CN1320056C - 抗冲改性的阻燃性聚碳酸酯模塑组合物 - Google Patents
抗冲改性的阻燃性聚碳酸酯模塑组合物 Download PDFInfo
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- CN1320056C CN1320056C CNB028212908A CN02821290A CN1320056C CN 1320056 C CN1320056 C CN 1320056C CN B028212908 A CNB028212908 A CN B028212908A CN 02821290 A CN02821290 A CN 02821290A CN 1320056 C CN1320056 C CN 1320056C
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- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- GFAUNYMRSKVDJL-UHFFFAOYSA-N formyl chloride Chemical class ClC=O GFAUNYMRSKVDJL-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000000892 gravimetry Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229940090668 parachlorophenol Drugs 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000003822 preparative gas chromatography Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组分(数字按重量份计) | V1 | V2 | 3 | 4 | V5 | 6 | 7 | 8 |
A1(PC) | 66.0 | 69.0 | 72.0 | 75.0 | 63.2 | 69.0 | 69.0 | 69.0 |
A2(PC) | - | - | - | - | - | - | - | - |
B1(接枝聚合物) | 3.0 | 3.0 | 3.0 | 3.0 | 4.9 | 4.9 | 4.9 | 4.9 |
B2(SAN) | 5.0 | 5.0 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 |
C1(BDP) | 11.0 | 11.0 | 11.0 | 11.0 | 12.8 | 12.8 | 12.8 | 12.8 |
C2(RDP/TPP混合物) | - | - | - | - | - | - | - | - |
D1(滑石)Naintsch A3 | 10.0 | 7.0 | 4.0 | 1.0 | 9.8 | 4.0 | - | - |
D2(滑石)Westmin 8 | - | - | - | - | - | - | - | - |
D3(纳米勃姆石)Plural 200 | - | - | - | - | - | - | - | - |
D4(硅灰石)Nyglos 4 | - | - | - | - | - | - | 4.0 | - |
D5(硅灰石)Wolkron 1005 | - | - | - | - | - | - | - | 4.0 |
D6(硅灰石)Nyglos 5 | - | - | - | - | - | - | - | - |
E(Teflon/B1母料10∶90) | 4.5 | 4.5 | 4.5 | 4.5 | 3.9 | 3.9 | 3.9 | 3.9 |
G1(脱模剂) | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
G2(稳定剂) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
ABS总量1) | 12.1 | 12.1 | 12.1 | 12.1 | 13.3 | 13.3 | 13.3 | 13.3 |
橡胶含量,重量%2) | 4.2 | 4.2 | 4.2 | 4.2 | 5.0 | 5.0 | 5.0 | 5.0 |
UL 94V(1.2mm) | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-1 |
UL 94V(1.0mm) | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
UL 94V(0.8mm) | V-1 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
HDT/A[℃] | 89 | 88 | 88 | 88 | 85 | 86 | 85 | 84 |
an(熔接缝)[kJ/m2] | 4 | 5 | 6 | 8 | 3 | 6 | 8 | 10 |
根据ISO 180/1U的冲击弯曲试验 | 断裂 | 断裂 | 未断裂 | 未断裂 | 断裂 | 未断裂 | 未断裂 | 未断裂 |
熔体粘度(260℃/1000s-1)(Pas) | 181 | 182 | 184 | 181 | 150 | 171 | 164 | 156 |
TGA(280℃质量损失)[%] | n.m. | n.m. | n.m. | n.m. | 0.2 | n.m. | n.m. | n.m. |
组分(数字按重量份计) | 9 | 10 | 11 | 12 | V13 | V14 | V15 | V16 |
A1(PC) | 69.0 | 70.0 | 74.0 | 71.0 | 73.0 | 65.3 | 65.3 | 71.2 |
A2(PC) | - | - | - | - | - | - | - | - |
B1(接枝聚合物) | 4.9 | 4.9 | 3.0 | 5.0 | 5.0 | 7.0 | 7.0 | 5.0 |
B2(SAN) | 4.9 | 4.9 | 5.0 | 5.0 | 5.0 | 6.0 | 6.0 | 5.0 |
C1(BDP) | 12.8 | 12.8 | 12.5 | 12.5 | 12.5 | 14.6 | 14.6 | 13.0 |
C2(RDP/TPP混合物) | - | - | - | - | - | - | - | - |
D1(滑石)Naintsch A3 | 2.0 | 3.0 | 1.0 | 2.0 | - | 2.0 | - | - |
D2(滑石)Westmin 8 | - | - | - | - | - | - | - | - |
D3(纳米勃姆石)Plural 200 | - | - | - | - | - | - | - | 0.7 |
D4(硅灰石)Nyglos 4 | 2.0 | - | - | - | - | - | - | - |
D5(硅灰石)Wolkron 1005 | - | - | - | - | - | - | - | - |
D6(硅灰石)Nyglos 5 | - | - | - | - | - | - | 2.0 | - |
E(Teflon/B1母料10∶90) | 3.9 | 3.9 | 4.0 | 4.0 | 4.0 | 4.6 | 4.6 | 4.6 |
G1(脱模剂) | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
G2(稳定剂) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
ABS总量1) | 13.3 | 13.3 | 11.6 | 13.6 | 13.6 | 17.1 | 17.1 | 14.1 |
橡胶含量,重量%2) | 5.0 | 5.0 | 4.0 | 5.2 | 5.2 | 6.7 | 6.7 | 5.5 |
UL 94V(1.2mm) | V-0 | V-0 | V-0 | V-0 | V-1 | V-0 | V-0 | V-1 |
UL 94V(1.0mm) | V-0 | V-0 | n.m. | n.m. | n.m. | V-0 | V-2 | n.m. |
UL 94V(0.8mm) | V-0 | V-0 | V-0 | V-0 | V-2 | V-2 | n.m. | n.m. |
HDT/A[℃] | 85 | 85 | 86 | 86 | 85 | 79 | 78 | n.m. |
an(熔接缝)[kJ/m2] | 7 | 7 | 8 | 8 | 9 | 7 | 9 | n.m. |
冲击弯曲试验 | 未断裂 | 未断裂 | 未断裂 | 未断裂 | 未断裂 | 未断裂 | 未断裂 | 未断裂 |
熔体粘度(260℃/1000s-1)(Pas) | 164 | 170 | 182 | 177 | 163 | 151 | 154 | 170 |
TGA(280℃质量损失)[%] | n.m. | 0.3 | n.m. | n.m. | n.m. | 0.5 | n.m. | n.m. |
组分(数字按重量份计) | V17 | V18 | V19 |
A1(PC) | 70.5 | - | 63.2 |
A2(PC) | - | 70.1 | - |
B1(接枝聚合物) | 4.9 | 5.5 | 4.9 |
B2(SAN) | 4.9 | 6.1 | 4.9 |
C1(BDP) | 14.0 | - | 12.8 |
C2(RDP/TPP混合物) | - | 10.9 | - |
D1(滑石)Naintsch A3 | - | - | - |
D2(滑石)Westmin 8 | - | 2.5 | - |
D3(纳米勃姆石)Plural 200 | 0.7 | - | - |
D4(硅灰石)Nyglos 4 | - | - | - |
D5(硅灰石)Wollkron 1005 | - | - | - |
D6(硅灰石)Nyglos 5 | - | - | 9.8 |
E(Teflon/B1母料10∶90) | 4.5 | 4.4 | 3.9 |
G1(脱模剂) | 0.4 | 0.4 | 0.4 |
G2(稳定剂) | 0.1 | 0.1 | 0.1 |
ABS总量1) | 13.9 | 15.6 | 13.3 |
橡胶含量,重量%2) | 5.4 | 5.7 | 5.0 |
UL 94V(1.2mm) | V-1 | V-0 | V-0 |
UL 94V(1.0mm) | n.m. | V-2 | V-0 |
UL 94V(0.8mm) | n.m. | n.m. | n.m. |
HDT/A[℃] | n.m. | 79 | 82 |
an(熔接缝)[kJ/m2] | n.m. | n.m. | 9 |
根据ISO 180/1U的冲击弯曲试验 | 未断裂 | 未断裂 | 断裂 |
熔体粘度(260℃/1000s-1)(Pas) | 146 | 180 | 157 |
TGA(280℃质量损失)[%] | n.m. | 1.5 | n.m. |
Claims (21)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE10152318.1 | 2001-10-26 | ||
DE10152318A DE10152318A1 (de) | 2001-10-26 | 2001-10-26 | Schlagzähmodifizierte flammwidrig ausgerüstete Polycarbonat-Formmassen |
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CN1633469A CN1633469A (zh) | 2005-06-29 |
CN1320056C true CN1320056C (zh) | 2007-06-06 |
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US (1) | US6914090B2 (zh) |
EP (1) | EP1442080A1 (zh) |
JP (1) | JP4237628B2 (zh) |
KR (1) | KR100865630B1 (zh) |
CN (1) | CN1320056C (zh) |
AR (1) | AR036908A1 (zh) |
BR (1) | BR0213493A (zh) |
CA (1) | CA2464618A1 (zh) |
DE (1) | DE10152318A1 (zh) |
MX (1) | MXPA04003811A (zh) |
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MXPA06002396A (es) * | 2003-09-01 | 2006-06-20 | Siemens Ag | Dispositivo de proteccion para componentes electronicos. |
US7232854B2 (en) * | 2004-02-03 | 2007-06-19 | General Electric Company | Polycarbonate compositions with thin-wall flame retardance |
WO2005075549A1 (en) * | 2004-02-03 | 2005-08-18 | General Electric Company | Polycarbonate composition with enhanced flex-fold properties |
WO2007044029A2 (en) * | 2004-12-03 | 2007-04-19 | Nano Science Diagnostic, Inc. | Method and apparatus for low quantity detection of bioparticles in small sample volumes |
US20060287422A1 (en) * | 2005-06-16 | 2006-12-21 | General Electric Company | Thermoplastic polycarbonate compositions with improved mechanical properties, articles made therefrom and method of manufacture |
US7446144B2 (en) * | 2005-09-14 | 2008-11-04 | Bayer Materialscience Llc | Thermoplastic molding composition and articles thermoformed therefrom |
CN100374504C (zh) * | 2005-11-09 | 2008-03-12 | 杭州鸿雁电器有限公司 | 一种聚碳酸酯/蒙脱土纳米复合材料及其制备方法 |
EP1956047A4 (en) | 2005-11-28 | 2009-12-23 | Mitsubishi Eng Plastics Corp | AROMATIC POLYCARBONATE RESIN COMPOSITION AND OBJECT MADE OF IT |
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- 2002-10-14 JP JP2003540253A patent/JP4237628B2/ja not_active Expired - Fee Related
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- 2002-10-14 CA CA002464618A patent/CA2464618A1/en not_active Abandoned
- 2002-10-14 CN CNB028212908A patent/CN1320056C/zh not_active Expired - Lifetime
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- 2002-10-14 MX MXPA04003811A patent/MXPA04003811A/es unknown
- 2002-10-14 EP EP02787485A patent/EP1442080A1/de not_active Withdrawn
- 2002-10-21 AR ARP020103964A patent/AR036908A1/es not_active Application Discontinuation
- 2002-10-22 US US10/277,824 patent/US6914090B2/en not_active Expired - Lifetime
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KR100865630B1 (ko) | 2008-10-27 |
AR036908A1 (es) | 2004-10-13 |
CN1633469A (zh) | 2005-06-29 |
WO2003037986A1 (de) | 2003-05-08 |
US20030109612A1 (en) | 2003-06-12 |
US6914090B2 (en) | 2005-07-05 |
DE10152318A1 (de) | 2003-05-08 |
JP2005507445A (ja) | 2005-03-17 |
BR0213493A (pt) | 2004-11-16 |
KR20050036883A (ko) | 2005-04-20 |
EP1442080A1 (de) | 2004-08-04 |
CA2464618A1 (en) | 2003-05-08 |
TWI241318B (en) | 2005-10-11 |
JP4237628B2 (ja) | 2009-03-11 |
MXPA04003811A (es) | 2004-07-30 |
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