CN1334357A - Process for preparing bimetal band with steel substrate - Google Patents
Process for preparing bimetal band with steel substrate Download PDFInfo
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- CN1334357A CN1334357A CN00110680A CN00110680A CN1334357A CN 1334357 A CN1334357 A CN 1334357A CN 00110680 A CN00110680 A CN 00110680A CN 00110680 A CN00110680 A CN 00110680A CN 1334357 A CN1334357 A CN 1334357A
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 59
- 239000010959 steel Substances 0.000 title claims abstract description 59
- 239000000758 substrate Substances 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 62
- 239000000956 alloy Substances 0.000 claims abstract description 62
- 238000005096 rolling process Methods 0.000 claims abstract description 36
- 238000002844 melting Methods 0.000 claims abstract description 11
- 238000000151 deposition Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 46
- 238000010438 heat treatment Methods 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 11
- 238000000889 atomisation Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000003801 milling Methods 0.000 claims description 7
- 239000012071 phase Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000009718 spray deposition Methods 0.000 claims description 6
- 239000001996 bearing alloy Substances 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 238000009689 gas atomisation Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 238000000280 densification Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 description 12
- 239000000843 powder Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000005204 segregation Methods 0.000 description 8
- 238000005245 sintering Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 229910000978 Pb alloy Inorganic materials 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000004663 powder metallurgy Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000209456 Plumbago Species 0.000 description 2
- 241001067915 Sagittaria kurziana Species 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910000714 At alloy Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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- Pressure Welding/Diffusion-Bonding (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
A bimetal band with steel substrate is made up through melting the alloy to be compounded, sufficiently breaking and atomizing by high-pressure gas, fast cooling, depositing the semi-liquid atomized stream onto continuously moving steel band, and rolling. Its advantages are high adhesion and compactness, and low cost.
Description
The present invention relates to the compounding technology of bimetallic material, a kind of manufacture method of bimetal band with steel substrate is provided especially.
Double metal composite strip, especially steel backing and non-ferrous metal composite strip (copper base alloy, aluminum base alloy, lead 2-base alloy, zinc base alloy etc.), be the broad-spectrum structured material of a class in the mechanical manufacturing engineering, its main application is as bush material, efficient absorbing material, thermoelastic material and New Building Materials etc., it is widely used in machine manufacturing, boats and ships, aircraft, automobile, instrument and traffic, and most important industrial sectors such as building are a kind of key industries materials.
The main technique flow process of making the rolling bimetal band in the modern industry is band shape continuous casting process, three kinds of powder sintering process and band shape technique for continuous rolling, band shape continuous casting process claims casting-rolling technology again, be will fusing the casting on the steel band that is preheating to assigned temperature of qualified alloy average rate, steel band moves continuously, and use high flash point thickened oil shower cooling rapidly, again with the cooling of jet of water secondary, after treating alloy graining and being bonded on the steel band, mill the unnecessary thickness of alloy, and further roll through milling train and to close, to flatten, coil into bimetal band at last continuously.The advantage of this technology is the production efficiency height, the once-combined shaping of alloy and steel band, technical process is comparatively simple, production cost is relatively low, its shortcoming is not to be suitable for the alloy with strong solidifying segregation tendency, as the plumbous bearing alloy of aluminium etc., the latter second plumbously mutually will produce serious gravity segregation phenomenon in alloy in band shape casting cycle, cause the compound manufacturing of bimetal band to be failed.
Powder sintering process claims powder metallurgic method again, its main technique flow process is divided two kinds, promptly be with shape stoking and bar blocks sintering process, the technical process of band shape stoking method is at first to carry out powdered preparation (being divided into metal-powder hybrid system and alloy powder atomization again), ready steel band (copper facing becomes naked band) is passed through shop powder machine continuously equably, spreading one deck is treated the alloy powder of composite bed equably in its surface, again through pre-burning freezing of a furnace sintering, cold soon, breaking down, sintering for the second time, cooling back finish to gauge is to last size, the advantage of this technology is to solve alloy gravity segregation problem effectively, the production efficiency height, be applicable to the bimetal band that the preparation alloy layer is thin, shortcoming is because during the loose sintering of powder, the alloy layer porosity is very high, although through rolling densification, but because the hole place fails fully to roll to close, the mechanical property of composite alloy layer is relatively low, require sintering temperature can not be higher than the fusing point of a certain component in the alloy simultaneously, otherwise low melting point will melt sinking mutually when sintering, cause the whole process flow failure.
The another kind of technical process of powder metallurgic method is a band shape continuous rolling method, the main technique principle is to use earlier the using powder metallurgy method to prepare alloy stick, the composite alloy coiled material is treated in preparation earlier after repeatedly rolling, and then make bimetal band with the spring tape composite rolling of surperficial sanding, in order to increase the interface binding power of alloy and steel band substrate, can between alloy band and steel band, increase by an intermediate layer film metal, to adjust the chemistry or the physical compatibility of interface metal layer.Technical process is similar therewith also has the bar blocks casting, its key distinction is that the former uses the using powder metallurgy method to prepare alloy stick, the latter then adopts the cast panel legal system to be equipped with the alloy stick, the latter's advantage is the alloy structure densification, good mechanical property, shortcoming is to be easy to produce solidifying segregation, and the powder metallurgy rule is just the opposite, compare with aforementioned band shape stoking method, the advantage of band shape continuous rolling method is to have alloy mechanical property preferably, and be suitable for preparing the thicker bimetal band of alloy layer, and to the better adaptability of alloy ingredient, shortcoming is that technical process is very complicated, and especially alloy strip will be through repeatedly process annealing in rolling, and the composite rolling of final alloy band and steel band needs higher deformation quantity, to guarantee the bonding strength at interface, in this complicated technical process,, all can cause the whole process flow failure as long as there is a ring control improper.
The object of the present invention is to provide a kind of manufacture method of bimetal band with steel substrate, can obtain composition by this method and be evenly distributed, the alloy structure of the second phase small and dispersed is particularly useful for making the monotectic alloy with serious gravity segregation tendency.
The invention provides a kind of manufacture method of bimetal band with steel substrate, it is characterized in that preparation process is as follows:
(1) will treat the composite alloy heat fused, and be heated to above 10~300 ℃ of liquidus line, make it to become a kind of single-phased alloy melt of uniform ingredients;
(2),, move through the spray deposition case of a sealing continuously with even velocity with preprepared steel coil strip;
(3) the qualified liquid bearing alloy of melting injects the atomizing case, with the high pressure gas atomizing nozzle metal liquid stream is fully pulverized immediately and is formed the atomized flow that certain space distributes;
(4) will be cooled to semi-solid metal atomization stream and be deposited on the steel band that moves continuously the atomizing nozzle below translational speed 0.5m-10m/mim;
(5) steel band that is loaded with depositing metal layers is continuously to milling train one lateral movement, and depositing metal layers is finished cooling curing and preliminary bonding with steel band on the steel band simultaneously;
(6) aforementioned steel band is adjusted to suitable rolling temperature,, sends into milling train immediately and carry out middle temperature rolling, draught 5%~40% a little less than the fusing point of low-melting metal phase;
(7) rolling bimetallic composite band is batched continuously;
(8) the bi-metal shaft bushing band of rolling is heat-treated.
Alloy heating means of the present invention can adopt the fuel heating, resistive heating, and high frequency or intermediate frequency power supply heating, any known heating techniques such as electric-arc heating or plasma heating, heating can be at atmosphere, carries out under vacuum or the protective atmosphere.Liquidus line of the present invention refers to divide on the alloy phase diagram straight line or the curve of single-phase liquid phase region, monotectic alloy is referred to the temperature of binode dotted line correspondence; Spring tape preheating technology of the present invention can be used direct resistive heating, tube furnace thermal radiation heating or radio-frequency coil direct heating, and described inertia atmosphere refers to Ar gas or N
2Tundish preheating of the present invention can be by resistive heating, intermediate frequency or high frequency electric source heating, the fuel heating waits any heating technique, preheating temperature is generally more than the fusing point of alloy, to avoid alloy melt premature coagulation in tundish, spraying gun described in the present invention refers to high pressure gas atomizing nozzle system, can be restricted atomizing nozzle or unrestricted type gas-atomizing nozzle, connecing the nozzle arrangement mode can be that line formula nozzle also can be the ring type nozzle, 1 °~90 ° of atomizing angle variation ranges, atomizing nozzle can be fixed or mechanical scanning type, and rare gas element refers to N
2Or Ar, preheating can be used tubular type tunnel stove before deposition steel band of the present invention rolled, also can heat with high frequency or heating in medium frequency stove, Heating temperature generally is lower than the fusing point of low melting point phase in the deposit alloy, Al-Pb alloy for example, Heating temperature should be lower than plumbous fusing point (327 ℃), milling train of the present invention can be general double-roll rolling mill, it also can be three-high mill, roll speed is controlled at 0.5~10m/min, rolling draught is 5%~40%, draught is too small then to be not enough to finish dense structure's purpose and to strengthen interface binding power, draught is excessive, then may make metal refining along the excessive deformation of steel band direction, and the latter will cause the alloy layer protuberance and make the compound failure of steel band.
Technical characterstic of the present invention is the composite rolling technology of the atomization technique of liquid metal and bimetal band is organically integrated, make the cooling fast in a short period of time of superheated single-phase liquid alloy, form semi-solid viscosity atomized flow and be bonded in the purpose that reaches inhibition gravity segregation and thinning microstructure structure on the deposition steel band that moves continuously, finish at alloy layer simultaneously and solidify, but in time carry out middle temperature rolling when not being chilled to room temperature as yet to reduce the porosity in the tissue, improve the bonding force between alloy layer and the interface.
Advantage on the technology of the present invention is conspicuous.(1) technical process of the present invention is very compact, it collects melting, spray deposition and rolling be that the whole technical process of one are on a production line, can finish, thereby effective simplification the relative very complicated Technology of original preparation bimetallic alloy band, this abbreviated system route not only helps adopting computer technology to carry out flow process control, and a large amount of plant and equipments and cost of labor have also been saved in the simplification of technical process.(2) the mutually possible solidifying segregation of low melting point in the inhibition deposit alloy that the fast cold principle of technology utilization atomizing provided by the invention can be successful, the monotectic alloy serious to solidifying segregation under the earth gravity field, the advantage on the technology of the present invention is especially outstanding.(3) can adjust the size of atomizing droplet easily by means of controlling atomization parameter (jet angle, sweep angle, deposition distance, atomization pressure, metal flow etc.), the latter causes precipitating the thin crystalline substances of axle such as alloy formation, this evenly tiny equiaxed grain structure has better plastic working ability than as-cast structure, help further middle temperature rolling processing, utilize these characteristics can enlarge the range of choice of deposit alloy, comprehensively described, the present invention is the new and high technology route that is based upon a kind of low cost production high-quality bimetal band on the rapid solidification principle basis.
Accompanying drawing 1 is the flow process signal of bimetal band with steel substrate preparation of the present invention.
Below by embodiment in detail the present invention is described in detail
Embodiment 1
Technical process as shown in Figure 1, (1) holding furnace, (2) atomization tank, (3) atomizing nozzle, (4) well heater, (6) steel band, (7) Abrollhaspel, (8) collector, (9) milling train, (10) winder, (11) crucible among the figure.
All the other are the plumbous bearing alloy of aluminium of Al for preparation 6%Pb-4Si, alloy is put into a plumbago crucible, use the resistance furnace heat fused, and be warming up to 1100 ℃ (the binode dotted line critical temperature by this alloy of Al-Pb binary phase diagram is about 950 ℃), after insulation 20min makes its full and uniformization, it is injected a middle insulation bag rapidly, the insulation bag is preheated to 1000 ℃ with resistance furnace, one small opening is arranged at the tundish bottom, make the Al-Pb alloy of the high-temperature fusion formation beam of making a bet, pod apertures is a garden shape, and aperture Φ 2.5mm is equipped with a non-limiting subsonic speed atomizing nozzle in the pod apertures bottom, (atomization parameter is an industrial nitrogen with being pulverized by the liquid metal beam atomizing of tundish bottom outlet ejection, 2MPa, 25 ° of atomizing angles, deposition is apart from 450mm), and metal atomization stream is deposited on preprepared one steel band that moves continuously.Strip material is the 08F steel, bandwidth 100mm, tape thickness 1.2mm, with steel strip surface fully clean deoil after, carry out mechanical hacking, and under the traction of tape handler, pass through a high-frequency induction coil, make it be heated to 200 ℃ and also pass through sedimentary province continuously with uniform acceleration, steel band translational speed 2m/min, the about 1mm of deposit thickness; The steel band that is loaded with metal refining shifts out after the atomizing case, by a radio-frequency induction coil steel band is carried out second-heating, and after making settled layer be warming up to 250 ℃, enter three-high mill and carry out middle temperature rolling, rolling draught is 30% of a deposit thickness, batch rolling by reeling machine at last, the back bimetallic strip thermal treatment under 350 ℃ * 4h condition that is shaped has obtained good interface combination and evenly tiny metallographic structure.
Industrial pure Al is put into a plumbago crucible, with the medium-frequency induction furnace heat fused and be warming up to 950 ℃.(660 ℃ of commercial-purity aluminium fusing points), Heating temperature is higher 290 ℃ and be incubated about 20min than fusing point, insulation bag in the middle of injecting one, be deposited on the prior ready steel band after with the step among the embodiment 1 high-temperature fusant being atomized then, (compare some technical parameters to be changed to draft-tube diameter be Φ 3.5mm with embodiment 1, atomizing gas is a technical argon, atomizing pressure 0.8MPa, the steel band translational speed is 3m/min, rolling draught 10%) spray rolls into and obtained good steel/aluminium interface combination after the shape and the industrial pure Al layer has evenly tiny metallographic structure.
Comparative example 1
Preparation is with the identical Al-Pb alloy of embodiment 1, and it is compound to carry out bimetal by the processing parameter in the embodiment of the invention 1, but steel band enters before the three-high mill processing parameter and changes (1) into and do not heat behind the spray deposition; (2) Heating temperature is 350 ℃; Splitting all appears rolling in alloy layer under two kinds of conditions, and the former cold cracking occurs by alloy layer, and hot tearing then appears in the latter, and the two all causes compound failure.
Comparative example 2
Select industrial pure Al for use, compound by processing parameter and steel band in the embodiment of the invention 2, but processing parameter is changed into (1) and is not carried out middle temperature rolling, direct winding behind the spray deposition; (2) rolling draught is 4%, and it is very low to be lower than under 5%, two kind of situation of specified minimum value of the present invention the bonding force of steel band and aluminium lamination, and tissue looseness in the deposition aluminium lamination, and the interface is checked has many places to separate hole.
Claims (6)
1, a kind of manufacture method of bimetal band with steel substrate is characterized in that:
(1) will treat the composite alloy heat fused, and be heated to above 10~300 ℃ of liquidus line, make it to become a kind of single-phased alloy melt of uniform ingredients;
(2),, move through the spray deposition case of a sealing continuously with even velocity with preprepared steel coil strip;
(3) the qualified liquid bearing alloy of melting injects the atomizing case, with the high pressure gas atomizing nozzle metal liquid stream is fully pulverized immediately and is formed the atomized flow that certain space distributes;
(4) will be cooled to semi-solid metal atomization stream and be deposited on the steel band that moves continuously the atomizing nozzle below translational speed 0.5m-10m/mim;
(5) steel band that is loaded with depositing metal layers is continuously to milling train one lateral movement, and depositing metal layers is finished cooling curing and preliminary bonding with steel band on the steel band simultaneously;
(6) aforementioned steel band is adjusted to suitable rolling temperature,, sends into milling train immediately and carry out middle temperature rolling, draught 5%~40% a little less than the fusing point of low-melting metal phase;
(7) rolling bimetallic composite band is batched continuously;
(8) the bi-metal shaft bushing band of rolling is heat-treated.
2. by the manufacture method of the described bimetal band with steel substrate of claim 1, it is characterized in that: treat that composite alloy is an aluminum base alloy, Al>50%; Copper base alloy Cu>50%, zinc base alloy Zn>50%; Sn base alloy Sn>50%; Or Pb base alloy Pb>5% is a kind of, and steel backing material is a soft steel.
3. by the manufacture method of the described bimetal band with steel substrate of claim 1, it is characterized in that: use restricted atomizing nozzle or unrestricted formula atomizing nozzle, 0.5 °~60 ° of atomizing angles, atomizing pressure 4atm-40atm; Nozzle is done scanning motion, and it is vertical with the steel band travel direction, and scan mode is mechanical scanning or pneumatic scanning.
4. press the manufacture method of the described bimetal band with steel substrate of claim 1, it is characterized in that: reach default temperature with preheating or pressure cooling before steel band is rolling, be lower than 5~300 ℃ of temperature that occur liquid phase in the alloy layer, type of heating is with resistance furnace, high frequency, intermediate frequency or self-resistance heating.
5. press the manufacture method of the described bimetal band with steel substrate of claim 1, it is characterized in that: alloy carries out middle temperature rolling immediately after carrying out spray deposition on the steel band, with the densification of finishing settled layer and the bonding force that improves settled layer and steel strip surface, rolling temperature is 100~600 ℃; When in the settled layer low melting point alloy being arranged, a little less than the fusing point of low melting point phase in the deposit alloy.
6. by the manufacture method of the described bimetal band with steel substrate of claim 1, it is characterized in that: the rolling deformation amount is 5%~40%, and roll speed is identical with steel band translational speed in the atomizing case.
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CNB001106805A CN1157492C (en) | 2000-07-19 | 2000-07-19 | Process for preparing bimetal band with steel substrate |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100374612C (en) * | 2005-12-26 | 2008-03-12 | 内蒙古科技大学 | Process and apparatus for continuous producing double-metal thin plate, thin band by atomized metal ejection |
CN101912876A (en) * | 2010-08-17 | 2010-12-15 | 苏州有色金属研究院有限公司 | Production method of magnesium alloy plate |
CN1714957B (en) * | 2004-11-25 | 2011-09-14 | 李铁铎 | Method and device for producing different metal material composite plate and strip |
CN102294452A (en) * | 2011-05-30 | 2011-12-28 | 北京中钢贸科技发展有限公司 | Device and method for automatically reeling amorphous/nanocrystalline strips |
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Cited By (12)
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CN1714957B (en) * | 2004-11-25 | 2011-09-14 | 李铁铎 | Method and device for producing different metal material composite plate and strip |
CN100374612C (en) * | 2005-12-26 | 2008-03-12 | 内蒙古科技大学 | Process and apparatus for continuous producing double-metal thin plate, thin band by atomized metal ejection |
CN101912876A (en) * | 2010-08-17 | 2010-12-15 | 苏州有色金属研究院有限公司 | Production method of magnesium alloy plate |
CN101912876B (en) * | 2010-08-17 | 2012-09-05 | 苏州有色金属研究院有限公司 | Production method of magnesium alloy plate |
CN102294452A (en) * | 2011-05-30 | 2011-12-28 | 北京中钢贸科技发展有限公司 | Device and method for automatically reeling amorphous/nanocrystalline strips |
CN102294452B (en) * | 2011-05-30 | 2013-05-22 | 北京中钢贸科技发展有限公司 | Device and method for automatically reeling amorphous/nanocrystalline strips |
EP2650388A1 (en) * | 2012-04-12 | 2013-10-16 | Linde Aktiengesellschaft | Device and treatment section for finishing a metal product section by section |
CN104589726A (en) * | 2014-12-01 | 2015-05-06 | 华南理工大学 | Multiphase dual-scale structural aluminum-tin based composite bearing bush strip and preparation method thereof |
CN108045069A (en) * | 2018-01-12 | 2018-05-18 | 西安航空学院 | Layer metal composite plate material preparation facilities and its application method |
CN108045069B (en) * | 2018-01-12 | 2023-07-14 | 西安航空学院 | Layered metal composite board preparation device and application method thereof |
CN112442648A (en) * | 2019-08-29 | 2021-03-05 | 青岛九环新越新能源科技股份有限公司 | Composite metal belt production equipment based on liquid metal |
CN114042918A (en) * | 2021-11-05 | 2022-02-15 | 潍柴动力股份有限公司 | Preparation process and preparation tool for copper-steel bimetal component and cylinder body |
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