CN1286123A - Monophasic waer surfactant-free non-toxic air refreshing agent composition and core type air refreshing device using same - Google Patents

Monophasic waer surfactant-free non-toxic air refreshing agent composition and core type air refreshing device using same Download PDF

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Publication number
CN1286123A
CN1286123A CN00124092.7A CN00124092A CN1286123A CN 1286123 A CN1286123 A CN 1286123A CN 00124092 A CN00124092 A CN 00124092A CN 1286123 A CN1286123 A CN 1286123A
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essence
air freshener
weight
surfactant
essence solution
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CN00124092.7A
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CN1193796C (en
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A·V·沃尔姆
J·W·Z·鲁伊岑戴尔
R·M·博登
M·J·R·怀特
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International Flavors and Fragrances Inc
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International Flavors and Fragrances Inc
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/044—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of an organic compound other than a macromolecular compound
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions

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  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Detergent Compositions (AREA)
  • Fats And Perfumes (AREA)

Abstract

Described is a single phase aqueous surfactant-free nontoxic air freshening composition containing 30-70% water, 5-20% of a fragrance, at least 60% of the components of which has a C log10P<=2.5 and 30-60 weight percent of a mixture of two glycol ether components:(i) dipropylene glycol methyl ether; and(ii) propylene glycol propyl ether or propylene glycol butyl ether.Also described is an air freshener device comprising a vessel for the aforementioned composition, an emanating surface and a wick for supplying the composition to the emanating surface.

Description

The nontoxic air freshener composition of single-phase aqueous surfactant-free and with the core pattern air freshener of said composition
Our invention is a kind of nontoxic air freshener composition of single water surfactant-free and with the core pattern air freshener of said composition.
Traditional liquia air refreshing device generally comprises a reservoir of depositing certain mixture, and this mixture may be the liquid that essence and solvent constitute, colloid solution, or microemulsion, wherein have one with distribute the core that the surface links to each other.This essence mixture is risen to by this core and distributes the surface, thereby and on this surface the pure and fresh ambient air of essence evaporation.Therefore the essence that is used in this air freshener generally is buttery, if other solvent is arranged then essence is just water insoluble.So in the solvent of essence is the system of water, must contain a kind of surfactant that essence can be dissolved in the water.The content of surfactant must be very high, for example accounts for the 10-15% of total mass percent or higher.
The surfactant that is used in these compositionss is traditional surfactant, generally is to be with anionic surfactant, as alkylbenzenesulfonate and lauryl sulfate.Certainly also use nontoxic surfactant, but their prices are expensive and can reduce the fragrance of fragrance.Because these surfactants all are nonvolatile, so they can not distribute surface evaporation.So, hindered the rising of essence in core, to such an extent as to hindered the due effect of distributing of essence along with the amount at the surfactant that distributes the surface is more and more.
Except essence and surfactant, also contain a kind of cosolvent in most of this aqueous systems, as ethanol and diethylene glycol monoethyl ether (DEGMEE).This compositions contains surfactant usually, and therefore above-mentioned identical unfavorable factor is just arranged.
Some liquia air refreshing device contains and does not seldom even contain water, does not therefore just have surfactant.As be dissolved in xiang semen among the DEGMEE (its structure is as follows).
Figure 0012409200031
If the amount of water is low then water is stable as monophasic amount, when accounting for 10% (weight) as the content when essence, the amount of water is lower than 20%.In view of these compositionss can not be born a large amount of water, just trend is expensive for they.
U.S. Patent No. 3,945,950 (being incorporated herein by reference) have been described the compositions of solid air freshening device, and this compositions has the different problem of the air freshener that contains fluid composition of being invented with us.This solid composite contains essence, diethylene glycol monoalky lether and gel, and this gel is fatty acid soaps or its slaine and the inert fluid of surfactant.As part or all of inert fluid, water is included in the compositions sometimes, but only accounts for a small amount of 4% (weight).
Apply for the U.S. Patent No. 4,663,081 (being incorporated herein by reference) on May 5th, 1987, pointed out to have the diethylene glycol monobutyl ether (DEGMBE) of following structure
When containing deliquescent essence, comparing with other glycol ethers can be unexpectedly in conjunction with a large amount of water, therefore more useful to cost.In U.S. Patent No. 4,663, further pointed out that the mixture of DEGMBE and water has most suitable volatilization character and sharp influence is arranged in 081 on the essence evaporation rate.This patent has also been described the essence that generally contains 5-30% (weight) in the compositions that contains DEGMBE; Be generally the essence of 8-20% (weight); More generally then be the essence of 10% (weight).Simultaneously this patent content of also pointing out essence in containing the compositions of DEGMBE is separated influence and can sneaks into the water yield of solution before taking place.This patent shows, when the content of essence in the solution during in 10% (weight), the water yield that can be attached in the phase solution is about 55% (weight); When the content of essence in the solution 20% the time, the water that can contain is at the most in 40% (weight).
U.S. Patent No. 4,663, point out again in 081: essence can be the essence of using in any traditional air freshener, and the characteristic of essence causes difference hardly for dissolution system.Describe in this patent: " before being separated, add entry in the solution of the various variable concentrations in the different glycol ethers of essence.Table 1 has shown tests the maximum water content that can have in the system of the various essence concentration in the glycol ether that records.
Table 1
Before being separated, can be incorporated into the maximum water content of essence/glycol ether mixture
Glycol ether The content of essence (%) in the mixture
????10 ????20 ????30 ????40 ????50
?PGMBE ????10 ????- ????- ????- ????-
?DEGMEE ????15 ????10 ????10 ????10 ????-
?DEGDME ????20 ????10 ????- ????- ????-
?TPGMME ????20 ????10 ????10 ????- ????-
?PGMPE ????20 ????10 ????10 ????- ????-
?PGMME ????20 ????10 ????10 ????10 ????-
?DPGMME ????20 ????20 ????10 ????10 ????-
?PGMEE ????30 ????20 ????10 ????10 ????-
?DEGMBE ????60 ????40 ????20 ????20 ????10
As seen from the above table, DEGMBE can bear more water than any other glycol ether under specific essence concentration.”
Word in last table and the whole application is defined as follows:
DEGMEE: compound structure is:
DEGDME: compound structure is:
Figure 0012409200053
TPGMME: compound structure is:
PGMPE: compound structure is:
Figure 0012409200055
PGMME: compound structure is:
DPGMME: compound structure is:
Figure 0012409200062
PGMBE: compound structure is:
DEGMBE: compound structure is:
Figure 0012409200064
PGMEE: compound structure is:
Figure 0012409200065
Below be set forth in U.S. Patent No. 4,663,081, the 4 hurdle, 15-17 is capable:
" go up table and shown that DEGMBE can bear more water than its any his glycol ether under specific essence concentration.”
Consider from the toxicity angle problem that the following structure of DEGMBE is related, In U.S. Patent No. 4,663, the system that proposes in 081 obviously needs a kind of substitute.
The purpose of Here it is our substitute that invention provided.
Be published in the compositions that 4 days PCT of December in 1997 application No.97/45516 shows and declared the pure and fresh and purification of a kind of mutually stable liquid, wherein comprise:
(a) butoxy propoxyl group propanol; Or other oxyalkylated alkoxypropan alcoholic solvents (be defined as down one of array structure:
(b) water
(c) Xiao Jiliang non-ionic surface active agent (arbitrarily)
(d) effectively the component of phase stable quantity is selected from alkyl sulfate surfactant, a kind of in alkyl ethoxy sulfate surfactant and their mixture.
But in PCT application No.97/45516, do not solve the problem that invention solved as us.
The present invention
Our invention is a kind of air freshener composition of single water surfactant-free, it is characterized by (a) nontoxic (b) no mutagenesis (c) environmental sound, and it basic composition is:
(ⅰ) 30-70% (weight) water
(ⅱ) the fragrant component of 5-20% (weight), at least 60% by one or more Clog in this fragrant component 10The material of P≤2.5 and 40% less than Clog 10The P value is at 2.5＜Clog 10Arbitrary component in P≤7.5 scopes
(ⅲ) mixture that constitutes by two kinds of glycol ether chemical compounds of 30-60% (weight), one of them is a dipropylene glycol monomethyl ether; Structure is as follows: Another then is the component of following structure (wherein R is n-pro-pyl or normal-butyl):
Figure 0012409200072
The partition coefficient of the n-butanol/water of " P " expression essence, the i.e. ratio of its equilibrium concentration in n-butyl alcohol and water.The partition coefficient " P " of the n-butanol/water of the essence of using in our invention is at 1-10 7.5About, and this value of at least 60% essence component is at 1-10 2.5About.Because the phase-splitting coefficient of essence component is at 1-10 in our this invention 7.5About, therefore adopting with 10 is the log at the end 10P expresses more convenient.The log of the essence used in our invention like this 10The P value about 1-7.5, vide ut supra, and the log of 60% essence 10The P value is about 1-2.5.
The log of many essence components 10The P value is on the books, as the data so many are just arranged among the Pomona92 data base of the Daylight Chemical Information System company (Daylight CIS) of California Irvine, also can quote from original.Yet log 10The P value is also supplied by Daylight CIS after calculating easily with " CLOGP " program.Arranged this moment in the Pomona92 data base, and this program has equally also been listed log 10The experiment value of P.By Hansch and Leo (Comprehensive Medicinal Chemistry, Volume4, C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ramsden, Editors, page295, Pergamon Press, 1990, this draw be with reference to) disconnected can the obtaining of program " calculate log 10P value ".This program is disconnected to be that chemical constitution with the various components of essence is a basis, considers its atomic quantity, type, atom connected mode and chemical bond again.For selecting the essence material in our invention, calculate the log of gained like this by physical-chemical process 10P value the most extensive the most reliable using is so it is than the log of experiment gained 10The P value is more desirable.
Useful (Clog in our invention experiment 10P≤2.5) essence shows below:
The essence component Approximate boiling point ???Clog 10P
Benzaldehyde ???179 ???1.480
Benzyl acetate ???215 ???1.960
The 1-carvone ???231 ???2.083
Hydroxycitronellal ???241 ???1.541
Linalool ???198 ???2.429
Phenethanol ???220 ???1.183
Coumarin ???291 ???1.412
Eugenol ???253 ???2.307
Indole ???2.142
MDJ (Methyl dihydro jasmonate) ???310 ???2.275
Beta-methyl naphthyl ketone ???300 ???2.275
Vanillin ???285 ???1.580
For our invention, the chemical compound of following structure is defined as with symbol [P nR] expression: Wherein R is meant n-pro-pyl or normal-butyl.
Dipropylene glycol monomethyl ether (structure is as follows) With [P nR] the weight ratio scope 1: 1-5: about 1.
Following embodiment is used to set forth the present invention, but the present invention only is subjected to the restriction of claims.
The essence that the embodiment I is prepared as follows
The essence component Parts by weight ??Clog 10P
Benzaldehyde ????20 ???1.480
Benzyl acetate ????20 ???1.960
The 1-carvone ????20 ???2.083
Hydroxycitronellal ????20 ???1.541
Linalool ????20 ???2.429
Phenethanol ????20 ???1.183
Coumarin ????20 ???1.412
Eugenol ????20 ???2.307
Indole ????5 ???2.142
MDJ (Methyl dihydro jasmonate) ????10 ???2.275
Beta-methyl naphthyl ketone ????20 ???2.275
Vanillin ????35 ???1.580
The benzene enanthol ????20 ???3.478
δ-undecalactone (Undecalactone) ????20 ???3.830
Patchouli alcohol ????20 ???4.530
Any ester in the benzoic acid ????20 ???5.233
On 10% level, above-mentioned essence mixes with following material: embodiment I (A) is 15 weight portion propylene glycol butyl ether (structure is as follows) (a):
Figure 0012409200101
(b) 37.5 weight portion dipropylene glycol methyl ethers (structure is as follows):
Figure 0012409200102
(c) 37.5 weight parts waters form limpid single-phase mixed liquor.
Embodiment I (B) (a) 10 weight portion propylene glycol butyl ether (b), 30 weight portion dipropylene glycol methyl ethers (c), 50 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (C) (a) 12.5 weight portion propylene glycol butyl ether (b), 35 weight portion dipropylene glycol methyl ethers (c), 42.5 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (D) (a) 10 weight portion propylene glycol butyl ether (b), 35 weight portion dipropylene glycol methyl ethers (c), 45 weight parts waters forms limpid single-phase mixed liquor.Embodiment I (E) (a) 10 weight portion propylene glycol butyl ether (b), 45 weight portion dipropylene glycol methyl ethers (c), 35 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (F) (a) 15 weight portion propylene glycol butyl ether (b), 42.5 weight portion dipropylene glycol methyl ethers (c), 32.5 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (G) (a) 10 weight portion propylene glycol butyl ether (b), 30 weight portion dipropylene glycol methyl ethers (c), 50 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (H) is 15 weight portion propylene glycol butyl ether (b), 10 weight portion dipropylene glycol propyl ether (structure is as follows) (a)
Figure 0012409200111
(c) 65 weight parts waters form limpid single-phase mixed liquor.
Embodiment I (I) (a) 25 weight portion propylene glycol monomethyl ethers (b), 20 weight portion dipropylene glycol positive propyl ethers (c), 45 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (J) (a) 20 weight portion propylene glycol monomethyl ethers (b), 15 weight portion dipropylene glycol positive propyl ethers (c), 55 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (K) (a) 10 weight portion propylene glycol n-butyl ethers (b), 35 weight portion propylene glycol monomethyl ethers (c), 45 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (L) (a) 10 weight portion propylene glycol n-butyl ethers (b), 40 weight portion propylene glycol monomethyl ethers (c), 405 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (M) (a) 10 weight portion propylene glycol butyl ether (b), 40 weight portion propylene glycol monomethyl ethers (c), 40 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (N) (a) 10 weight portion propylene glycol butyl ether (b), 35 weight portion propylene glycol monomethyl ethers (c), 45 weight parts waters forms limpid single-phase mixed liquor.
Embodiment I (O) (a) 17.5 weight portion propylene glycol butyl ether (b), 37.5 weight portion propylene glycol monomethyl ethers (c), 35 weight parts waters forms limpid single-phase mixed liquor.Sample I (A)-I (O) all adds following composition respectively:
Composition Percentage by weight
??UVASORB _ ???0.002
??KATHON _CG ???0.05
Dyestuff ???0.05
The mixture of above-mentioned gained is respectively applied for the air freshener of a kind of IFF type nonelectronic (nonelectic) core.All experiments are under stable situation, and the release period of core is all greater than 45 days.Following table has shown the phase that exhausts of every kind of sample and the percentage ratio that burst size accounts for former content:
Sample Exhaust the phase (my god) Essence burst size (the former content of %)
????Ⅰ(A) ????62 ????????????68
????Ⅰ(B) ????57 ????????????72
????Ⅰ(C) ????71 ????????????82
????Ⅰ(D) ????58 ????????????84
????Ⅰ(E) ????69 ????????????78
????Ⅰ(F) ????82 ????????????89
????Ⅰ(G) ????74 ????????????73
????Ⅰ(H) ????67 ????????????69
????Ⅰ(I) ????64 ????????????80
????Ⅰ(J) ????74 ????????????82
????Ⅰ(K) ????73 ????????????79
????Ⅰ(L) ????82 ????????????90
????Ⅰ(M) ????84 ????????????89
????Ⅰ(N) ????71 ????????????78
????Ⅰ(O) ????74 ????????????77
On the whole, our invention has had very big improvement to original technology of this system, because our characteristic of invention makes such system nontoxic, and no mutagenesis, environmental sound.
This air freshener has narration in the U.S. Patent No. 4,663,081 of bulletin on May 5th, 1987, the description of this patent is incorporated herein by reference.

Claims (8)

1. the air freshener composition of a single water surfactant-free is characterized in that,
It is that (a) is nontoxic, (b) no mutagenesis, and (c) environmental sound is made of following composition basically:
(ⅰ) 30-70 percentage by weight water;
(ⅱ) the essence component of 5-20 percentage by weight, wherein at least 60% component is by one or more Clog 10The material of P≤2.5 constitutes, 40% less than the Clogl of perfume ingredient 0The P value is 2.5＜Clog 10P≤7.5;
(ⅲ) mixture that constitutes by two kinds of glycol ether chemical compounds of 30-60 percentage by weight, a kind of is the dipropylene glycol monomethyl ether of following structure:
Figure 0012409200021
Another kind is the component of following structure:
Figure 0012409200022
Wherein R is n-pro-pyl or normal-butyl (P nR) and dipropylene glycol monomethyl ether and (P nR) weight ratio is 1: 1-5: 1.
2. compositions as claimed in claim 1 is characterized in that R is a n-pro-pyl.
3. compositions as claimed in claim 1 is characterized in that R is a normal-butyl.
4. an air freshener comprises the container of depositing essence solution, and evaporating surface and the core that evaporating surface essence solution is provided is characterized in that essence solution is compositions as claimed in claim 1.
5. an air freshener comprises the container of depositing essence solution, and evaporating surface and the core that evaporating surface essence solution is provided is characterized in that essence solution is compositions as claimed in claim 2.
6. an air freshener comprises the container of depositing essence solution, and evaporating surface and the core that evaporating surface essence solution is provided is characterized in that essence solution is compositions as claimed in claim 3.
7. air freshener as claimed in claim 4 is characterized in that the evaporating surface of air freshener and core are to form by the cellulosic material of integral body is folding.
8. as air freshener as described in the claim 7, it is characterized in that cellulosic material is a paper.
CNB001240927A 1999-08-26 2000-08-23 Monophasic waer surfactant-free non-toxic air refreshing agent composition and core type air refreshing device using same Expired - Fee Related CN1193796C (en)

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US09/383,969 US6180595B1 (en) 1999-08-26 1999-08-26 Single phase aqueous surfactant-free nontoxic air freshening composition and wick-containing air freshening device using said composition

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CN103054756A (en) * 2012-12-31 2013-04-24 义乌市美之源化妆品有限公司 Ethanol-free perfume

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US20080069780A1 (en) * 2006-04-05 2008-03-20 S.C. Johnson & Son, Inc. High Concentration Single Phase Gycol Aerosol Air Sanitizer with Dimethyl Ether Propellant/Solvent
MX2009001819A (en) * 2006-08-24 2009-02-26 Givaudan Sa Volatile substance dispensing apparatus.
DK2629807T3 (en) 2010-10-22 2017-05-22 Agilex Flavor&Fragrances WATER-BASED AIR FRESH COMPOSITIONS
CN103989245B (en) * 2014-06-06 2015-08-05 山东中烟工业有限责任公司 The Chinese style flue-cured tobacco odor type tobacco juice for electronic smoke of the sweet soapy feeling in a kind of effective reduction oral cavity
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Publication number Priority date Publication date Assignee Title
CN101959535A (en) * 2008-02-27 2011-01-26 小林制药株式会社 Aromatic agent composition for openable storage space
CN103054756A (en) * 2012-12-31 2013-04-24 义乌市美之源化妆品有限公司 Ethanol-free perfume

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