CN117551370A - Degradable composite barrier coating applied to film-based material and production equipment thereof - Google Patents
Degradable composite barrier coating applied to film-based material and production equipment thereof Download PDFInfo
- Publication number
- CN117551370A CN117551370A CN202311573001.0A CN202311573001A CN117551370A CN 117551370 A CN117551370 A CN 117551370A CN 202311573001 A CN202311573001 A CN 202311573001A CN 117551370 A CN117551370 A CN 117551370A
- Authority
- CN
- China
- Prior art keywords
- grinding
- bin
- film
- based material
- installation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 54
- 239000011248 coating agent Substances 0.000 title claims abstract description 51
- 239000000463 material Substances 0.000 title claims abstract description 43
- 230000004888 barrier function Effects 0.000 title claims abstract description 24
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 238000000227 grinding Methods 0.000 claims abstract description 90
- 238000009434 installation Methods 0.000 claims abstract description 41
- 230000007246 mechanism Effects 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000007599 discharging Methods 0.000 claims abstract description 5
- 239000008187 granular material Substances 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 35
- 238000003860 storage Methods 0.000 claims description 22
- 238000004140 cleaning Methods 0.000 claims description 20
- 239000004744 fabric Substances 0.000 claims description 20
- 238000012216 screening Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000002572 peristaltic effect Effects 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- CHTHALBTIRVDBM-UHFFFAOYSA-N furan-2,5-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)O1 CHTHALBTIRVDBM-UHFFFAOYSA-N 0.000 abstract description 12
- 238000004132 cross linking Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 4
- 230000000903 blocking effect Effects 0.000 abstract description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003431 cross linking reagent Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000011850 water-based material Substances 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000004576 sand Substances 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 229920006237 degradable polymer Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 229920001046 Nanocellulose Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- -1 on the one hand Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
- B01F21/02—Methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
- B01F21/10—Dissolving using driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
- B01F23/51—Methods thereof
- B01F23/511—Methods thereof characterised by the composition of the liquids or solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
- B01F23/53—Mixing liquids with solids using driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
- B01F23/59—Mixing systems, i.e. flow charts or diagrams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/70—Pre-treatment of the materials to be mixed
- B01F23/71—Grinding materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/70—Pre-treatment of the materials to be mixed
- B01F23/713—Sieving materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
- B01F27/191—Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/23—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis
- B01F27/232—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes
- B01F27/2322—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes with parallel axes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/85—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with two or more stirrers on separate shafts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/83—Mixing plants specially adapted for mixing in combination with disintegrating operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/836—Mixing plants; Combinations of mixers combining mixing with other treatments
- B01F33/8361—Mixing plants; Combinations of mixers combining mixing with other treatments with disintegrating
- B01F33/83613—Mixing plants; Combinations of mixers combining mixing with other treatments with disintegrating by grinding or milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C21/00—Disintegrating plant with or without drying of the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
- B02C23/10—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
- B02C23/12—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone with return of oversize material to crushing or disintegrating zone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C7/00—Crushing or disintegrating by disc mills
- B02C7/02—Crushing or disintegrating by disc mills with coaxial discs
- B02C7/08—Crushing or disintegrating by disc mills with coaxial discs with vertical axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C7/00—Crushing or disintegrating by disc mills
- B02C7/11—Details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C7/00—Crushing or disintegrating by disc mills
- B02C7/11—Details
- B02C7/12—Shape or construction of discs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/46—Constructional details of screens in general; Cleaning or heating of screens
- B07B1/50—Cleaning
- B07B1/52—Cleaning with brushes or scrapers
- B07B1/522—Cleaning with brushes or scrapers with brushes
- B07B1/524—Cleaning with brushes or scrapers with brushes the brushes being rotating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/30—Mixing paints or paint ingredients, e.g. pigments, dyes, colours, lacquers or enamel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Coating Apparatus (AREA)
Abstract
The invention discloses a degradable composite barrier coating applied to a film-based material and production equipment thereof, comprising an installation bin, wherein a grinding mechanism is arranged at the middle position of the top of the installation bin, a material conveying pump is arranged at the middle position of two sides of the installation bin, and a material discharging pipe and a material feeding pipe are respectively arranged at the output end and the input end of two groups of material conveying pumps; according to the invention, PVA is used as a main material, FDCA and pre-polymerized PEF are used as cross-linking agents to prepare the water-based PVA coating, and because PEF granules cannot be dissolved in the water-based material, FDCA is selected to be added, self-polymerization is also carried out in the cross-linking process, and self-crosslinking network is formed by the PVA and the cross-linking of the FDCA, so that the cross-linking degree in a system is improved, furan groups are introduced into the system, the overall water resistance of the system is improved, the OTR performance of the material is improved, the water vapor blocking performance is also improved, and the PVA and the PEF are both degradable materials, so that the water-based PVA coating is environment-friendly.
Description
Technical Field
The invention relates to the technical field of degradable coatings, in particular to a degradable composite barrier coating applied to a film-based material and production equipment thereof.
Background
In the past, with the implementation of plastic-limiting command and the continuous improvement of environmental awareness of people, the food packaging industry has begun to use paper-based materials such as paper and paperboard to replace synthetic polymers in a large number. However, as with conventional polymeric packaging materials, paper-based packaging also needs to have high strength, high barrier functionality. For food packaging, atmospheric water vapor and oxygen are critical to the ability to penetrate the packaging material and spoil the food. In order to avoid the influence of oxygen and moisture transfer on the quality of food, to improve the shelf life of food, good gas barrier properties and liquid permeation resistance are of great importance for food packaging materials, which are also the most interesting properties for researchers. Due to the characteristics of cellulose materials, on the one hand, cellulose is highly hydrophilic and on the other hand, fibers are interwoven to form a porous network structure, so that paper and paperboard materials generally have very strong liquid absorption and air permeability, which greatly limit the use of paper-based materials in the field of direct food packaging.
At present, the method for improving the barrier property of the paper-based package mainly comprises the following steps:
(1) dipping oils, waxes, resins, latex, and the like;
(2) depositing a dense oxide film on the surface;
(3) compounding plastic with paper to prepare a paper-plastic composite material;
(4) the surface is coated with a synthetic or natural polymer.
The first 3 methods are widely used and have remarkable effects, but most of the materials used are not degradable, and the recycling and repulping of paper products are difficult and not environment-friendly. The surface coating method has simple process and easy production, and particularly, the use of degradable polymers as coating materials is the main development direction at present. Degradable materials are a type of degradable polymer coating materials which can be decomposed into small molecular polymers from large molecular polymers through internal melting of polymers caused by external actions (light, heat, microorganisms and mechanical actions), and common degradable polymer coating materials include nanocellulose, polyhydroxybutyrate (PHB), polylactic acid (PLA), polyvinyl alcohol (PVA) and the like.
In China, the paint is divided into powder paint and liquid paint, the powder paint can be mixed with water or other mixed solvents to prepare liquid paint, the liquid paint is generally paint, the paint is mainly resin, oil or emulsion, pigment and filler are added or not added, corresponding auxiliary agents are added, and the viscous liquid prepared by using organic solvents or water is required to be ground in production, and large particles are ground into fine particles, so that the quality of the paint is improved.
The current production equipment has certain disadvantages:
1. when larger particle powder is ground, only a simple grinding process can be performed, and when multiple grinding is needed, the device is required to grind in different grinding equipment, so that unnecessary troubles are increased, a certain amount of paint is lost, and time and efficiency are delayed.
2. In addition, when the paint is incompletely ground, rapid separation cannot be performed, the ground paint needs to be sorted again, and the incompletely ground large particles need to be ground again, so that screening cannot be performed simultaneously during grinding, and efficiency is reduced.
3. When screening, the coating is screened through the screen cloth, but the coating falls on the screen cloth and is still in a standing state, so that the efficiency of the coating screen cloth is low, and simultaneously, the coating is easy to block the aperture of the screen cloth, so that the screening speed of the screen cloth is further slowed down, and the screen cloth is gradually blocked.
Disclosure of Invention
The invention aims to provide a degradable composite barrier coating applied to a film-based material and production equipment thereof, so as to solve the related problems in the prior art.
In order to achieve the above purpose, the present invention provides the following technical solutions: the utility model provides a be applied to production facility of degradable composite barrier coating on membrane base material, includes the installation storehouse, the intermediate position department at installation storehouse top is provided with grinding machanism, the intermediate position department of installation storehouse both sides is provided with the delivery pump, two sets of delivery pump's output and input are provided with discharging pipe and inlet pipe respectively, the inboard intermediate position department of installation storehouse is provided with the storage silo, the edge at storage silo top is provided with annular collection frame, the both sides of annular collection frame bottom are provided with the back flow, the inside both sides of annular collection frame are provided with rabbling mechanism, the top of annular collection frame is provided with the screen cloth.
Preferably, the grinding mechanism comprises a grinding bin, a trough, a driving motor, a rotating shaft, a collecting pipe, a first grinding disc, a second grinding disc, grinding blocks and a grinding groove, wherein the first grinding disc is arranged at the top of the inner side of the grinding bin, the trough is arranged at the middle position of the top of the first grinding disc, the collecting pipe is arranged at the middle position of the top of the first grinding disc, the driving motor is arranged at the top of the collecting pipe, the rotating shaft is arranged at the output end of the driving motor, the second grinding disc and the grinding blocks are respectively arranged at the bottom and the bottom of the outer side of the rotating shaft, the grinding groove is arranged at the bottom of the inner side of the grinding bin, and the screening mechanism is arranged at the bottom of the grinding blocks.
Preferably, the screening mechanism comprises a driving shaft, a cleaning brush, a mounting rod, a connecting rod, a cleaning block and a driving gear, wherein the driving gear is arranged at the bottom of the driving shaft, the mounting rod is arranged at the top of the outer side of the driving shaft, the cleaning brush is arranged at the bottom of the mounting rod, the connecting rods are arranged at two sides of the bottom of the mounting rod, and the cleaning block is arranged at the bottom of the connecting rod.
Preferably, the stirring mechanism comprises a protection bin, driven gears, stirring shafts and stirring blades, wherein the stirring shafts are rotatably arranged on two sides of the bottom inside the protection bin, the driven gears are arranged at the tops of the stirring shafts, six groups of stirring blades are arranged at the bottoms of two sides of the stirring shafts, and the bottoms of the stirring shafts penetrate through the storage bin and extend to the bottom inside the installation bin.
Preferably, the bottom of the driving shaft penetrates through the screen mesh and extends to the inside of the protection bin, and the driving gear is meshed with the two groups of driven gears.
Preferably, a feeding hole is formed in one side of one end of the back of the installation bin, and the feeding hole is located below the storage bin.
Preferably, the bottom of the return pipe penetrates through the storage bin, and the annular collecting frame and the installation bin are mutually communicated through the return pipe.
Preferably, the top of the protection bin is in a V shape, and the protection bin is positioned below the screen.
A degradable composite barrier coating applied to a film-based material and production equipment thereof, the application steps are as follows:
compared with the prior art, the invention provides the degradable composite barrier coating applied to the film-based material, which has the following beneficial effects:
1. the PVA is used as a main material, the FDCA and the pre-polymerized PEF are used as cross-linking agents, so that the water-based PVA coating is prepared, because PEF granules cannot be dissolved in the water-based material, FDCA is selected to be added, self-polymerization is also carried out in the cross-linking process, self-crosslinking network is formed by the PVA and the cross-linking of the FDCA, the cross-linking degree in the system is improved, furan groups are introduced into the system, the overall water resistance of the system is improved, the OTR performance of the material is improved, the water vapor blocking performance is also improved, and the PVA and the PEF are both degradable materials, so that the water-based PVA coating is environment-friendly.
2. According to the invention, by arranging the grinding mechanism, the coating powder can be subjected to double grinding, so that the coating can be ground more thoroughly and more finely, the second grinding disc and the grinding block are driven by the driving motor to rotate at a high speed, preliminary grinding can be performed between the rotating second grinding disc and the first grinding disc, the ground coating powder enters the grinding groove, the coating powder is ground again under the action of the rotating grinding block, and the coating can be ground more thoroughly by different modes.
3. The invention is provided with the screen, when the ground paint falls from the inside of the grinding groove, the paint can fall on the top of the screen in advance, the screen is conical, so that the paint on the screen can slide, fine grinding enters the inside of the storage bin through the screen for storage, the powder with larger particles can slide into the inside of the annular collecting frame along the inclined edge of the screen, and falls back to the bottom of the installation bin again through the return pipe for preparation for secondary grinding, the screen can perform screening effect while grinding, and the screened large particles can be recovered for secondary grinding again, so that the time is greatly saved and the efficiency is improved.
4. According to the invention, the screening mechanism is arranged at the bottom of the grinding block, so that the cleaning brush on the screening mechanism synchronously rotates along with the grinding block, and as the cleaning brush is in contact with the top of the screen, the screen can be crushed and cleaned, so that the screening of the coating can be promoted, and meanwhile, particles blocked in the two holes can be cleaned out, and fall into the annular collecting frame to be recovered, so that the condition that the screen cannot be used due to the blocking of the screen is effectively avoided.
Drawings
FIG. 1 is a front cross-sectional view of the present invention;
FIG. 2 is a rear view of the present invention;
FIG. 3 is a schematic view of a polishing mechanism according to the present invention;
FIG. 4 is a schematic view of a screening mechanism according to the present invention;
FIG. 5 is a top view of the annular collection frame of the present invention;
fig. 6 is a side cross-sectional view of the guard compartment of the present invention.
In the figure: 1. a mounting bin; 2. a grinding mechanism; 201. a grinding bin; 202. a trough; 203. a driving motor; 204. a rotating shaft; 205. a header; 206. a first sanding plate; 207. a second sanding plate; 208. grinding the blocks; 209. grinding the groove; 3. a screening mechanism; 301. a drive shaft; 302. a cleaning brush; 303. a mounting rod; 304. a connecting rod; 305. a cleaning block; 306. a drive gear; 4. a stirring mechanism; 401. a protective bin; 402. a driven gear; 403. a stirring shaft; 404. stirring the leaves; 5. a material conveying pump; 6. a storage bin; 7. a feed pipe; 8. a discharge pipe; 9. an annular collection frame; 10. a return pipe; 11. and (3) screening.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Referring to fig. 1-6, the present invention provides a technical solution: the utility model provides a be applied to production facility of degradable composite barrier coating on membrane base material, including installation storehouse 1, the intermediate position department at installation storehouse 1 top is provided with grinding machanism 2, the intermediate position department of installation storehouse 1 both sides is provided with feed pump 5, the output and the input of two sets of feed pumps 5 are provided with discharging pipe 8 and inlet pipe 7 respectively, the intermediate position department of installation storehouse 1 inboard is provided with storage silo 6, the edge at storage silo 6 top is provided with annular collection frame 9, the both sides of annular collection frame 9 bottom are provided with back flow 10, the inside both sides of annular collection frame 9 are provided with rabbling mechanism 4, the top of annular collection frame 9 is provided with screen cloth 11.
As a preferable scheme of the present embodiment: the grinding mechanism 2 comprises a grinding bin 201, a trough 202, a driving motor 203, a rotating shaft 204, a collecting pipe 205, a first grinding disc 206, a second grinding disc 207, a grinding block 208 and a grinding groove 209, wherein the first grinding disc 206 is arranged at the top of the inner side of the grinding bin 201, the trough 202 is arranged at the middle position of the inner side of the first grinding disc 206, the collecting pipe 205 is arranged at the middle position of the top of the first grinding disc 206, the driving motor 203 is arranged at the top of the collecting pipe 205, the rotating shaft 204 is arranged at the output end of the driving motor 203, the second grinding disc 207 and the grinding block 208 are respectively arranged at the bottom and the bottom of the outer side of the rotating shaft 204, the grinding groove 209 is arranged at the bottom of the inner side of the grinding bin 201, and the screening mechanism 3 is arranged at the bottom of the grinding block 208 and can grind paint for a plurality of times.
As a preferable scheme of the present embodiment: screening mechanism 3 includes drive shaft 301, cleaning brush 302, installation pole 303, connecting rod 304, cleans piece 305 and drive gear 306, and the bottom of drive shaft 301 is provided with drive gear 306, and the top in the drive shaft 301 outside is provided with installation pole 303, and the bottom of installation pole 303 is provided with cleaning brush 302, and the both sides of installation pole 303 bottom are provided with connecting rod 304, and the bottom of connecting rod 304 is provided with cleans piece 305, can clean the coating at screen cloth 11 top to the inside of annular collection frame 9 fast.
As a preferable scheme of the present embodiment: the stirring mechanism 4 comprises a protection bin 401, driven gears 402, stirring shafts 403 and stirring blades 404, wherein the stirring shafts 403 are rotatably arranged on two sides of the inner bottom of the protection bin 401, the driven gears 402 are arranged on the top of the stirring shafts 403, six groups of stirring blades 404 are arranged on the bottoms of the two sides of the stirring shafts 403, and the bottoms of the stirring shafts 403 penetrate through the storage bin 6 and extend to the inner bottom of the installation bin 1, so that the paint can be stirred and mixed.
As a preferable scheme of the present embodiment: the bottom of the driving shaft 301 extends through the screen 11 to the inside of the guard bin 401, and the driving gear 306 is meshed with two sets of driven gears 402, and drives the two sets of driven gears 402 to rotate.
As a preferable scheme of the present embodiment: one side of the back side one end of the installation bin 1 is provided with a feed inlet, and the feed inlet is positioned below the storage bin 6, so that the material can be discharged conveniently.
As a preferable scheme of the present embodiment: the bottom of the return pipe 10 penetrates through the interior of the storage bin 6, and the return pipe 10 mutually communicates the annular collecting frame 9 with the interior of the installation bin 1.
As a preferable scheme of the present embodiment: the top of the protection bin 401 is V-shaped, and the protection bin 401 is positioned below the screen 11 to prevent paint from gathering at the top of the protection bin 401.
Embodiment 1, as shown in fig. 4-6, further, driving shaft 301 drives driving gear 306 to rotate inside of protection bin 401, driving gear 306 drives two sets of driven gears 402 meshed with driving gear 306 to rotate, driven gears 402 drive stirring shaft 403 and stirring blade 404 to simultaneously rotate, so that paint and solvent inside storage bin 6 can be mixed with each other, paint inside installation bin 1 can be stirred, paint caking possibly occurring inside installation bin 1 can be broken up, protection bin 401 is in a V-shaped design, and paint can be prevented from being accumulated at the top of protection bin 401.
In embodiment 2, as shown in fig. 4-5, when the ground powder falls on the screen 11, the large-particle paint that does not pass through the screen 11 falls inside the annular collecting frame 9, and because the driving shaft 301 drives the mounting rod 303 to rotate simultaneously, the mounting rod 303 drives the two groups of cleaning blocks 305 to rotate simultaneously through the two groups of connecting rods 304, the rotation of the cleaning blocks 305 pushes the paint inside the annular collecting frame 9, the paint is pushed to the return pipe 10, and enters the bottom inside the mounting bin 1 through the return pipe 10, and the paint is recovered and ground again.
A degradable composite barrier coating applied to a film-based material and production equipment thereof, the application steps are as follows:
to sum up: firstly, pour the coating to be ground into the inside of the installation bin 1 through the feed inlet, open two sets of delivery pumps 5 and work, carry the coating of the inside bottom of installation bin 1 to the inside of header 205 through inlet pipe 7 and discharging pipe 8, get into between first sand table 206 and the second sand table 207 through silo 202, driving motor 203 work drives second sand table 207 and abrasive brick 208 through pivot 204 and rotates, the cooperation of second sand table 207 and first sand table 206 can be to the preliminary grinding of coating, the coating is ground after the back and is fallen in the inside of grinding groove 209, through the rotation of abrasive brick 208, carry out secondary grinding again, the coating through secondary grinding falls on the top of screen cloth 11, because screen cloth 11 is the toper, the coating slides on the surface of screen cloth 11, tiny coating powder falls into the inside of storage silo 6 through screen cloth 11, the great powder of granule can slide to the inside of annular collection frame 9 along the surface of screen cloth 11 simultaneously and collect.
The grinding block 208 rotates and simultaneously drives the driving shaft 301 to synchronously rotate, the driving shaft 301 drives the mounting rod 303 and the cleaning brush 302 to synchronously rotate, the cleaning brush 302 is in contact with the screen 11, the cleaning brush 302 not only can push the paint to rapidly screen, but also can clean the paint blocked in the screen, so that the paint enters the annular collecting frame 9, and then the paint reenters the mounting bin 1 through the return pipe 10.
Finally, it should be noted that the above description is only for illustrating the technical solution of the present invention, and not for limiting the scope of the present invention, and that the simple modification and equivalent substitution of the technical solution of the present invention can be made by those skilled in the art without departing from the spirit and scope of the technical solution of the present invention.
Claims (10)
1. The degradable composite barrier coating applied to the film-based material comprises PVA and is characterized in that: dissolving 20g of PVA1799 in 100ml of water, placing in a water bath kettle at 95 ℃ and stirring until PVA is completely dissolved, thus obtaining 20% PVA aqueous solution; to the PVA aqueous solution, 0.2g of the preservative Nepal's butyl ester was added at room temperature. Stirring for 10min, adding 0.2ml of concentrated hydrochloric acid, stirring for ten min, and discharging; the self-made titanium catalyst was added to the above solution, and after stirring for ten minutes, 50g of FDCA10% solution was added with a peristaltic pump while 50g of ethylene glycol was dropped, and heated to 90℃for 30 minutes.
2. A production plant for degradable composite barrier coatings applied on film-based materials according to claim 1, comprising a mounting bin (1), characterized in that: the utility model discloses a grinding machine, including installation storehouse (1), feeding pump (5), discharge pipe (8) and inlet pipe (7) are provided with respectively to the intermediate position department at installation storehouse (1) top, the intermediate position department of installation storehouse (1) both sides is provided with feeding pump (5), two sets of the output and the input of feeding pump (5), the inboard intermediate position department of installation storehouse (1) is provided with storage silo (6), the edge at storage silo (6) top is provided with annular collection frame (9), the both sides of annular collection frame (9) bottom are provided with back flow (10), the inside both sides of annular collection frame (9) are provided with rabbling mechanism (4), the top of annular collection frame (9) is provided with screen cloth (11).
3. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 2, wherein: grinding mechanism (2) are including grinding storehouse (201), silo (202), driving motor (203), pivot (204), collection pipe (205), first grinding dish (206), second grinding dish (207), grinding piece (208) and grinding groove (209), the inboard top in grinding storehouse (201) is provided with first grinding dish (206), the inside intermediate position department of first grinding dish (206) is provided with silo (202), the intermediate position department at first grinding dish (206) top is provided with collection pipe (205), the top of collection pipe (205) is provided with driving motor (203), the output of driving motor (203) is provided with pivot (204), the bottom and the bottom in the pivot (204) outside are provided with second grinding dish (207) and grinding piece (208) respectively, the inboard bottom in grinding storehouse (201) is provided with grinding groove (209), the bottom of grinding piece (208) is provided with screening mechanism (3).
4. A production facility for a degradable composite barrier coating applied to a film-based material as claimed in claim 3, wherein: screening mechanism (3) are including drive shaft (301), cleaning brush (302), installation pole (303), connecting rod (304), clean piece (305) and drive gear (306), the bottom of drive shaft (301) is provided with drive gear (306), the top in the drive shaft (301) outside is provided with installation pole (303), the bottom of installation pole (303) is provided with cleaning brush (302), the both sides of installation pole (303) bottom are provided with connecting rod (304), the bottom of connecting rod (304) is provided with cleans piece (305).
5. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 2, wherein: the stirring mechanism (4) comprises a protection bin (401), driven gears (402), stirring shafts (403) and stirring blades (404), wherein the stirring shafts (403) are rotatably arranged on two sides of the inner bottom of the protection bin (401), the driven gears (402) are arranged at the top of the stirring shafts (403), six groups of stirring blades (404) are arranged at the bottoms of the two sides of the stirring shafts (403), and the bottoms of the stirring shafts (403) penetrate through the inner portion of the storage bin (6) and extend to the inner bottom of the installation bin (1).
6. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 5, wherein: the bottom of the driving shaft (301) penetrates through the screen (11) and extends to the inside of the protection bin (401), and the driving gear (306) is meshed with two groups of driven gears (402).
7. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 2, wherein: one side of one end of the back of the installation bin (1) is provided with a feed inlet, and the feed inlet is positioned below the storage bin (6).
8. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 2, wherein: the bottom of the return pipe (10) penetrates through the storage bin (6), and the annular collecting frame (9) and the inside of the installation bin (1) are mutually communicated by the return pipe (10).
9. The production equipment of the degradable composite barrier coating applied to the film-based material as claimed in claim 5, wherein: the top of the protection bin (401) is in a V shape, and the protection bin (401) is positioned below the screen (11).
10. A degradable composite barrier coating applied to a film-based material and production equipment thereof, comprising the production equipment of the degradable composite barrier coating applied to the film-based material according to any one of claims 1 to 9, and the application method comprises the following steps:
step one, a step one; firstly, paint to be ground is poured into the installation bin (1) through a feed inlet, two groups of material conveying pumps (5) are opened to work, paint at the bottom of the installation bin (1) is conveyed to the inside of a collecting pipe (205) through a feed pipe (7) and a discharge pipe (8), the paint enters between a first grinding disc (206) and a second grinding disc (207) through a feed groove (202), a driving motor (203) works to drive the second grinding disc (207) and a grinding block (208) to rotate through a rotating shaft (204), the cooperation of the second grinding disc (207) and the first grinding disc (206) can primarily grind the paint, the paint falls into the inside of a grinding groove (209) after grinding, and secondary grinding is performed through the rotation of the grinding block (208).
Step two: the coating through secondary grinding falls on the top of screen cloth (11), because screen cloth (11) are the toper, and coating slides on the surface of screen cloth (11), tiny coating powder falls into the inside of storage silo (6) through screen cloth (11), and the inside that the bigger powder of granule can slide to annular collection frame (9) along the surface of screen cloth (11) is collected simultaneously.
Step three: the grinding block (208) rotates and simultaneously drives the driving shaft (301) to synchronously rotate, the driving shaft (301) drives the mounting rod (303) and the cleaning brush (302) to synchronously rotate, the cleaning brush (302) and the screen (11) are in contact with each other, the cleaning brush (302) not only can push the paint to rapidly screen, but also can clean the paint blocked in the screen, and the paint enters the annular collecting frame (9).
Step four: and then drive shaft (301) drive gear (306) rotate in the inside of protection storehouse (401), drive gear (306) drive with its intermeshing's two sets of driven gear (402) rotate, driven gear (402) drive (403) and stirring leaf (404) rotate simultaneously, can mix the inside coating of storage silo (6) and solvent each other, can stir the inside coating of installation storehouse (1) simultaneously, break up the coating caking that probably appears in the inside installation storehouse (1).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202311573001.0A CN117551370B (en) | 2023-11-23 | Degradable composite barrier coating applied to film-based material and production equipment thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202311573001.0A CN117551370B (en) | 2023-11-23 | Degradable composite barrier coating applied to film-based material and production equipment thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN117551370A true CN117551370A (en) | 2024-02-13 |
CN117551370B CN117551370B (en) | 2024-07-23 |
Family
ID=
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB500952A (en) * | 1937-08-14 | 1939-02-14 | Morton Smith | Improvements in or relating to mixing or grinding mills and the like |
JP2001224979A (en) * | 2000-02-15 | 2001-08-21 | Nippon Kouatsu Electric Co | Pulverizing machine |
CN106243331A (en) * | 2016-07-27 | 2016-12-21 | 浙江大学 | A kind of preparation method of poly-furandicarboxylic acid glycol ester |
CN109562609A (en) * | 2016-08-12 | 2019-04-02 | 科莱恩塑料和涂料有限公司 | Oxygen-barrier property plastic material |
CN213824544U (en) * | 2020-11-26 | 2021-07-30 | 莆田市涵江区安泰涂料有限公司 | Raw material stirring device for production of exterior wall emulsion paint coating |
CN213886013U (en) * | 2020-10-27 | 2021-08-06 | 河北庆昌农业科技有限公司 | Blendor is used in chemical fertilizer production |
CN215655328U (en) * | 2021-08-17 | 2022-01-28 | 青岛锐涂新材料科技有限公司 | Production polyurea is grinding machine for coating |
WO2022041422A1 (en) * | 2020-08-24 | 2022-03-03 | 清远瑞华助剂有限公司 | Natural antimicrobial agent and processing device therefor |
WO2022262128A1 (en) * | 2021-06-16 | 2022-12-22 | 浙江宏电环保股份有限公司 | Production process and device for environmentally friendly expansion-type steel structure fireproof coating |
CN218394040U (en) * | 2022-10-10 | 2023-01-31 | 衢州市居家红建材有限公司 | Grinder is used in processing of putty powder |
CN219073085U (en) * | 2022-12-28 | 2023-05-26 | 江西易必居新型建材有限公司 | Grinding equipment |
CN116672942A (en) * | 2023-06-07 | 2023-09-01 | 江苏安特克新材料研究院有限公司 | High-performance anti-corrosion fireproof inorganic ceramic composite coating spraying preparation equipment |
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB500952A (en) * | 1937-08-14 | 1939-02-14 | Morton Smith | Improvements in or relating to mixing or grinding mills and the like |
JP2001224979A (en) * | 2000-02-15 | 2001-08-21 | Nippon Kouatsu Electric Co | Pulverizing machine |
CN106243331A (en) * | 2016-07-27 | 2016-12-21 | 浙江大学 | A kind of preparation method of poly-furandicarboxylic acid glycol ester |
CN109562609A (en) * | 2016-08-12 | 2019-04-02 | 科莱恩塑料和涂料有限公司 | Oxygen-barrier property plastic material |
WO2022041422A1 (en) * | 2020-08-24 | 2022-03-03 | 清远瑞华助剂有限公司 | Natural antimicrobial agent and processing device therefor |
CN213886013U (en) * | 2020-10-27 | 2021-08-06 | 河北庆昌农业科技有限公司 | Blendor is used in chemical fertilizer production |
CN213824544U (en) * | 2020-11-26 | 2021-07-30 | 莆田市涵江区安泰涂料有限公司 | Raw material stirring device for production of exterior wall emulsion paint coating |
WO2022262128A1 (en) * | 2021-06-16 | 2022-12-22 | 浙江宏电环保股份有限公司 | Production process and device for environmentally friendly expansion-type steel structure fireproof coating |
CN215655328U (en) * | 2021-08-17 | 2022-01-28 | 青岛锐涂新材料科技有限公司 | Production polyurea is grinding machine for coating |
CN218394040U (en) * | 2022-10-10 | 2023-01-31 | 衢州市居家红建材有限公司 | Grinder is used in processing of putty powder |
CN219073085U (en) * | 2022-12-28 | 2023-05-26 | 江西易必居新型建材有限公司 | Grinding equipment |
CN116672942A (en) * | 2023-06-07 | 2023-09-01 | 江苏安特克新材料研究院有限公司 | High-performance anti-corrosion fireproof inorganic ceramic composite coating spraying preparation equipment |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109576825A (en) | A kind of type materials recycling technique free of cleaning | |
CN114798672B (en) | Plant-based biodegradable material manufacturing equipment and process | |
CN115042346A (en) | Processing equipment and process for crushing and recycling waste composite fiber material | |
CN217248745U (en) | Prilling granulator is used in compound fertilizer production | |
CN117551370A (en) | Degradable composite barrier coating applied to film-based material and production equipment thereof | |
CN117551370B (en) | Degradable composite barrier coating applied to film-based material and production equipment thereof | |
CN113564750A (en) | Spinning process for preparing regenerated polyester long fibers from waste fiber products | |
CN112221667B (en) | Epoxy is prepared and is used high-efficient grinding device | |
CN212524341U (en) | Seed benevolence screening reducing mechanism is used in tung oil production | |
US20220105666A1 (en) | Method for manufacturing injection molding material and injection molding material | |
CN215353754U (en) | Sorting device is used in production of glossy ganoderma spore powder | |
CN212018509U (en) | Loading attachment is used in waterproof material production and processing | |
CN209254908U (en) | A kind of paint pulverizer of classification grinding | |
CN105543992B (en) | Bamboo charcoal particles of polylactic acid spinning system | |
CN206170416U (en) | Novel granulator | |
CN110901111A (en) | Preparation method of vegetable preservative film | |
CN217257610U (en) | Multistage cutting device based on ultra-high molecular weight polyethylene granulator | |
CN215843193U (en) | Waste treatment device is used in processing of bamboo wood fiber board | |
CN221187223U (en) | Polymer plastic masterbatch screening plant | |
CN216778685U (en) | Device for producing hemostatic material | |
CN219552018U (en) | Polysaccharide extraction and separation device | |
CN217830931U (en) | Cleaning device for plastic product production | |
CN115122523B (en) | PTFE rubber composite production line | |
CN109576826A (en) | A kind of polyester waste material regeneration technology | |
CN209289571U (en) | A kind of recycled plastic refining exclusion device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant |