl base ether, the polyoxyethylene tridecyl ether, the polyoxyethylene nonylplenyl ether, NONIN HS 240, polyoxyethylene monostearate, Arlacel-60, Arlacel-40, Arlacel-83, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monooleate dehydration, glyceryl monostearate, polyglyceryl fatty acid ester, non-ionic surface active agents such as polyoxyethylene octadecylamine.
As UV absorbent, can cooperate para-amino benzoic acid, p-aminobenzoate, the p-(dimethylamino)-benzoic acid pentyl ester, salicylate, the anthranilic acid menthyl ester, umbelliferone, Esculin, the cinnamic acid benzene methyl, cinoxate, more skin ulcer azulene, urocanic acid, 2-(2-hydroxy-5-methyl base phenyl) benzotriazole, the 4-methoxy benzophenone, 2-hydroxyl-4-methoxy benzophenone, dioxybenzone, octabenzone, the dihydroxy dimethoxy-benzophenone, ス リ ソ ベ Application ゾ Application, the benzo resorcinol, the octyldimethyl p-aminobenzoate, ethylhexyl p-methoxycinnamic acid ester etc.
As inorganic filler, can cooperate titanium oxide, Talcum, zinc oxide, aqueous silicon dioxide, magnesium carbonate, calcium hydrogen phosphate, magnesium silicate, kieselguhr, silicic acid anhydride, bentonite etc.
As the pH regulator agent, can cooperate acetic acid, formic acid, lactic acid, tartaric acid, oxalic acid, benzoic acid, glycolic, malic acid, citric acid, hydrochloric acid, nitric acid, sulphuric acid, sodium hydroxide, potassium hydroxide, methylamine, ethamine, propylamine, dimethylamine, diethylamine, di-n-propylamine, trimethylamine, triethylamine, tripropyl amine (TPA), a carbinolamine, monoethanolamine, monopropylene glycol amine, dimethanolamine, diethanolamine, dipropanolamine, trimethanolamine, triethanolamine, tripropanol amine etc.
Suitably cooperate the pH value of the mastic obtain preferably not look after in right amount above-mentioned each composition and bring stimulation to skin, preferred 5~8, more preferably 5.5~7.5, further preferred 6~7.
In addition, the support of coating mastic for example is film of synthetic resin such as polyethylene, polypropylene, polyethylene terephthalate, ethylene-vinyl acetate copolymer, vinyl chloride, polyurethane, polyester, polyamide, staple fibre, polyester, flexible materials such as non-woven fabrics, cloth, retractility cloth, paper, cellophane such as the layered product of flexible nonwoven fabrics, non-woven paper, above-mentioned synthetic resin made membrane or sheet material and non-woven fabrics or non-woven paper, absorbent cotton can suitably select well known to a person skilled in the art material according to its purposes.And, on the base cloth that the packs layer is coated in flexible support formation, on the surface of this packs layer, further cover with fissility thin film or paper, can keep stability of formulation.In addition,, make and peel off the shape that easy subsides are paid easily, pay on the face so that paste at an easy rate for peeling paper design secant, sewing machine eye etc.In addition, there is no particular limitation for the color of base cloth, since be can not give the outward appearance of preparation bring too big influence and with the relevant material of activation sense that improves usability and skin, for example white, the colour of skin, yellow, redness, green, blueness, pink, light blue, dark brown etc. are preferably regulated deep or light as required.
The preparation method of sheet-type packs of the present invention be in blender, mentioned component mixed and/or dissolving evenly, with its extend be unstained or painted base cloth on, peeling paper pasted pays thereon, be cut into the shape of face.In addition, suitably cut away eye, nose, mouth and jawbone and partly make suitable shape, be processed into maneuverable product.In addition, be purpose with some position that is used on the face, also can be processed into nose for the nose that is suitable for the position with packs, be highly suitable for the shape at purpose position for what be suitable for the position with packs etc. with eye.In addition, meanings such as the effect reduction that the pollution from prevent the preservation process, volatile material evaporation etc. causes consider, sheet-type packs is preferably kept in the bag of sealing or the container stand-by.
Sheet-type packs of the present invention is had an effect to skin by the vitamin C that contains in the fruit extract and 'alpha '-hydroxy acids or other vitamins, thereby activation skin, in addition because water-retaining property is good, also show softish skin sense of touch, and have stabilizing the emotions and make us lax good effects such as fragrance.Particularly use the sheet-type packs of the wetting agent that glycols and fruit extract combine, water-retaining property and shape-retaining ability before the cohesiveness of preparation and compendency, the use are good, do not show zest when using in addition, unexistent very good quality production before aspect the usability being to skin yet.In addition, except this wetting agent, be that water-retaining property and shape-retaining ability before the cohesiveness of sheet-type packs of main component and compendency, the use is good also, as suitable especially to the good sheet-type packs of the skin Caring effect of skin mild with water soluble polymer, cross-linking agent, water and antiseptic.
Embodiment
Illustrate in greater detail sheet-type packs of the present invention below in conjunction with embodiment and test example, but they can not be as any qualification of the present invention.
Embodiment 1
Synthetic aluminium silicate 4 weight % are distributed among the distilled water 78.6 weight %, to wherein adding and dissolving gelatin 1 weight %, Ethylene glycol diglycidyl ether 0.05 weight %, grapefruit extract 0.045 weight %, Fructus Mali pumilae extract 0.045 weight %, citrus fruit juice 0.003 weight %, lemon juice 0.002 weight %, pears certain kind of berries fruit juice 0.05 weight %, methyl parahydroxybenzoate 0.2 weight %, add the mixture of sodium polyacrylate 6 weight %, Polyethylene Glycol 10 weight % and propyl p-hydroxybenzoate 0.05 weight % again, stir.Then, it is extended makes thickness reach about 1.4mm dying on the light orange base cloth, pastes a pair thin film.Then, be cut into the shape of face, cut away eye, nose, mouth and jawbone and partly make suitable shape, obtain sheet-type packs.
Embodiment 2~20
According to composition shown in table 1, table 2, the table 3 and content, be prepared similarly to Example 1, obtain sheet-type packs.
Table 1
Embodiment composition (%) | ??2 | ???3 | ???4 | ???5 | ???6 | ????7 | ????8 | ????9 | |
Fruit extract | Grapefruit extract | ???5 | ???3 | ???0.3 | ????0.1 | ||||
The blackberry extract | |||||||||
Fructus Mali pumilae extract | ??0.01 | ???10 | ???15 | ||||||
Apple juice | |||||||||
The mandarin orange extract | ????5 | ||||||||
Citrus fruit juice | ???5 | ???2 | ???0.2 | ????5 | |||||
Fructus Vitis viniferae extract | |||||||||
Citron extract | ???0.3 | ||||||||
Lemon juice | ???5 | ???15 | |||||||
Pears certain kind of berries fruit juice | ???5 | ???10 | ???0.2 | ????0.05 | |||||
Proportion | ??1.10 | ???1.06 | ???1.02 | ???0.98 | ???1.01 | ????1.20 | ????0.99 | ????1.01 | |
??pH(1→10) | ??5.0 | ???4.2 | ???4.7 | ???3.3 | ???3.4 | ????4.3 | ????3.5 | ????4.0 | |
Pol (wt%) | ??21 | ???23 | ???23 | ???20 | ???21 | ????22 | ????19 | ????19 | |
Polyethylene Glycol | ??25 | ???5 | ???15 | ????5 | |||||
Polypropylene glycol | ??10 | ???1 | ???5 | ???10 | ????10 | ????3 | |||
Gelatin | ??3 | ???5 | ???4 | ???0.9 | ???1 | ????0.5 | ????10 | ||
Sodium polyacrylate | ???5 | ???3 | ???4 | ???6 | ????7 | ????5 | ????15 | ||
Kaolin | ???5 | ????15 | |||||||
Aluminum acetate | ???0.5 | ||||||||
Synthetic aluminium silicate | ???3 | ????5 | ????4 | ||||||
The sorbitol polyglycidyl ether | ??0.05 | ???0.01 | |||||||
Polyethyleneglycol diglycidylether | ???0.01 | ???0.1 | ????0.25 | ||||||
Propylene glycol diglycidylether | ???0.3 | ||||||||
Glycerin diglycidyl ether | ???0.1 | ???0.02 | ????0.5 | ||||||
The polyglycereol polyglycidyl ether | ???0.2 | ||||||||
Glycerol shrink triglycidyl ether | ???0.01 | ????0.25 | ????0.5 | ||||||
Methyl parahydroxybenzoate | ???1 | ???0.1 | ????9.9 | ????4.5 | |||||
Ethylparaben | ??0.01 | ???0.1 | ????0.1 | ????0.5 | |||||
Propyl p-hydroxybenzoate | ???0.005 | ???0.01 | ???0.1 | ????0.05 | ????0.1 | ||||
Spice | ???0.001 | ???0.01 | |||||||
Water | ??61.9 | ???60 | ???60 | ???65 | ???63.6 | ????62.4 | ????62 | ????64.4 | |
Base cloth (dyeing) | Light red | Do not dye | Pink | Pale green | Do not dye | Orange | Green | Yellow |
Table 2
Embodiment composition (%) | ???10 | ???11 | ??12 | ??13 | ??14 | ??15 | ?16 | ????17 | |
Fruit extract | Grapefruit extract | ???0.6 | ???0.1 | ?0.001 | ????1 | ||||
The blackberry extract | ??1 | ?0.002 | |||||||
Fructus Mali pumilae extract | ???1 | ???0.1 | ??0.05 | ?0.001 | ????5 | ||||
Apple juice | ??0.5 | ?0.005 | |||||||
The mandarin orange extract | |||||||||
Citrus fruit juice | ???0.1 | ??0.05 | ????1 | ||||||
Fructus Vitis viniferae extract | ??0.01 | ?0.001 | |||||||
Citron extract | ????2 | ||||||||
Lemon juice | ???0.02 | ???0.1 | ??0.01 | ||||||
Pears certain kind of berries fruit juice | ???0.1 | ????1 | |||||||
Proportion | ???1.11 | ???1.02 | ??0.95 | ??1.09 | ??1.10 | ??0.99 | ?1.01 | ????1.07 | |
??pH(1→10) | ???4.2 | ???3.6 | ??3.4 | ??4.6 | ??4.4 | ??4.0 | ?3.9 | ????4.8 | |
Pol (wt%) | ???19 | ???21 | ??20 | ??22 | ??23 | ??22 | ?21 | ????23 | |
Polyethylene Glycol | ???15 | ??3 | ??15 | ??5 | ????7 | ||||
Polypropylene glycol | ???5 | ???10 | ??1 | ??1 | ?2 | ????3 | |||
Gelatin | ???2 | ???0.3 | ??2.5 | ??3 | ??10 | ?3 | ????1 | ||
Sodium polyacrylate | ???6 | ???4 | ??1 | ??10 | ??8 | ????6 | |||
Kaolin | ??1 | ??8 | ?10 | ||||||
Aluminum acetate | ??0.01 | ??2 | ?2 | ||||||
Synthetic aluminium silicate | ???0.05 | ??1 | ?1 | ????4 | |||||
The sorbitol polyglycidyl ether | ?0.3 | ||||||||
Polyethyleneglycol diglycidylether | ???0.05 | ??0.4 | ?0.2 | ||||||
Propylene glycol diglycidylether | ??0.1 | ?0.25 | |||||||
Glycerin diglycidyl ether | ?0.5 | ||||||||
The polyglycereol polyglycidyl ether | ?0.5 | ????0.05 | |||||||
Glycerol shrink triglycidyl ether | ???0.08 | ??0.1 | ?0.25 | ||||||
Methyl parahydroxybenzoate | ???0.3 | ??0.5 | ??0.3 | ????0.1 | |||||
Ethylparaben | ??0.5 | ????0.1 | |||||||
Propyl p-hydroxybenzoate | ???0.1 | ??0.4 | ?0.04 | ????0.05 | |||||
Spice | ????0.005 | ||||||||
Water | ???70 | ???85 | ??90 | ??95 | ??64.6 | ??75 | ?80 | ????68.7 | |
Base cloth (dyeing) | In vain | The colour of skin | Yellowish | Light blue | Do not dye | Do not dye | Do not dye | Do not dye |
Table 3
Comparative example
Embodiment composition (%) | ???18 | ????19 | ????20 | ||||||
Fruit extract | Grapefruit extract | ????3.5 | |||||||
The blackberry extract | |||||||||
Fructus Mali pumilae extract | ????13.5 | ||||||||
Apple juice | |||||||||
The mandarin orange extract | ???0.005 | ||||||||
Citrus fruit juice | ????3.5 | ||||||||
Fructus Vitis viniferae extract | ????0.005 | ||||||||
Citron extract | ????7 | ||||||||
Lemon juice | |||||||||
Pears certain kind of berries fruit juice | ????3.5 | ||||||||
Proportion | ???1.16 | ????1.03 | ????1.10 | ||||||
????pH(1→10) | ???4.3 | ????4.5 | ????4.4 | ||||||
Pol (wt%) | ???22 | ????22 | ????23 | ||||||
Polyethylene Glycol | ????0.5 | ????20 | |||||||
Polypropylene glycol | ???0.5 | ????16 | |||||||
Gelatin | ???10 | ????7 | |||||||
Sodium polyacrylate | ????3.7 | ||||||||
Kaolin | |||||||||
Aluminum acetate | |||||||||
Synthetic aluminium silicate | ???3 | ||||||||
The sorbitol polyglycidyl ether | ????0.01 | ||||||||
Polyethyleneglycol diglycidylether | |||||||||
Propylene glycol diglycidylether | ????0.04 | ||||||||
Glycerin diglycidyl ether | |||||||||
The polyglycereol polyglycidyl ether | ????1 | ||||||||
Glycerol shrink triglycidyl ether | ???1 | ||||||||
Methyl parahydroxybenzoate | ???0.5 | ????0.5 | ????0.25 | ||||||
Ethylparaben | |||||||||
Propyl p-hydroxybenzoate | |||||||||
Spice | |||||||||
Water | ???85 | ????60 | ????60 | ||||||
Base cloth (dyeing) | Do not dye | Do not dye | Do not dye |
The embodiment 1 that opens flat 8-188527 communique with the spy in first to file compares with embodiment in following test example as a comparative example.Comparative example 1
Synthetic aluminium silicate 4 weight % are distributed among the distilled water 76.5 weight %, to wherein adding and dissolving gelatin 1 weight %, 2% succinyl ケ Off ィ ラ Application aqueous solution, 0.1 weight %, Ethylene glycol diglycidyl ether 0.05 weight %, water solublity intacellin 2 weight %, allantoin 0.1 weight %, methyl parahydroxybenzoate 0.2 weight %, add the mixture of sodium polyacrylate 6 weight %, Polyethylene Glycol 10 weight % and propyl p-hydroxybenzoate 0.05 weight % again, stir.Then, it is extended makes thickness reach about 1.4mm dying on nattier blue base cloth, paste a pair thin film.Then, be cut into the shape of face, cut away eye, nose, mouth and jawbone and partly make suitable shape, obtain sheet-type packs.Test example 1: viscosity test
The result who embodiment 1,6,11,18,19,20 is implemented viscosity test is as shown in table 4.The sample of placing in advance more than 30 minutes is used in test under 25 ℃-60%Rh condition, implement under the same conditions.At first the bonding plane with sample is fixed on the horizontal stand up.Then, the steel ball that makes 20/32 inch of diameter rolls on bonding plane according to the distance of sine curve by height 17.35cm landing base 30cm.Estimate as adhesion strength with contact point to the distance (cm) of place of arrival of steel ball at this moment.In addition, as the steel ball that uses, materials used is the SUJ2 of JIS G4805 (high-carbon chromium plating bearing steel steel), and precision is the prime quality of JIS B1501 (ball bearing steel ball).
Table 4
Test example 2: the remaining test of water quantities and oil content amount in the epidermis
Adhesion strength | |
Embodiment 1 | ????3cm |
Embodiment 6 | ????2cm |
Embodiment 11 | ????5cm |
Embodiment 18 | ????13cm |
Embodiment 19 | ????10cm |
Embodiment 20 | ????15cm |
For embodiment 3,10,13, with water quantities and the oil content amount of using back mensuration epidermis, the result who compares respectively is as shown in table 5 before use.Test makes the tested person in advance after persistencing 30 minutes under the condition of 25 ℃-60%Rh, and the SKICOS 301 that uses (strain) Amick to produce measures the water quantities and the oil content amount of buccal.Then, the sample that will be cut into 3cm * 3cm attaches 15 minutes on tested person's buccal and forehead, measure the water quantities and the oil content amount of buccal afterwards equally.
Table 5
Test example 3: usability evaluation test
Water quantities (mgH 2O/cm 2) | Oil content amount (μ g/cm 2) | |||
Before the use | After the use | Before the use | After the use | |
Embodiment 3 | ????50 | ????103 | ????72 | ????19 |
Embodiment 10 | ????54 | ????110 | ????82 | ????25 |
Embodiment 13 | ????51 | ????120 | ????65 | ????14 |
Carry out the usability test for embodiment 1 and comparative example 1.Test is given more than 20 year old 50 of women with each 1 on embodiment 1 and 2 two kinds of samples of comparative example, makes it to use on the different dates respectively.Afterwards, allow the tested person that (to the affine sense of skin), (effect, soak into sense) and (lax sense) are estimated with 5 ranks.The result of the test of table 6 expression (to the affine sense of skin), the result of the test of table 7 expression (effect, soak into sense), the result of the test of table 8 expression (lax feel).
Table 6 (to the affine sense of skin) (representing) with %
Very good | Good | Uncertain | Poorly | Bad fully | |
Embodiment 1 | ????18 | ????60 | ????10 | ????12 | ????0 |
Comparative example 1 | ????14 | ????68 | ????10 | ????8 | ????0 |
Table 7 (effect, soak into sense) (representing) with %
Very good | Good | Uncertain | Poorly | Bad fully | |
Embodiment 1 | ????18 | ????42 | ????26 | ????14 | ????0 |
Comparative example 1 | ????8 | ????56 | ????22 | ????12 | ????0 |
Table 8 (lax sense) (representing) with %
Test example 4: cutaneous safety test
Very good | Good | Uncertain | Poorly | Bad fully | |
Embodiment 1 | ????48 | ????46 | ????4 | ????2 | ????0 |
Comparative example 1 | ????40 | ????46 | ????10 | ????4 | ????0 |
Implement the cutaneous safety test for embodiment 1,2,4,7,17 and comparative example 1.Test is carried out sealing in 48 hours to 30 of the normal men and women of health and is attached, and observes after peeling off through the skin intensity of variation after 1 hour and 24 hours, according to following standard evaluation skin irritation degree.Result of the test is as shown in table 9.
-: confirm that skin does not change
±: skin is rubescent a little
+: skin is obviously rubescent
++: serious macule appears in skin
Table 9
Peel off the back elapsed time | Judge sample | ??++ | ??+ | ??± | ??- | Add up to (people) | Positive rate (%) |
± more than | |||||||
After 1 hour | Embodiment 1 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 |
Embodiment 2 | ??0 | ??0 | ??1 | ??29 | ????30 | ????3.3 | |
Embodiment 4 | ??0 | ??0 | ??2 | ??28 | ????30 | ????6.7 | |
Embodiment 7 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 | |
Embodiment 17 | ??0 | ??0 | ??1 | ??29 | ????30 | ????3.3 | |
Comparative example 1 | ??0 | ??0 | ??4 | ??26 | ????30 | ????13.3 | |
After 24 hours | Embodiment 1 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 |
Embodiment 2 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 | |
Embodiment 4 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 | |
Embodiment 7 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 | |
Embodiment 17 | ??0 | ??0 | ??0 | ??30 | ????30 | ????0.0 | |
Comparative example 1 | ??0 | ??0 | ??1 | ??29 | ????30 | ????3.3 |
As mentioned above, judge the viscosity that sheet-type packs of the present invention has appropriateness, usability is good, and cutaneous safety is good.In addition, it is good also to judge the relaxing effect that the effect of skin and fruit ingredient are produced.
Industrial applicibility
Sheet-type packs of the present invention acts on skin by the vitamin C that contains in the fruit extract and 'alpha '-hydroxy acids or other vitamins and causes activating skin, in addition because water-retaining property is good, also show soft skin sense of touch, and have to set the mind at rest and make us the lax good effects such as fragrance. Particularly use the sheet-type packs of the NMF that is combined by glycols and fruit extract, water-retaining property and shape-retaining ability before the adherence of preparation and compendency, the use are good, do not show the excitant to skin when using in addition, unexistent very good product before aspect the use sense being yet. In addition, except this NMF, also water-retaining property and the shape-retaining ability before the adherence of the sheet-type packs take water soluble polymer, crosslinking agent, water and anticorrisive agent as main component and compendency, the use is good, as suitable especially to the good sheet-type packs of the skin makeup effect of skin mild.
Therefore, sheet-type packs of the present invention is because easy and simple to handle, and security, use sense and good to the effect of skin to skin are particularly suitable for being applied in health products or the cosmetic field of nursing one's health skin or beauty treatment usefulness, and be industrially very useful.
Modification according to the 19th of treaty
1, sheet-type packs is characterized in that containing proportion and is 0.95~1.20, pH is 3.3~5.0, pol is the fruit extract of 19~23 weight %.
2, sheet-type packs as claimed in claim 1 is characterized in that comprising base cloth and substrate.
3, sheet-type packs as claimed in claim 1 or 2 is characterized in that the proportioning of fruit extract accounts for 0.0003~33.87 weight % of substrate total amount.
4, sheet-type packs as claimed in claim 3 is characterized in that the ratio of fruit extract accounts for 0.03~96.77 weight % of wetting agent total amount.
5,, it is characterized in that substrate contains wetting agent 1~35 weight %, water soluble polymer 3~25 weight %, cross-linking agent 0.05~20 weight % and water 60~95 weight % as claim 3 or 4 described sheet-type packs.
6, sheet-type packs as claimed in claim 5 is characterized in that further containing in the substrate antiseptic 0.005~10 weight %.
7, as any described sheet-type packs in the claim 1~6, it is characterized in that further containing glycols.
8, sheet-type packs as claimed in claim 7, the proportioning that it is characterized in that glycols and fruit extract is 1~35: 0.01~30.
9,, it is characterized in that glycols is Polyethylene Glycol and/or polypropylene glycol as claim 7 or 8 described sheet-type packs.
10, as any described sheet-type packs in the claim 1~9, it is characterized in that fruit extract is by being selected from the Rosehips extract, the mandarin orange extract, citrus fruit juice, the blackberry extract, Fructus actinidiae chinensis extract, the Semen Cucumidis sativi extract, Fructus Gardeniae extract, grapefruit extract, Fructus Crataegi extract, the Pericarpium Zanthoxyli extract, the whitethorn extract, the juniperus communis extract, Fructus Jujubae extract, デ ュ-Network extract, Fructus Lycopersici esculenti extract, Fructus Vitis viniferae extract, Fructus Luffae extract, pears certain kind of berries fruit juice, Fructus Mali pumilae extract, apple juice, citron extract, constituting more than a kind or 2 kinds in the lemon juice.
11,, it is characterized in that it being to apply some make up or the health product use as skin Caring as any described sheet-type packs in the claim 1~10.
Claims (11)
1, sheet-type packs contains fruit extract.
2, sheet-type packs as claimed in claim 1, the proportion that it is characterized in that fruit extract is 0.95~1.20, and pH is 3.3~5.0, and pol is 19~23 weight %.
3, sheet-type packs as claimed in claim 1 or 2 is characterized in that the proportioning of fruit extract accounts for 0.0003~33.87 weight % of substrate total amount.
4, sheet-type packs as claimed in claim 3 is characterized in that the ratio of fruit extract accounts for 0.03~96.77 weight % of wetting agent total amount.
5,, it is characterized in that substrate contains wetting agent 1~35 weight %, water soluble polymer 3~25 weight %, cross-linking agent 0.05~20 weight % and water 60~95 weight % as claim 3 or 4 described sheet-type packs.
6, sheet-type packs as claimed in claim 5 is characterized in that further containing in the substrate antiseptic 0.005~10 weight %.
7, as any described sheet-type packs in the claim 1~6, it is characterized in that further containing glycols.
8, sheet-type packs as claimed in claim 7, the proportioning that it is characterized in that glycols and fruit extract is 1~35: 0.01~30.
9,, it is characterized in that glycols is Polyethylene Glycol and/or polypropylene glycol as claim 7 or 8 described sheet-type packs.
10, as any described sheet-type packs in the claim 1~9, it is characterized in that fruit extract is by being selected from the Rosehips extract, the mandarin orange extract, citrus fruit juice, the blackberry extract, Fructus actinidiae chinensis extract, the Semen Cucumidis sativi extract, Fructus Gardeniae extract, grapefruit extract, Fructus Crataegi extract, the Pericarpium Zanthoxyli extract, the whitethorn extract, the juniperus communis extract, Fructus Jujubae extract, デ ュ-Network extract, Fructus Lycopersici esculenti extract, Fructus Vitis viniferae extract, Fructus Luffae extract, pears certain kind of berries fruit juice, Fructus Mali pumilae extract, apple juice, citron extract, constituting more than a kind or 2 kinds in the lemon juice.
11,, it is characterized in that it being to apply some make up or the health product use as skin Caring as any described sheet-type packs in the claim 1~10.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1942899 | 1999-01-28 | ||
JP19428/1999 | 1999-01-28 | ||
JP19428/99 | 1999-01-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1338918A true CN1338918A (en) | 2002-03-06 |
CN1158986C CN1158986C (en) | 2004-07-28 |
Family
ID=11999018
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008032475A Expired - Lifetime CN1158986C (en) | 1999-01-28 | 2000-01-28 | Sheet-type packs |
Country Status (11)
Country | Link |
---|---|
US (1) | US7045137B1 (en) |
EP (1) | EP1147759B1 (en) |
KR (1) | KR100614090B1 (en) |
CN (1) | CN1158986C (en) |
AU (1) | AU764018B2 (en) |
BR (1) | BR0008192B1 (en) |
CA (1) | CA2360784C (en) |
DE (1) | DE60024058T2 (en) |
MY (1) | MY128817A (en) |
TW (1) | TWI228424B (en) |
WO (1) | WO2000044336A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102215815A (en) * | 2008-11-28 | 2011-10-12 | 株式会社太平洋 | Mask pack comprising cosmetic cotton-like material prepared from paper mulberry |
CN104257566A (en) * | 2014-10-22 | 2015-01-07 | 天津郁美净集团有限公司 | Composition for cosmetics with conditioning action as well as application thereof |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030133968A1 (en) * | 2000-05-15 | 2003-07-17 | Kazunori Muta | Sheet-type packs |
CA2395209C (en) | 2000-11-09 | 2011-10-18 | Teikoku Seiyaku Co., Ltd. | Pack agent in a sheet form |
TWI324933B (en) * | 2001-06-27 | 2010-05-21 | Hisamitsu Pharmaceutical Co | Sheet-type packs |
KR20020040719A (en) * | 2002-04-18 | 2002-05-30 | 김대도 | Orange pack |
KR20040034019A (en) * | 2002-10-16 | 2004-04-28 | 이정훈 | Honey cosmetics |
PT1757309E (en) * | 2004-04-28 | 2013-05-07 | Hisamitsu Pharmaceutical Co | Adhesive material |
KR101384397B1 (en) | 2007-12-26 | 2014-04-11 | (주)아모레퍼시픽 | Cosmetic compositions in the form of a pack formulation for a lip skin |
CA2716612C (en) * | 2008-02-29 | 2014-02-18 | The Procter & Gamble Company | Hair care compositions and methods for increasing hair diameter |
KR100895515B1 (en) * | 2009-01-02 | 2009-04-30 | 꽃뫼영농조합법인 | Mask pack including extraction of liriope platyphylla |
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JPS5449334A (en) | 1977-09-27 | 1979-04-18 | Riido Kemikaru Kk | Pack agent |
JPS60115507A (en) | 1983-11-28 | 1985-06-22 | Sunstar Inc | Cosmetic pack |
JPH0380867A (en) | 1989-08-24 | 1991-04-05 | Taiyo Chem Kk | Deodorizing material |
JPH0353730U (en) * | 1989-09-26 | 1991-05-24 | ||
JP3075438B2 (en) | 1992-04-03 | 2000-08-14 | 三省製薬株式会社 | Novel acylated kefiran, its use and production method |
WO1993025186A1 (en) | 1992-06-16 | 1993-12-23 | Klein Marvin E | Composition for the treatment of skin |
KR960015185B1 (en) * | 1993-04-15 | 1996-11-01 | 주식회사 엘지화학 | Disposable water tissue products containing antibiosis plant extract |
KR960015183B1 (en) * | 1993-05-03 | 1996-11-01 | 주식회사 엘지화학 | Disposable absorbent articles containing encapsulation materials |
US5578312A (en) * | 1993-05-05 | 1996-11-26 | Parrinello; Vincene M. | Skin care system and method for improving moisture retention in skin |
FR2719473B1 (en) | 1994-05-04 | 1996-06-21 | Rocher Yves Biolog Vegetale | Method for accelerating cell renewal of the skin and cosmetic compositions for its implementation. |
JP3257905B2 (en) * | 1994-07-29 | 2002-02-18 | 一丸ファルコス株式会社 | Skin sticking sheet |
JP3553174B2 (en) * | 1995-01-09 | 2004-08-11 | 久光製薬株式会社 | Sheet pack |
FR2734574A1 (en) * | 1995-05-24 | 1996-11-29 | Pacific Corp | Adhesive formulation for cosmetic and medical use |
JPH1053527A (en) | 1996-08-09 | 1998-02-24 | Tanabe Seiyaku Co Ltd | Percutaneous absorbent preparation containing caffeine |
GB2321587A (en) | 1997-01-29 | 1998-08-05 | Anna Kavaya | Medicated/scented feet wipes |
JPH11269031A (en) | 1998-03-20 | 1999-10-05 | Kanebo Ltd | Transparent sheet-form cosmetic material, production thereof and makeup method |
TWI233810B (en) | 1999-02-19 | 2005-06-11 | Hisamitsu Pharmaceutical Co | A paster sheet |
-
2000
- 2000-01-27 TW TW089101340A patent/TWI228424B/en not_active IP Right Cessation
- 2000-01-27 MY MYPI20000303A patent/MY128817A/en unknown
- 2000-01-28 WO PCT/JP2000/000459 patent/WO2000044336A1/en active IP Right Grant
- 2000-01-28 CN CNB008032475A patent/CN1158986C/en not_active Expired - Lifetime
- 2000-01-28 CA CA2360784A patent/CA2360784C/en not_active Expired - Lifetime
- 2000-01-28 US US09/890,224 patent/US7045137B1/en not_active Expired - Lifetime
- 2000-01-28 KR KR1020017009496A patent/KR100614090B1/en active IP Right Grant
- 2000-01-28 DE DE60024058T patent/DE60024058T2/en not_active Expired - Lifetime
- 2000-01-28 BR BRPI0008192-2A patent/BR0008192B1/en not_active IP Right Cessation
- 2000-01-28 AU AU22548/00A patent/AU764018B2/en not_active Expired
- 2000-01-28 EP EP00901968A patent/EP1147759B1/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102215815A (en) * | 2008-11-28 | 2011-10-12 | 株式会社太平洋 | Mask pack comprising cosmetic cotton-like material prepared from paper mulberry |
CN102215815B (en) * | 2008-11-28 | 2012-11-07 | 株式会社太平洋 | Mask pack comprising cosmetic cotton-like material prepared from paper mulberry |
CN104257566A (en) * | 2014-10-22 | 2015-01-07 | 天津郁美净集团有限公司 | Composition for cosmetics with conditioning action as well as application thereof |
CN104257566B (en) * | 2014-10-22 | 2017-02-01 | 天津郁美净集团有限公司 | Composition for cosmetics with conditioning action as well as application thereof |
Also Published As
Publication number | Publication date |
---|---|
EP1147759B1 (en) | 2005-11-16 |
DE60024058T2 (en) | 2006-08-03 |
TWI228424B (en) | 2005-03-01 |
KR100614090B1 (en) | 2006-08-23 |
MY128817A (en) | 2007-02-28 |
US7045137B1 (en) | 2006-05-16 |
KR20020011960A (en) | 2002-02-09 |
CN1158986C (en) | 2004-07-28 |
DE60024058D1 (en) | 2005-12-22 |
EP1147759A4 (en) | 2003-07-09 |
AU2254800A (en) | 2000-08-18 |
EP1147759A1 (en) | 2001-10-24 |
AU764018B2 (en) | 2003-08-07 |
CA2360784A1 (en) | 2000-08-03 |
BR0008192B1 (en) | 2013-05-07 |
CA2360784C (en) | 2010-10-05 |
WO2000044336A1 (en) | 2000-08-03 |
BR0008192A (en) | 2002-02-05 |
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