CN1305414A - Ink-jet printable substrate with anticurl layer - Google Patents
Ink-jet printable substrate with anticurl layer Download PDFInfo
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- CN1305414A CN1305414A CN99807450A CN99807450A CN1305414A CN 1305414 A CN1305414 A CN 1305414A CN 99807450 A CN99807450 A CN 99807450A CN 99807450 A CN99807450 A CN 99807450A CN 1305414 A CN1305414 A CN 1305414A
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- base material
- modified base
- colouring agent
- described modified
- curl backing
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
- B41M5/504—Backcoats
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
Landscapes
- Ink Jet (AREA)
- Paper (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Laminated Bodies (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The present invention is directed to improved substrates containing an anticurl layer, which minimizes the tendency of the substrate to curl. The present invention also relates to improved substrates comprising an anticurl layer on a back surface of the substrate and a colorant-receiving composition of the front surface of the substrate. The colorant-receiving composition provides superior print quality and colorant stability to the substrate. The improved substrates of the present invention enable the production of superior print quality while providing enhanced lightfastness for colorants and colorant compositions against radiation including radiation in the visible wavelength range.
Description
Technical field
Involved in the present invention is the modified base material of band non-curl backing.The modified base material according to the present invention, not only can improve printing quality, and when the colouring agent on the base material is subjected to electromagnetic radiation, can improve the photostability of colouring agent.Further, modified base material of the present invention have minimum curling in, good printing quality and colouring agent stability can be provided.The modified base material makes that making the printed substrate with good printing quality and minimum curling (comparing with general base material) becomes possibility.
Background of invention
A subject matter of colouring agent is that they tend to fade when being subjected to electromagnetic radiation (for example, sunlight or artificial light and analog thereof).It is believed that: when being subjected to illumination, the fading of most of colouring agents owing to light degradation mechanism.These mechanism of degradations are included under the colouring agent environmental condition of living in, the oxidation of colouring agent and reduction.The fading of colouring agent also rely on it resident base material.
The product analysis of light stable product and intermediate product has disclosed several important light resolution models.They comprise the electronics emission from the colouring agent, reaction with ground state or excited singlet oxygen, center carbon-benzyl ring bond fission forms amino substituted benzophenone, and for example triphenhlmethane dye reduces and generates colourless leuco dye and electronics or hydrogen atom extraction formation free radical intermediate.
Different factors, temperature for example, humidity, gaseous reactant comprises O
2, O
3, SO
3And NO
2And water-soluble, non-volatile light degradation product can affect fading of toner.Affect and have some dependences between the factor that toner fades.This is generally speaking can not be applied to colouring agent and base material because observe this complex behavior that fades of the specific colorants on the specific base material.Under constant temperature, observe: for various colouring agents-base material system, the increase of relative humidity of atomsphere will be accelerated fade (for example, McLaren, K., J.Soc.Dyers Colour, 1956,72,527) of colouring agent.For example, when relative humidity of atomsphere increases, fiber can be because of the increase of fiber moisture content swelling.This can help gaseous reactant to diffuse through matrix structure.
Make the ability of the light source of colouring agent generation photochemical transformations also depend on the distribution of light source, particularly can the most effectively make wavelength that colouring agent changes the radiation ratio and when applying an EWL, the quantum yield of colouring agent degraded.Based on the photochemistry principle, can estimate that high-octane light (short wavelength) can more effectively be facilitated than low-energy light (long wavelength) fades.Studies show that thing is not always as top saying.Surpass 100 kinds of colouring agents and study the back and find that visible light can make least stable colouring agent fade usually different classes of, yet those colouring agents with high-light-fastness more are mainly by ultraviolet degradation (McLaren, K., J.Soc.Dyers Colour, 1956,72,86).
Base material is quite important to the influence of colouring agent stability.One or more kind chemical groups in the base material can postpone or quicken colouring agent and fade.This class group can be a kind of ground state material or a kind of excitation state material.The porosity of base material also is the key factor that affects toner stability.High porosity helps moisture and gaseous reactant sees through base material, thereby can accelerate fading of colouring agent.Base material makes the influence of the light of its wavelength that is not subjected to causing degraded play a kind of protectant effect by the colouring agent of screening.When the photochemistry of the industrial polymer of considering dyeing, the purity of base material also is an important consideration object.For example, the technical grade cotton, viscose rayon, polyethylene, polypropylene and PI all contain carbonyl impurities.These impurity absorbing wavelength are greater than the light (light is daylight) of 300nm, so these impurity can impel reactive materials to cause colouring agent fade (van Beek, H.C.A., Col.Res.Appl., 1983,8 (3), 176).
Conventional printing element has the acceptable printing quality, yet also has some printing defects, and these defectives can cause printing quality poorer than what expect.Printing defects, for example " feathering " and " wick effect " is dispersed in colouring agent or coloring agent component (not wish that this thing happens) outside the desirable printing image and/or make colouring agent or coloring agent component enter printing element.The result has produced a fuzzy printing image, wherein considerable colouring agent or coloring agent component move to the following of desired printing element zone or outside.
For printing quality and the colouring agent stability that improves printing element, one or more are planted the colouring agent receiving plane of coatings applications to base material, typically, coating contains anti-wick effect and anti-feathering component, and be present in solvent, as water, in the colouring agent stabilizing agent.After solvent was removed from coating, base material tended to curl to coated surfaces.For example, the polyethylene/paper/polyvinyl base material that scribbles coating on the colouring agent receiving plane tends to towards toner receiving plane curl (that is, when colouring agent receives coating up the time, the edge of base material tends to upsweep).For the curling tendency that makes printing element drops to minimumly, on technology, done many kinds and attempted.Yet up to the present, these attempt not obtaining success completely.
The modified base material that therefore, need have good base material stability.Also need to have anti-curling characteristic and good printing quality and minimum printing defects can be provided on technology, described defective is " profit of spreading and sinking in phenomenon " and the modified base material of " wicking phenomenon " of dye compositions for example.On technology, need to have the modified base material of the anti-characteristic of curling more, its can make printing defects drop to minimum in, be provided for the significant photostability to the effect of sunshine and artificial light of miscellaneous colouring agent and dye compositions on the other hand.
Summary of the invention
The present invention is devoted to aforesaid needs, and a kind of modified base material that is used for colouring agent and coloring agent component is provided.The modified base material contains one deck non-curl backing, this layer can make base material curling drop to minimum.Modified base material of the present invention can produce good printing quality, can make simultaneously colouring agent and coloring agent component to radioresistance, comprises the radiation in the visible wavelength region, the time have a stronger light resistance.
The present invention also relates to a kind ofly have non-curl backing, contain the modified base material that colouring agent receives composition in the front of base material at substrate backside.Colouring agent receives that composition provides good printing quality and for the colouring agent stability of base material.
The present invention also relates to have one deck non-curl backing, contain the modified base material of colouring agent or dye compositions in the front of base material at the back side of base material.Colouring agent or dye compositions can contain one or more plants the colouring agent stabilizing agent.Preferably, has the porphines of extremely short triplet lifetime as the colouring agent stabilizing agent.
Remarkable base material stability can be by non-curl backing of the present invention and various printing element is compound obtains.Further, remarkable printing quality, the printing vibration, colouring agent stability and base material stability can obtain by compound above-mentioned modified base material and dye compositions.These and other characteristic of the present invention and advantage will become obvious after the detailed description of following public embodiment and appended claims is investigated.Detailed Description Of The Invention
The present invention relates to have the modified base material of one deck non-curl backing.The modified base material has good base material stability, can produce simultaneously good printing quality and make colouring agent or coloring agent component to radioresistance the time, comprises the radiation in the visible wavelength region, the time have a stronger light resistance.The modified base material can use any colouring agent or coloring agent component, particularly contains colouring agent or dye compositions that one or more plant light stabilizer.
Modified base material of the present invention has the bottom that one deck scribbles non-curl backing.Non-curl backing contains one or more kind polymer adhesives and randomly one or more plant sugar and/or starch.Bottom, non-curl backing are coated with thereon, include, but not limited to paper, wood, and timber products or compound, Woven fabric, supatex fabric, textile, plastics, glass, metal, or any other can be stayed top base material to adhesive composition.The embodiment of applicable base materials sees United States Patent (USP) (patent application serial number 08/843,410 is authorized Kimberly ClarkWorldwide company, incorporates in full as a reference) here.
Bottom can scribble one or more and plant above-mentioned coating.In specific embodiments of the invention, bottom is a kind of fiber containing base material that applies or do not apply, for example, and gloss base material, the matt light base material of image and high-quality unglazed finish and wet strength medium; Or a kind of film, for example White-opalescent film (for example, KIMDURA
, K-C), hyaline membrane (for example, MELINEX
, ICI) reflective membrane, and vinyl; Or a kind of nonwoven, for example TYVEK
Preferably, bottom is a kind of coating or uncoated paper.More preferably, bottom is a kind of fibrous paper that comprises, scribbles polymer film on the two sides of paper, for example poly coating paper.A kind of suitable coating paper of polyethylene/paper/poly typical case such as Jen-coat paper of containing.
When bottom is coating paper when (comprise fibrous paper, scribble polymer film on the two sides of paper), available one or more plant the wet ability that processing methods improve bottom, but its result will coat water based paint.A kind of processing method is that bottom is carried out Corona discharge Treatment.Another kind of processing method is that the one or both sides at bottom carry out the gel coating.Carry out one or more bottoms of planting the particularly suitable of above-mentioned processing and be commercially using Schoeller paper, be denoted as SN1435 and SN1436.SN1435 is a kind of paper with 7.3 mil thick of gloss ornamenting and front gel layer.SN1436 is a kind of paper that gloss ornamenting and tow sides all have 6.2 mil thick of gel layer that has.
Non-curl backing can contain one or more plants polymer adhesive, the binder substance that is suitable for comprises, but be not limited to, natural polymer, synthesis modification natural polymer or synthetic polymer, embodiment is at " water-soluble polymer (Water-Soluble Polymers) ", C.L.McCormick, J.Bock, and D.N.Schulz, in Vol.17, " polymer science and engineering encyclopedia (Encyclopedia of Polymer Science andEngineering) ", John Wiley and Sons, Pubishers (1989) can find among the pgs.730-84.Preferably, adhesive composition contains one or more plants following polymers: polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVOH), PHEMA, poly hydroxy ethyl acrylate, polyacrylamide, poly-first acrylamide, polyethylene glycol, carboxymethyl cellulose, sodium carboxymethylcellulose, hydroxypropyl cellulose, hydroxyethylcellulose, polyacrylic acid and polyacrylate, polymethylacrylic acid and poly-methyl acrylate, polyvinylsulfonic acid and polyvinylsulfonic acid salt, poly--2-acrylamide-2-methyl propane sulfonic acid and poly--2-acrylamide-2-methyl propane sulfonic acid salt, polypropylene acyl-oxygen base trimethyl ammonium chloride, poly-first acryloxy trimethyl ammonium chloride and polydiene propyl-dimethyl ammonium chloride.In specific embodiments of the invention, adhesive ingredients contains hydroxypropyl cellulose, carboxymethyl cellulose or their mixture.
Non-curl backing also can contain one or more plants sugar and/or starch.Preferably, one or more contain one or more dextrin.The dextrin that is fit to comprises linear dextrin (lineardextrins) and cyclodextrin.The linear dextrin that is fit to includes, but not limited to can be from ArcherDaniel Midland Corpora tion, Clinton, and Iowa, the commodity of locating to have bought are called CLINTON 926
TMLinear dextrin.The cyclodextrin that is fit to comprises, but be not limited to, alpha-cyclodextrin, beta-schardinger dextrin-, gamma-cyclodextrin, δ-cyclodextrin, hydroxypropyl, the ethoxy beta-schardinger dextrin-, ethoxy α cyclodextrin, carboxymethyl α cyclodextrin, the carboxymethyl beta cyclodextrin, carboxymethyl γ cyclodextrin, octyl group amber acidifying α cyclodextrin, octyl group amber acidifying beta cyclodextrin, octyl group amber acidifying γ cyclodextrin and sulphation beta cyclodextrin, with the sulphation gamma-cyclodextrin (Cerestar USA Incorporated, Hammond, Indiana).Preferably, non-curl backing contains linear dextrin, beta-schardinger dextrin-(β-CD), hydroxypropyl (hp-β-CD), or their mixture.
In an embodiment of the present invention, non-curl backing contain about 100 to the polymer adhesives of about 10 percetages by weight and about 0 to about 90 percetages by weight dextrin.More preferably, adhesive ingredients contain about 75 to the polymer adhesives of about 25 percetages by weight and about 25 to about 75 percetages by weight dextrin.Most preferably, adhesive ingredients contain about 65 to the polymer adhesives of about 25 percetages by weight and about 35 to about 75 percetages by weight dextrin.
Except polymer adhesive and dextrin, non-curl backing of the present invention also can contain extra component.The embodiment of this class additional component includes, but not limited to charge carrier; The thermal oxidation resistance stabilizing agent; Rheology modifier; Crosslinking agent; Plasticizer; Charge control additive, for example quaternary ammonium salt; The control additive that flows, hydrophobic silica for example, zinc stearate, calcium stearate, lithium stearate, polyvinyl stearate, and polyethylene powders; Filler, calcium carbonate for example, clay and talcum powder; Surfactant; Antitack agent; Chelating agent; And TINUVIN
Compound; Other additive that in common process, uses.Charge carrier is known for those skilled in the art, and typical material is the metallic that is coated with polymer.Surfactant preferably comprises, but is not limited to C
12To C
18Surfactant, for example cetyl trimethyl ammonium chloride and carboxy methyl amylose and other surfactant, for example alkyl aryl polyethyleneglycol ether (TritonX-100) and SURFYNOL
420.TINUVIN
Compound is the compounds that Ciba-Geigy company produces, comprising benzophenone, and BTA and hindered amines.Preferred TINUVIN
Compound include, but not limited to 2-(2 '-hydroxyl-3 '-second month in a season-butyl-5 '-Te-butyl phenyl)-BTA, poly--(N-beta-hydroxyethyl-2,2,6,6 ,-tetramethyl-4-hydroxy-piperdine base succinate and 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chloro-BTA.Status and the quantity of this class additional component in colouring component is known for those skilled in the art.Typically, one or more are planted above-mentioned additive and account for about 1% to 14% of non-curl backing gross weight.
In embodiments of the invention, non-curl backing contains particulate filler.In non-curl backing, add selected particulate matter and can cause forming the more coarse external coating surface of one deck, this has improved processing characteristics (promptly, printer roller is easier to grab and colludes base material), with prevent " separating (set-off) " (that is preventing that, non-curl backing from contacting on a large scale with contiguous paper or base material).The particle grain size size is less than or equal to the particle size in the existing non-curl backing that required printing quality can be provided.Any particle as long as it does not cause the negativity influence to the non-curl backing performance of modified base material, can use.The particle that uses includes, but not limited to starch granules, polyamide granules, polyethylene particle and aluminum hydroxide particles.Preferably, particle contains about 12 polyamide granules to about 50 micron-scales.
Non-curl backing can include, but not limited to the scraper coating with the coating process of any routine, dip-coating, and spraying, the intaglio plate print roll coating, the scraper plate coating, groove is coated with, nip coating, and print roll coating.Preferably, should from bathe, transfer on the roller that stretches in the bath non-curl backing and transfer at least on the surface of bottom, non-curl backing is applied on the bottom by this process.Allow coating bottom by the top of rod or below, this can make unnecessary coating break away from bottom.In case apply, bottom dried in the baking oven of routine or otherwise.
The quantity that is coated onto the non-curl backing of bottom surface can change with the type of institute's use bottom and the applicable cases of final products.For example, with the paper that not have coating as the bottom of bottom with compare as the bottom of bottom with the paper or the film of coating, the former may need more non-curl backing coating owing to the porosity increase of bottom.Preferably, the coating weight that is coated to the non-curl backing of bottom should be about 3.0 to about 60.0g/m
2(area refers to the surface area of bottom).More preferably, the weight of coating is about 9.0 to about 23.0g/m
2(area refers to the surface area of bottom).Most preferably, the weight of coating is about 15.0 to about 20.0g/m
2(area refers to the surface area of bottom).
The one side that the present invention also relates to a kind of bottom has non-curl backing, and another side has the modified base material of colouring agent receiving layer.Preferably, modified base material of the present invention contains one deck United States Patent (USP) (number of patent application 09/058,385, application on April 9th, 1998, authorize KimberlyClark Worldwide company, its totality is incorporated this paper into as a reference) described colouring agent receiving layer.In specific embodiment of the present invention, the modified base material contains one deck bottom, one deck non-curl backing (at the back side of bottom) and one deck contain hydroxypropyl cellulose, carboxymethyl cellulose, HP-, and the colouring agent receiving layer (in the front of base) of alkyl aryl polyethyleneglycol ether (Tritor X-100).
The quantity that is coated onto the colouring agent receiving layer of bottom surface can change with non-curl backing.Similar with non-curl backing, with the paper that not have coating as the bottom of bottom with compare as the bottom of bottom with the paper or the film of coating, the former may need more colouring agent receiving layer coating owing to the porosity increase of bottom.Preferably, the coating weight that is coated to the colouring agent receiving layer of bottom should be about 3.0 to about 60.0g/m
2(area refers to the surface area of bottom).More preferably, the weight of coating is about 9.0 to about 23.0g/m
2(area refers to the surface area of bottom).Most preferably, the weight of coating is about 15.0 to about 20.0g/m
2(area refers to the surface area of bottom).Preferably, the amount that is coated to the colouring agent receiving layer coating of bottom equals to be coated to the amount of the non-curl backing coating of bottom.
When modified base material of the present invention contained aforesaid non-curl backing and colouring agent receiving layer, the modified base material can be made with above-mentioned any conventional coating process.Non-curl backing at first can be coated on the bottom, oven dry then is coated with the colouring agent receiving layer again, and then oven dry.Selectively, the colouring agent receiving layer at first can be coated on the bottom, oven dry then is coated with non-curl backing again, and then oven dry.Preferably, non-curl backing and colouring agent receiving layer are coated on the bottom simultaneously, then oven dry.Should note preventing polluting between a kind of coating composition and the another kind of coating composition.The method of producing a kind of particularly suitable of modified base material of the present invention comprises such process, wherein non-curl backing is coated to the back side of bottom; The colouring agent receiving layer is coated to the front of bottom; Bottom is passed through between the top and bottom of Meyer rod, and this can make unnecessary coating break away from from the two sides of bottom; Dry bottom in general baking oven.
No matter use which kind of colouring agent or coloring agent component, modified base material of the present invention all can be used as printing element.Preferably, employed colouring agent or coloring agent component comprise colouring agent or the dye compositions with improved photostability in the modified base material of the present invention, and wherein colouring agent stabilizing agent and colouring agent interrelate.This based colorant and dye compositions are seen United States Patent (USP) (patent application serial number 08/843,410 is authorized Kimberly Clark Worldwide company, and its totality is incorporated this paper into as a reference).Preferably, colouring agent or dye compositions contain one or more plants the colouring agent stabilizing agent, its representative species be have an extremely short triplet lifetime porphines (for example, see Kub á t, et al., Photophysical properties ofmetal complexes of meso-tetrakis (4-sulphonatophenyl) por-phyrin, J.Photochem.and Photbio.A:Chemistry 96 (1996), the 93-97 page or leaf, its totality is incorporated herein by reference).Particularly suitable porphines includes, but not limited to have the porphines of following structural:
Wherein R is any part that proton is provided, and M is a cobalt, copper or iron, and preferably, R is SO
3H,
COOH, or R
1COOH, wherein R
1Be the alkyl of 1 to 6 carbon, or its corresponding salt.
Preferably, the representative species of colouring agent stabilizing agent is following porphines, these porphines are Cu-intermediary (meso)-four-(4-sulfanatophenyl)-porphines (being denoted as CuTPPS4) and Cu-intermediary-four-(N-methyl-4-pyridine radicals)-porphines (being denoted as CuTMPS4), and structural formula is as follows:
Wherein, copper ion can replace with cobalt or iron ion.Clear: for CuTPPS4,
CoTPPS4 or FeTPPS4, when in solution, acceptable salts, for example sodium salt replaces the sulfuric acid part.Colourant solution can be with about 0.1% to the porphines of 10%wt/wt, more preferably, about 0.3% to 1%wt/wt porphines, most preferably, approximately the porphines of 0.5%wt/wt comes stable.
Although do not want to be subjected to following restriction, in theory, modified base material of the present invention and aforementioned stable compound can make dye molecule get back to ground state from excitation state effectively, thereby reach the quencher to dye molecule excitation state.This has reduced the possibility that can cause the colourless oxidation reaction of dye chromophore or other chemical reaction to take place.The of the present invention novel base material that has the aforementioned stable compound can play stabilization to any dyestuff or colouring agent.Non-limiting suitable dyes and colouring agent list can be disclosed in the U.S. Patent Application Serial Number 08/843,410, authorize Kimberly Clark Worldwide company, are incorporated herein its full content as a reference.
Except that colouring agent and colouring agent stabilizing agent, the coloring agent component that is coated on the modified base material of the present invention also can contain additional component, and this depends on its purposes.The embodiment of this class additional component includes, but not limited to one or more and plants includants; Charge carrier; The thermal oxidation resistance stabilizing agent; Rheology modifier; Crosslinking agent; Plasticizer; Charge control additive, for example quaternary ammonium salt; The control additive that flows, hydrophobic silica for example, zinc stearate, calcium stearate, lithium stearate, polyvinyl stearate, and polyethylene powders; Filler, calcium carbonate for example, clay and talcum powder; Surfactant; Buffer/PH conditioning agent; Chelating agent; Wetting agent; Corrosion inhibitor; Bactericide; And TINUVIN
Compound; Other additive well known to those skilled in the art.Charge carrier is known for those skilled in the art, and typical material is the metallic that is coated with polymerization.Surfactant preferably comprises, but is not limited to C
12To C
18Surfactant, for example cetyl trimethyl ammonium chloride and carboxy methyl amylose, and acetylenediol, for example SURFYNOL
104E.Preferred reducing agents/PH conditioning agent includes, but not limited to borax, hydrochloric acid and NaOH.Preferred chelating agent includes, but not limited to EDTA and EDTA complex compound or salt.Preferred wetting agent includes, but not limited to 1, the pure and mild glycerine of 2-ethylene.Preferred corrosion inhibitor includes, but not limited to trade name COBRATEC
99 BTAs of selling.Preferred bactericide includes, but not limited to 2, the 6-dimethyl--(commodity are called GIV-GARDDXN to diox-4-alcohol acetic ester (m-dioxan-4-ol acetate)
).TINUVIN
Compound is the compounds that Ciba-Geigy company produces, comprising benzophenone, and BTA and hindered amines.Preferred TINUVIN
Compound include, but not limited to 2-(2 '-hydroxyl-3 '-second month in a season-butyl-5 '-the tert-butyl phenyl)-BTA, poly--(N-beta-hydroxyethyl-2,2,6,6 ,-tetramethyl-4-hydroxy-piperdine base succinate and 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chloro-BTA.Status and the quantity of this class additional component in coloring components is known for those skilled in the art.
Modified base material of the present invention also can use the coloured composition that is contained in the carrier.For many application, carrier is a kind of polymer, typically a kind of thermosetting or thermoplastic polymer, and the latter is more commonly used.The thermosetting that is fit to and the embodiment of thermoplastic polymer authorize Kimberly Clark Worldwide company referring to U.S. Patent Application Serial Number 08/843,410, and this paper introduces its totality as a reference.
The present invention will be further elaborated by the following examples, but must not limit the invention in the scope of embodiments.On the contrary, be readily appreciated that, after the description that runs through here, can the various embodiments of the invention process be revised and the equivalence replacement, and not deviate from aim of the present invention for those skilled in the art.
Embodiment 1
The anticurl coating composition can make by following component is joined in 1470 parts of deionized waters: 25 parts of hydroxypropyl celluloses (Hercules chemicals), 75 parts of CMCs (Hercules chemicals), 42 parts of linear dextrin CLINTON 926
TM(ADM, Clinton, Iowa) and 2 parts of alkyl aryl polyethyleneglycol ethers (Triton X-100) (Rohm and Hass).Composition is heated and stirs, require to do like this, to obtain clear solution.Before being coated onto base material, with the solution cool to room temperature.
Embodiment 2
With the scraper rubbing method non-curl backing component among the embodiment 1 is coated on the Jen-coat ink-jet gloss base plate of 7 mil thick, uses oven for drying.Use Meyer rod is so that obtain about 15g/cm
2Relatively-stationary dry coating weight.
Embodiment 3
Non-curl backing component among the embodiment 1 is coated to has the high glaze ornamenting, tow sides all have on the Schoeller paper (Schoeller paper is denoted as SN1436) of 6.2 mil thick of gel layer.Use the scraper rubbing method, so that obtain about 15g/cm
2Relatively-stationary dry coating weight.
Embodiment 4
Non-curl backing component among the embodiment 1 is coated to the back side of SN1436 paper, colouring agent is received the another side that composition is coated to this paper.Use the scraper rubbing method, so that all obtain about 15g/cm on the two sides
2Relatively-stationary dry coating weight.Then that coating paper is dry in conventional baking oven.
As described in the present invention, obviously,, can carry out many conversion and modification to the present invention, and not deviate from aim of the present invention and scope for those those skilled in the art.
Claims (22)
1. one kind comprises one deck bottom, has worn one deck non-curl backing at first of bottom, and the modified base material that uses with colouring agent, and wherein non-curl backing contains one or more polymer materials.
2. the described modified base material of claim 1, wherein bottom comprises paper, wood, Woven fabric, supatex fabric, plastics, glass, metal, or their mixture.
3. the described modified base material of claim 2, wherein bottom comprises the paper of a kind of coating or uncoated, a kind of film, a kind of paper/film mixture or a kind of film/paper/film mixture.
4. the described modified base material of claim 3, wherein bottom comprises the paper of a kind of coating or uncoated.
5. the described modified base material of claim 3, wherein bottom comprises a kind of cellulose plate that scribbles at least a polyethylene film.
6. the described modified base material of claim 1, wherein polymer material comprises polyvinylpyrrolidone, polyvinyl alcohol, PHEMA, poly hydroxy ethyl acrylate, polyacrylamide, PMAm, polyethylene glycol, carboxymethyl cellulose, sodium carboxymethylcellulose, hydroxypropyl cellulose, hydroxyethylcellulose, polyacrylic acid and polyacrylate, polymethylacrylic acid and poly-methyl acrylate, polyvinylsulfonic acid ester and polyvinylsulfonic acid salt, poly--2-acrylamide-2-methyl propane sulfonic acid and poly--2-acrylamide-2-methyl propane sulfonic acid salt, polypropylene acyl-oxygen base trimethyl ammonium chloride, poly-first acryloxy trimethyl ammonium chloride and polydiene propyl-dimethyl ammonium chloride or their mixture.
7. the described modified base material of claim 6, wherein polymer material comprises hydroxypropyl cellulose, carboxymethyl cellulose or their mixture.
8. the described modified base material of claim 7, wherein polymer material comprises the mixture of hydroxypropyl cellulose and carboxymethyl cellulose.
9. the described modified base material of claim 1, wherein non-curl backing also comprises a kind of linear dextrin or a kind of cyclodextrin.
10. the described modified base material of claim 9, wherein base material also contains one deck colouring agent receiving layer second of bottom, and second at first reverse side.
11. the described modified base material of claim 10, wherein the colouring agent receiving layer contains hydroxypropyl cellulose, carboxymethyl cellulose and hydroxypropyl.
12. the described modified base material of claim 11, with the surface of the opposite bottom of first surface on also be printed on printing ink.
13. the described modified base material of claim 12, wherein printing ink contains a kind of colouring agent stabilizing agent that comprises a kind of porphines.
14. the described modified base material of claim 13, wherein porphines can be represented with following molecular formula:
Wherein, M is a cobalt, copper or iron; R is selected from COOH, CH
3COOH, CH
3CH
2COOH, SO
3H, CH
3CH
2COOH, SO
3H,
15. the described modified base material of claim 14, wherein porphines is Cu-intermediary-four-(4-sulfanatophenyl)-porphines or Cu-intermediary-four-(N-methyl-4-pyridine radicals)-porphines, and structural formula is as follows respectively:
Or Co-intermediary-four-(4-sulfanatophenyl)-porphines or Co-intermediary-four-(N-methyl-4-pyridine radicals)-porphines, structural formula is as follows respectively:
16. a printing process comprises: printing ink is printed on the surface of the described modified base material of claim 11.
17. the described method of claim 16, wherein printing process comprises ink jet printing.
18. the reverse side at non-curl backing has one deck bottom, one deck non-curl backing, one deck colouring agent receiving layer, and the modified base material that uses with colouring agent.Wherein non-curl backing and colouring agent receiving layer all contain hydroxypropyl cellulose and carboxymethyl cellulose.
19. the described modified base material of claim 18, wherein non-curl backing also contains a kind of linear dextrin.
20. the described modified base material of claim 18, wherein the colouring agent receiving layer also contains hydroxypropyl.
21. the method for the modified base material that a manufacturing is used with colouring agent, this method comprises:
Coating one deck non-curl backing on bottom, wherein non-curl backing contains at least a polymer material and at least a dextrin.
22. the described method of claim 21, wherein bottom comprises the cellulose plate that scribbles the layer of polyethylene film, and non-curl backing contains hydroxypropyl cellulose, carboxymethyl cellulose and linear dextrin.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8952898P | 1998-06-15 | 1998-06-15 | |
| US60/089528 | 1998-06-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1305414A true CN1305414A (en) | 2001-07-25 |
Family
ID=22218142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99807450A Pending CN1305414A (en) | 1998-06-15 | 1999-06-15 | Ink-jet printable substrate with anticurl layer |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1089881A1 (en) |
| JP (1) | JP2002518212A (en) |
| KR (1) | KR20010052837A (en) |
| CN (1) | CN1305414A (en) |
| AU (1) | AU4684299A (en) |
| BR (1) | BR9911092A (en) |
| CA (1) | CA2333568A1 (en) |
| WO (1) | WO1999065700A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101296802B (en) * | 2005-04-13 | 2010-09-29 | 惠普开发有限公司 | Inkjet anti-curl compositions for media and systems for processing the media |
| WO2012113356A3 (en) * | 2011-12-02 | 2012-11-08 | 牡丹江恒丰纸业股份有限公司 | Manufacturing device and preparation method for cigarette paper having flame-retarding stripes |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8273066B2 (en) | 2003-07-18 | 2012-09-25 | Kimberly-Clark Worldwide, Inc. | Absorbent article with high quality ink jet image produced at line speed |
| WO2006011799A1 (en) | 2004-07-30 | 2006-02-02 | Fuji Photo Film B.V. | Recording medium |
| JP6181976B2 (en) * | 2013-05-24 | 2017-08-16 | 独立行政法人国立高等専門学校機構 | Composite polymer that exhibits gel-like morphology by water absorption |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5068140A (en) * | 1989-08-02 | 1991-11-26 | Xerox Corporation | Transparencies |
| US5277965A (en) * | 1990-08-01 | 1994-01-11 | Xerox Corporation | Recording sheets |
| EP0605840A3 (en) * | 1992-12-25 | 1994-12-14 | Mitsubishi Paper Mills Ltd | Ink jet recording sheet. |
| DE69407574T2 (en) * | 1993-03-02 | 1998-05-14 | Mitsubishi Paper Mills Limited, Tokio/Tokyo | INK-JET RECORDING LAYER |
| JPH07290818A (en) * | 1994-03-04 | 1995-11-07 | Mitsubishi Paper Mills Ltd | Ink jet recording tack sheet |
| US5501902A (en) * | 1994-06-28 | 1996-03-26 | Kimberly Clark Corporation | Printable material |
| JP2002511893A (en) * | 1996-11-27 | 2002-04-16 | キンバリー クラーク ワールドワイド インコーポレイテッド | Improved support and colorant stabilizer |
-
1999
- 1999-06-15 WO PCT/US1999/013458 patent/WO1999065700A1/en not_active Application Discontinuation
- 1999-06-15 JP JP2000554559A patent/JP2002518212A/en active Pending
- 1999-06-15 BR BR9911092-0A patent/BR9911092A/en unknown
- 1999-06-15 KR KR1020007014167A patent/KR20010052837A/en not_active Application Discontinuation
- 1999-06-15 CA CA002333568A patent/CA2333568A1/en not_active Abandoned
- 1999-06-15 EP EP99930270A patent/EP1089881A1/en not_active Withdrawn
- 1999-06-15 CN CN99807450A patent/CN1305414A/en active Pending
- 1999-06-15 AU AU46842/99A patent/AU4684299A/en not_active Abandoned
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101296802B (en) * | 2005-04-13 | 2010-09-29 | 惠普开发有限公司 | Inkjet anti-curl compositions for media and systems for processing the media |
| WO2012113356A3 (en) * | 2011-12-02 | 2012-11-08 | 牡丹江恒丰纸业股份有限公司 | Manufacturing device and preparation method for cigarette paper having flame-retarding stripes |
| AU2012220111B2 (en) * | 2011-12-02 | 2016-04-21 | Mudanjiang Hengfeng Paper Co., Ltd | Manufacturing device and preparation method for cigarette paper having flame-retarding stripes |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010052837A (en) | 2001-06-25 |
| JP2002518212A (en) | 2002-06-25 |
| BR9911092A (en) | 2001-02-20 |
| EP1089881A1 (en) | 2001-04-11 |
| WO1999065700A1 (en) | 1999-12-23 |
| CA2333568A1 (en) | 1999-12-23 |
| AU4684299A (en) | 2000-01-05 |
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