CN117164331B - Mirror surface anti-slip ceramic tile and production process thereof - Google Patents

Mirror surface anti-slip ceramic tile and production process thereof Download PDF

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CN117164331B
CN117164331B CN202311114841.0A CN202311114841A CN117164331B CN 117164331 B CN117164331 B CN 117164331B CN 202311114841 A CN202311114841 A CN 202311114841A CN 117164331 B CN117164331 B CN 117164331B
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CN117164331A (en
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罗永学
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Guangdong Hao Sheng Ceramics Co ltd
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Abstract

The invention discloses a mirror surface anti-slip ceramic tile and a production process thereof, which not only have the high-brightness and high-refraction effect like a mirror surface, but also have excellent anti-slip effect. The method comprises the following steps: (1) Mixing the raw materials, ball milling, pulping, removing iron, spraying powder and aging to obtain a basic raw material for later use; (2) Mixing raw materials, ball milling, slurry discharging, iron removal, powder spraying and aging to obtain a raw material A for standby; taking 13-15 parts by weight of diatomite particles and 15-18 parts by weight of quartz sand particles as raw materials, mixing, wet grinding, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with a 60-mesh, 80-mesh and 100-mesh sieve to obtain a raw material B, and preserving heat for later use; (3) laying out a basic raw material, and pressing to obtain a basic blank layer; (4) Then, distributing the raw materials A on the basic blank layer, uniformly scattering the raw materials B among the raw materials A in the distribution process, and pressing to obtain an optimized blank layer; (5) applying a primer and spraying ink; (6) overglazing; and (7) firing to obtain the mirror surface anti-slip ceramic tile.

Description

Mirror surface anti-slip ceramic tile and production process thereof
Technical Field
The invention relates to the field of ceramic bricks, in particular to a mirror surface anti-slip ceramic brick and a production process thereof.
Background
Ceramic tiles have a long history and are mainly used for building decoration and design and are paved on the surfaces of walls, floors or products.
With the progress and development of society, the requirements of users on ceramic tiles are higher and higher, so that the effects of the surfaces of the ceramic tiles are maintained, and good anti-skid performance is required, in other words, the ceramic tiles have various functional characteristics at the same time.
In the prior art, a good anti-slip effect needs to be obtained, polishing can be performed, and chemical substances can be used for corroding the ceramic tile to a certain extent, so that the anti-slip effect is obtained, but the methods cannot guarantee the high brightness and high refraction effect of the ceramic tile, and certain damage can be caused to the ceramic tile, so that the ceramic tile is damaged.
It can be seen how to further optimize the product and improve the quality of the ceramic tile is one of the directions of development by those skilled in the art.
Disclosure of Invention
The invention discloses a mirror surface anti-slip ceramic tile and a production process thereof, which not only have the high-brightness and high-refraction effect like a mirror surface, but also have excellent anti-slip effect.
The invention relates to a mirror surface anti-slip ceramic tile, which is sequentially provided with a basic green body layer, an optimized green body layer, a ground glaze layer, a pattern layer and a surface glaze layer.
The invention also provides a production process of the mirror surface anti-slip ceramic tile, which comprises the following steps:
(1) Taking raw materials, which comprise: 19-23 parts by weight of kaolin, 20-26 parts by weight of feldspar, 20-25 parts by weight of silica sand, 10-15 parts by weight of talcum, 3-5 parts by weight of bentonite, 10-12 parts by weight of water abrasive and 3-5 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 15-18 parts by weight of kaolin, 18-23 parts by weight of feldspar, 10-13 parts by weight of silica sand, 8-10 parts by weight of talcum, 3-5 parts by weight of bentonite and 1-3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking 13-15 parts by weight of diatomite particles and 15-18 parts by weight of quartz sand particles as raw materials, mixing, wet grinding, removing iron and impurities, drying, keeping the agglomeration humidity, and sieving with 60-mesh, 80-mesh and 100-mesh sieves to obtain a raw material B for standby;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, distributing the raw materials A on the basic blank layer, uniformly scattering the raw materials B among the raw materials A in the distribution process, and pressing to obtain an optimized blank layer;
(5) Applying ground glaze and spraying ink;
(6) Applying surface glaze;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
Preferably, the diatomite particles and the quartz sand particles in the step (2) have particle diameters of 20-100 μm.
Preferably, the optimized blank layer accounts for 20-25% of the total height of the two blank layers.
Preferably, the arrangement mode of the uniform scattering of the raw material B is that the raw material B is uniformly scattered in sequence according to the order of 60 meshes, 80 meshes and 100 meshes.
Preferably, the raw material B has a 60 mesh, 80 mesh and 100 mesh ratio of 1:1:1.
Preferably, the ground coat comprises a base ground coat, diatomite particles and quartz particles.
Preferably, the particle size of the diatomite particles and the quartz particles of the ground coat is 20-40 mu m.
Preferably, the overglaze comprises specular glaze, diatomite particles, quartz particles, titanium dioxide particles.
Preferably, the particle size of diatomite particles, quartz particles and titanium dioxide particles of the overglaze is 0.1-18 mu m.
The invention discloses a production process of a mirror surface anti-slip ceramic tile, wherein the whole green brick is pressed twice, firstly, a basic green body layer is pressed after being distributed, and secondly, the green body layer is added and optimized. The raw materials of the base green body layer with high compression resistance of the ceramic brick keep the structure more tightly combined, and the intermolecular adhesion degree is high and stronger after firing. The strength of the secondary pressing process is effectively utilized, the optimized blank layer is relatively thin, the position of the raw material of the optimized blank layer can be reasonably controlled if the pressing times are relatively small, and the basic blank layer needs stronger pressure to keep the structure.
Raw material B is dried after wet grinding in the preparation process, different drying time and temperature are controlled, the agglomerated particle size of the raw material B can be effectively controlled, diatomite and quartz can generate a certain gap and good adsorption performance after being fired, and the ceramic tile can be adsorbed by stepping on the ceramic tile in a sucking disc manner in the use process, so that the friction force is improved, and the anti-slip effect is further realized.
Detailed Description
The invention discloses a mirror surface anti-slip ceramic tile and a production process thereof, which not only have the high-brightness and high-refraction effect like a mirror surface, but also have excellent anti-slip effect.
The invention provides a mirror surface anti-slip ceramic tile, which is sequentially provided with a basic green body layer, an optimized green body layer, a ground glaze layer, a pattern layer and a surface glaze layer.
The invention also provides a production process of the mirror surface anti-slip ceramic tile, which comprises the following steps:
(1) Taking raw materials, which comprise: 19-23 parts by weight of kaolin, 20-26 parts by weight of feldspar, 20-25 parts by weight of silica sand, 10-15 parts by weight of talcum, 3-5 parts by weight of bentonite, 10-12 parts by weight of water abrasive and 3-5 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 15-18 parts by weight of kaolin, 18-23 parts by weight of feldspar, 10-13 parts by weight of silica sand, 8-10 parts by weight of talcum, 3-5 parts by weight of bentonite and 1-3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking 13-15 parts by weight of diatomite particles and 15-18 parts by weight of quartz sand particles as raw materials, mixing, wet grinding, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with a 60-mesh, 80-mesh and 100-mesh sieve to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, distributing the raw materials A on the basic blank layer, uniformly scattering the raw materials B among the raw materials A in the distribution process, and pressing to obtain an optimized blank layer;
(5) Applying ground glaze and spraying ink;
(6) Applying surface glaze;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
Preferably, the diatomite particles and the quartz sand particles in the step (2) have particle diameters of 20-100 μm.
Preferably, the optimized blank layer accounts for 20-25% of the total height of the two blank layers.
Preferably, the arrangement mode of the uniform scattering of the raw material B is that the raw material B is uniformly scattered in sequence according to the order of 60 meshes, 80 meshes and 100 meshes.
Preferably, the raw material B has a 60 mesh, 80 mesh and 100 mesh ratio of 1:1:1.
Preferably, the base glaze comprises a base glaze, diatomite particles and quartz particles, and the proportion is preferably that of the base glaze 20: diatomite particles 2-3: quartz particles 3-4.
Preferably, the particle size of the diatomite particles and the quartz particles of the ground coat is 20-40 mu m.
Preferably, the overglaze comprises mirror frit, diatomite particles, quartz particles and titanium dioxide particles, and the proportion is preferably mirror frit 20, diatomite particles 0.5-2, quartz particles 3-5 and titanium dioxide particles 2-3.
Preferably, the particle size of diatomite particles, quartz particles and titanium dioxide particles of the overglaze is 0.1-18 mu m.
Wherein the chemical components of the basic raw materials comprise Na2O, K2O, siO2, B2O3, zrO2, tiO2 and AL 2 O 3 Li2O, and the like.
The chemical components of the raw material A comprise Na2O, K2O, B O3, zrO2 and AL 2 O 3 Li2O, and the like.
The others described in the above raw material composition are other conventional, existing raw materials applied in the art.
The agglomeration means that the raw material B is uniformly mixed into the raw material A, the particle sizes of the raw material B and the raw material A are kept similar in a state of keeping humidity, namely in a state of distributing, better mixing is achieved, after firing, the raw material B can achieve effective pores good for water storage, good sucking disc effect can be achieved through water vapor introduced into the glaze, and anti-slip effect is improved.
And by utilizing the effect of the ground glaze and the overglaze effective factors of diatomite and quartz, the pores from large to small are formed from bottom to top, and the deep adsorption anti-skid capability can be realized.
The base primer is a conventional primer in the prior art and is not described in detail herein.
The mirror glaze is also a mirror glaze used in the prior art and is conventional in the art, such as alumina PG80F ceramic glaze commercially available, model PG70/HTM30/SRN70, comprising AL 2 O 3 Na2O, etc.
In the preparation of the glaze, the effective components are added, the body of the ceramic tile is provided with the capillary channel, part of green bricks start to the surface layer overglaze, the suction holes like a cone shape can be formed, the bottom holes are large, the moisture of the ceramic tile capillary holes is effectively kept, and therefore, in the use process, the suction disc adsorbs the vamp, and the anti-slip effect is formed.
Furthermore, the effective molecular grain size of the overglaze is small, the formed pores are small, high hardness can be maintained, effective moisture can enter the capillary pores, impurities are prevented from entering, and good reflection effect can be maintained, so that the surface brightness is enough, and the ornamental effect of the mirror surface is maintained.
DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION
A production process of a mirror surface anti-slip ceramic tile comprises the following steps:
(1) Taking raw materials, which comprise: 19-23 parts by weight of kaolin, 20-26 parts by weight of feldspar, 20-25 parts by weight of silica sand, 10-15 parts by weight of talcum, 3-5 parts by weight of bentonite, 10-12 parts by weight of water abrasive and 3-5 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 15-18 parts by weight of kaolin, 18-23 parts by weight of feldspar, 10-13 parts by weight of silica sand, 8-10 parts by weight of talcum, 3-5 parts by weight of bentonite and 1-3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking 13-15 parts by weight of diatomite particles and 15-18 parts by weight of quartz sand particles, wherein the particle sizes of the particles are 20-100 mu m, mixing, wet grinding, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with a 60-mesh, 80-mesh and 100-mesh sieve to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, uniformly distributing the raw materials A on the basic blank layer, uniformly distributing the raw materials B among the raw materials A in the distribution process, sequentially uniformly distributing the raw materials according to the order of 60 meshes, 80 meshes and 100 meshes, and pressing to obtain an optimized blank layer;
optimizing the blank layer to be 20-25% of the total height of the two blank layers;
the weight ratio of 60 meshes, 80 meshes and 100 meshes of the raw material B is 1:1:1;
(5) Applying ground glaze and spraying ink;
the ground coat comprises a basic ground coat, diatomite particles and quartz particles, wherein the particle sizes of the particles are 20-40 mu m;
(6) Applying surface glaze;
the overglaze comprises mirror glaze, diatomite particles, quartz particles and titanium dioxide particles, wherein the particle size of the particles is 0.1-18 mu m;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
Example 1
A production process of a mirror surface anti-slip ceramic tile comprises the following steps:
(1) Taking raw materials, which comprise: 19 parts by weight of kaolin, 20 parts by weight of feldspar, 20 parts by weight of silica sand, 10 parts by weight of talcum, 3 parts by weight of bentonite, 10 parts by weight of water abrasive and 3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 15 parts by weight of kaolin, 18 parts by weight of feldspar, 10 parts by weight of silica sand, 8 parts by weight of talcum, 3 parts by weight of bentonite and 1 part by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing to obtain a raw material A for later use;
taking 13 parts by weight of diatomite particles and 15 parts by weight of quartz sand particles, which are 50-80 mu m in particle size, mixing, wet-milling, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with 60-mesh, 80-mesh and 100-mesh sieves to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, uniformly distributing the raw materials A on the basic blank layer, uniformly distributing the raw materials B among the raw materials A in the distribution process, sequentially uniformly distributing the raw materials according to the order of 60 meshes, 80 meshes and 100 meshes, and pressing to obtain an optimized blank layer;
optimizing the blank layer to account for 20% of the total height of the two blank layers;
the weight ratio of 60 meshes, 80 meshes and 100 meshes of the raw material B is 1:1:1;
(5) Applying ground glaze and spraying ink;
the ground coat comprises a basic ground coat, diatomite particles and quartz particles, wherein the particle sizes of the particles are 30-32 mu m;
(6) Applying surface glaze;
the overglaze comprises mirror glaze, diatomite particles, quartz particles and titanium dioxide particles, wherein the particle size of the particles is 3-5 mu m;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
Example 2
A production process of a mirror surface anti-slip ceramic tile comprises the following steps:
(1) Taking raw materials, which comprise: 23 parts by weight of kaolin, 26 parts by weight of feldspar, 25 parts by weight of silica sand, 15 parts by weight of talcum, 5 parts by weight of bentonite, 12 parts by weight of water abrasive and 5 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 18 parts by weight of kaolin, 23 parts by weight of feldspar, 13 parts by weight of silica sand, 10 parts by weight of talcum, 5 parts by weight of bentonite and 3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking 15 parts by weight of diatomite particles and 18 parts by weight of quartz sand particles, wherein the particle sizes of the particles are 40-70 mu m, mixing, wet milling, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with 60-mesh, 80-mesh and 100-mesh sieves to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, uniformly distributing the raw materials A on the basic blank layer, uniformly distributing the raw materials B among the raw materials A in the distribution process, sequentially uniformly distributing the raw materials according to the order of 60 meshes, 80 meshes and 100 meshes, and pressing to obtain an optimized blank layer;
optimizing the blank layer to account for 25% of the total height of the two blank layers;
the weight ratio of 60 meshes, 80 meshes and 100 meshes of the raw material B is 1:1:1;
(5) Applying ground glaze and spraying ink;
the ground coat comprises a basic ground coat, diatomite particles and quartz particles, wherein the particle sizes of the particles are 30-32 mu m;
(6) Applying surface glaze;
the overglaze comprises mirror glaze, diatomite particles, quartz particles and titanium dioxide particles, wherein the particle size of the particles is 3-5 mu m;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
Example 3
A production process of a mirror surface anti-slip ceramic tile comprises the following steps:
(1) Taking raw materials, which comprise: 21 parts by weight of kaolin, 24 parts by weight of feldspar, 22 parts by weight of silica sand, 13 parts by weight of talcum, 4 parts by weight of bentonite, 11 parts by weight of water abrasive and 4 parts by weight of other materials are mixed, ball-milled, slurried, deironized, powder sprayed and aged to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 16 parts by weight of kaolin, 20 parts by weight of feldspar, 12 parts by weight of silica sand, 9 parts by weight of talcum, 4 parts by weight of bentonite and 2 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking 14 parts by weight of diatomite particles and 17 parts by weight of quartz sand particles, which are 40-50 mu m in particle size, mixing, wet-milling, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with 60-mesh, 80-mesh and 100-mesh sieves to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, uniformly distributing the raw materials A on the basic blank layer, uniformly distributing the raw materials B among the raw materials A in the distribution process, sequentially uniformly distributing the raw materials according to the order of 60 meshes, 80 meshes and 100 meshes, and pressing to obtain an optimized blank layer;
the optimized blank layer accounts for 23% of the total height of the two blank layers;
the weight ratio of 60 meshes, 80 meshes and 100 meshes of the raw material B is 1:1:1;
(5) Applying ground glaze and spraying ink;
the ground coat comprises a basic ground coat, diatomite particles and quartz particles, wherein the particle sizes of the particles are 30-32 mu m;
(6) Applying surface glaze;
the overglaze comprises mirror glaze, diatomite particles, quartz particles and titanium dioxide particles, wherein the particle size of the particles is 5-6 mu m;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
The above description is provided for the details of the mirror surface anti-slip ceramic tile and the production process thereof, and those skilled in the art will be able to change the specific implementation and application scope according to the ideas of the embodiments of the present invention, so the disclosure should not be construed as limiting the invention.

Claims (5)

1. The production process of the mirror surface anti-slip ceramic tile is characterized by comprising the following steps of:
(1) Taking raw materials, which comprise: 19-23 parts by weight of kaolin, 20-26 parts by weight of feldspar, 20-25 parts by weight of silica sand, 10-15 parts by weight of talcum, 3-5 parts by weight of bentonite, 10-12 parts by weight of water abrasive and 3-5 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removing, powder spraying and ageing to obtain a basic raw material for later use;
(2) Taking raw materials, which comprise: 15-18 parts by weight of kaolin, 18-23 parts by weight of feldspar, 10-13 parts by weight of silica sand, 8-10 parts by weight of talcum, 3-5 parts by weight of bentonite and 1-3 parts by weight of other materials, and mixing, ball milling, slurry discharging, iron removal, powder spraying and ageing are carried out to obtain a raw material A for standby;
taking raw materials: 13-15 parts by weight of diatomite particles with the particle size of 50-100 mu m and 15-18 parts by weight of quartz sand particles with the particle size of 50-100 mu m, mixing, wet grinding, removing iron and impurities, drying, keeping the agglomeration humidity, sieving with a 60-mesh, 80-mesh and 100-mesh sieve to obtain a raw material B, and preserving heat for later use;
(3) Laying a basic raw material, and pressing to obtain a basic green body layer;
(4) Then, distributing the raw materials A on the basic blank layer, uniformly scattering the raw materials B among the raw materials A in the distribution process, and pressing to obtain an optimized blank layer;
(5) Applying ground glaze and spraying ink;
the ground coat comprises a basic ground coat, diatomite particles with the particle size of 20-40 mu m and quartz particles with the particle size of 20-40 mu m;
(6) Applying surface glaze;
the overglaze comprises a mirror glaze, diatomite particles with the particle size of 0.1-18 mu m, quartz particles with the particle size of 0.1-18 mu m and titanium dioxide particles with the particle size of 0.1-18 mu m;
(7) Firing to obtain the mirror surface anti-slip ceramic tile.
2. The process for producing a specular non-slip ceramic tile according to claim 1, wherein said optimal green layer comprises 20-25% of the total two green layers.
3. The process for producing a mirror surface anti-slip ceramic tile according to claim 1, wherein the raw material B is uniformly dispersed in a manner of being uniformly dispersed in order of 60 mesh, 80 mesh, 100 mesh.
4. A process for producing a specular anti-slip ceramic tile according to claim 3, wherein the raw material B has a 60 mesh, 80 mesh, 100 mesh mass ratio of 1:1:1.
5. A mirror surface anti-slip ceramic tile, characterized in that it is manufactured by the production process of the mirror surface anti-slip ceramic tile according to any one of claims 1 to 4, which is sequentially provided with a basic green body layer, an optimized green body layer, a ground glaze layer, a pattern layer and a cover glaze layer.
CN202311114841.0A 2023-08-31 2023-08-31 Mirror surface anti-slip ceramic tile and production process thereof Active CN117164331B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05105559A (en) * 1991-10-22 1993-04-27 Inax Corp Antislip tile and its production
JPH05330895A (en) * 1992-06-03 1993-12-14 Inax Corp Production of antislipping tile
JP2006136689A (en) * 2004-11-11 2006-06-01 Hiroshima Kasei Ltd Antislip member for sole, method of manufacturing antislip sole, antislip sole, and antislip shoes
CN107459334A (en) * 2017-08-30 2017-12-12 常州市绿意管道有限公司 A kind of Antiskid ceramic tile
WO2018032127A1 (en) * 2016-08-15 2018-02-22 广东宏宇新型材料有限公司 Glaze and tile for high-temperature gold-colored glazed tile, and manufacturing method thereof
CN111995437A (en) * 2020-09-10 2020-11-27 淄博峰霞陶瓷有限公司 Super wear-resistant anti-skid ceramic tile and preparation method thereof
WO2023021193A1 (en) * 2021-08-19 2023-02-23 Headmade Materials Gmbh Binder component for a feedstock compound for use in a shaping and sintering process, particulate feedstock compound, and shaping and sintering process
CN116177991A (en) * 2023-03-12 2023-05-30 景德镇陶瓷大学 Method for preparing glazed outdoor brick by using various inferior raw materials

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05105559A (en) * 1991-10-22 1993-04-27 Inax Corp Antislip tile and its production
JPH05330895A (en) * 1992-06-03 1993-12-14 Inax Corp Production of antislipping tile
JP2006136689A (en) * 2004-11-11 2006-06-01 Hiroshima Kasei Ltd Antislip member for sole, method of manufacturing antislip sole, antislip sole, and antislip shoes
WO2018032127A1 (en) * 2016-08-15 2018-02-22 广东宏宇新型材料有限公司 Glaze and tile for high-temperature gold-colored glazed tile, and manufacturing method thereof
CN107459334A (en) * 2017-08-30 2017-12-12 常州市绿意管道有限公司 A kind of Antiskid ceramic tile
CN111995437A (en) * 2020-09-10 2020-11-27 淄博峰霞陶瓷有限公司 Super wear-resistant anti-skid ceramic tile and preparation method thereof
WO2023021193A1 (en) * 2021-08-19 2023-02-23 Headmade Materials Gmbh Binder component for a feedstock compound for use in a shaping and sintering process, particulate feedstock compound, and shaping and sintering process
CN116177991A (en) * 2023-03-12 2023-05-30 景德镇陶瓷大学 Method for preparing glazed outdoor brick by using various inferior raw materials

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