CN1321885C - Method for preparing film of tube of directed nano carbon on soft base - Google Patents
Method for preparing film of tube of directed nano carbon on soft base Download PDFInfo
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- CN1321885C CN1321885C CNB031030785A CN03103078A CN1321885C CN 1321885 C CN1321885 C CN 1321885C CN B031030785 A CNB031030785 A CN B031030785A CN 03103078 A CN03103078 A CN 03103078A CN 1321885 C CN1321885 C CN 1321885C
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- tube film
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- nanometer tube
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Abstract
The present invention relates to a method for preparing a directed carbon nanometer tube film on a soft base, which comprises the following steps: firstly, growing a multilayered directed carbon nanometer tube film on a hard basement; secondly, grinding the multilayered directed carbon nanometer tube film into flat on a superfine metallurgical abrasive paper; thirdly, coating an adhesive layer on the soft basement which needs generating the multilayered directed carbon nanometer tube film; fourthly, sticking the soft basement on the surface of the ground multilayered directed carbon nanometer tube film; then, taking off the multilayered directed carbon nanometer tube film from the soft basement; finally, the directed carbon nanometer tube film of the soft basement is made. The present invention has the characteristics of simple manufacturing process, low manufacturing cost, high productive efficiency, etc. The present invention can be conveniently used in different complicated occasions, and can manufacture large-area carbon nanotube films arranged in direction.
Description
Technical field the invention belongs to the manufacture method of carbon nano-tube film, particularly makes the manufacture method of aligned carbon nanotube film in soft substrate.
The existing carbon nano-tube film of background technology has two kinds of forms.A kind of is directly to deposit the film with the carbon nanotube that aligns on quartz, silicon base (being so-called hard substrate).These films can be used for making the emitting electrons element of electric elements such as flat-panel monitor, X-ray generating pipe, incandescent lamp; Also can be directly to be deposited in the jewel substrate, as the heat dissipation film of semiconductor components and devices.Another kind is to be combined into laminated film with polymkeric substance, and slicing mode is adopted to being stochastic distribution in the position of the carbon nanotube in this laminated film, and a part of carbon nanotube is exposed from film.This composite membrane can be used as flat-panel monitor, and heat conducting film absorbs the microwave film.From utilizing the unidirectional excellent in performance aspect of carbon nanotube, first kind of film is good, but the carbon nano-tube film of first method manufacturing is hard substrate, thereby has limited its range of application.Though second kind of film used conveniently, because mix in the system process at matrix material simultaneously to being stochastic distribution the position of carbon nanotube, the homodisperse of carbon nanotube is inhomogeneous, will influence the use properties of carbon nanotube widely.As heat conducting film, effect is just poor as present carbon nano tube compound material.
Summary of the invention the purpose of this invention is to provide a kind of manufacturing process with carbon nano-tube film of above-mentioned two kinds of film characteristics, can both maximally utilise the axial excellent in performance of carbon nanotube under various conditions.
The technological line of manufacturing carbon nano-tube film of the present invention is described below:
1, utilizes the technology of the multi-layer oriented carbon nanotube of existing growth, deposition of carbon nanotubes film on quartz or silicon base; 2, on No. 800 abrasive paper for metallograph, grind flat carbon nano-tube film; 3, in the soft substrate of needs generation carbon nano-tube film, apply one deck tackiness agent, again this substrate is bonded at the surface of ground carbon nano-tube film; 4, take this substrate off from carbon nano-tube film, form the aligned carbon nanotube film of soft substrate.Wherein said soft substrate is metallic membrane, plastics or paper substrates.
Through above-mentioned 4 steps, just be transferred in the soft substrate at the aligned carbon nanotube film that forms on quartz or the silicon base, thereby be made into soft substrate aligned carbon nanotube film.Repeat the above-mentioned the 3rd and the 4th step, just can successively transfer to the multilayer carbon nanotube film that is deposited on quartz or the silicon base in the soft substrate very easily, be made into the soft substrate aligned carbon nanotube of multi-disc film.
The existing processes multi-layer oriented carbon nanotube of growing that utilizes of the present invention, only be in order once to generate multi-layer oriented carbon nanotube, obtain the soft substrate aligned carbon nanotube of multi-disc film by the present invention then, in fact utilize existing processes growth individual layer aligned carbon nanotube, be adapted to the present invention too.
Tackiness agent of the present invention can be non-setting adhesive or other tackiness agent.
Soft substrate of the present invention can be softish materials such as metallic membrane, plastics, paper, also can be exactly directly to use Pressure sensitive adhesive tape, does not so just need in addition adhesive coating again.
The soft substrate carbon nano-tube film of made of the present invention can directly be pasted use.For example can stick on the cell phone rear cover, play the effect of inhaling ripple; Can stick in the refrigerator, play deodorization or the like.
On the soft substrate carbon nano-tube film basis that the present invention is made into, can also be according to the different purposes of carbon nano-tube film, adopt filming technologies such as plating, electroless plating, plasma sputtering, layer of metal film is made on surface at the carbon nano-tube film of soft substrate, has the carbon nanotube that aligns or the composite membrane of metal thereby produce.In this case, available corresponding solvent is removed tackiness agent and soft substrate.
The present invention has its unique advantage aspect making single-layer carbon nano-tube film, its technology is simple, cost of manufacture is low, the production efficiency height can be advantageously used in various, complicated occasion, and can make the large-area carbon nano-tube film that aligns at low cost.
Embodiment the present invention will be further described by following examples.
Embodiment 1.
At first utilize chemical Vapor deposition process, the deposit multilayer carbon nano-tube film is 30 minutes on quartz substrate, obtains the carbon nanotube of three layers of oriented growth; On No. 800 abrasive paper for metallograph, grind flat carbon nano-tube film; Be bonded at the surface of ground carbon nano-tube film then with Pressure sensitive adhesive tape; Directly take Pressure sensitive adhesive tape off subsequently from carbon nano-tube film.Like this, on Pressure sensitive adhesive tape, just made a single-layer carbon nano-tube film.On remaining carbon nano-tube film, stick another Pressure sensitive adhesive tape again, take off again, just made another single-layer carbon nano-tube film.Can make three single-layer carbon nano-tube films in this way.
Embodiment 2.
At first utilize chemical Vapor deposition process, the deposit multilayer carbon nano-tube film is 10 minutes on quartz substrate, obtains single-layer carbon nano-tube; On No. 800 abrasive paper for metallograph, grind flat carbon nano-tube film; Need waiting coating one deck Resins, epoxy on the aluminium film of carbon nano-tube film, again this sheet aluminium film is closely pasted on the carbon nano-tube film, behind epoxy cure, take this sheet aluminium film off, the carbon nano-tube film that individual layer aligns is transferred on this sheet aluminium film.
Claims (3)
1, a kind of method of in soft substrate, making carbon nano-tube film, utilize the technology of the multi-layer oriented carbon nanotube of existing growth, deposition of carbon nanotubes film on quartz or silicon base, it is characterized in that at first on No. 800 abrasive paper for metallograph, grinding flat carbon nano-tube film, in the soft substrate of needs generation carbon nano-tube film, apply one deck tackiness agent, again this substrate is bonded at the surface of ground carbon nano-tube film, take this substrate off from carbon nano-tube film then, form the aligned carbon nanotube film of soft substrate, wherein said soft substrate is metallic membrane, plastics or paper substrates.
2, method according to claim 1 is characterized in that described soft substrate is a Pressure sensitive adhesive tape.
3, method according to claim 1 and 2 is characterized in that adopting plating, electroless plating or plasma sputtering technology to make layer of metal film on the surface of the carbon nano-tube film of soft substrate.
Priority Applications (1)
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CNB031030785A CN1321885C (en) | 2003-01-23 | 2003-01-23 | Method for preparing film of tube of directed nano carbon on soft base |
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CNB031030785A CN1321885C (en) | 2003-01-23 | 2003-01-23 | Method for preparing film of tube of directed nano carbon on soft base |
Publications (2)
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CN1519196A CN1519196A (en) | 2004-08-11 |
CN1321885C true CN1321885C (en) | 2007-06-20 |
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CNB031030785A Expired - Fee Related CN1321885C (en) | 2003-01-23 | 2003-01-23 | Method for preparing film of tube of directed nano carbon on soft base |
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CN103723700B (en) * | 2013-12-10 | 2015-06-17 | 浙江大学 | Method for preparing aligned carbon nanotube on surface of polymeric membrane |
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CN1349478A (en) * | 1999-04-16 | 2002-05-15 | 联邦科学和工业研究组织 | Multilayer carbon nanotube films |
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- 2003-01-23 CN CNB031030785A patent/CN1321885C/en not_active Expired - Fee Related
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CN1349478A (en) * | 1999-04-16 | 2002-05-15 | 联邦科学和工业研究组织 | Multilayer carbon nanotube films |
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