CN1318665C - Tourmaline magnetic fibre and manufacturing method thereof - Google Patents
Tourmaline magnetic fibre and manufacturing method thereof Download PDFInfo
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- CN1318665C CN1318665C CNB2004100151652A CN200410015165A CN1318665C CN 1318665 C CN1318665 C CN 1318665C CN B2004100151652 A CNB2004100151652 A CN B2004100151652A CN 200410015165 A CN200410015165 A CN 200410015165A CN 1318665 C CN1318665 C CN 1318665C
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Abstract
The present invention provides a tourmaline magnetic functional fiber and a preparation method. Components comprise polymers, magnetic particles, tourmaline superfine powder and coupling agents. Compared with previous far-infrared magnetic fibers, the present invention can generate strong magnetic fields, and the selected tourmaline functional superfine powder has the advantages of natural materials, no harm to human bodies and environmental protection. The tourmaline functional superfine powder has weak currents of 0.06mA and can continuously stimulate skin, the regulating action of the nervous system is enhanced, and the blood circulation of the whole body is promoted. The tourmaline functional superfine powder in the fiber can transmit high-concentration negative oxygen ions, and health products, such as clothes, bedding articles, etc. made of the fiber have the functions of enhancement of cell viability, enhancement of the myocardial function, improvement of the sleep of human bodies and promotion of metabolism.
Description
Technical field:
The present invention relates to functional chemical fibre and manufacture method thereof, be specially a kind of bioelectricity that has, can launch efficient far infrared, discharge anion and have the artificial fibre and the manufacture method thereof of magnetic naturally.
Background technology:
In the modern society, people not only are satisfied with and solve the basic living problems, and beginning strides forward to higher level.Natural fabric just is used to be woven into the clothes that cloth is made resisting cold more since ancient times, artificial fibre then is the synthetics that is used for substituting natural fabric the modern times, progress and development along with science, people are except constantly weeding out the old and bring forth the new on the kind of chemical synthetic fiber, become on one's body the fabric of paying attention to more the chemical synthetic fiber of the new function of tool is worn in, the deep layer of skin is penetrated accelerate blood circulation, microcirculation improvement state by the magnetic line of force, far infrared; By the effective absorption of skin to negative oxygen ion, improve the oxygen content of cell, quicken the metabolism of human body, negative oxygen ion energy active balance vegetative nerve reaches the effect that keeps healthy with auxiliary curing simultaneously.
Magnetic fibre, far IR fibre, negative-ion fiber all are the functional fibres that human body is had certain health-care function.This is all carried out this both at home and abroad and carried out big quantity research.For the existing many patent documentations reports of far IR fibre, for example, introduced in polymer, adding the method that the far infrared powder prepares far IR fibre for Japanese patent laid-open 1-24837 number; Disclose for Chinese patent CN1081475 number and in synthetic fiber material, added the technology that far-infared ceramic powder is made far infrared health care type synthetic fiber; Chinese patent CN1095118 number a kind of preparation method of far-infrared ceramic chemical fibre is also disclosed.For magnetic fibre many patent documentations report is arranged also, for example, the flat 3-130413 of Japan Patent discloses a kind of method of mixing the system fiber that adopts Chinese patent CN1252460 number, and these fibers have far-infrared functional and magnetic function simultaneously.But the correlation function raw material non-natural extract of Cai Yonging wherein, whether the pure long-term use of functionalized chemical additive can have injury to human body, and academia has different versions.And this kind function is too single, and practical health care is worth not obvious.
Summary of the invention:
At the deficiencies in the prior art, Temalen magnetic function fiber of the present invention can solve in the prior art magnetic particle of difference in functionality and chemical functional particulate powder mixed and use but cause function relative single, non-natural, the problem of not environmental protection, a kind of bioelectricity that has is provided, and has had the composite functional fiber and the manufacturing technology thereof of emission efficient far infrared, negative oxygen ion and the magnetic line of force.It can have negative ion concentration, far infrared transmissivity and the stronger magnetic field intensity of higher concentration.
The technical scheme of the technical problem that the present invention solves is:
Adopt a certain proportion of polymer, magnetic particle, Temalen superfine powder, after adding the even mixing of coupling agent, under 180-240 ℃ of temperature, be mixed and made into concentrated master batch, mix with polymer support in proportion again through being spun into silk, again through adding bullet, being made for Temalen magnetic function fiber after magnetizing.
Indirect method is adopted in the production of Temalen magnetic function fiber of the present invention, promptly makes Temalen magnetic earlier and concentrates master batch, carries out spinning production again, obtains magnetic Temalen magnetic function fiber after magnetizing.
It is with the Temalen superfine powder that Temalen magnetic concentrates master batch: magnetic particle is that 6-10: 10-14 is fully dried back and 0.12-0.3 part coupling agent under through 100 ℃ of temperature; 80 parts of polymer; after the high speed mixer high-speed mixing; under 180-240 ℃ of temperature, make comminutor or extruder is produced highly enriched master batch through twin-screw.Before mixing, Temalen powder and magnetic powder are wanted intensive drying, and moisture is lower than 10PPM.
Temalen magnetic function fiber is Temalen magnetic to be concentrated master batch add evenly mixing in the polymer to by the concentrated master batch of 15-30% Temalen, carry out spinning production through 220-340 ℃ of fusion method, after spinning out undrawn yarn, place again that stretching 2-4 doubly makes the composite finished product silk under 135 ℃ of temperature.
The gap of employed magnetizing apparatus when magnetizing, magnetic field intensity must be more than or equal to 30000 Gausses, magnetizing apparatus is electronic magnetizing apparatus or constant magnetizing apparatus: be magnetized fabric evenly lentamente by the magnetizing apparatus gap, fabric should stop 3-8 about second in the motion in magnetic field.Can obtain Temalen magnetic function fiber of the present invention.
Temalen superfine powder in the component of gained Temalen functional fiber extremely: magnetic particle: coupling agent: polymer is 6-10: 10-14: 0.12-0.3: 380.
The composition of Temalen superfine powder is: a kind of in iron Tourmaline, lithium Tourmaline, the magnesium Tourmaline etc.Through after the ultra-fine grinding, average grain diameter is 0.2-0.5 μ m.
Import magnetic particle composition is one or more in tri-iron tetroxide, strontium ferrite, barium ferrite, Conjugate ferrite and neodymium iron boron, the tweezer iron boron among the present invention.Through superfine modified average grain diameter is 0.2-0.5 μ m.
The coupling agent that is added in fiber among the present invention is aluminium titanium complexing agent, γ-glycidoxypropyltrimewasxysilane, γ-methacryloxy trimethoxy silane, N-β-(amino-ethyl)-γ TSL 8330, a kind of in the γ aminopropyltriethoxywerene werene.
The polymer that is adopted in the fiber of the present invention is a conventional polymer: as polyethylene terephthalate (PET), and polypropylene (PP), polycaprolactam (PA-6), poly-a kind of in the dioctyl phthalate butanediol ester (PBT) etc.The melt index of polypropylene (PP) is 15-35.
Temalen magnetic function fiber needle of the present invention can not only produce stronger magnetic field for former far infrared magnetic fiber, and selected Temalen function superfine powder, and selection is natural, and human body is not had injury, more helps environmental protection.Test through Shanghai test center of the Chinese Academy of Sciences, the far infrared transmissivity of Temalen function superfine powder reaches 93%, is higher than the various far infrared additives such as iron oxide, magnesia, aluminium oxide, zinc oxide, titanium dioxide or high technology ceramics powder that industry adopts far away.Temalen function superfine powder itself has the weak current of 0.06mA, and can constantly produce skin stimulates, and strengthens neural regulating action, promotes the blood circulation of whole body.Through Shanghai test center of Chinese Academy of Sciences test, Temalen function superfine powder and can launch 2500/cubic centimetre of the negative oxygen ions of high concentration.As everyone knows, fresh air is very important to human body, and this is because contain the negative oxygen ion of high concentration in the fresh air.The importance of negative oxygen ion is by be called " the air vitamin " of medical circle expert image.80% of negative oxygen ion leans on human body skin to absorb, and can effectively improve the oxygen content of cell, strengthens cell viability, improves pulmonary function, and myocardial function improves sleep, enhances metabolism.
Specific embodiment:
Embodiment 1:
First step: make the hyperconcetration master batch
The component that concentrates master batch is:
Iron Tourmaline superfine powder: tri-iron tetroxide: aluminium titanium complexing agent: polyethylene terephthalate (PET) is 8: 12: 0.3: 80, and adopt dual-screw pelletizer 190-230 ℃ of granulation.Temalen powder and magnetic powder are wanted intensive drying, and moisture is lower than 10PPM.
Second step: melt spinning
Fibre fractionation is a Temalen magnetic hyperconcetration master batch: polyethylene terephthalate (PET) is to adopt long filament or short fiber spinning machine at 260-310 ℃ melt spinning at 25: 75.Temalen hyperconcetration master batch must be dry.
Third step: magnetize
Adopt electronic magnetizing apparatus to magnetize, magnetic field intensity is 50000 Gausses when magnetizing, and is magnetized fabric evenly lentamente by the magnetizing apparatus gap, and fabric should stop about 5 seconds in magnetic field in the motion.
Embodiment 2
First step: make the hyperconcetration master batch
The component that concentrates master batch is:
Lithium Temalen superfine powder: tweezer iron boron ultrafine dust: γ aminopropyltriethoxywerene werene: poly-is 6: 14: 0.3 to dioctyl phthalate butanediol ester (PBT): 80, and adopt double screw extruder 190-230 ℃ of granulation.Temalen powder and magnetic powder are wanted intensive drying, and moisture is lower than 10PPM.
Second step: melt spinning
Fibre fractionation is a Temalen magnetic hyperconcetration master batch: poly-is 25: 75 to dioctyl phthalate butanediol ester (PBT)
Adopt long filament or short fiber spinning machine at 260-310 ℃ of melt spinning.Temalen hyperconcetration master batch must be dry.
Third step: magnetize
Adopt electronic magnetizing apparatus to magnetize, magnetic field intensity is 50000 Gausses when magnetizing, and is magnetized fabric evenly lentamente by the magnetizing apparatus gap, and fabric should stop about 5 seconds in magnetic field in the motion.
Embodiment 3
First step: make the hyperconcetration master batch
The component that concentrates master batch is:
Magnesium Tourmaline superfine powder: neodymium iron boron ultrafine dust: γ-methacryloxy trimethoxy silane: polypropylene (PP) is 10: 10: 0.3: 80, and adopt double screw extruder 190-230 ℃ of granulation.Temalen powder and magnetic powder are wanted intensive drying, and moisture is lower than 10PPM.
Second step: melt spinning
Fibre fractionation is a Temalen magnetic hyperconcetration master batch: polypropylene (PP) is to adopt long filament or short fiber spinning machine at 260-310 ℃ melt spinning at 25: 75.Temalen hyperconcetration master batch must be dry.
Third step: magnetize
Adopt electronic magnetizing apparatus to magnetize, magnetic field intensity is 50000 Gausses when magnetizing, and is magnetized fabric evenly lentamente by the magnetizing apparatus gap, and fabric should stop about 5 seconds in magnetic field in the motion.
Claims (8)
1. a Temalen magnetic fibre is characterized in that component is made of polymer, magnetic particle, Temalen superfine powder, coupling agent; Temalen superfine powder: magnetic particle: coupling agent: polymer is 6-10: 10-14: 0.12-0.3: 380.
2. Temalen magnetic fibre as claimed in claim 1 is characterized in that the Temalen superfine powder: magnetic particle: coupling agent: polymer is 6: 14: 0.3: 380.
3. Temalen magnetic fibre as claimed in claim 1 is characterized in that the Temalen superfine powder: magnetic particle: coupling agent: polymer is 8: 12: 0.3: 380.
4. Temalen magnetic fibre according to claim 1, it is characterized in that the Temalen superfine powder: magnetic particle: coupling agent: polymer is 10: 10: 0.3: 380.
5. as any described Temalen magnetic fibre of claim of claim 1 to 4, the composition that it is characterized in that described Temalen superfine powder is: any one in iron Tourmaline, lithium Tourmaline, the magnesium Tourmaline, through after the ultra-fine grinding, average grain diameter is 0.2-0.5 μ m.
6. Temalen magnetic fibre as claimed in claim 5, it is characterized in that described magnetic particle composition is one or more in tri-iron tetroxide, strontium ferrite, barium ferrite, Conjugate ferrite and neodymium iron boron, the tweezer iron boron, is 0.2-0.5 μ m through superfine modified average grain diameter.
7. as Temalen magnetic fibre as described in the claim 6, it is characterized in that described coupling agent is aluminium titanium complexing agent, γ-glycidoxypropyltrimewasxysilane, γ-methacryloxy trimethoxy silane, N-β-(amino-ethyl)-γ TSL 8330, a kind of in the γ aminopropyltriethoxywerene werene.
8. Temalen magnetic fibre manufacture method is characterized in that:
Step 1: with the Temalen superfine powder: magnetic particle be 6-10: 10-14 under fully oven dry back and 0.12-0.3 part coupling agent through 100 ℃ of temperature, 80 parts of polymer, after the high speed mixer high-speed mixing, under 180-240 ℃ of temperature, produce highly enriched master batch through dual-screw pelletizer or extruder; Before mixing, Temalen powder and magnetic powder are wanted intensive drying, and moisture is lower than 10PPM;
Step 2: Temalen magnetic is concentrated master batch add evenly mixing in the polymer to by the concentrated master batch of 15-30% Temalen, carry out spinning production through 220-340 ℃ of fusion method, after spinning out undrawn yarn, place again that stretching 2-4 doubly makes the composite finished product silk under 135 ℃ of temperature;
Step 3: magnetize, magnetic field intensity must be more than or equal to 30000 Gausses, and magnetizing apparatus is electronic magnetizing apparatus or constant magnetizing apparatus, are magnetized fabric evenly lentamente by the magnetizing apparatus gap, and fabric should stop in magnetic field 3-8 second in the motion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2004100151652A CN1318665C (en) | 2004-01-16 | 2004-01-16 | Tourmaline magnetic fibre and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2004100151652A CN1318665C (en) | 2004-01-16 | 2004-01-16 | Tourmaline magnetic fibre and manufacturing method thereof |
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| CN1558005A CN1558005A (en) | 2004-12-29 |
| CN1318665C true CN1318665C (en) | 2007-05-30 |
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| CNB2004100151652A Expired - Fee Related CN1318665C (en) | 2004-01-16 | 2004-01-16 | Tourmaline magnetic fibre and manufacturing method thereof |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1598087A (en) * | 2004-09-23 | 2005-03-23 | 雷新琦 | Nano Temalen, medical stone and magnetic multi-component synthesizing fibre and its preparation technology and textile |
| CN101108053B (en) * | 2007-06-20 | 2012-01-18 | 广东康佰健康卧室连锁管理有限公司 | Magnetic bed mattress |
| CN101871139A (en) * | 2010-06-25 | 2010-10-27 | 上海心动材料科技有限公司 | Far infrared anionic magnetic fiber and manufacturing method thereof |
| CN102250480B (en) * | 2011-05-25 | 2013-06-05 | 广东高怡新工程塑料有限公司 | Plastic-based magnetic composite material and preparation method thereof |
| CN102206382B (en) * | 2011-05-25 | 2013-02-20 | 广东高怡新工程塑料有限公司 | Plastic-based composite material with permanent magnetism function and preparation method thereof |
| CN104060402B (en) * | 2014-07-04 | 2016-06-15 | 湖州润源丝织有限公司 | A kind of condensing needling structure |
| CN104499078B (en) * | 2015-01-15 | 2016-08-24 | 宁波保税区韬鸿化工科技有限公司 | Anion healthy nylon fibre |
| CN108360084A (en) * | 2018-01-30 | 2018-08-03 | 苏州宝力塑胶材料有限公司 | Long-acting strong magnetic fiber long filament of rare earth permanent-magnetic material and preparation method thereof |
| CN108301065A (en) * | 2018-01-30 | 2018-07-20 | 舟山欣欣化纤有限公司 | The long-acting strong magnetic staple fiber and its small lot preparation method of rare earth permanent-magnetic material |
| CN108360078A (en) * | 2018-01-30 | 2018-08-03 | 苏州宝力塑胶材料有限公司 | Strong magnetic fiber magnetic master batch and preparation method thereof |
| CN108251915A (en) * | 2018-01-30 | 2018-07-06 | 舟山欣欣化纤有限公司 | Long-acting strong magnetic fiber long filament of rare earth permanent-magnetic material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360093A (en) * | 2000-12-21 | 2002-07-24 | 上海惠尔婷高级内衣有限公司 | Health-care anionic fibre and its preparing process |
| CN1455033A (en) * | 2002-05-04 | 2003-11-12 | 刘良宏 | Health-care fiber and preparing method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360093A (en) * | 2000-12-21 | 2002-07-24 | 上海惠尔婷高级内衣有限公司 | Health-care anionic fibre and its preparing process |
| CN1455033A (en) * | 2002-05-04 | 2003-11-12 | 刘良宏 | Health-care fiber and preparing method thereof |
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Owner name: GUANGDONG KANG BAI HEALTHY BEDROOM CHAIN MANAGEME Free format text: FORMER OWNER: GUANGZHOU KANG BAI HEALTH GOODS CO., LTD. Effective date: 20080704 |
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Effective date of registration: 20080704 Address after: Room 1801, Linjiang business center, 323 Yanjiang Road, Yuexiu District, Guangdong, Guangzhou Patentee after: Guangzhou Combest Health Bedroom Co., Ltd. Address before: Guangdong Province, Guangzhou City, the two Road No. 48 building 16 layer shipping Patentee before: Guangzhou Combest Health Articles Co., Ltd. |
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Granted publication date: 20070530 Termination date: 20140116 |