CN1326609C - 煤焦油加氢制柴油用催化剂及利用该催化剂制备柴油的工艺 - Google Patents
煤焦油加氢制柴油用催化剂及利用该催化剂制备柴油的工艺 Download PDFInfo
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- CN1326609C CN1326609C CNB2005100125544A CN200510012554A CN1326609C CN 1326609 C CN1326609 C CN 1326609C CN B2005100125544 A CNB2005100125544 A CN B2005100125544A CN 200510012554 A CN200510012554 A CN 200510012554A CN 1326609 C CN1326609 C CN 1326609C
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- Prior art keywords
- catalyst
- fuel oil
- coal tar
- diesel oil
- catalysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 111
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 45
- 239000011280 coal tar Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims description 8
- 239000000295 fuel oil Substances 0.000 claims abstract description 48
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 43
- 238000005336 cracking Methods 0.000 claims abstract description 18
- 238000005516 engineering process Methods 0.000 claims abstract description 18
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 12
- 238000004821 distillation Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 238000006477 desulfuration reaction Methods 0.000 claims description 16
- 230000023556 desulfurization Effects 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 6
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 5
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 5
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 5
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 5
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 3
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000012545 processing Methods 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical compound [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
Description
指标 | 单位 | 条件1 | 条件2 | 条件3 | |
加氢反应器 | 反应温度 | ℃ | 360 | 360 | 360 |
氢压 | MPa | 5.0 | 6.5 | 8.0 | |
空速 | h-1 | 1.0 | 0.9 | 0.8 | |
氢油体积比 | 900 | 900 | 900 | ||
脱芳提质反应器 | 反应温度 | ℃ | 260 | 260 | 260 |
氢压 | MPa | 4.3 | 4.6 | 4.9 | |
空速 | h-1 | 1.8 | 1.5 | 1.2 | |
氢油体积比 | 500 | 500 | 500 | ||
油品名称 | 柴油 | 柴油 | 柴油 | ||
密度 | (20℃)g/cm3 | 0.85 | 0.84 | 0.85 | |
馏 | 初馏 | ℃ | 178 | 180 | 180 |
10% | ℃ | 202 | 201 | 201 |
程 | 50% | ℃ | 243 | 245 | 246 |
90% | ℃ | 328 | 326 | 328 | |
终馏 | ℃ | 363 | 363 | 362 | |
氮 | m% | 0.02 | 0.04 | 0.03 | |
硫 | m% | 0.12 | 0.13 | 0.12 | |
凝固点 | ℃ | -3 | -3 | -3 | |
粘度 | (20℃)mm2/s | 3.68 | 3.62 | 3.59 | |
闪点 | ℃ | 78 | 78 | 78 | |
酸度 | mgKOH/100ml | 3.5 | 3.6 | 3.6 | |
实际胶质 | mg/100ml | ||||
灰份 | m% | 0.003 | 0.004 | 0.003 | |
10%残碳 | m% | 0.05 | 0.06 | 0.08 | |
十六烷值 | 45 | 46 | 46 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100125544A CN1326609C (zh) | 2005-05-25 | 2005-05-25 | 煤焦油加氢制柴油用催化剂及利用该催化剂制备柴油的工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100125544A CN1326609C (zh) | 2005-05-25 | 2005-05-25 | 煤焦油加氢制柴油用催化剂及利用该催化剂制备柴油的工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1706917A CN1706917A (zh) | 2005-12-14 |
CN1326609C true CN1326609C (zh) | 2007-07-18 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2005100125544A Expired - Fee Related CN1326609C (zh) | 2005-05-25 | 2005-05-25 | 煤焦油加氢制柴油用催化剂及利用该催化剂制备柴油的工艺 |
Country Status (1)
Country | Link |
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CN (1) | CN1326609C (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101280198B (zh) * | 2007-12-05 | 2015-08-05 | 青岛科技大学 | 噻吩生产废弃污染物-含硫焦油的处理方法 |
CN101781577B (zh) * | 2009-12-21 | 2013-05-15 | 曲靖众一精细化工股份有限公司 | 利用混合煤焦油生产轻质燃料油的方法 |
CN102008974B (zh) * | 2010-11-29 | 2012-10-03 | 同济大学 | 用于煤沥青轻质化工艺的二段床反应催化剂的制备方法及其使用方法 |
CN105312073B (zh) * | 2014-08-01 | 2017-11-28 | 中国石油化工股份有限公司 | 一种烃油脱硫催化剂及其制备方法和烃油脱硫的方法 |
CN105289701B (zh) * | 2014-08-01 | 2017-12-22 | 中国石油化工股份有限公司 | 一种烃油脱硫催化剂及其制备方法和烃油脱硫的方法 |
CN105289681B (zh) * | 2014-08-01 | 2017-11-28 | 中国石油化工股份有限公司 | 一种烃油脱硫催化剂及其制备方法和烃油脱硫的方法 |
CN105289632B (zh) * | 2014-08-01 | 2017-11-24 | 中国石油化工股份有限公司 | 一种烃油脱硫催化剂及其制备方法和烃油脱硫的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4435277A (en) * | 1981-04-15 | 1984-03-06 | Institut Francais Du Petrole | Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals |
US4973397A (en) * | 1988-07-05 | 1990-11-27 | Exxon Research And Engineering Company | Hydrotreating process with mixed catalysts |
CN1351130A (zh) * | 2000-10-26 | 2002-05-29 | 中国石油化工股份有限公司 | 一种煤焦油加氢生产柴油的方法 |
-
2005
- 2005-05-25 CN CNB2005100125544A patent/CN1326609C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4435277A (en) * | 1981-04-15 | 1984-03-06 | Institut Francais Du Petrole | Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals |
US4973397A (en) * | 1988-07-05 | 1990-11-27 | Exxon Research And Engineering Company | Hydrotreating process with mixed catalysts |
CN1351130A (zh) * | 2000-10-26 | 2002-05-29 | 中国石油化工股份有限公司 | 一种煤焦油加氢生产柴油的方法 |
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Publication number | Publication date |
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CN1706917A (zh) | 2005-12-14 |
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