CN116751480A - Anti-counterfeiting printing ink - Google Patents

Anti-counterfeiting printing ink Download PDF

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Publication number
CN116751480A
CN116751480A CN202310911019.0A CN202310911019A CN116751480A CN 116751480 A CN116751480 A CN 116751480A CN 202310911019 A CN202310911019 A CN 202310911019A CN 116751480 A CN116751480 A CN 116751480A
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CN
China
Prior art keywords
parts
powder
printing ink
agent
raw materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN202310911019.0A
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Chinese (zh)
Inventor
罗运政
唐德宏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Xinghua Printing Co ltd
Original Assignee
Hefei Xinghua Printing Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Xinghua Printing Co ltd filed Critical Hefei Xinghua Printing Co ltd
Priority to CN202310911019.0A priority Critical patent/CN116751480A/en
Publication of CN116751480A publication Critical patent/CN116751480A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to the technical field of printing ink, and discloses anti-counterfeiting printing ink which is characterized by comprising the following raw materials in percentage by weight: 33-35 parts of modified alkyd resin, 39-41 parts of water-soluble acrylic resin, 4-6 parts of adhesion promoter, 8-10 parts of quartz powder, 7-9 parts of ceramic powder, 42-44 parts of epoxy resin, 24-26 parts of butyrolactone, 5-30 parts of fluorescent rare earth nano particles, 2-4 parts of graphite powder, 3-5 parts of diabase powder, 2-4 parts of talcum powder, 3-5 parts of mica powder, 53-55 parts of propylene oxide butyl ether, 10-35 parts of fluorescent pigment, 44-46 parts of polyglycidyl ether, 5-6 parts of zircon sand, 4-6 parts of plasticizer, 6-8 parts of dispersing agent, 5-7 parts of defoaming agent, 1-15 parts of flatting agent and 2-3 parts of ultraviolet absorbent are homogenized in an organic solvent of propylene oxide butyl ether and polyglycidyl ether, and filling materials such as graphite powder, diabase powder, talcum powder, mica powder, zircon sand and the like are added, so that the wear resistance of the printing ink can be improved.

Description

Anti-counterfeiting printing ink
Technical Field
The invention relates to the technical field of ink, in particular to anti-counterfeiting printing ink.
Background
Printing is a technique of transferring ink to the surfaces of materials such as paper, textiles, plastics, leather and the like by performing procedures such as plate making, ink application, pressurization and the like on originals such as characters, pictures, photos and anti-counterfeiting, and copying the contents of the originals in batches. The printing oil, i.e. the printing ink, is an important material for printing, patterns and characters are displayed on a printing stock through printing or spray painting, and the printing ink comprises main components and auxiliary components which are uniformly mixed and repeatedly rolled to form a viscous colloidal fluid.
Comprises resin, pigment, filler auxiliary agent, organic solvent, etc. The printing device is used for printing books and periodicals, including decorations, architectural decorations, electronic circuit boards and the like. As social demands increase, so too does the variety of inks. The existing printing ink is usually slow in drying speed or poor in adhesive force, and is easy to fall off and wear, so that time and resources are wasted.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides anti-counterfeiting printing ink, and solves the problems of the prior art.
In order to achieve the above purpose, the present invention provides the following technical solutions: the anti-counterfeiting printing ink is characterized by comprising the following raw materials in percentage by weight: 33-35 parts of modified alkyd resin, 39-41 parts of water-soluble acrylic resin, 4-6 parts of adhesion promoter, 8-10 parts of quartz powder, 7-9 parts of ceramic powder, 42-44 parts of epoxy resin, 24-26 parts of butyrolactone, 5-30 parts of fluorescent rare earth nano particles, 2-4 parts of graphite powder, 3-5 parts of diabase powder, 2-4 parts of talcum powder, 3-5 parts of mica powder, 53-55 parts of propylene oxide butyl ether, 10-35 parts of fluorescent pigment, 44-46 parts of polyglycidyl ether, 5-6 parts of zircon sand, 4-6 parts of plasticizer, 6-8 parts of dispersing agent, 5-7 parts of defoaming agent, 1-15 parts of flatting agent and 2-3 parts of ultraviolet absorbent.
Preferably, the preparation method of the anti-counterfeiting printing ink is characterized by comprising the following steps of:
s1, weighing raw materials such as modified alkyd resin, epoxy resin, butyrolactone, water-soluble acrylic resin, epoxypropane butyl ether, polyglycidyl ether and the like, and conveying the raw materials into homogenizing equipment by utilizing a conveying mechanism;
s2, conveying the raw materials entering the homogenizing equipment to be pretreated for 1.2-2.3h at the rotating speed of 2100-3200 rpm of the average equipment;
s3, weighing graphite powder, diabase powder, fluorescent rare earth nano particles, quartz powder, talcum powder, mica powder, ceramic powder and zircon sand, and conveying the weighed materials into a stirring barrel by using a conveying mechanism for uniform stirring;
s4, screening through a 800-900 mesh screen to obtain mixed filling fine powder;
s6, throwing the mixed filling fine powder obtained by screening into homogenizing equipment;
s7, adding the plasticizer, the dispersing agent, the defoaming agent, the ultraviolet absorbent, the adhesion promoter, the fluorescent pigment, the ethanol and the leveling agent into homogenizing equipment, controlling the temperature in the homogenizing equipment at 75-80 ℃ and the rotating speed at 2100-3200 rpm, stirring for 2.5-3h, cooling to 27-30 ℃, standing and standing for 1.5-2h;
s8, filtering the mixed feed liquid after standing, wherein the particle size of the obtained slurry is 10-20 mu m, and adjusting the viscosity according to the requirement.
S9, after the preparation is finished, the materials are put into a tank for storage.
Preferably, the plasticizer is one or more of an epoxidized oil, an epoxidized fatty acid monoester, and an epoxidized tetrahydrophthalate.
Preferably, the dispersing agent is one or a mixture of two of sodium pyrophosphate and sodium hexametaphosphate.
Preferably, the defoamer is one or a mixture of more of polysiloxane, polyether modified silicon, high-carbon alcohol and natural grease.
Preferably, the leveling agent is one or a mixture of more of silicone oil, polydimethylsiloxane and polyether polyester modified organosiloxane.
Preferably, the fluorescent pigment is an organic ultraviolet fluorescent pigment having a conjugated structure macromolecule.
The invention provides anti-counterfeiting printing ink which has the following beneficial effects:
the invention adopts modified alkyd resin and epoxy resin to be homogenized in the organic solvent of epoxypropane butyl ether and polyglycidyl ether, and is added with graphite powder, diabase powder, talcum powder, mica powder, zircon sand and other filling fine materials, so that the wear resistance of the printing ink can be improved, and in addition, fluorescent rare earth nano particles and fluorescent pigment are added, so that the printing anti-counterfeiting function of the printing ink can be realized.
The invention adopts the ultraviolet absorber to prevent a great amount of ultraviolet light harmful to colored objects in solar rays from decomposing and fading color molecules finally through chemical oxidation-reduction, and the method for preventing the harmful ultraviolet light from damaging the color has physical and chemical methods
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention provides a technical scheme that: the anti-counterfeiting printing ink is characterized by comprising the following raw materials in percentage by weight: 33-35 parts of modified alkyd resin, 39-41 parts of water-soluble acrylic resin, 4-6 parts of adhesion promoter, 8-10 parts of quartz powder, 7-9 parts of ceramic powder, 42-44 parts of epoxy resin, 24-26 parts of butyrolactone, 5-30 parts of fluorescent rare earth nano particles, 2-4 parts of graphite powder, 3-5 parts of diabase powder, 2-4 parts of talcum powder, 3-5 parts of mica powder, 53-55 parts of propylene oxide butyl ether, 10-35 parts of fluorescent pigment, 44-46 parts of polyglycidyl ether, 5-6 parts of zircon sand, 4-6 parts of plasticizer, 6-8 parts of dispersing agent, 5-7 parts of defoaming agent, 1-15 parts of flatting agent and 2-3 parts of ultraviolet absorbent.
Further, the preparation method of the anti-counterfeiting printing ink is characterized by comprising the following steps of:
s1, weighing raw materials such as modified alkyd resin, epoxy resin, butyrolactone, water-soluble acrylic resin, epoxypropane butyl ether, polyglycidyl ether and the like, and conveying the raw materials into homogenizing equipment by utilizing a conveying mechanism;
s2, conveying the raw materials entering the homogenizing equipment to be pretreated for 1.2-2.3h at the rotating speed of 2100-3200 rpm of the average equipment;
s3, weighing graphite powder, diabase powder, fluorescent rare earth nano particles, quartz powder, talcum powder, mica powder, ceramic powder and zircon sand, and conveying the weighed materials into a stirring barrel by using a conveying mechanism for uniform stirring;
s4, screening through a 800-900 mesh screen to obtain mixed filling fine powder;
s6, throwing the mixed filling fine powder obtained by screening into homogenizing equipment;
s7, adding the plasticizer, the dispersing agent, the defoaming agent, the ultraviolet absorbent, the adhesion promoter, the fluorescent pigment, the ethanol and the leveling agent into homogenizing equipment, controlling the temperature in the homogenizing equipment at 75-80 ℃ and the rotating speed at 2100-3200 rpm, stirring for 2.5-3h, cooling to 27-30 ℃, standing and standing for 1.5-2h;
s8, filtering the mixed feed liquid after standing, wherein the particle size of the obtained slurry is 10-20 mu m, and adjusting the viscosity according to the requirement.
S9, after the preparation is finished, the materials are put into a tank for storage.
Further, the plasticizer is one or a mixture of epoxidized oil, epoxidized fatty acid monoester and epoxidized tetrahydrophthalate.
Further, the dispersing agent is one or two of sodium pyrophosphate and sodium hexametaphosphate.
Further, the defoamer is one or a mixture of more of polysiloxane, polyether modified silicon, high-carbon alcohol and natural grease.
Further, the leveling agent is one or a mixture of more of silicone oil, polydimethylsiloxane and polyether polyester modified organosiloxane.
Further, the fluorescent pigment is an organic ultraviolet fluorescent pigment with a conjugated structure macromolecule.
It is noted that relational terms such as first and second, and the like are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Moreover, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. The anti-counterfeiting printing ink is characterized by comprising the following raw materials in percentage by weight: 33-35 parts of modified alkyd resin, 39-41 parts of water-soluble acrylic resin, 4-6 parts of adhesion promoter, 8-10 parts of quartz powder, 7-9 parts of ceramic powder, 42-44 parts of epoxy resin, 24-26 parts of butyrolactone, 5-30 parts of fluorescent rare earth nano particles, 2-4 parts of graphite powder, 3-5 parts of diabase powder, 2-4 parts of talcum powder, 3-5 parts of mica powder, 53-55 parts of propylene oxide butyl ether, 10-35 parts of fluorescent pigment, 44-46 parts of polyglycidyl ether, 5-6 parts of zircon sand, 4-6 parts of plasticizer, 6-8 parts of dispersing agent, 5-7 parts of defoaming agent, 1-15 parts of flatting agent and 2-3 parts of ultraviolet absorbent.
2. The preparation method of the anti-counterfeiting printing ink is characterized by comprising the following steps of:
s1, weighing raw materials such as modified alkyd resin, epoxy resin, butyrolactone, water-soluble acrylic resin, epoxypropane butyl ether, polyglycidyl ether and the like, and conveying the raw materials into homogenizing equipment by utilizing a conveying mechanism;
s2, conveying the raw materials entering the homogenizing equipment to be pretreated for 1.2-2.3h at the rotating speed of 2100-3200 rpm of the homogenizing equipment;
s3, weighing graphite powder, diabase powder, fluorescent rare earth nano particles, quartz powder, talcum powder, mica powder, ceramic powder and zircon sand, and conveying the weighed materials into a stirring barrel by using a conveying mechanism for uniform stirring;
s4, screening through a 800-900 mesh screen to obtain mixed filling fine powder;
s6, throwing the mixed filling fine powder obtained by screening into homogenizing equipment;
s7, adding the plasticizer, the dispersing agent, the defoaming agent, the ultraviolet absorbent, the adhesion promoter, the fluorescent pigment, the ethanol and the leveling agent into homogenizing equipment, controlling the temperature in the homogenizing equipment at 75-80 ℃ and the rotating speed at 2100-3200 rpm, stirring for 2.5-3h, cooling to 27-30 ℃, standing and standing for 1.5-2h;
s8, filtering the mixed feed liquid after standing, wherein the particle size of the obtained slurry is 10-20 mu m, and the viscosity is adjusted according to the requirement;
s9, after the preparation is finished, the materials are put into a tank for storage.
3. The anti-counterfeit printing ink of claim 1, wherein: the plasticizer is one or a mixture of more of epoxidized oil, epoxidized fatty acid monoester and epoxidized tetrahydrophthalate.
4. The anti-counterfeit printing ink of claim 1, wherein: the dispersing agent is one or two of sodium pyrophosphate and sodium hexametaphosphate.
5. The anti-counterfeit printing ink of claim 1, wherein: the defoamer is one or a mixture of more of polysiloxane, polyether modified silicon, high-carbon alcohol and natural grease.
6. The anti-counterfeit printing ink of claim 1, wherein: the leveling agent is one or a mixture of more of silicone oil, polydimethylsiloxane and polyether polyester modified organosiloxane.
7. The anti-counterfeit printing ink of claim 1, wherein: the fluorescent pigment is an organic ultraviolet fluorescent pigment with conjugated structure macromolecules.
CN202310911019.0A 2023-07-24 2023-07-24 Anti-counterfeiting printing ink Withdrawn CN116751480A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310911019.0A CN116751480A (en) 2023-07-24 2023-07-24 Anti-counterfeiting printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310911019.0A CN116751480A (en) 2023-07-24 2023-07-24 Anti-counterfeiting printing ink

Publications (1)

Publication Number Publication Date
CN116751480A true CN116751480A (en) 2023-09-15

Family

ID=87953351

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310911019.0A Withdrawn CN116751480A (en) 2023-07-24 2023-07-24 Anti-counterfeiting printing ink

Country Status (1)

Country Link
CN (1) CN116751480A (en)

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Application publication date: 20230915