CN1330688A - 含碘和/或溴的聚碳酸酯在具有高x－射线反差的模塑制品中的用途以及由此材料生产的模塑制品 - Google Patents

含碘和/或溴的聚碳酸酯在具有高x－射线反差的模塑制品中的用途以及由此材料生产的模塑制品 Download PDF

Info

Publication number: CN1330688A
Authority: CN; China
Prior art keywords: preferred; contain; bromination; iodinating; polycarbonate
Prior art date: 1998-12-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN99814500A

Other languages

English (en)

Chinese (zh)

Inventor

M·德布勒

S·纽曼

A·布伦纳

W·科勒

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee

Bayer AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-12-18

Filing date

1999-12-07

Publication date

2002-01-09

1999-12-07 Application filed by Bayer AG filed Critical Bayer AG

2002-01-09 Publication of CN1330688A publication Critical patent/CN1330688A/zh

Status Pending legal-status Critical Current

Links

ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 16
229910052740 iodine Inorganic materials 0.000 title claims abstract description 15
239000011630 iodine Substances 0.000 title claims abstract description 15
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims abstract description 8
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims abstract description 8
229910052794 bromium Inorganic materials 0.000 title claims abstract description 8
229920000515 polycarbonate Polymers 0.000 title claims description 46
239000004417 polycarbonate Substances 0.000 title claims description 45
239000012815 thermoplastic material Substances 0.000 claims abstract description 12
239000000203 mixture Substances 0.000 claims description 19
230000031709 bromination Effects 0.000 claims description 16
238000005893 bromination reaction Methods 0.000 claims description 16
230000002083 iodinating effect Effects 0.000 claims description 15
239000000463 material Substances 0.000 claims description 14
229920003023 plastic Polymers 0.000 claims description 11
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
239000004033 plastic Substances 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 9
239000000654 additive Substances 0.000 claims description 7
229920006352 transparent thermoplastic Polymers 0.000 claims description 7
-1 fatty acid ester Chemical class 0.000 claims description 6
230000000996 additive effect Effects 0.000 claims description 5
YQEMORVAKMFKLG-UHFFFAOYSA-N 2-stearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 4
OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 claims description 4
239000000975 dye Substances 0.000 claims description 4
150000003852 triazoles Chemical class 0.000 claims description 4
238000010521 absorption reaction Methods 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
238000005809 transesterification reaction Methods 0.000 claims description 3
239000003054 catalyst Substances 0.000 claims description 2
235000014113 dietary fatty acids Nutrition 0.000 claims description 2
239000000194 fatty acid Substances 0.000 claims description 2
229930195729 fatty acid Natural products 0.000 claims description 2
239000000945 filler Substances 0.000 claims description 2
239000003063 flame retardant Substances 0.000 claims description 2
235000011187 glycerol Nutrition 0.000 claims description 2
239000003112 inhibitor Substances 0.000 claims description 2
229940059574 pentaerithrityl Drugs 0.000 claims description 2
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
229910000073 phosphorus hydride Inorganic materials 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
239000003381 stabilizer Substances 0.000 claims description 2
230000003068 static effect Effects 0.000 claims description 2
150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
239000000523 sample Substances 0.000 claims 2
125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims 1
XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 17
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 14
229920000642 polymer Polymers 0.000 description 9
238000000034 method Methods 0.000 description 8
239000000206 moulding compound Substances 0.000 description 7
239000001294 propane Substances 0.000 description 7
239000006085 branching agent Substances 0.000 description 6
229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 6
CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 description 5
238000000465 moulding Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000007334 copolymerization reaction Methods 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
238000002601 radiography Methods 0.000 description 4
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 3
KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 3
125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
239000012964 benzotriazole Substances 0.000 description 3
125000004464 hydroxyphenyl group Chemical group 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
239000000178 monomer Substances 0.000 description 3
JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 2
HJZJMARGPNJHHG-UHFFFAOYSA-N 2,6-dimethyl-4-propylphenol Chemical compound CCCC1=CC(C)=C(O)C(C)=C1 HJZJMARGPNJHHG-UHFFFAOYSA-N 0.000 description 2
QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
229930185605 Bisphenol Natural products 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
238000009833 condensation Methods 0.000 description 2
150000001925 cycloalkenes Chemical class 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
229920000139 polyethylene terephthalate Polymers 0.000 description 2
239000005020 polyethylene terephthalate Substances 0.000 description 2
229920000193 polymethacrylate Polymers 0.000 description 2
239000004926 polymethyl methacrylate Substances 0.000 description 2
230000008569 process Effects 0.000 description 2
229920001169 thermoplastic Polymers 0.000 description 2
239000004416 thermosoftening plastic Substances 0.000 description 2
YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
SPPWGCYEYAMHDT-UHFFFAOYSA-N 1,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(C(C)C)C=C1 SPPWGCYEYAMHDT-UHFFFAOYSA-N 0.000 description 1
YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
VAPDZNUFNKUROY-UHFFFAOYSA-N 2,4,6-triiodophenol Chemical compound OC1=C(I)C=C(I)C=C1I VAPDZNUFNKUROY-UHFFFAOYSA-N 0.000 description 1
BPRYUXCVCCNUFE-UHFFFAOYSA-N 2,4,6-trimethylphenol Chemical compound CC1=CC(C)=C(O)C(C)=C1 BPRYUXCVCCNUFE-UHFFFAOYSA-N 0.000 description 1
ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 1
DOTJECRZGHUBNR-UHFFFAOYSA-N 2,6-diiodo-4-propylphenol Chemical compound CCCC1=CC(I)=C(O)C(I)=C1 DOTJECRZGHUBNR-UHFFFAOYSA-N 0.000 description 1
ODBVXWOPZVVMLM-UHFFFAOYSA-N 2,6-dimethyl-4-(2-methylbutyl)phenol Chemical compound CCC(C)CC1=CC(C)=C(O)C(C)=C1 ODBVXWOPZVVMLM-UHFFFAOYSA-N 0.000 description 1
VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical compound OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
BLDLRWQLBOJPEB-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfanylphenol Chemical compound OC1=CC=CC=C1SC1=CC=CC=C1O BLDLRWQLBOJPEB-UHFFFAOYSA-N 0.000 description 1
XSVZEASGNTZBRQ-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfinylphenol Chemical compound OC1=CC=CC=C1S(=O)C1=CC=CC=C1O XSVZEASGNTZBRQ-UHFFFAOYSA-N 0.000 description 1
QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical compound OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical class CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 1
KYGLCUAXJICESS-UHFFFAOYSA-N 2-[2,3-di(propan-2-yl)phenyl]phenol Chemical compound CC(C)C1=CC=CC(C=2C(=CC=CC=2)O)=C1C(C)C KYGLCUAXJICESS-UHFFFAOYSA-N 0.000 description 1
WRLVTKZXVVEUPL-UHFFFAOYSA-N 2-chloro-4-propylphenol Chemical compound CCCC1=CC=C(O)C(Cl)=C1 WRLVTKZXVVEUPL-UHFFFAOYSA-N 0.000 description 1
FIWYWGLEPWBBQU-UHFFFAOYSA-N 2-heptylphenol Chemical compound CCCCCCCC1=CC=CC=C1O FIWYWGLEPWBBQU-UHFFFAOYSA-N 0.000 description 1
ORVCATCRRUXRCE-UHFFFAOYSA-N 2-iodooxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1OI ORVCATCRRUXRCE-UHFFFAOYSA-N 0.000 description 1
LDQYTDPXIMNESL-UHFFFAOYSA-N 2-methyl-4-propylphenol Chemical compound CCCC1=CC=C(O)C(C)=C1 LDQYTDPXIMNESL-UHFFFAOYSA-N 0.000 description 1
DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
WNLHHAAYHRAAKQ-UHFFFAOYSA-N 4-(2-methylbutyl)phenol Chemical compound CCC(C)CC1=CC=C(O)C=C1 WNLHHAAYHRAAKQ-UHFFFAOYSA-N 0.000 description 1
SUCTVKDVODFXFX-UHFFFAOYSA-N 4-(4-hydroxy-3,5-dimethylphenyl)sulfonyl-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(S(=O)(=O)C=2C=C(C)C(O)=C(C)C=2)=C1 SUCTVKDVODFXFX-UHFFFAOYSA-N 0.000 description 1
RIBPTGQSXYJRBQ-UHFFFAOYSA-N 4-[2,5-di(propan-2-yl)phenyl]phenol Chemical compound CC(C)C1=CC=C(C(C)C)C(C=2C=CC(O)=CC=2)=C1 RIBPTGQSXYJRBQ-UHFFFAOYSA-N 0.000 description 1
HJSPWKGEPDZNLK-UHFFFAOYSA-N 4-benzylphenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC=C1 HJSPWKGEPDZNLK-UHFFFAOYSA-N 0.000 description 1
WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 1
VSMDINRNYYEDRN-UHFFFAOYSA-N 4-iodophenol Chemical compound OC1=CC=C(I)C=C1 VSMDINRNYYEDRN-UHFFFAOYSA-N 0.000 description 1
GBKVQKGOOOWOHK-UHFFFAOYSA-N C(OC1=CC=CC=C1)(OC1=CC=CC=C1)=O.[I] Chemical compound C(OC1=CC=CC=C1)(OC1=CC=CC=C1)=O.[I] GBKVQKGOOOWOHK-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
239000004425 Makrolon Substances 0.000 description 1
RVSXIZFYTBXOTC-UHFFFAOYSA-N N1=CN=CN=C1.OC1=C(C=CC(=C1)OCCCCCC)C1=CC=CC(=C1)C1=CC=CC=C1 Chemical compound N1=CN=CN=C1.OC1=C(C=CC(=C1)OCCCCCC)C1=CC=CC(=C1)C1=CC=CC=C1 RVSXIZFYTBXOTC-UHFFFAOYSA-N 0.000 description 1
235000003140 Panax quinquefolius Nutrition 0.000 description 1
240000005373 Panax quinquefolius Species 0.000 description 1
JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
JDZJVWAHZYIHFA-UHFFFAOYSA-N [Br].C1(=CC=CC=C1)O Chemical compound [Br].C1(=CC=CC=C1)O JDZJVWAHZYIHFA-UHFFFAOYSA-N 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
239000002168 alkylating agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000005266 casting Methods 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
239000002872 contrast media Substances 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
150000002497 iodine compounds Chemical class 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
238000010030 laminating Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
229920005787 opaque polymer Polymers 0.000 description 1
238000005457 optimization Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
229960001553 phloroglucinol Drugs 0.000 description 1
125000002444 phloroglucinyl group Chemical group [H]OC1=C([H])C(O[H])=C(*)C(O[H])=C1[H] 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
239000013638 trimer Substances 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
- C08G64/06—Aromatic polycarbonates not containing aliphatic unsaturation
- C08G64/08—Aromatic polycarbonates not containing aliphatic unsaturation containing atoms other than carbon, hydrogen or oxygen
- C08G64/10—Aromatic polycarbonates not containing aliphatic unsaturation containing atoms other than carbon, hydrogen or oxygen containing halogens
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B90/00—Instruments, implements or accessories specially adapted for surgery or diagnosis and not covered by any of the groups A61B1/00 - A61B50/00, e.g. for luxation treatment or for protecting wound edges
- A61B90/39—Markers, e.g. radio-opaque or breast lesions markers
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/001—Toy-moulding appliances; Toy moulding

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Toys (AREA)
Materials For Medical Uses (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Polyesters Or Polycarbonates (AREA)
Laminated Bodies (AREA)

CN99814500A 1998-12-18 1999-12-07 含碘和/或溴的聚碳酸酯在具有高x－射线反差的模塑制品中的用途以及由此材料生产的模塑制品 Pending CN1330688A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19858788		1998-12-18
DE19858788.0		1998-12-18

Publications (1)

Publication Number	Publication Date
CN1330688A true CN1330688A (zh)	2002-01-09

Family

ID=7891783

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN99814500A Pending CN1330688A (zh)	1998-12-18	1999-12-07	含碘和/或溴的聚碳酸酯在具有高x－射线反差的模塑制品中的用途以及由此材料生产的模塑制品

Country Status (6)

Country	Link
EP (1)	EP1141129A1 (de)
JP (1)	JP2002533515A (de)
CN (1)	CN1330688A (de)
AU (1)	AU1971300A (de)
CA (1)	CA2355142A1 (de)
WO (1)	WO2000037562A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN107108863A (zh) *	2014-12-23	2017-08-29	新泽西鲁特格斯州立大学	生物相容性的碘化二酚单体和聚合物

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2005325319A (ja) *	2004-04-15	2005-11-24	Teijin Chem Ltd	ポリカーボネート樹脂組成物
AU2005272944B2 (en) *	2004-08-13	2009-01-15	Reva Medical, Inc.	Inherently radiopaque bioresorbable polymers for multiple uses
JP5347244B2 (ja) *	2006-08-04	2013-11-20	三菱化学株式会社	ハロゲン含有ポリカーボネート樹脂の製造方法
EA202191884A1 (ru)	2019-02-28	2021-12-08	Спид Кеа Минерал Гмбх	Паста для маркировки текстильных тканей и/или других продуктов, не способных к рентгеновскому контрасту

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4182787A (en) *	1978-06-19	1980-01-08	General Electric Company	Optically transparent, radiographically opaque tubing
CA1338093C (en) *	1988-09-06	1996-02-27	Takashi Nakajima	Disposable medical instruments and a method of manufacturing sterilized disposable medical instruments
JPH0641416A (ja) *	1992-07-24	1994-02-15	Nippon Steel Chem Co Ltd	難燃性ポリカーボネート樹脂組成物およびその成形品
DE4229642A1 (de) *	1992-09-04	1994-03-10	Bayer Ag	Pulvermischungen für matte Polycarbonat-Formmassen
JPH0857033A (ja) *	1994-08-25	1996-03-05	Terumo Corp	Ｘ線造影性医療用成型品
DE19726191A1 (de) *	1997-06-20	1998-12-24	Bayer Ag	Verwendung von Jod-phenyl-carbonat-haltigen Polycarbonaten zur Herstellung von speziellen Formteilen

1999
- 1999-12-07 EP EP99963402A patent/EP1141129A1/de not_active Withdrawn
- 1999-12-07 AU AU19713/00A patent/AU1971300A/en not_active Abandoned
- 1999-12-07 JP JP2000589625A patent/JP2002533515A/ja active Pending
- 1999-12-07 WO PCT/EP1999/009556 patent/WO2000037562A1/de not_active Application Discontinuation
- 1999-12-07 CN CN99814500A patent/CN1330688A/zh active Pending
- 1999-12-07 CA CA002355142A patent/CA2355142A1/en not_active Abandoned

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN107108863A (zh) *	2014-12-23	2017-08-29	新泽西鲁特格斯州立大学	生物相容性的碘化二酚单体和聚合物
CN107108863B (zh) *	2014-12-23	2021-03-19	新泽西鲁特格斯州立大学	生物相容性的碘化二酚单体和聚合物

Also Published As

Publication number	Publication date
AU1971300A (en)	2000-07-12
WO2000037562A1 (de)	2000-06-29
EP1141129A1 (de)	2001-10-10
CA2355142A1 (en)	2000-06-29
JP2002533515A (ja)	2002-10-08

Legal Events

Date	Code	Title	Description
2002-01-09	C06	Publication
2002-01-09	PB01	Publication
2002-03-13	C10	Entry into substantive examination
2002-03-13	SE01	Entry into force of request for substantive examination
2004-07-14	C02	Deemed withdrawal of patent application after publication (patent law 2001)
2004-07-14	WD01	Invention patent application deemed withdrawn after publication
2008-07-18	REG	Reference to a national code	Ref country code: HK Ref legal event code: WD Ref document number: 1042915 Country of ref document: HK

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JPS6242946B2 (de)	1987-09-10
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