CN1325587C - Surpergrade scrubbing-resistant interior wall paint and its prearation method - Google Patents
Surpergrade scrubbing-resistant interior wall paint and its prearation method Download PDFInfo
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- CN1325587C CN1325587C CNB2004100391694A CN200410039169A CN1325587C CN 1325587 C CN1325587 C CN 1325587C CN B2004100391694 A CNB2004100391694 A CN B2004100391694A CN 200410039169 A CN200410039169 A CN 200410039169A CN 1325587 C CN1325587 C CN 1325587C
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Abstract
The present invention relates to a super scrubbing-resistant paint for internal wall surfaces and a preparation method thereof. The paint for internal wall surfaces is prepared from water, defoaming agents, wetting agents, antiseptic agents, dispersing agents, pH modifying agents, rutile titanium dioxide power, ground limestone, film-forming additives, propanediol, butyldiglycol, hydroxy ethyl cellulose thickening agents, pure acrylic emulsion, covering substances, sodium benzoate, mildew inhibitors, alkali-soluble expanding thickening agents and essence. The present invention comprises the following preparation steps: 1. compounding the paint; 2. thickening and dispersing in a high speed: 3. mixing the paint. Obtained products of the present invention have the advantages of strong covering power, bright coating layer, strong adhesive force, good stain resistance and scrubbing resistance with more than 10000 times.
Description
Technical field
The present invention relates to a kind of super scrubbable acrylic inner wall surface lacquer and preparation method thereof.
Background technology
The inner wall surface lacquer that occurs on the market adopts vinyl acetate emulsion as filmogen usually, and its addition is 30～35%, and the volumetric concentration of pigment (PVC) is more than 30.In order to improve the opacifying power of product, used the filler of many ultra-fine, high order numbers in the product, the oil number of these fillers is big, specific surface area is big.So the product that prior art is produced, the paint film fullness ratio is good, good hand touch, but because pigment volume concentration (PVC) is too high, the particle diameter of selected resin emulsion is bigger, so that be unfavorable for film forming, cause the compactness of paint film poor, poor water resistance, the highest scrubbing resistance number of times is 5000～6000 times.
Summary of the invention
The present invention aims to provide a kind of super scrubbable inner wall surface lacquer, and this wall paint also is based on the protection HUMAN HEALTH simultaneously, and the protection environment improves the performance of indoor decoration coating and develops.Product of the present invention also has the excellent properties that this area like product is possessed except having above-mentioned outstanding scrub resistance.For example, product of the present invention does not use heavy metal material and compound and additives such as formaldehyde, halogenide, solvent or aromatics, hydrocarbon polymer and lead, cadmium, chromium, mercury in formulating of recipe and production process, be the decorative material for internal wall of a kind of health and environment-friendly type.
The present invention also provides the preparation method of this super scrubbable inner wall surface lacquer.
The present invention is used for the water resistant type pure acrylic acid emulsion of high-weatherability, high gloss of paint for outer surface of wall as the filmogen of inner wall surface lacquer.Indexs such as the oil number by adjusting pigment and filler in the prescription, specific surface area, settling volume, the selection oil number is respectively 16～18 and 30～35 titanium dioxide and water-ground limestone, the pigment volume concentration (PVC) of prescription is controlled between 18～28, to reach best paint film compactness.
To achieve these goals, the present invention realizes according to following technical scheme:
A kind of raw material of super scrubbing-tolerant internal wall wall paint consists of: 240～300 parts of water, 2～5 parts of defoamers, 1～2 part of wetting agent, 1～1.5 portion of sanitas, 5～7 parts of dispersion agents, 1～2.5 part of pH adjusts agent, 200～300 parts of oil numbers are the titanium dioxide of 16-18,50～100 parts of oil numbers are the water-ground limestone of 30-35,8～12 parts of film coalescence aid, 20～30 parts of propylene glycol, 15～18 parts of diethylene glycol monobutyl ethers, 2.5～3.5 parts of Natvosols, 350～450 parts of pure acrylic acid emulsions, 40～50 parts of overcovers, 1～1.5 part of Sodium Benzoate, 2～4 parts of mould inhibitors, 2～4 parts of alkali swelling thickening materials and 0.2～0.5 part of essence, above consumption is all in weight part.
More than various raw materials can use conventional products well known by persons skilled in the art, wherein preferred described defoamer is defoamer CF-246; Preferred described wetting agent is wetting agent X-405; Preferred described sanitas is sanitas LXE; Preferred described dispersion agent is a dispersion agent 1124; Preferred described titanium dioxide is rutile titanium white powder R-595; The order number of preferred described water-ground limestone is between 1000～1500 orders; Preferred described mould inhibitor is mould inhibitor EPW; Preferred described pure acrylic acid emulsion is that solid content accounts for 48～51% AC-261; Preferred described alkali swelling thickening material is thickening material TT-935, and it is a kind of acrylic acid alkali swelling thickening material that is used for.
It is alkaline reagents that described pH adjusts agent, as ammoniacal liquor and AMP-95, preferably uses AMP-95, and the total addition level of AMP-95 is 1 ‰～2.5 ‰.
Described film coalescence aid is propylene glycol phenylate or alcohol ester-12, preferred propylene glycol phenylate, and the propylene glycol phenylate can be absorbed by emulsion particle, forms excellent filming continuously, gives product coalescent performance.
Described overcover is a kind of emulsion OP-62 of the hollow spheres polymkeric substance that is formed by styrene polymerization, and the solid content of emulsion is 30%, and viscosity is 65～70KU, and the particle diameter of sphere polymers is 0.3 μ m.
The preparation method of super scrubbing-tolerant internal wall wall paint of the present invention may further comprise the steps:
(1) joins lacquer
Amounts of components (weight part)
Water 200～250
Defoamer 1～2
Wetting agent 1～2
Sanitas 1～1.5
Dispersion agent 5～7
PH adjusts agent 0.5～1.5
Oil number is the rutile titanium white powder 200～300 of 16-18
Oil number is the water-ground limestone 50～100 of 30-35
Film coalescence aid 8～12
Propylene glycol 20～30
Diethylene glycol monobutyl ether 15～18
Defoamer 0.5～1.5
Above-mentioned raw materials is added in the stirring tank of high speed dispersor in order successively, start high speed dispersor, preferred 40～80 rev/mins of rotating speed, more preferably 60 rev/mins, preferred 5～20 minutes of jitter time more preferably 10 minutes, makes all auxiliary agents and pigment, filler fully wetting;
(2) thickening and high speed dispersion
2.5～3.5 parts of Natvosol thickening materials are added in the mixture that steps (1) obtain, improve gradually and disperse rotating speed to 1000～1500 rev/min, preferred 1320 rev/mins, high speed dispersion 25～35 minutes, hierarchy of control temperature is below 60 ℃;
(3) paint
Slurry scattered in the step (2) is moved in the paint cylinder of stirrer, stirs down the following raw material of adding successively:
Amounts of components (weight part)
Pure acrylic acid emulsion 350～450
Overcover 40～50
Defoamer 0.5～1.5
PH adjusts agent 0.5～1
Water 40～50
Sodium Benzoate 1～1.5
Mould inhibitor 2～4
Alkali swelling thickening material 2～4
Essence 0.2～0.5
Stirred 15～25 minutes, and detected viscosity, standard is 95～100KU, if the higher proper amount of clear water that just adds of viscosity is transferred rare; If viscosity is on the low side, just use the dilution in 1: 1 of alkali swelling thickening material and water slowly to add, till the viscosity of regulation, filter, preferably using the aperture is that 120 purpose filtering nets filter, and promptly obtains desired product.
The construction technology of product of the present invention is:
Putty must be solid, firm, and higher-strength is arranged, in order to avoid disadvantages such as shedding, cracking, poor adhesive force occur, is sure not the excessive water that adds during dilute with water, in order to avoid constructional deficiencies such as sagging, dry film shedding, opacifying power difference when construction occurring.
Owing to used the pure acrylic resin of water resistant type, and control suitable pigment volume concentration (PVC), after product of the present invention is applied to metope and drying, the membranaceous structure of matter that one deck has good water tolerance and compactness can be on metope, formed, up to ten thousand times scouring can be stood.Stable performance of the present invention is not with acid, alkaloid substance generation chemical reaction.In addition, the present invention is pollution-free to air, can not be detrimental to health, and is a kind of inner wall surface lacquer of environment-friendly type.
The performance of product of the present invention detects by national standard " synthetic resins interior wall coating) " GB/T9756-2001, and contrasts with national standard, the results are shown in Table 1:
Table 1
| Project | Index | |||
| Premium grads | Acceptable end product | Salable product | Product detected value of the present invention | |
| Condition in container application property low-temperature stability drying time (surface drying)/h≤appearance of film contrast ratio (white and light color) 〉=alkali resistance scrub resistance/time 〉= | No lump is uniform state and brushes accessible 2 normal 0.95 0.93 0.90 24h that never degenerate in two roads and do not have unusual 1,000 500 200 after the stirring | The ≈ 1 normal ≈ 0.95 that meets the requirements meets the requirements 〉=and 10000 | ||
As seen from Table 1, product of the present invention has surpassed the technical indicator, particularly scrubbing resistance number of times of the premium grads that national standard requires considerably beyond national standard, and has substantially exceeded the scrubbing resistance number of times of commercially available like product.
Product of the present invention contain hazardous substance is as shown in table 2 by the result that national standard " limits of harmful substances in the indoor decorating material interior wall coating " GB/18582 detects, and contrasts with national standard:
Table 2
| Project | The value of limiting the quantity of | Product detected value of the present invention |
| Volatile organic compounds (VOC)/(g/L) | 200 | ≈58 |
| Free formaldehyde/(g/Kg) | 0.1 | ≈0.02 |
| Heavy metal/(mg/Kg) | Dissoluble lead Pb≤90 | Do not detect |
| Soluble cadmium Cd≤75 | Do not detect | |
| Soluble chromium Co≤60 | Do not detect | |
| Soluble mercury Hg≤60 | Do not detect |
By the result in the table 2 as can be known, the index that the harmful substance contents of product of the present invention requires well below national standard, so product of the present invention is the decorative material for internal wall of a kind of health, safety and environment-friendly type.
Embodiment
Below in conjunction with specific embodiment content of the present invention is described in detail, but should be appreciated that content of the present invention is not subjected to the specifically described restriction of embodiment.
Purity grade and manufacturer raw materials used among the embodiment are as follows:
Defoamer CF-246: England Blackburn chemical company
Wetting agent X-405: Dow Chemical company limited
Sanitas LXE: U.S. Rhom and Hass
Dispersion agent 1124: U.S. Rhom and Hass
PH adjusts agent AMP-95: Dow Chemical company limited
Rutile titanium white powder R-595: U.S. Mei Lilian company
Water-ground limestone 1000 orders: the brilliant good fortune superfine powder in Jiangling factory
Propylene glycol phenylate: Shanghai Jinshan Chemical Co., Ltd.
Propylene glycol: Dow Chemical company limited
Diethylene glycol monobutyl ether: German BASF chemical company
Natvosol thickening material 250 HBR: Long company is striden the Asia by the U.S.
Pure acrylic acid latex A C-261: U.S. Rhom and Hass
Overcover OP-62: U.S. Rhom and Hass
Sodium Benzoate: Wuhan Youji Industrial Company Limited
Mould inhibitor EPW: Britain Sol company
Alkali swelling thickening material TT-935: U.S. Rhom and Hass
Essence: the glad sunshine essence in Shuande, Guangdong essence corporation
Above raw material is technical grade.
Embodiment 1
Amounts of components (weight part)
Water 210
Defoamer CF-246 1.5
Wetting agent X-405 1.5
Sanitas LXE 1
Dispersion agent 1,124 6
PH adjusts agent AMP-95 1
Rutile titanium white powder R-595 200
Water-ground limestone 1000 orders 65
Propylene glycol phenylate 10
Propylene glycol 25
Diethylene glycol monobutyl ether 15
Defoamer CF-246 0.5
Above various raw materials are added in order successively in the stirring tank of high speed dispersor (JFJ450, the mechanical company limited of the good letter of Yixing City), start high speed dispersor, rotating speed disperseed 10 minutes about 600 rev/mins, made all auxiliary agents and pigment, filler fully wetting.
Add simultaneously Natvosol thickening material 250 HBR (Long company is striden the Asia by the U.S.) of 2.5 weight parts lentamente at dispersive, improve gradually again and disperse rotating speed to 1320 rev/min, high speed dispersion 30 minutes, hierarchy of control temperature is below 60 ℃.
Scattered slurry is moved in the paint cylinder of high speed dispersor, rotating speed adds following material successively at 80 rev/mins:
Amounts of components (weight part)
Pure acrylic acid latex A C-261 380
Overcover OP-62 40
Defoamer CF-246 1
PH adjusts agent AMP-95 0.5
Water 33.8
Sodium Benzoate 1
Mould inhibitor EPW 3
Alkali swelling thickening material TT-935 4
Essence (flowers and fruits type) 0.2
Stirred 20 minutes, after testing, viscosity is 98KU.
Embodiment 2
Amounts of components (weight part)
Water 215
Defoamer CF-246 1
Wetting agent X-405 1
Sanitas LXE 1
Dispersion agent 1,124 6.5
PH adjusts agent AMP-95 1
Rutile titanium white powder R-595 240
Water-ground limestone 1000 orders 40
Propylene glycol phenylate 10
Propylene glycol 22
Diethylene glycol monobutyl ether 14
Defoamer CF-246 0.5
Above various raw materials are added in order successively in the stirring tank of high speed dispersor (JFJ450, the mechanical company limited of the good letter of Yixing City), start high speed dispersor, rotating speed disperseed 10 minutes about 600 rev/mins, made all auxiliary agents and pigment, filler fully wetting.Scattered slurry is moved in the paint cylinder of high speed dispersor, rotating speed adds following material successively at 100 rev/mins:
Amounts of components (weight part)
Pure acrylic acid latex A C-261 360
Overcover OP-62 50
Defoamer CF-246 1
PH adjusts agent AMP-95 0.5
Water 29.1
Sodium Benzoate 1
Mould inhibitor EPW 3
Alkali swelling thickening material TT-935 3
Essence (odor type yesterday) 0.2
Stirred 20 minutes, after testing, viscosity is 100KU.
Embodiment 1 gathers with the performance of embodiment 2 products
Claims (9)
1, a kind of super scrubbable inner wall surface lacquer is characterized in that the prescription of this wall paint is (by weight): 240～300 parts of water, 2～5 parts of defoamers, 1～2 part of wetting agent, 1～1.5 portion of sanitas, 5～7 parts of dispersion agents, 1～2.5 part of pH adjusts agent, 200～300 parts of rutile titanium white powder that oil number is 16-18,50～100 parts of oil numbers are the water-ground limestone of 30-35,8～12 parts of film coalescence aid, 20～30 parts of propylene glycol, 15～18 parts of diethylene glycol monobutyl ethers, 2.5～3.5 parts of Natvosols, 350～450 parts of pure acrylic acid emulsions, 40～50 parts of overcovers, 1～1.5 part of Sodium Benzoate, 2～4 parts of mould inhibitors, 2～4 parts of alkali swelling thickening materials and 0.2～0.5 part of essence.
2, a kind of inner wall surface lacquer according to claim 1 is characterized in that film coalescence aid is the propylene glycol phenylate.
3, a kind of inner wall surface lacquer according to claim 1 is characterized in that it is AMP-95 that pH adjusts agent.
4, a kind of inner wall surface lacquer according to claim 1 is characterized in that described pure acrylic acid emulsion is that solid content is 48～51% AC-261.
5, a kind of preparation method of super scrubbable inner wall surface lacquer is characterized in that this method may further comprise the steps:
(1) joins lacquer
Water-ground limestone, 8～12 parts of film coalescence aid, 20～30 parts of propylene glycol, 15～18 parts of diethylene glycol monobutyl ethers, 0.5～1.5 part of defoamer of being 30-35 with 200～250 parts of water, 1～2 part of defoamer, 1～2 part of wetting agent, 1～1.5 portion of sanitas, 5～7 parts of dispersion agents, 0.5～1.5 part of pH rutile titanium white powder that to adjust agent, 200～300 parts of oil numbers be 16-18,50～100 parts of oil numbers add in the stirring tank of high speed dispersor successively, stir, make all auxiliary agents and pigment, filler fully wetting;
(2) thickening and high speed dispersion
2.5～3.5 parts of Natvosol thickening materials are added in the mixture that steps (1) obtain, improve gradually and disperse rotating speed to 1000～1500 rev/min, disperseed 25～35 minutes, hierarchy of control temperature is below 60 ℃;
(3) paint
Slurry scattered in the step (2) is moved in the paint cylinder of stirrer, under 70～120 rev/mins stirring velocity, add 350～450 parts of pure acrylic acid emulsions, 40～50 parts of overcovers, 0.5～1.5 part of defoamer, 0.5～1 part of pH adjustment agent, 40～50 parts of water, 1～1.5 part of Sodium Benzoate, 2～4 parts of mould inhibitors, 2～4 parts of alkali swelling thickening materials and 0.2～0.5 part of essence successively, stirred 15～25 minutes, when viscosity reaches 95～100KU, filter, promptly obtain desired product.
6, method as claimed in claim 5 is characterized in that the rotating speed of step (1) high speed dispersion machine is 40～80 rev/mins, disperses 5～20 minutes.
7, method as claimed in claim 6, the rotating speed that it is characterized in that high speed dispersor is 60 rev/mins, disperses 10 minutes.
8, method as claimed in claim 5 is characterized in that the rotating speed of high speed dispersor is brought up to 1320 rev/mins.
9, method as claimed in claim 5 is characterized in that using 120 purpose filtering nets to filter.
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| CNB2004100391694A CN1325587C (en) | 2004-02-18 | 2004-02-18 | Surpergrade scrubbing-resistant interior wall paint and its prearation method |
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| CNB2004100391694A CN1325587C (en) | 2004-02-18 | 2004-02-18 | Surpergrade scrubbing-resistant interior wall paint and its prearation method |
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| CN1325587C true CN1325587C (en) | 2007-07-11 |
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| CN103059674A (en) * | 2013-02-04 | 2013-04-24 | 福建省创益建材科技有限公司 | Environment-friendly interior wall coating |
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| CN105017887A (en) * | 2014-04-22 | 2015-11-04 | 蒋和平 | Paint capable of achieving completion by painting only once and preparation method thereof |
| CN104449165A (en) * | 2014-11-14 | 2015-03-25 | 三棵树涂料股份有限公司 | Strain-resistant inner wall latex paint and preparation method thereof |
| CN104530842A (en) * | 2014-12-25 | 2015-04-22 | 三棵树涂料股份有限公司 | Elastic high-stain-resistance water-based paint composition and preparation method thereof |
| CN104479486B (en) * | 2014-12-31 | 2016-06-08 | Ppg涂料(天津)有限公司 | The water base finish compositions of anti-stick company, its preparation method and the base material with its coating |
| CN104673035B (en) * | 2015-03-11 | 2017-08-22 | 马清浩 | Wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance |
| CN105801739B (en) * | 2016-04-11 | 2018-09-14 | 华南理工大学 | A kind of styrene-acrylic emulsion and the high PVC interiro wall latex paint of resistance to scrub prepared therefrom |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0492087A2 (en) * | 1990-12-04 | 1992-07-01 | OPTIPLAST Gesellschaft für Kunststoffspezialbeschichtungen mbH | Coating composition for wallpapers and wallpapers produced therewith |
| US5416150A (en) * | 1989-10-16 | 1995-05-16 | Hachiro Shinpo | Resin composition |
| CN1118365A (en) * | 1995-08-10 | 1996-03-13 | 康颂 | Bright coating for construction and its manufacture |
| CN1245190A (en) * | 1999-08-02 | 2000-02-23 | 郑利雄 | Water-soluble paint for wall and its preparing process |
| CN1344771A (en) * | 2001-09-25 | 2002-04-17 | 张良 | Polyacrylate paint and its production process |
| CN1394922A (en) * | 2002-08-02 | 2003-02-05 | 崔玉国 | High-elasticity external wall paint and its preparation method |
| CN1456615A (en) * | 2003-01-22 | 2003-11-19 | 邓毓荣 | Mutifunctional wall painting composition for external and internal wall space, formulating method thereof |
-
2004
- 2004-02-18 CN CNB2004100391694A patent/CN1325587C/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5416150A (en) * | 1989-10-16 | 1995-05-16 | Hachiro Shinpo | Resin composition |
| EP0492087A2 (en) * | 1990-12-04 | 1992-07-01 | OPTIPLAST Gesellschaft für Kunststoffspezialbeschichtungen mbH | Coating composition for wallpapers and wallpapers produced therewith |
| CN1118365A (en) * | 1995-08-10 | 1996-03-13 | 康颂 | Bright coating for construction and its manufacture |
| CN1245190A (en) * | 1999-08-02 | 2000-02-23 | 郑利雄 | Water-soluble paint for wall and its preparing process |
| CN1344771A (en) * | 2001-09-25 | 2002-04-17 | 张良 | Polyacrylate paint and its production process |
| CN1394922A (en) * | 2002-08-02 | 2003-02-05 | 崔玉国 | High-elasticity external wall paint and its preparation method |
| CN1456615A (en) * | 2003-01-22 | 2003-11-19 | 邓毓荣 | Mutifunctional wall painting composition for external and internal wall space, formulating method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 聚丙稀酸酯乳液的开发与应用 关键，肖铡，四川化工与腐蚀控制，第3卷第4期 2000 * |
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