CN1256181A - Multilayer spraying deposition method and equipment for preparation of large deposited blank - Google Patents

Multilayer spraying deposition method and equipment for preparation of large deposited blank Download PDF

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Publication number
CN1256181A
CN1256181A CN98112773A CN98112773A CN1256181A CN 1256181 A CN1256181 A CN 1256181A CN 98112773 A CN98112773 A CN 98112773A CN 98112773 A CN98112773 A CN 98112773A CN 1256181 A CN1256181 A CN 1256181A
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matrix
deposition
spray
spray gun
cooling
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CN98112773A
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CN1067307C (en
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陈振华
严红革
康智涛
袁武华
黄培云
陈刚
傅定发
刘诗月
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Central South University
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Central South University
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Abstract

The present invention includes two spray guns and their motion controller, substrate elevator mechanism and forced cooling mechanism. It can be used to produce very large deposited pipe blank and ingot blank without size limitation principally. The present invention has also advantages of high cooling speed, no component segregation, fine and homogeneous crystallite, low oxygen content, etc. It is incomparable, especialy in preparing grain-reinforced metal-base composite material.

Description

The multilayer spraying deposition method and the equipment of preparation large deposited blank
The present invention relates to a kind of multilayer spraying deposition method and equipment for preparing large deposited blank.
Spray deposition technique is that the Singer A by Britain teaches in the seventies and proposes the earliest, principle is: molten metal or alloy are atomized in inert atmosphere forms particle jetting stream, inject directly on the matrix of water-cooled, through bump, coalescent, solidify and form settling.Spray deposition technique is a kind of novel blank-making method, is widely used in various alloys of preparation and matrix material pipe thereof, slab, ingot blank etc.In recent years, though spray deposition technique has obtained fast development, all be the principle that adopts Singer professor A to propose in essence." Arms Material scientific and engineering " the 17th volume, the 2nd phase (1994) has been introduced the equipment and the technological process of this technology, and this technology has the characteristics of powder metallurgy and rapid solidification concurrently, has overcome the shortcoming of the component segregation in the casting metallurgy, the grain structure of blank is tiny, and oxygen level is low.Jet deposition equipment as shown in Figure 1, 2, comprising crucible 1, nozzle 2, deposition matrix 3, spray chamber 4, vapor pipe 5, transmission mechanism 6, interior device for cooling 7 with shake nozzle 10.The common feature of equipment is that deposit preform forms through the matrix deposition by jetting fluid grain stream is disposable, and the deficiency of existence is that sedimental cooling rate generally has only 10 1~10 2K/s, and be difficult to prepare large thick-wall pipe and the very big ingot blank of diameter, if solve problem,, often cause shortcomings such as sedimental component segregation, grain structure is thick, the pyrocondensation hole defect is many then because setting rate is not high enough by improving injection density.
The purpose of this invention is to provide a kind of method and apparatus that can prepare the multi-layer spray deposition of large deposited blank.
The present invention---a kind of multilayer spraying deposition method and equipment for preparing large deposited blank, when preparing large jet deposited base, the spray gun of atomization metal melt is done linear reciprocating motion along the deposition matrix, because matrix also can move reciprocatingly, longer in the timed interval that the back surface sediments of same position reaches last surface sediments, form the sputter border in the deposit preform easily, influence the quality of deposit preform.In order to eliminate this sputter border, realize optimum deposition condition, processing parameter is selected as follows in process of production: nozzle diameter is 2.5~5mm, the round frequency of spray gun is 1/10~1/30Hz, jetting height is 100~300mm, and the melt overheat temperature is 100~300 ℃, and atomization air pressure is 0.8~1.5MPa, deposition matrix rising or falling speed is 1~20mm/min, and the matrix rotational frequency is 1~1/6Hz.Composition by the control metal melt can prepare gradient material, adopts the spray gun of special construction can also prepare large jet deposited matrix material heavy wall pipe and ingot blank.
For realizing above-mentioned spray-deposition method, jet deposition device structure of the present invention such as Fig. 3, shown in Figure 4.
When the large-scale pipe of preparation, adopt equipment shown in Figure 3, comprise crucible 1, spray gun 2, matrix 3, spray chamber 4, the present invention also comprises two spray gun motion control devices, matrix hoisting appliance, the sedimental strong device for cooling of cooling.Crucible 1, spray gun 2 are fixed on the motion guide plate 11 jointly, and guide plate 11 is as the upper cover plate of spray chamber 4, and motion controller 15 acts on the guide plate 11, controls its travel direction, speed speed and movement travel.Deposition matrix hoisting appliance is made up of one group of gear drive and lifting controller 12, the speed in the time of can controlling the height of matrix 3 liftings and lifting.Strong device for cooling comprises refrigerant supply 13, switch-valve and conduit, its effect is: after the metallic particles injection stream deposits on the matrix 3, open in the matrix below, face the coolant duct jet orifice 14 of deposition matrix immediately to the settling ejected coolant, make it external cooling, heat-eliminating medium is liquid nitrogen or rare gas element.According to the difference that the preparation blank requires, the movement locus of two gun systems and the sedimental type of cooling also can be adjusted.By jointly controlling of lifting controller 12 and motion controller 15, can adjust the physical dimension of pipe, the thickness of pipe can be unrestricted in principle.
When the large-scale ingot blank of preparation, adopt equipment shown in Figure 4.Comprise crucible 1, spray gun 2, matrix 3, oblique spraying mechanism, matrix hoisting appliance, the present invention also comprises oblique spray motion control device, the sedimental strong device for cooling of cooling of control spray gun 2 and guide plate motion 11 thereof.Tiltedly the spray motion control device is made up of crucible 1, spray gun 2, motion guide plate 11 and motion controller 15, guide plate 11 is as the upper cover plate of spray chamber 4, motion by motion controller 15 control guide plates 11, travel direction, speed and stroke are adjustable, can control the diameter of ingot blank thus, the diameter of ingot blank is unrestricted in principle.The angle of motion guide plate 11 and horizontal plane can be adjusted between 10 °~50 °.Strong device for cooling is made up of refrigeration system 16 and condenser 17, and the temperature of condenser 17 is by refrigeration system 16 controls.Height by hoisting appliance 12 control ingot blanks.
Description of drawings:
The jet deposition pipe production unit structural representation that Fig. 1 is traditional;
The jet deposition ingot blank production unit structural representation that Fig. 2 is traditional;
Fig. 3 the present invention prepares large jet deposited heavy wall pipe device structure synoptic diagram;
Fig. 4 the present invention prepares large jet deposited ingot blank device structure synoptic diagram.
The present invention is owing to increased motion control device (horizontal movement and oblique spray motion control device), spray Penetrate deposition pipe wall thickness and can do very greatly, in principle unrestricted, solved existing jet deposition skill Art is difficult to prepare the shortcoming of heavy wall pipe; The jet deposition ingot blank also can be done very greatly, and its diameter in principle Unrestricted. The present invention has the cooling rate height, no component segregation, deposit preform crystalline substance when the preparation large deposited blank Grain fine microstructures, evenly, the advantage such as oxygen content is low, technology, equipment are simple is particulate reinforced metal-based Especially has the incomparable advantage of other method on the composite manufacture.
Embodiment:
1: when preparation Al-Fe-V-Si alloy pipe stock, with alloy melting, the melt overheat temperature is 300 ℃ in crucible 1, jetting height is 200mm, atomization air pressure is 1.0MPa, and nozzle diameter is 4.2mm, and the matrix rotational frequency is 1/6Hz, the round frequency of crucible 1 is 1/30Hz, movement travel is 600mm, and the pipe external diameter of producing is  700mm, and internal diameter is  300mm, long is 1200mm, 1.0 tons of weight.Strong device for cooling adopts rare gas element as refrigerant.
2: at preparation 6066Al/SiC PDuring matrix material jet deposition pipe, in crucible 1 with alloy melting, the melt overheat temperature is 150 ℃, jetting height is 150mm, atomization air pressure is 1.0MPa, and nozzle diameter is 3.8mm, and ceramic powder fluidization gaseous tension is 0.6MPa, the powder flow rate is 20% of a metal flow rate, the matrix rotational frequency is 1/6Hz, and the round frequency of crucible 1 is 1/30Hz, and movement travel is 600mm, the pipe external diameter of producing is  650mm, internal diameter is  300mm, and long is 1000mm, weight 600Kg, SiCp content is 15wt% in the deposit preform, is uniformly dispersed.Strong device for cooling adopts rare gas element as refrigerant.
3: when preparation Al-Fe-V-Si jet deposition ingot blank, with alloy melting, the melt overheat temperature is 300 ℃ in crucible 1, jetting height is 250mm, atomization air pressure is 1.0MPa, and nozzle diameter is 3.6mm, and the matrix rotational frequency is 1Hz, the round frequency of crucible 1 is 1/10Hz, movement travel is 630mm, and the matrix rising or falling speed is 10mm/min, and the ingot blank diameter of producing is  630mm, long is 1000mm, weight 750Kg.Strong device for cooling adopts fluorine Lyons as refrigeration agent.
4: at preparation 7075/SiC pDuring jet deposition matrix material ingot blank, with alloy melting, the melt overheat temperature is 200 ℃ in crucible 1, jetting height is 200mm, and atomization air pressure is 1.0MPa, and nozzle diameter is 4.0mm, SiCp powder flow rate is 20% of a metal flow rate, the matrix rotational frequency is 1Hz, and the round frequency of crucible 1 is 1/10Hz, and movement travel is 630mm, the matrix rising or falling speed is 15mm/min, the ingot blank diameter of producing is  630mm, and long is 1000mm, weight 700Kg ton.The content of SiCp is 15wt% in the deposit preform, is uniformly dispersed.Strong device for cooling adopts fluorine Lyons as refrigeration agent.

Claims (7)

1. multilayer spraying deposition method for preparing large jet deposited base, it is characterized in that: when preparing large jet deposited base, the spray gun of atomization metal melt is done linear reciprocating motion along the deposition matrix, nozzle diameter is 2.5~5mm, and the round frequency of spray gun is 1/10~1/30Hz, and jetting height is 100~300mm, the melt overheat temperature is 100~300 ℃, atomization air pressure is 0.8~1.5MPa, and deposition matrix rising or falling speed is 1~20mm/min, and the matrix rotational frequency is 1~1/6Hz.
2. realize that the described method of claim 1 prepares the multi-layer spray deposition equipment of large thick-wall jet deposition pipe for one kind, comprise crucible, spray gun, matrix, double spray gun structure, spray chamber, it is characterized in that: the present invention also comprises control device, the matrix hoisting appliance of two spray guns of control and guide plate motion thereof, cools off sedimental strong device for cooling.
3. realize that the described method of claim 1 prepares the multi-layer spray deposition equipment of large jet deposited ingot blank for one kind, comprise crucible, spray gun, matrix, oblique spraying mechanism, matrix hoisting appliance, it is characterized in that: the present invention also comprises oblique spray motion control device, the sedimental strong device for cooling of cooling of control spray gun and guide plate motion thereof.
4. according to claim 1 and 3 described method and apparatus, it is characterized in that: tiltedly the angle of the motion guide plate of spraying mechanism and horizontal plane is adjustable between 10 °~50 °.
5. according to claim 1 and 2 described method and apparatus, it is characterized in that: heat-eliminating medium is rare gas element or liquid nitrogen, and the conduit mouth of forced cooling device is opened in the matrix below, faces the deposition matrix.
6. according to claim 1 and 3 described method and apparatus, it is characterized in that: strong cold charge is changed to a circulating condensing system, is refrigeration agent with fluorine Lyons, dispels the heat by condenser.
7. according to right 1 described multilayer spraying deposition method,, can produce the tubing of various profiles, as tapered tube, special roll forming pipe by the movement rate and the curve movement of control spray gun place guide plate.
CN98112773A 1998-12-07 1998-12-07 Multilayer spraying deposition method and equipment for preparation of large deposited blank Expired - Fee Related CN1067307C (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786058A (en) * 2010-03-19 2010-07-28 中国计量学院 Method for judging working conditions required by depositing atomized impact inject flow drop on substrate
CN102626843A (en) * 2012-02-17 2012-08-08 汤汉良 Manufacturing method for automobile parts made of aluminum-based composite material through spray deposition
CN103055661A (en) * 2012-12-31 2013-04-24 东南大学 Device and method for removing acidic gas from smoke at high temperature
CN103962558A (en) * 2013-01-24 2014-08-06 宝山钢铁股份有限公司 Method for preparing composite tube blank continuously by spray forming
CN106623935A (en) * 2016-10-09 2017-05-10 湖南工业大学 Spray deposition platform
CN106835000A (en) * 2016-12-09 2017-06-13 武汉船用机械有限责任公司 A kind of supersonic flame spraying method suitable for thin and long units
CN110369924A (en) * 2019-08-15 2019-10-25 路秀稳 A kind of economic benefits and social benefits alloy powder breakpoint formula spray welding unit
CN110965011A (en) * 2019-12-30 2020-04-07 格林美股份有限公司 Motor rotor collecting ring repairing device
CN111926297A (en) * 2020-09-22 2020-11-13 爱发科电子材料(苏州)有限公司 Manufacturing method of aluminum and aluminum alloy target blank
CN113732270A (en) * 2021-09-08 2021-12-03 昆山晶微新材料研究院有限公司 Additive manufacturing method and device for cylindrical metal cast ingot

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1025559A (en) * 1996-07-11 1998-01-27 Furukawa Electric Co Ltd:The Metal thermal spraying device

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786058A (en) * 2010-03-19 2010-07-28 中国计量学院 Method for judging working conditions required by depositing atomized impact inject flow drop on substrate
CN102626843A (en) * 2012-02-17 2012-08-08 汤汉良 Manufacturing method for automobile parts made of aluminum-based composite material through spray deposition
CN103055661A (en) * 2012-12-31 2013-04-24 东南大学 Device and method for removing acidic gas from smoke at high temperature
CN103962558A (en) * 2013-01-24 2014-08-06 宝山钢铁股份有限公司 Method for preparing composite tube blank continuously by spray forming
CN106623935A (en) * 2016-10-09 2017-05-10 湖南工业大学 Spray deposition platform
CN106835000B (en) * 2016-12-09 2019-05-17 武汉船用机械有限责任公司 A kind of supersonic flame spraying method suitable for thin and long units
CN106835000A (en) * 2016-12-09 2017-06-13 武汉船用机械有限责任公司 A kind of supersonic flame spraying method suitable for thin and long units
CN110369924A (en) * 2019-08-15 2019-10-25 路秀稳 A kind of economic benefits and social benefits alloy powder breakpoint formula spray welding unit
CN110965011A (en) * 2019-12-30 2020-04-07 格林美股份有限公司 Motor rotor collecting ring repairing device
CN110965011B (en) * 2019-12-30 2022-05-17 格林美股份有限公司 Motor rotor collecting ring repairing device
CN111926297A (en) * 2020-09-22 2020-11-13 爱发科电子材料(苏州)有限公司 Manufacturing method of aluminum and aluminum alloy target blank
CN113732270A (en) * 2021-09-08 2021-12-03 昆山晶微新材料研究院有限公司 Additive manufacturing method and device for cylindrical metal cast ingot
CN113732270B (en) * 2021-09-08 2023-09-01 昆山晶微新材料研究院有限公司 Additive manufacturing method and device for cylindrical metal cast ingot

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