CN1196777C - Transparent solid detergent composition - Google Patents
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- CN1196777C CN1196777C CN 00137160 CN00137160A CN1196777C CN 1196777 C CN1196777 C CN 1196777C CN 00137160 CN00137160 CN 00137160 CN 00137160 A CN00137160 A CN 00137160A CN 1196777 C CN1196777 C CN 1196777C
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Abstract
The present invention aims at providing an improved transparent solid detergent composition whose use feeling, dissolving decrement, etc., are improved. The transparent solid detergent composition is characterized in that over 3.5% of fatty acid salt of specific taurine counter ions, fatty acid sodium salt and/or fatty acid potassium salt, a humectant and water are mixed.
Description
The invention relates to transparent solid detergent composition, particularly the improvement of forming about the fatty acid balance ion.
Transparent solid detergent composition because of its transparent feel, has very high video picture, when adding dyestuff or pigment in right amount, can present certain tone or the metal sensation of the degree of depth, so be widely used in the senior material etc. of washing one's face.
In the past, as the moiety of transparent solid detergent composition, main flow was in substrate materials such as fatty acid soaps, as transparentizing agent, added glycerine, sucrose etc.
As the fatty acid soaps of substrate material, what mainly use is to utilize sodium, potassium etc. to make the basic metal soap of the counterion of lipid acid.
These fatty acid alkali metal soap have low price, and advantage such as foam, alveolar substance is also good, but also have shortcoming moltenly subtracts greatly slightly, presents the sensation of shouting pain etc. after the use.Consider the sensation of pricking after the use, also utilize the soap of making by weak base such as trolamine and Methionin and lipid acid, but still be not fully improved.
The present invention is in view of the problem in the above-mentioned old technology, and its objective is provides a kind of usability, and molten subtract etc. is able to improved transparent solid detergent composition.
For achieving the above object; present inventors have carried out a large amount of research; find by using N methyl taurine an alkali metal salt, taurine an alkali metal salt, the hypotaurine an alkali metal salt of lipid acid; obtain a kind of good transparent solid detergent composition; do not damage transparent feel; do not produce molten subtracting and sensation of pricking yet, and so far finish the present invention.
That is, this transparent solid detergent composition of the present invention, feature is to have cooperated following composition:
More than 3.5% with one or two or more kinds soap in the compound shown in the following formula (I)～(III)
R-COO
-H
2N
+(CH
3)-CH
2-CH
2-SO
3 -X
+ …(I)
R-COO
-H
3N
+-CH
2-CH
2-SO
3 -X
+ …(II)
R-COO
-H
3N
+-CH
2-CH
2-SO
2 -X
+ …(III)
(R represents that saturated or unsaturated alkyl, the X of 7-23 carbon atom represent basic metal or organic bases in the formula),
With fatty acid sodium salt and/or lipid acid sylvite,
And wetting Agent for Printing Inks
And water.
In addition, in the said composition of the present invention, the counterion of lipid acid, in mole, suitable scope is:
The counterion of general formula (I)～(III): 5～50
Sodium: 40～95
Potassium: 0～20.
The best proportioning of this composition of the present invention, fatty acid salt adds up to 35～55 weight %, wetting Agent for Printing Inks is that 15～35 weight %, water are 15～25 weight %.
In this composition of the present invention, with respect to the wetting Agent for Printing Inks total amount, the following polyethers wetting Agent for Printing Inks that preferably contains 5～50 weight %, that is, and the polyethers wetting Agent for Printing Inks of in molecule, had addition polymerization on the multivalence alcohol parent nucleus of 3 above hydroxyls 2～100 mole propylene oxide and ethylene oxide below 50 moles.
Composition of the present invention preferably forms transparent solid detergent composition as follows,, in soap, wetting Agent for Printing Inks and the water inflow type tool with the heating and melting attitude, carries out the mixing transparent solid detergent composition that promptly obtains of type tool of cooling curing that is.
In addition, said among the present invention " transparent solid detergent composition ", the meaning is under the state of removing toners such as dyestuff, pigment, is actually transparent.
The 1st figure is the optimum manufacturing process explanatory view of transparent solid detergent composition of the present invention.
Below describe with regard to best example of the present invention.
Among the present invention, the R of above-mentioned formula (I)～(III) is the saturated or unsaturated alkyl of 7-23 carbon atom, as concrete example, branched saturated hydrocarbon group, 8-heptadecene base, oleyls, 4 such as straight chain saturation alkane bases such as heptyl, octyl group, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, tetracosyl, 2-methyl heptadecyl, 2-ethyl pentyl group are for example arranged, straight chain unsaturated alkyl, 2-methyl octadecanes-side chain unsaturated alkyls such as 6-thiazolinyl such as 6-octadecane dialkylene.
Among above-mentioned formula (I), (II), (III), X is organic basess such as basic metal such as sodium, potassium, lithium, trolamine, diethanolamine, Methionin.
Among the present invention, the lipid acid R-COO of fatty acid sodium salt or lipid acid sylvite
-R, definition is identical with the R of the lipid acid of above-mentioned formula (I)～(III).
Equally, preferably use the sodium soap identical, the lipid acid of lipid acid potassium with formula (I)～(III).
Among the present invention, in the lipid acid of heating and melting, as counterion, adding the taurine that contains with the lipid acid equivalent is the alkaline agent of counterion, sodium ion, potassium ion, neutralizes.
Among the present invention,, sucrose or many alcohols such as sucrose, Sorbitol Powder, glycerine, 1,3 butylene glycol, propylene glycol, dipropylene glycol are for example arranged as the most handy wetting Agent for Printing Inks.As wetting Agent for Printing Inks best among the present invention, preferably use on the multivalence alcohol parent nucleus that in molecule, has 3 above hydroxyls, addition polymerization the polyethers based compound of 2-100 mole propylene oxide and ethylene oxide below 50 moles.Polyethers is a wetting Agent for Printing Inks, for dosage fits best 5～50 weight % that always preserve moisture.As multivalence alcohol parent nucleus at this moment, except glycerine, two glycerine, tetramethylolmethane, Dipentaerythritol, the various monoses of enumerating below also having, disaccharides, oligose etc.
As disaccharides, trehalose, sucrose, maltose, lactose etc. are for example arranged.As polyose, for example there are gentianose, raffinose, melizitose, stachyose, Mierocrystalline cellulose, half glycan, starch, chitin former etc.As sugar alcohol, D-Sorbitol Powder, D-seminose, D-mannitol etc. are for example arranged.As saccharide carboxylic acids, D-mannonic acid, maltonic acid, saccharonic acid, uronic acid etc. are for example arranged.As carbohydrate derivates, inositol, alpha-acrose, glucosone, methyl methose pyranoside, sorbitanic, ethyl glucitol furanoside, Gluconolactone, arbutin, single acetyl Sorbitol Powder, diacetyl sorbitanic, sorbitanic laurate, sorbitanic oleic acid ester, glucose phosphate etc. are for example arranged.
This transparent solid detergent composition among the present invention, except above-mentioned essential composition, also can be as required, suitably cooperate following composition, contained soap alkali in the promptly common detergent composition, alkyl sulfuric ester (salt), Voranol EP 2001 sulfuric acid (salt), hydroxyalkyl ether carboxylic acid anion surfactants such as (salt), tetrahydroglyoxaline is an amphoterics, trimethyl-glycine is amphotericses such as amphoterics, Voranol EP 2001, polyoxyethylene fatty acid ester, sucrose fatty ester, alkyl glycoside, nonionogenic tensides such as many alcoholic extract hydroxyl groups fatty ether, positive tensio-active agents such as trimethylammonium alkyl ammomium chloride, Herba Swertiae bimaculatae (セ Application Block リ), Chinese herbaceous peony, White flag, plant extraction compositions such as Equisetum, tranexamic acid, medicaments such as arbutin, spices, compositions such as sanitas.
This transparent solid detergent composition of the present invention is preferably made shown in the 1st figure.
That is, lower alcohols such as various fatty acids, ethanol at 40～60 ℃ of following heating and meltings, to wherein adding the bases that forms counterion, are neutralized again.To wherein adding wetting Agent for Printing Inks, other additives, medicaments such as carbohydrate, many alcohols, carry out uniform dissolution again, can further add spices, pigment as required, more this liquid be flowed in the mould, treat its cooling curing.Remove mould subsequently, cut off as required, in 40-60 days, carry out dry maturation.Again as required with its grinding, surface drying, shaping, wiping, packing.
Below best example of the present invention is described.
Evaluation method
Below estimate in the following manner in the test example.
Solidified nature
Zero: when forming solid state as a whole
△: form solid state as a whole, when soft
*: when not forming solid state as a whole
The transparency
Whether it is thick that each sample evenly is cut into 20mm, is placed on 26 the type, judge can distinguish and read.
◎: can know and distinguish and read
Zero: can distinguish and read
△: what can be distinguished is read
*: can not distinguish and read
Homogeneity
Zero: be the homogeneous transparent shape as a whole
△: though transparent as a whole, part is inhomogeneous
*: there is crystallization to separate out as a whole
Foaming
Operated by the women person of participating in the experiment (20,20-40 year), the form when washing one's face usually is applied in detected bar soap on hand, with the tap water foaming, and estimates.
◎: extremely good
Zero: foaming is good
△: common foaming
*: it is bad to foam
Sensation of pricking after washing one's face
Operated by the women person of participating in the experiment (20,20-40 year), the form when washing one's face usually is applied in detected bar soap on hand, washes one's face with the tap water foaming, and estimates.
◎: there is not sensation of pricking, extremely good
Zero: there is not sensation of pricking, good
△: common
*: tingle
Molten subtracting
Press JIS K-3304 standard, the solubleness that will rub is done molten subtracting and is estimated.
That is, (section 15mm * 20mm) mounting is rotated this film to on 40 ℃ of water-moistened from the beginning pellicular fronts of modulation, and friction dissolving 10 minutes is obtained the friction solubleness that each decides area according to the weight before and after the friction dissolving with the test portion sheet of certainweight.
◎: below 20
○：20～35
△：35～50
*: more than 50
The counterion research of lipid acid
At first, present inventors use sodium, N methyl taurine sodium, N-Sodium taurine salt, hypotaurine sodium to make the counterion of mixed fatty acid, and the modulation transparent solid detergent composition carries out various evaluations.The results are shown in following table 1.
Specifically, the ratio in the following table cooperates the salt of mixed fatty acid (tallow fatty acids/coco-nut oil fatty acid=8/2), respectively as soap.
The mixing element of this soap 40 weight %, Sorbitol Powder 10 weight %, glycerine 5 weight %, granulated sugar 10 weight %, ethanol 15 weight % and ion exchanged water 20 weight % is made raw material, and the type tool of the utilization legal system of mixing gets detergent composition.That is, uniform dissolution is carried out in above-mentioned raw materials heating under 70～80 ℃, then injection type tool with postcooling, curing, dry maturation, obtains solid detergent composition.
Counterion, if below do not have special appointment, in lipid acid and equivalent alkali, all represent with mole.
Table 1
Test example 1 test example 2 test examples 3 test examples 4
Sodium 100 80 80 80
N methyl taurine sodium-20--
N-Sodium taurine salt--20-
Inferior ox sulphur ester sodium---20
Solidified nature 0000
Transparency ◎ ◎ ◎ ◎
Homogeneity 0000
Foaming △ 000
Sensation of pricking after washing one's face * ◎ ◎ ◎
The molten zero ◎ ◎ ◎ that subtracts
From above-mentioned table 1 as can be known; for identical lipid acid; with with sodium during as counterion relatively, all there is remarkable improvement the back sensation of pricking that when the taurine that adds N methyl taurine sodium, N-Sodium taurine salt, N-hypotaurine sodium is counterion, foams, washes one's face, molten aspect such as subtract.
Taurine is the mol ratio of counterion
Present inventors study the optimum balance ion ratio (mol ratio) of N methyl taurine sodium.Test method is as the criterion with above-mentioned table 1 example.
Table 2
Test example 6789 10 11 12
5
Sodium 99 95 90 80 70 60 50 40
N methyl taurine 15 10 20 30 40 50 60
Sodium
Solidified nature 00000000
Transparency ◎ ◎ ◎ ◎ ◎ ◎ ◎ △
Homogeneity 0000000 *
Foam 000000 0-
Sensation of pricking after washing one's face * 00 ◎ ◎ ◎ ◎-
Molten subtract 000 ◎ ◎ ◎ ◎-
As known from Table 2, the counterion mol ratio as N methyl taurine has positive effect more than 5.Present inventors further study N methyl taurine sodium lipid acid, clearly know, by existing more than the 3.5 weight % in composition, can obtain additive effect.
The additive effect of potassium ion
Generally say, add potassium ion, the remollescent of promotion trend is being arranged aspect raising washability, the foaming.Therefore, present inventors study the effect of adding potassium ion under the various use levels of N methyl taurine sodium.
Test method is as the criterion with above-mentioned, and counterion is represented with mol ratio.
Table 3
Test example 14 15 16 17 18 19 20
13
Sodium 90 85 80 70 60 50 40 30
Potassium 10 10 10 10 10 10 10 10
N methyl taurine 05 10 20 30 40 50 60
Sodium
Solidified nature 0000000 *
Transparency ◎ ◎ ◎ ◎ ◎ ◎ zero-
Homogeneity 000000 0-
Foam 000000 0-
Shouting pain after washing one's face * 00 ◎ ◎ ◎ ◎-
Sense
Molten subtract △ 00 ◎ ◎ ◎ ◎-
Table 4
Test example 22 23 24 25 26 27
21
Sodium 80 75 70 60 50 40 30
Potassium 20 20 20 20 20 20 20
N methyl taurine 05 10 20 30 40 50
Sodium
Solidified nature 000000 *
Transparency ◎ ◎ ◎ ◎ ◎ ◎-
Homogeneity 00000 0-
Foaming ◎ ◎ ◎ ◎ ◎ ◎-
Shouting pain after washing one's face * 00 ◎ ◎ ◎-
Sense
Molten subtract △ 00 ◎ ◎ zero-
Table 5
Test example 29 30 31 32 33 34
28
Sodium 70 60 50 40 60 50 40
Potassium 30 30 30 30 40 40 40
N methyl taurine 0 10 20 30 0 10 20
Sodium
Solidified nature 000 * zero * *
Transparency ◎ * * * * * *
Homogeneity zero * * * * * *
Foaming ◎------
Shouting pain after washing one's face *------
Sense
Molten subtracting *------
The counterion mol ratio that is appreciated that potassium from above-mentioned table 3～5 though can improve foaming, surpasses 20 when following at 20 o'clock, be difficult to again form and solidify, and homogeneity is also very poor.
The soap use level
Below, present inventors study the soap use level in the composition.
That is,, obtain composition by they being mixed with adequate rate with modulated soap part and rest part.
The soap part
The salt of mixed fatty acid (the different C18=60/20/10/10 of C14/C16/C18/) is fitted in sodium soap/lipid acid potassium/lipid acid N methyl taurine sodium=70/10/20.
Rest part
Constitute rest part for 20 parts by 10 parts of Sorbitol Powders, 5 parts of glycerine, 10 parts of granulated sugar, 15 parts of ethanol and ion exchanged water.
Above soap part and rest part with ratio shown in the table 6, are heated under 40～60 ℃, and uniform dissolution is followed injection type tool, and cooling, curing, dry maturation obtain solid detergent composition.
Table 6
Test example 35 36 37 38 39 40 41
Soap part 30 35 40 45 50 55 60
Solidified nature * 000000
Homogeneity-0 0000 *
According to the result of above-mentioned table 6, the soap use level in the composition is preferably 35～55 weight %.
The Research on dose of preserving moisture
Below, present inventors are to the dosage research of preserving moisture in the composition.
Test is performed as follows.That is, add ethanol with its about 60 ℃ of heating down in reactor in mixed fatty acid (the different C18=60/20/10/10 of C14/C16/C18/), the ratio adding sodium hydroxide/N methyl taurine sodium in following table neutralizes, and obtains fatty acid soaps alkali composition.The according to the form below ratio in this fatty acid soaps alkali composition and wetting Agent for Printing Inks, further adds ethanol 10 weight %, ion exchanged water 20 weight %, 70～80 ℃ of following heating for dissolving, and the type tool of the utilization method of mixing obtains detergent composition.The results are shown in following table 7～10.
Table 7
Experimental example 42 43 44 45 46
Na/N-N-methyltaurine 95/5
Sodium
Soap alkali composition 25 35 45 55 60
The dosage 45 35 25 15 10 of always preserving moisture
Solidified nature △ 000 makes can not
Transparency ◎ ◎ ◎ ◎-
Homogeneity 000 0-
Foam 000 0-
Sensation of pricking 0000 after washing one's face-
Molten subtract △ 00 0-
Experimental example 47 48 49 50 51
Na/N-N-methyltaurine 75/25
Sodium
Soap alkali composition 25 35 45 55 60
The dosage 45 35 25 15 10 of always preserving moisture
Solidified nature * 0000
The transparency-◎ ◎ ◎ △
Homogeneity-0 00 △
Foaming-zero zero zero zero
Sensation of pricking after washing one's face-◎ ◎ 00
Molten subtracting-zero ◎ ◎ zero
Table 9
Experimental example 52 53 54 55 56
Na/N-N-methyltaurine 50/50
Sodium
Soap alkali composition 25 35 45 55 60
The dosage 45 35 25 15 10 of always preserving moisture
Solidified nature * 0000
The transparency-◎ ◎ zero △
Homogeneity-0 00 △
Foaming-zero ◎ ◎ zero
Twinge sense-◎ ◎ ◎ zero after washing one's face
Molten subtracting-◎ ◎ ◎ ◎
Table 10
Experimental example 57 58 59 60 61
Na/N-N-methyltaurine 40/60
Sodium
Soap alkali composition 25 35 45 55 60
The dosage 45 35 25 15 10 of always preserving moisture
Solidified nature * △ 000
The transparency-△ * * *
Homogeneity-△ * * *
Foaming-△ 000
Sensation of pricking after washing one's face-◎ ◎ ◎ zero
Molten subtracting-zero ◎ ◎ ◎
Clearly know from above-mentioned table 7～10, in counterion, when increasing the ratio of N methyl taurine,,, can obtain the raising of the transparency by adding an amount of wetting Agent for Printing Inks though the transparency has reduction slightly.Particularly, when the use level of wetting Agent for Printing Inks was 15～35 weight % in the composition, the transparency, sensation of pricking, molten aspect such as subtract all were improved.
Polyethers is the additive effect of wetting Agent for Printing Inks
In mixed fatty acid (the different C18=60/20/10/10 of C14/C16/C18/), add ethanol; make its about 60 ℃ of heating down in reactor; ratio with sodium hydroxide/potassium hydroxide/N methyl taurine sodium=80/10/10 neutralizes again, obtains fatty acid soaps alkali composition.
Wetting Agent for Printing Inks 25 weight %, ethanol 15 weight % and the ion exchanged water 20 weight % of this fatty acid soaps alkali composition 40 weight %, following table ratio (weight ratio) are mixed, 40～60 ℃ of heating down, uniform dissolution, be injected in the type tool, cooling, curing, dry maturation obtain solid detergent composition.
Table 11
Test example 62 63 64 65
Sorbitol Powder 40 40 40 40
Glycerine 20 15 10 0
Granulated sugar 40 40 40 40
POP (9) two glycerine 05 10 50
Ether
Solidified nature 0000
Homogeneity 0000
Foam 0000
Shouting pain 00 ◎ ◎ after washing one's face
Sense
The molten 00 ◎ ◎ that subtract
Know clearly that from table 11 to be wetting Agent for Printing Inks improving aspect sensation of pricking, molten the subtracting polyethers, with other wetting Agent for Printing Inks compositions relatively, have good effect.
Taurine is the kind of counterion
Below, present inventors study the kind of above-mentioned formula (I)～(III).
Promptly; to the different C18=60/20/10/10 of mixed fatty acid C14/C16/C18/) in add ethanol, with its about 60 ℃ of heating down in reactor, be that the ratio of counterion=70/10/20 adds with the taurine of sodium hydroxide/potassium hydroxide/following table; neutralization obtains fatty acid soaps alkali composition.
The mixing element of this fatty acid soaps alkali composition 40 weight %, Sorbitol Powder 10 weight %, glycerine 5 weight %, granulated sugar 10 weight %, ethanol 15 weight % and ion exchanged water 20 weight % is made raw material, utilize the above-mentioned same type tool method of mixing, obtain detergent composition.
Table 12
Test the foaming of routine counterion solidified nature homogeneity sensation of pricking is molten and subtract
66 N methyl taurine sodium, 000 ◎ ◎
67 N methyl taurine potassium, 000 ◎ ◎
68 N-Sodium taurine salts, 000 ◎ ◎
69 N-taurine potassium, 000 ◎ ◎
70 N-hypotaurine sodium, 000 ◎ ◎
71 N-hypotaurine potassium, 000 ◎ ◎
72 N methyl taurine trolamines, 000 ◎ ◎
From the result of above-mentioned table 12 as can be known, be that the basic metal of counterion does not have particular determination for taurine.
Below best fit example of the present invention is described.Any cooperation example is all made according to a conventional method.
Any one all has the good transparency, anti-molten subtracting property, usability.
Cooperate example 1
Lauric acid 7.0 weight %
Tetradecanoic acid 10.0 weight %
Palmitinic acid 3.0 weight %
Stearic acid 6.0 weight %
Unimac 5680 1.5 weight %
Sorbitol Powder 7.5 weight %
Ethanol 15.0 weight %
According to ground (エ デ ト) hydrochlorate 0.1 weight %
Sodium hydroxide 1.1 weight %
N methyl taurine sodium 9.2 weight %
Hydroxyalkyl ether carboxylic acid sodium 3.0 weight %
Salt 0.5 weight %
Granulated sugar 10.0 weight %
POP (9) two glyceryl ethers 5.0 weight %
BHT 0.1 weight %
Pigment is an amount of
Ion exchanged water all the other
Cooperate example 2
Lauric acid 5.0 weight %
Tetradecanoic acid 10.0 weight %
Palmitinic acid 3.0 weight %
Stearic acid 5.0 weight %
Unimac 5680 3.0 weight %
Glycerine 10.0 weight %
Two glycerine, 3.5 weight %
Sorbitol Powder 4.0 weight %
Ethanol 10.0 weight %
Edetate 0.1 weight %
Sodium hydroxide 3.6 weight %
N methyl taurine sodium 3.5 weight %
Hydroxyalkyl ether carboxylic acid sodium 2.0 weight %
POE (60) hardened castor oil 2.0 weight %
Lauroyl imidazolinium betaine 2.0 weight %
Salt 0.5 weight %
Granulated sugar 10.0 weight %
BHT 0.1 weight %
Pigment is an amount of
Ion exchanged water all the other
Cooperate example 3
Lauric acid 8.0 weight %
Tetradecanoic acid 12.0 weight %
Palmitinic acid 4.0 weight %
Stearic acid 6.0 weight %
Oleic acid 4.0 weight %
Sorbitol Powder 11.0 weight %
Glycerine 5.0 weight %
Ethanol 16.5 weight %
Edetate 0.1 weight %
Sodium hydroxide 4.2 weight %
N methyl taurine sodium 5.5 weight %
Salt 0.5 weight %
Granulated sugar 11.0 weight %
BHT 0.1 weight %
Titanium oxide 0.1 weight %
Pigment is an amount of
Ion exchanged water all the other
Cooperate example 4
Lauric acid 7.0 weight %
Tetradecanoic acid 10.0 weight %
Palmitinic acid 3.0 weight %
Stearic acid 6.0 weight %
Unimac 5680 1.5 weight %
Sorbitol Powder 7.5 weight %
Ethanol 15.0 weight %
Edetate 0.1 weight %
Sodium hydroxide 6.0 weight %
N-taurine potassium 2.1 weight %
Hydroxyalkyl ether carboxylic acid sodium 3.0 weight %
Salt 0.5 weight %
Granulated sugar 10.0 weight %
POP (9) two glyceryl ethers 0.1 weight %
Pigment is an amount of
Ion exchanged water all the other
As described above, transparent solid detergent composition of the present invention by being the counterion that alkaline agent is made lipid acid with specific taurine, can obtain the good transparency, anti-molten subtracting property, the usability after washing one's face.
Claims (4)
1. transparent solid detergent composition, feature is by following components matching:
Following formula more than 3.5% (one or two or more kinds soap in the expression of the I～III) compound and fatty acid sodium salt and/or lipid acid sylvite and wetting Agent for Printing Inks, and water,
R-COO
-H
2N
+(CH
3)-CH
2-CH
2-SO
3 -X
+ …(I)
R-COO
-H
3N
+-CH
2-CH
2-SO
3 -X
+ …(II)
R-COO
-H
3N
+-CH
2-CH
2-SO
2 -X
+ …(III)
R represents that saturated or unsaturated alkyl, the X of 7-23 carbon atom represent basic metal or organic bases in the formula,
Wherein, fatty acid salt add up to 35～55 weight %, wetting Agent for Printing Inks is that 15～35 weight %, water are 15～25 weight %.
2. according to the transparent solid detergent composition of claim 1, feature is in the said composition, lipid acid R-COO
-Counterion, with molar ratio computing, the formula (counterion of I～III): 5～50, sodium: 40～95, potassium: 0～20.
3. according to the transparent solid detergent composition of claim 1, feature is with respect to the wetting Agent for Printing Inks total amount, contain 5～50 weight %, the polyethers of had addition polymerization on the multivalence alcohol parent nucleus of 3 above hydroxyls in molecule 2～100 mole propylene oxide and ethylene oxide below 50 moles is a wetting Agent for Printing Inks.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00137160 CN1196777C (en) | 2000-09-18 | 2000-09-18 | Transparent solid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00137160 CN1196777C (en) | 2000-09-18 | 2000-09-18 | Transparent solid detergent composition |
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| Publication Number | Publication Date |
|---|---|
| CN1344790A CN1344790A (en) | 2002-04-17 |
| CN1196777C true CN1196777C (en) | 2005-04-13 |
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|---|---|---|---|
| CN 00137160 Expired - Lifetime CN1196777C (en) | 2000-09-18 | 2000-09-18 | Transparent solid detergent composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107001999A (en) * | 2014-12-05 | 2017-08-01 | 高露洁-棕榄公司 | Cleansing bar containing taurine |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112016012014A2 (en) * | 2013-12-10 | 2017-08-08 | Colgate Palmolive Co | SOAP BAR |
| CN110305745B (en) * | 2019-07-30 | 2021-05-11 | 北京周整无为健康管理有限责任公司 | Elongated stone soap and preparation method thereof |
-
2000
- 2000-09-18 CN CN 00137160 patent/CN1196777C/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107001999A (en) * | 2014-12-05 | 2017-08-01 | 高露洁-棕榄公司 | Cleansing bar containing taurine |
| US10400199B2 (en) | 2014-12-05 | 2019-09-03 | Colgate-Palmolive Company | Cleansing bars with taurine |
| CN107001999B (en) * | 2014-12-05 | 2020-02-07 | 高露洁-棕榄公司 | Cleansing bar containing taurine |
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| Publication number | Publication date |
|---|---|
| CN1344790A (en) | 2002-04-17 |
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