CN116948523B - 一种uv树脂组合物及其应用 - Google Patents
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Abstract
本发明涉及涂层领域,公开了一种UV树脂组合物及其应用。所述UV树脂组合物中含有化合物1与化合物2,所述化合物1为含有可聚合基团的梯形结构的化合物;所述化合物2为可聚合基团修饰的纳米金属氧化锆粒子。该涂层用于柔性显示器表层,起到提高出光效率和保护显示器的作用。
Description
技术领域
本发明涉及涂层领域,更具体地涉及一种UV树脂组合物及其应用。
背景技术
柔性显示继平板显示后慢慢进入人们的生活,未来会有较大的市场。而相对于非柔性显示表面,表面涂层需要在硬度、耐磨的基础上改善提高弯折性,对此,公告号为CN107207906A的发明专利提供了一种解决方案,使用带有环氧基团的或者丙烯酸基团的硅烷偶联剂在碱性条件下制备无机-有机杂化材料,可以较好的在满足硬度耐磨的基础上,弯折次数大于20w次,达到保护显示器的目的,但出光效率仅为90-91%;针对提高显示器件透过率的解决方案,公告号为WO2020106884A1的专利中使用带有可聚合基团修饰的金属氧化物纳米粒子通过打印后固化的方式,提高涂层的折射率,从而提高器件的透过率,但涂层位于组件内侧,不具备硬度和耐磨的功能。
发明内容
本发明采用的具体方案为:一种UV树脂组合物,所述UV树脂组合物中含有化合物1与化合物2,所述化合物1为含有可聚合基团的梯形结构的化合物;所述梯形结构为含有化学式1的结构;
化学式1:
R1,R2为含有可聚合基团的结构单元;
所述化合物2为有可聚合基团修饰的纳米氧化锆粒子。
所述UV树脂组合物含有:40-90份化合物1;10-50份化合物2;0.1-5份引发剂;0.1-5份流平剂;10-80份溶剂;0-50份单体稀释剂。
所述UV树脂组合物采用刮涂、旋涂的方式在基材表面进行涂布,烘干后UV固化成膜。
所述UV树脂组合物用于柔性显示器表面。
本发明相对于现有技术具有如下有益效果:
本发明提供一种UV树脂组合物及其应用,UV树脂组合物中含有化合物1与化合物2,所述化合物1为含有可聚合基团的梯形结构的化合物,该结构能够满足耐弯折,高硬度高耐磨的要求;化合物2为有可聚合基团的纳米氧化锆粒子,纳米氧化锆粒子能搞提高材料的折射率,从而提高显示器件的出光效率。本发明无机-有机杂化材料和带有聚合功能的氧化锆纳米粒子进行组合,在显示器表层涂布后,同时满足了上述两项要求,简化了工艺制程。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚明了,下面通过具体实施例来描述本发明。但是应该理解,这些描述只是示例性的,而并非要限制本发明的范围。此外,在以下说明中,省略了对公知结构和技术的描述,以避免不必要地混淆本发明的概念。
本发明公开了一种UV树脂组合物,所述UV树脂组合物中含有化合物1与化合物2,所述化合物1为含有可聚合基团的梯形结构的化合物;所述梯形结构为含有化学式1的结构;
化学式1:
R1,R2为含有环氧基团可聚合的功能性结构单元,如:以及含有双键的丙烯酸常见聚合单元。所述化合物2为有可聚合基团的纳米氧化锆粒子。所述化合物2为高温水热法制备的氧化锆纳米粒子,所述氧化锆纳米粒子的粒径<10nm。
所述UV树脂组合物固化后,以重量份计含有:40-90份化合物1;10-50份化合物2;0.1-5份引发剂;0.1-5份流平剂;0-50份单体稀释剂。
所述单体稀释剂为丙烯酸单体、环氧单体稀释剂;丙烯酸单体稀释剂选自沙多玛公司的提供的丙烯酸单体(如SR423,SR238,CD421,TMPTA,DPHA);环氧单体稀释剂选自常州强力新材提供的(如TCM101,TCM201,TCM104))单官能团或者多官能团单体稀释剂。
引发剂为的自由基引发剂和阳离子引发剂,如有机膦诸如联苯(2,4,6-三甲基苯甲酰基)-氧化膦(TPO)、Irgacure 819或Irgacure 184,ITX等;阳离子引发剂为irgacure250,irgacure290等。
流平剂可以选择BYK 331、BYK 377、BYK 378等。
溶剂可以选择PGMEA,PGME,MIBK,根据涂布效果选择合适的比例。
本发明中的UV树脂组合物添加抗指纹助剂,如KY-1203,KY-1271,RS-90,DIC的DAC-HP助剂以提高表面接触角和抗污能力,所述UV树脂组合物固化后,以重量份计含有抗指纹助剂的份数为0.1-2份。
所述树脂组合物混配方法为将上述树脂、助剂、引发剂、溶剂等按照一定比例进行称量后,采用物理混合的方法混合均匀即可。
所述UV树脂组合物采用刮涂、旋涂的方式在基材表面进行涂布,烘干后UV固化成膜。所述UV树脂组合物用于柔性显示器表面,提高出光效率,保护显示器。
化合物1的制备:参考专利CN107207906A进行制备
以取代基为例,合成梯形化合物1(梯形A)
三口瓶中加入碳酸钾0.06g,水13.6g,四氢呋喃40g,室温搅拌30min,加入2-(3,4-环氧环己基)乙基三甲氧基硅烷30g,室温搅拌72h后,水洗真空移除溶剂,得到树脂A,分子量Mw为7200,Pd=2.0;
以3-(甲基丙烯酰氧基)丙基三甲氧基硅烷为原料,制备梯形化合物2(梯形B)
三口瓶中加入3-(甲基丙烯酰氧基)丙基三甲氧基硅烷30g,四氢呋喃40ml,水15g,升温至40-50℃,加入氨水1-2滴继续搅拌6h,水洗,干燥,真空移除溶剂,得到无色粘稠树脂B,分子量Mn=3500,Pd=1.9。
制备化合物2
参考专利:CN103328374A进行聚合基团可修饰纳米氧化锆粒子的制备
丙烯酸类纳米氧化锆粒子C
氮气保护下,在三口瓶中加入30ml苄醇和0.08ml水,搅拌30min后,N2保护下加入4ml异丙醇锆,高速搅拌4h至澄清溶液,转入高压釜中,15min加热至250℃,之后每3min升温15℃至325℃,冷却至室温,离心得到纳米氧化锆晶体。
纳米氧化锆晶体用1N的盐酸浸泡1h过滤洗至中性,加入KH570(3-(甲基丙烯酰氧基)丙基三甲氧基硅烷),质量比为3:1,80-150℃反应2-3h,离心处理,干燥得到丙烯酸修饰的纳米氧化锆粒子C,粒径5nm。
相同的方案用KH560制备含有环氧结构的纳米二氧化锆粒子D。
纳米氧化锆晶体用1N的盐酸浸泡1h过滤洗至中性,加入KH560(3-(2,3-环氧丙氧)丙基三甲氧基硅烷),质量比为3:1,80-150℃反应2-3h,离心处理,干燥得到环氧基团修饰的纳米氧化锆粒子D,粒径5nm。
UV组合物的制备
按照下述表格中记载的份数进行称量测试,得到产品:
调配比例:
测试方法:
按照表格中的比例进行调配,涂布与PET基材上,经过100℃*1min烘烤,之后1000mw/s进行UV固化2s,得到平整的涂层,进行测试;
硬度:铅笔硬度测试仪
耐磨:往复摩擦测试仪,2cm*2cm,#0000钢丝绒,1000次,V表示涂层外观无变化,满足要求,X表示涂层外观有划痕;
透过率:ULTRASCAN VIS
弯折次数:弯折测试机,内弯半径为1.5mm,弯折次数为200000次,V表示满足要求无裂痕,X表示有涂层裂痕或者涂层爆裂;
涂布后测试数据如下:
实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | |
硬度: | 4H | 4H | 4H | 5H | H |
耐磨: | V | V | V | V | X |
透过率: | 97% | 98% | 97% | 90% | 99% |
弯折次数: | V | V | V | V | X |
从实验数据来看,同时添加化合物1和化合物2的树脂和单独添加一种相比,性能更优。本发明采用可修饰的纳米氧化锆粒子和无机-有机杂化材料配成UV组合物,固化后同时达到提高出光效率和保护柔性显示器的目的。
以上解释说明仅为本发明的一种具体实施方式,但本发明的具体保护范围不仅限以上解释说明,任何在本发明揭露的技术思路范围内,及根据本发明的技术方案加以简单地替换或改变,都应在本发明的保护范围之内。
Claims (3)
1.一种UV树脂组合物,其特征在于,按重量份计,所述UV树脂组合物组成为:80份梯形化合物、20份氧化锆粒子、2份光引发剂819、1份抗指纹助剂KY-1271、1份BYK-378、80份PGMEA溶剂;
所述梯形化合物的制备方法为:三口瓶中加入3-(甲基丙烯酰氧基)丙基三甲氧基硅烷30g,四氢呋喃40ml,水15g,升温至40-50℃,加入氨水1-2滴继续搅拌6h,水洗,干燥,真空移除溶剂,得到无色粘稠树脂;
所述氧化锆粒子的制备方法为:氮气保护下,在三口瓶中加入30ml苄醇和0.08ml水,搅拌30min后,N2保护下加入4ml异丙醇锆,高速搅拌4h至澄清溶液,转入高压釜中,15min加热至250℃,之后每3min升温15℃至325℃,冷却至室温,离心得到纳米氧化锆晶体;纳米氧化锆晶体用1N的盐酸浸泡1h过滤洗至中性,加入KH570,质量比为3:1,80-150℃反应2-3h,离心处理,干燥得到氧化锆粒子。
2.根据权利要求1所述的UV树脂组合物,其特征在于,所述UV树脂组合物采用刮涂、旋涂的方式在基材表面进行涂布,烘干后UV固化成膜。
3.一种如权利要求1-2任一项的所述UV树脂组合物的应用,其特征在于,所述UV树脂组合物用于柔性显示器表面。
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