CN1277944A - Etching paste for automobile glass and the use thereof - Google Patents
Etching paste for automobile glass and the use thereof Download PDFInfo
- Publication number
- CN1277944A CN1277944A CN 99109219 CN99109219A CN1277944A CN 1277944 A CN1277944 A CN 1277944A CN 99109219 CN99109219 CN 99109219 CN 99109219 A CN99109219 A CN 99109219A CN 1277944 A CN1277944 A CN 1277944A
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- CN
- China
- Prior art keywords
- parts
- self
- adhesive paper
- etching
- symbol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
Abstract
The present invention relates to an automobile glass etching paste which is prepared by mixing ammonium fluoride, oxalic acid, ammonium sulphate, glycerine, phosphoric acid, barium sulphate and water, mould etching method or the silk screen printing method is used to etch automobile license plate number or other pattern on automobile glass. The invented etching paste is not poisonous, no pollution, low in cost, easy to apply, quick etching speed, etc.
Description
The invention belongs to the glass etching technical field, more specifically say so a kind of automobile glass etching paste formulation and application method thereof.
Raising along with living standards of the people, automobile will become the integral part of people's life day by day, the personal automobile owning amount is in continuous growth, but the quantity of annual stolen automobile is also in rapid rising, behind some lawless person's stolen cars, usually be to remove car plate, be replaced with own brand, car is disposed of stolen goods.Stolen in order to prevent automobile, people also have many precautionary measures as atas such as installation theftproof locks on automobile, but the ata expense is higher, and antitheft reliability is limited; Also have on vehicle glass etching mark of car or figure, symbol, this kind method, sign are very easily found and are recognized, and be difficult for altering, the trade mark of each vehicle is again unique, be can multiple, therefore the bandit to the desire crime will play the effect of threatening, though automobile stolen after, also solve a case than being easier to identification, if glass by the glass that more renews after smashing, owing to leave a trace, therefore also helps in time solving a case.
For mark of car is etched on the vehicle glass, uses suitable etching reagent and adopt simple engraving method.In existing technology, literal, symbol etc. is engraved on the self-adhesive paper with the computer carving machine for the CN1135428A patent application as publication number, scratch literal, the symbol at following required quarter then, stick the paper that soaked hydrofluoric acid at last, after 2～3 minutes, take off hydrofluoric acid paper, at required literal, the symbol of promptly obtaining on glass, the hydrofluoric acid that this method adopts is highly toxic substance, and relevant department's strictness bans use of; And for example publication number for the CN1125668A patent application adopt blasting method with mark of car " impacts " on glass, this method contaminate environment, necessary closure construction; Also as " vehicle glass and the manufacture method thereof that have license plate number " of publication number for CN1167051A patent application proposition, then need vehicle glass is unloaded down, install after the etching again, this method obviously is that the car owner is not acceptant.
The objective of the invention is to overcome the shortcoming of prior art, propose a kind of nontoxicity, automobile glass etching paste formulation effective, easy to use.
Another object of the present invention provides the application method of etching paste of the present invention on vehicle glass.
The composition of etching paste of the present invention comprises Neutral ammonium fluoride, oxalic acid, ammonium sulfate, glycerine, phosphoric acid, barium sulfate, water, their content (in parts by weight):
1.5～3.0 parts of 14～17 parts of oxalic acid of Neutral ammonium fluoride
18～22 parts of 4～6 parts of glycerine of ammonium sulfate
10～15 parts in 9～22 parts of barium sulfate of phosphatase 11
10～15 parts in water
Also can add an amount of polyvinyl alcohol thickening material in the above-mentioned prescription, according to construction requirement, regulate the denseness of etching paste, if need look up operation, the denseness of etching paste can be coagulated the soup a bit, as looks squarely or overlook operation and then can add or not add thickening material less.
The preparation method of etching paste of the present invention: component is added in the container in proportion, at room temperature, adopt artificial or mechanical method to stir and get final product.Etching paste after mixing up temporarily need not, should seal and at room temperature preserve.
The concrete application of automobile etching paste of the present invention:
One. the molding etching method
1. the Arabic numerals body of making Chinese character that 35 provinces commonly used, municipality directly under the Central Government are called for short, 26 phonetic alphabet and 0～1 with steel disc in advance is as the punching dedicated tool, and other figure or symbol can be made into the punching dedicated tool according to requiring temporarily;
2. according to actual requirement, (1) is gone on foot the Chinese character of making, letter or figure, symbol punching dedicated tool is installed on the template, self-adhesive paper places under the template, it is carried out punching, regulate the stroke screw of punch press during punching, reach and self-adhesive paper is cut off and do not injured till the following lining paper again, scratch font or figure on the self-adhesive paper then, symbolic component, tear lining paper off, remaining be hollow stripping pattern self-adhesive paper, perhaps use the computer carving machine mark of car or other figure, symbol is engraved on the self-adhesive paper, scratches font or figure, symbolic component, tear lining paper off, also can obtain hollow stripping pattern self-adhesive paper;
3. be attached on the vehicle glass after the hollow stripping pattern self-adhesive paper permutation and combination that (2) step is made, coat glass etching cream equably at hollow position, its thickness is identical with self-adhesive paper thickness, tear self-adhesive paper off after 5 minutes, can obtain required mark of car or other figure, symbol with the remaining etching paste of clear water flush away again.
Two. silk screen print method: with mark of car or other figure, symbol, adopting conventional plate making art to make screen printing forme, is printing ink with glass etching cream, and mark of car or other figure, sign indicator are imprinted on the vehicle glass, after 5 minutes, get final product with clear water flush away etching paste.
The raw material of etching paste of the present invention and to prepare the self-adhesive paper that hollow stripping pattern uses all are commercially available prod.
Advantage of the present invention and effect:
Automobile glass etching cream of the present invention is nontoxic, pollution-free, is used for the effect that etching mark of car or other figure, sign indicator have the frosted method; Can be modulated into the etching paste of various denseness according to construction requirement, can look squarely, overlook or look up construction, not be subjected to the restriction of space-time; Engraving method of the present invention is because the punching dedicated tool made in advance in word commonly used, only need during construction its permutation and combination get final product, and the etching paste fruit that promptly took effect in 5 minutes, therefore the speed of constructing is fast, efficient is high, each car calculates with 8 blocks of glass, and just all etching was intact in 20 minutes; What is more important adopts the inventive method behind etching mark of car or distinctive mark on the vehicle glass, can prevent that automobile is stolen, threatens crime, even stolen back vehicle glass update all owing to leave vestige, also helps detection.In sum, etching paste of the present invention and application method thereof are more advanced than prior art, will be subjected to the welcome of car owner and vehicular traffic administrative authority.
Further specify characteristics of the present invention below by specific embodiment:
Example 1
14 parts of Neutral ammonium fluorides, 3 parts of oxalic acid, 5 parts in ammonium sulfate, 21 parts of glycerine, 20 parts of phosphoric acid, 14 parts in barium sulfate, water are poured in the container for 12 parts, promptly obtained product A after mixing.
Example 2
16 parts of Neutral ammonium fluorides, 2 parts of oxalic acid, 6 parts in ammonium sulfate, 19 parts of glycerine, 21 parts of phosphoric acid, 11 parts in barium sulfate, water are poured in the container for 14 parts, promptly obtained product B after mixing.
Example 3
This example is to scribe the capital B03456 trade mark on windshield.
Literal, the numeral of the hollow stripping pattern self-adhesive paper after the punching are attached to it on windshield glass after making up by B13456, apply the etching paste A that example 1 obtains equably at hollow position then, tear self-adhesive paper off after 5 minutes, use the residual etching paste of clear water flush away again, promptly etch mark of car on the windshield glass with frosted finish effect.
Claims (3)
1. automobile glass etching cream is characterized in that composition comprises Neutral ammonium fluoride, oxalic acid, ammonium sulfate, glycerine, phosphoric acid, barium sulfate and water, its component content (in parts by weight):
1.5～3.0 parts of 14～17 parts of oxalic acid of Neutral ammonium fluoride
18～22 parts of 4～6 parts of glycerine of ammonium sulfate
10～15 parts in 9～22 parts of barium sulfate of phosphatase 11
10～15 parts in water
2. the application of the described etching paste of claim 1 is characterized in that it being to adopt the molding etching method, and detailed process is followed successively by:
(1) make the punching dedicated tool of the Arabic numerals body of Chinese character that 35 provinces commonly used, municipality directly under the Central Government are called for short, 26 phonetic alphabet and 0～1 in advance with steel disc, other figure or symbol can be made into the punching dedicated tool according to requiring temporarily;
(2) according to actual requirement, (1) is gone on foot the Chinese character of making, letter or figure, symbol punching dedicated tool is installed on the template, self-adhesive paper places under the template, it is carried out punching, regulate the stroke screw of punch press during punching, reach and self-adhesive paper is cut off and do not injured till the following lining paper again, scratch font or figure on the self-adhesive paper then, symbolic component, tear lining paper off, remaining is hollow stripping pattern self-adhesive paper, perhaps uses the computer carving machine with mark of car or other figure, symbol is engraved on the self-adhesive paper, scratches font or figure, symbolic component, tear lining paper off, obtain hollow stripping pattern self-adhesive paper;
(3) be attached on the vehicle glass after the hollow stripping pattern self-adhesive paper permutation and combination that (2) step is made, coat glass etching cream equably at hollow position, its thickness is identical with self-adhesive paper thickness, tears self-adhesive paper off after 5 minutes, gets final product with the remaining etching paste of clear water flush away again.
3. the application of the described etching paste of claim 1, it is characterized in that adopting silk screen print method, mark of car or figure, symbol can be made screen printing forme by known plate making art, with glass etching cream is printing ink, mark of car or figure, symbol are imprinted on the vehicle glass, get final product with the remaining etching paste of clear water flush away after 5 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99109219 CN1277944A (en) | 1999-06-22 | 1999-06-22 | Etching paste for automobile glass and the use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99109219 CN1277944A (en) | 1999-06-22 | 1999-06-22 | Etching paste for automobile glass and the use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1277944A true CN1277944A (en) | 2000-12-27 |
Family
ID=5273768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99109219 Pending CN1277944A (en) | 1999-06-22 | 1999-06-22 | Etching paste for automobile glass and the use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1277944A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006074791A1 (en) * | 2005-01-11 | 2006-07-20 | Merck Patent Gmbh | Printable medium for the etching of silicon dioxide and silicon nitride layers |
| WO2007006381A1 (en) * | 2005-07-12 | 2007-01-18 | Merck Patent Gmbh | Combined etching and doping media for silicon dioxide layers and subjacent silicon |
| CN100457660C (en) * | 2004-12-21 | 2009-02-04 | 陈荷丽 | Etching agent of motor-driven vehicle glass and applying method thereof |
| US7923118B2 (en) * | 2005-08-24 | 2011-04-12 | Lg Display Co., Ltd. | Etching tape and method of fabricating array substrate for liquid crystal display using the same |
| ITPI20100007A1 (en) * | 2010-01-21 | 2011-07-22 | Schott Italvetro S P A | METHOD FOR THE REALIZATION OF LOGOS, SCRIPTURES AND AREAS ON A GLASS THROUGH A SERIGRAPHIC APPLICATION. |
| CN102358837A (en) * | 2011-11-14 | 2012-02-22 | 厦门市豪尔新材料有限公司 | Etching paste and preparation method thereof |
| CN102958305A (en) * | 2011-08-21 | 2013-03-06 | 比亚迪股份有限公司 | Glass window and decorating method thereof |
| CN103342473A (en) * | 2013-07-25 | 2013-10-09 | 胡建军 | Acid-free glass product frosting solution |
| CN104045241A (en) * | 2014-06-16 | 2014-09-17 | 刘存海 | Micro-fluorine glass etching and polishing method |
| CN104057740A (en) * | 2014-06-17 | 2014-09-24 | 观致汽车有限公司 | Labeling method for mark on automobile rear windshield glass |
| CN105621893A (en) * | 2014-12-01 | 2016-06-01 | 焦作飞鸿安全玻璃有限公司 | Production method of etched and printed glass |
| CN106086587A (en) * | 2016-06-14 | 2016-11-09 | 北京工业大学 | A kind of containing aluminum high-boron high-speed steel and preparation method thereof |
-
1999
- 1999-06-22 CN CN 99109219 patent/CN1277944A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457660C (en) * | 2004-12-21 | 2009-02-04 | 陈荷丽 | Etching agent of motor-driven vehicle glass and applying method thereof |
| WO2006074791A1 (en) * | 2005-01-11 | 2006-07-20 | Merck Patent Gmbh | Printable medium for the etching of silicon dioxide and silicon nitride layers |
| US7837890B2 (en) | 2005-01-11 | 2010-11-23 | Merck Patent Gmbh | Printable medium for the etching of silicon dioxide and silicon nitride layers |
| WO2007006381A1 (en) * | 2005-07-12 | 2007-01-18 | Merck Patent Gmbh | Combined etching and doping media for silicon dioxide layers and subjacent silicon |
| US7923118B2 (en) * | 2005-08-24 | 2011-04-12 | Lg Display Co., Ltd. | Etching tape and method of fabricating array substrate for liquid crystal display using the same |
| ITPI20100007A1 (en) * | 2010-01-21 | 2011-07-22 | Schott Italvetro S P A | METHOD FOR THE REALIZATION OF LOGOS, SCRIPTURES AND AREAS ON A GLASS THROUGH A SERIGRAPHIC APPLICATION. |
| WO2011089573A1 (en) * | 2010-01-21 | 2011-07-28 | Schott Italvetro S.P.A. | A method for the realization of logos, writings and areas on glass by means of serigraphic application |
| CN102958305A (en) * | 2011-08-21 | 2013-03-06 | 比亚迪股份有限公司 | Glass window and decorating method thereof |
| CN102358837A (en) * | 2011-11-14 | 2012-02-22 | 厦门市豪尔新材料有限公司 | Etching paste and preparation method thereof |
| CN102358837B (en) * | 2011-11-14 | 2014-04-16 | 厦门市豪尔新材料有限公司 | Etching paste and preparation method thereof |
| CN103342473A (en) * | 2013-07-25 | 2013-10-09 | 胡建军 | Acid-free glass product frosting solution |
| CN104045241A (en) * | 2014-06-16 | 2014-09-17 | 刘存海 | Micro-fluorine glass etching and polishing method |
| CN104045241B (en) * | 2014-06-16 | 2016-09-14 | 刘存海 | A kind of micro-fluorine glass etching finishing method |
| CN104057740A (en) * | 2014-06-17 | 2014-09-24 | 观致汽车有限公司 | Labeling method for mark on automobile rear windshield glass |
| CN105621893A (en) * | 2014-12-01 | 2016-06-01 | 焦作飞鸿安全玻璃有限公司 | Production method of etched and printed glass |
| CN106086587A (en) * | 2016-06-14 | 2016-11-09 | 北京工业大学 | A kind of containing aluminum high-boron high-speed steel and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |