CN1213694A - Formulation and prodn. method of gas light oil - Google Patents

Formulation and prodn. method of gas light oil Download PDF

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Publication number
CN1213694A
CN1213694A CN 98110412 CN98110412A CN1213694A CN 1213694 A CN1213694 A CN 1213694A CN 98110412 CN98110412 CN 98110412 CN 98110412 A CN98110412 A CN 98110412A CN 1213694 A CN1213694 A CN 1213694A
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oil
sodium
gasoline
light oil
gas light
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CN 98110412
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CN1058048C (en
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张云
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Abstract

A fuel-gas light oil is prepared from light oil as primary raw material and the secondary raw material including sodium borohydride, sodium chloride, alcohol and dicarbonate through proportional mixing, laying aside, deposition and filter. Its advantages are high flame temp 350-400 deg.C higher than that of liquefied petroleum gas, stable flame, no smoke, odour, residual liquid, carbon deposit and explosion, and ordinary-pressure application.

Description

A kind of prescription of gas light oil and production method thereof
The invention belongs to the petroleum gas technical field, relate to the decomposition gasification of lightweight oil.
At present, the most general civilian fuel is liquefied petroleum gas (LPG) both at home and abroad, usually can is in high-pressure cylinder, not only transportation difficulty, and exist the explosive hidden danger of gas leakage, thereby poisoning, explosion hazard happen occasionally, and caused the vast cities and towns remote from the petroleum gas place of production, the rural gas difficulty of using; The liquefied petroleum gas (LPG) of can in gas tank often has the raffinate that can not gasify, and what have is recovered, and the healthy of people seriously endangered in the corner that is poured on the public arena that has, and threatening the people's lives and property safety; In the petroleum refining product, C 5-C 8Lightweight oil can not be as domestic fuel and purposes is narrower; Studying a kind of prescription and making method of gas light oil, develop new domestic gas fuel, is the important technology problem of pendulum in face of us; Someone once used the lightweight oil liquefied synthetic gas, because existing combustion gas, to begin flame big, diminish subsequently, one pot of dish has not been fried just flame-out, use powerful oxygen supply pump electricity consumption inflation instead, in case have a power failure, outage do not have ready-made food to suffer a loss yet, and also exists raffinate, problem such as smelly, knot charcoal is arranged, be difficult to promote the use of.
Task of the present invention provides prescription of a kind of gas light oil and preparation method thereof, to remedy existing LPG (liquefied petroleum gas) supply anxiety, open up new domestic fuel for vast remote city and rural area, reach the purpose that makes full use of the energy, thereby overcome the above-mentioned deficiency of existing in prior technology.
Task of the present invention realizes with following technical scheme:
Gas light oil is made up of body material and auxiliary material; The body material lightweight oil is meant C 5-C 8Pentane in the scope, petroleum naphtha, gasoline, any in the sherwood oil etc., auxiliary material is meant: the dimerization ring is defended diene iron, ethanol, ethyl acetate, sherwood oil, hydrogen peroxide, sodium bicarbonate, sodium borohydride, methyl tertiary butyl ether, sodium-chlor, potassium permanganate, hydrazine hydrate, acetone, copper sulfate, butylacetate, Virahol, gasoline, weight proportion is: lightweight oil: the dimerization ring is defended diene iron: ethanol: ethyl acetate: sherwood oil: hydrogen peroxide: sodium bicarbonate: sodium borohydride: methyl tertiary butyl ether: sodium-chlor: potassium permanganate: hydrazine hydrate: acetone: copper sulfate: butylacetate: Virahol: gasoline=100000: 5-15: 5-10: 5-15: 5-15: 0.5-1.5: 0.3-3: 0.15-0.5: 0.05-0.25: 0.01-0.1: 0.3-1.5: 0.1-1: 0.5-1.5: 0.1-1.5: 0.3-0.8: 0.5-1.5: 30-60; Its best proportioning is: 100000: 6-10: 6-8: 8-10: 8-10: 0.8-1: 0.5-1: 0.15-0.2: 0.05-0.1: 0.05-0.1: 0.4-0.6: 0.2-0.4: 1-1.2: 0.2-0.5: 0.5-0.8: 0.5-0.8: 40-50; According to seasonal variation, select a kind of body material and several auxiliary material to form the prescription of producing gas light oil.
Production method by above-mentioned said gas light oil is: in proportion with a kind of raw material in the body material lightweight oil, certain several auxiliary material takes by weighing certain amount, earlier lightweight oil is put into reactor, then each group auxiliary material is defended diene iron according to the dimerization ring, gasoline, methyl tertiary butyl ether, sodium-chlor, ethanol, sodium bicarbonate, sodium borohydride, ethyl acetate, potassium permanganate, hydrogen peroxide, the order of hydrazine hydrate or dimerization ring are defended diene iron, gasoline, acetone, copper sulfate, ethanol, butylacetate, Virahol, ethyl acetate, sherwood oil, sodium bicarbonate, put into reactor and stirring in the every interval 5-15 of the order of hydrogen peroxide minute, left standstill 40 minutes, and filtered and deposit in the finished product jar, promptly get gas light oil of the present invention; Time spent in the suction gasification kitchen range, adds an amount of Cellmic C 121 and sulfuric acid or adds an amount of sodium bicarbonate and sulfuric acid from the finished product jar in the reactor outside the gasification kitchen range.
Gas light oil of the present invention, raw material sources are wide, and the auxiliary material consumption is few, and is low with the equal units of heat product cost of liquefied petroleum gas (LPG), and flame temperature is high and stable.
The invention will be further described with embodiment below:
Embodiment 1, in the spring, autumn or winter are according to pentane: the dimerization ring is defended diene iron: gasoline: methyl tertiary butyl ether: sodium-chlor: ethanol: sodium bicarbonate: sodium borohydride: ethyl acetate: potassium permanganate: hydrogen peroxide: hydrazine hydrate=100000: 6: 50: 0.05: 0.1: 6: 0.6: 0.15: 8: 0.5: 0.8: 0.3 ratio takes by weighing, according to pentane, the dimerization ring is defended diene iron, gasoline, methyl tertiary butyl ether, sodium-chlor, ethanol, sodium bicarbonate, sodium borohydride, ethyl acetate, potassium permanganate, hydrogen peroxide, the order of hydrazine hydrate, every interval 5-15 minute, put into reactor and stirring, staticly settled 40 minutes, filter and deposit in the finished product jar, in the time spent suction gasification kitchen range, and add an amount of Cellmic C 121 and sulfuric acid in the reactor outside the gasification kitchen range; This product normal pressure is stored, minute-pressure is used, safety does not have blast, smokeless, nontoxic, odorless, nothing knot charcoal, pollution-free, no raffinate, employing electronic striking, need not electrical pump inflation or inflator inflates, flame stabilization, flame temperature is than the high 350-400 of high-quality liquefied gas ℃, and product cost is low, the per kilogram gas light oil is compared with per kilogram high-quality liquefied petroleum gas (LPG), and 20-40% reduces cost.
Implement 2, summer according to gasoline: the dimerization ring is defended diene iron: acetone: copper sulfate: ethanol: butylacetate: Virahol: ethyl acetate: sherwood oil: sodium bicarbonate: hydrogen peroxide=100000: 10: 1.2: 0.2: 8: 0.6: 0.8: 10: 10: 0.8: 1 ratio takes by weighing, according to gasoline, the dimerization ring is defended diene iron, third bronze medal, copper sulfate, ethanol, butylacetate, Virahol, ethyl acetate, sherwood oil, sodium bicarbonate, the order of hydrogen peroxide, put into reactor and stirring in every interval 5-15 minute, left standstill 40 minutes, filter and deposit in the finished product jar, in the time spent suction gasification kitchen range, and add an amount of sodium bicarbonate and sulfuric acid in the reactor outside the gasification kitchen range.
Embodiment 3, and body material adds an amount of sodium bicarbonate and sulfuric acid with sherwood oil or petroleum naphtha, auxiliary material and production method with embodiment 1 in the reactor during use outside the gasification kitchen range.

Claims (5)

1, a kind of gas light oil, it is made up of body material lightweight oil and auxiliary material, it is characterized in that the body material lightweight oil is meant at C 5-C 8Any in pentane in the scope, petroleum naphtha, gasoline, the sherwood oil, auxiliary material refers to that the dimerization ring defends diene iron, ethanol, ethyl acetate, sherwood oil, hydrogen peroxide, sodium bicarbonate, sodium borohydride, methyl tertiary butyl ether, sodium-chlor, potassium permanganate, hydrazine hydrate, acetone, copper sulfate, butylacetate, Virahol, gasoline, according to seasonal variation, select a kind of body material and several auxiliary material compositing formula.
2, gas light oil according to claim 1, it is characterized in that the weight proportion of said lightweight oil and auxiliary material is: lightweight oil: the dimerization ring is defended diene iron: ethanol: ethyl acetate: sherwood oil: hydrogen peroxide: sodium bicarbonate: sodium borohydride: methyl tertiary butyl ether: sodium-chlor: potassium permanganate: hydrazine hydrate: acetone: copper sulfate: butylacetate: Virahol; Gasoline=100000; 5-15: 5-10: 5-15: 5-15: 0.5-1.5: 0.3-3: 0.15-0.5: 0.05-0.25: 0.01-0.1: 0.3-1.5: 0.1-1: 0.5-1.5: 0.1-1.5: 0.3-0.8: 0.5-1.5: 30-60.
3, gas light oil according to claim 2, it is characterized in that the weight proportion of said lightweight oil and auxiliary material is: lightweight oil: the dimerization ring is defended diene iron: ethanol: ethyl acetate: sherwood oil: hydrogen peroxide: sodium bicarbonate: sodium borohydride: methyl tertiary butyl ether: sodium-chlor; Potassium permanganate: hydrazine hydrate: acetone: copper sulfate: butylacetate: Virahol: gasoline=100000: 6-10: 6-8: 8-10: 8-10: 0.8-1: 0.5-1: 0.15-0.2: 0.05-0.1: 0.05-0.1: 0.4-0.6: 0.2-0.4: 1-1.2: 0.2-0.5: 0.5-0.8: 0.5-0.8: 40-50.
4, a kind of method of manufacturing the described gas light oil of claim 2, it is characterized in that earlier lightweight oil being put into reactor, then each group auxiliary material is defended diene iron according to the dimerization ring, gasoline, methyl tertiary butyl ether, sodium-chlor, ethanol, sodium bicarbonate, sodium borohydride, ethyl acetate, potassium permanganate, hydrogen peroxide, hydrazine hydrate, or the dimerization ring is defended diene iron, gasoline, acetone, copper sulfate, ethanol, butylacetate, Virahol, ethyl acetate, sherwood oil, sodium bicarbonate, the order of hydrogen peroxide was put into reactor and stirring, was staticly settled 40 minutes in every interval 5-15 minute, filter and deposit in the finished product jar, promptly get gas light oil of the present invention.
5, use the described gas light oil of claim 2, it is characterized in that adding in the reactor outside the gasification kitchen range an amount of Cellmic C 121 and sulfuric acid or sodium bicarbonate and sulfuric acid.
CN98110412A 1998-08-18 1998-08-18 Formulation and prodn. method of gas light oil Expired - Fee Related CN1058048C (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1092232C (en) * 2000-01-27 2002-10-09 鲁希诺 Synthetic liquefied gas
CN100577778C (en) * 2005-09-30 2010-01-06 郝秉雨 Synergist for improving natural gas burning temperature and its apparatus
CN102304399A (en) * 2011-08-04 2012-01-04 北京喜福祥新能源科技有限公司 Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods
CN102690694A (en) * 2012-06-08 2012-09-26 袁自远 Methanol gasoline additive
CN101434880B (en) * 2007-11-15 2012-12-26 中国石油化工股份有限公司 Oxidative desulfurization method for liquefied petroleum gas
CN105238457A (en) * 2014-07-10 2016-01-13 许成荫 Fuel capable of efficiently reducing diesel fuel consumption
CN105238470A (en) * 2014-07-10 2016-01-13 许成荫 Environmental-friendly mixed fuel and preparation method therefor
CN106164226A (en) * 2014-04-08 2016-11-23 国际壳牌研究有限公司 There is the diesel fuel of the ignition Characteristics of improvement
CN107541304A (en) * 2017-08-28 2018-01-05 柳玉庭 A kind of preparation method of novel gas
CN109207208A (en) * 2018-09-05 2019-01-15 四川超能优新能源科技有限公司 A kind of environment friendly energy conservation fuel and preparation method thereof
CN109777538A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF heavy oil
CN109777526A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF diesel oil
CN109777527A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF gasoline
CN109797013A (en) * 2018-09-18 2019-05-24 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF fuel oil
CN111763542A (en) * 2020-03-12 2020-10-13 榆林碳氢研究院股份有限公司 Economical and environment-friendly boiler alcohol-based fuel and preparation method thereof
US11512261B2 (en) 2018-04-20 2022-11-29 Shell Usa, Inc. Diesel fuel with improved ignition characteristics

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064881A (en) * 1991-09-23 1992-09-30 珠海经济特区大通工业发展公司 Civil liquid fuel and manufacture method thereof
CN1099406A (en) * 1994-02-02 1995-03-01 张殿清 Pollutionless efficient safety fuel and its making process, range using this fuel
CN1044259C (en) * 1994-08-16 1999-07-21 孙明路 Synthetic liquid fuel and its producing process
CN1136584A (en) * 1996-01-15 1996-11-27 李逢春 Synthetic liquefied gas and its energy saving device

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1092232C (en) * 2000-01-27 2002-10-09 鲁希诺 Synthetic liquefied gas
CN100577778C (en) * 2005-09-30 2010-01-06 郝秉雨 Synergist for improving natural gas burning temperature and its apparatus
CN101434880B (en) * 2007-11-15 2012-12-26 中国石油化工股份有限公司 Oxidative desulfurization method for liquefied petroleum gas
CN102304399A (en) * 2011-08-04 2012-01-04 北京喜福祥新能源科技有限公司 Emulsifier special for alcohol-based fuel and alcohol-based fuel prepared from same as well as preparation methods
CN102690694A (en) * 2012-06-08 2012-09-26 袁自远 Methanol gasoline additive
CN106164226B (en) * 2014-04-08 2018-02-06 国际壳牌研究有限公司 Diesel fuel with improved ignition Characteristics
CN106164226A (en) * 2014-04-08 2016-11-23 国际壳牌研究有限公司 There is the diesel fuel of the ignition Characteristics of improvement
CN105238457A (en) * 2014-07-10 2016-01-13 许成荫 Fuel capable of efficiently reducing diesel fuel consumption
CN105238470A (en) * 2014-07-10 2016-01-13 许成荫 Environmental-friendly mixed fuel and preparation method therefor
CN107541304A (en) * 2017-08-28 2018-01-05 柳玉庭 A kind of preparation method of novel gas
US11512261B2 (en) 2018-04-20 2022-11-29 Shell Usa, Inc. Diesel fuel with improved ignition characteristics
CN109207208A (en) * 2018-09-05 2019-01-15 四川超能优新能源科技有限公司 A kind of environment friendly energy conservation fuel and preparation method thereof
CN109777538A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF heavy oil
CN109777526A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF diesel oil
CN109777527A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF gasoline
CN109797013A (en) * 2018-09-18 2019-05-24 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF fuel oil
CN111763542A (en) * 2020-03-12 2020-10-13 榆林碳氢研究院股份有限公司 Economical and environment-friendly boiler alcohol-based fuel and preparation method thereof

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