CN116535170B - Preparation method of novel polymer surface mortar - Google Patents
Preparation method of novel polymer surface mortar Download PDFInfo
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- CN116535170B CN116535170B CN202310818367.3A CN202310818367A CN116535170B CN 116535170 B CN116535170 B CN 116535170B CN 202310818367 A CN202310818367 A CN 202310818367A CN 116535170 B CN116535170 B CN 116535170B
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- 229920000642 polymer Polymers 0.000 title claims abstract description 72
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 238000002156 mixing Methods 0.000 claims abstract description 62
- 239000000839 emulsion Substances 0.000 claims abstract description 60
- 238000003756 stirring Methods 0.000 claims abstract description 57
- 229920002748 Basalt fiber Polymers 0.000 claims abstract description 43
- 239000000178 monomer Substances 0.000 claims abstract description 34
- 229920000728 polyester Polymers 0.000 claims abstract description 25
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- 239000010881 fly ash Substances 0.000 claims abstract description 23
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims abstract description 21
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910000077 silane Inorganic materials 0.000 claims abstract description 20
- 230000000977 initiatory effect Effects 0.000 claims abstract description 19
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims abstract description 17
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 17
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004568 cement Substances 0.000 claims abstract description 11
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 claims abstract description 10
- UGVRJVHOJNYEHR-UHFFFAOYSA-N 4-chlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=CC=C1 UGVRJVHOJNYEHR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 23
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- IVKNZCBNXPYYKL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 IVKNZCBNXPYYKL-UHFFFAOYSA-N 0.000 claims description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000011344 liquid material Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011398 Portland cement Substances 0.000 claims description 14
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 13
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 16
- 230000007797 corrosion Effects 0.000 abstract description 16
- 238000006116 polymerization reaction Methods 0.000 abstract description 5
- 230000001804 emulsifying effect Effects 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 13
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 5
- 238000005457 optimization Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
- C04B24/42—Organo-silicon compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymerisation Methods In General (AREA)
- Silicon Polymers (AREA)
Abstract
The invention discloses a preparation method of novel polymer surface mortar, and relates to the technical field of building materials. When the novel polymer plastering mortar is prepared, 3-aminopropyl trimethoxy silane and 4-chlorobenzophenone are reacted to prepare photoinitiated silane, and polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane are reacted to prepare photoinitiated organosilicon polyester; preparing modified basalt fibers by reacting basalt fibers with photoinitiated organic silicon polyester; emulsifying soft monomer, hard monomer and allyl triethoxysilane as monomers with an emulsifier, initiating polymerization with an initiator to prepare polymer emulsion, and reacting to prepare the polymer emulsion; mixing and stirring cement, modified basalt fiber, fly ash, polymer emulsion and pure water to obtain the novel polymer plastering mortar. The novel polymer plastering mortar prepared by the invention has good bonding property and corrosion resistance.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a preparation method of novel polymer plastering mortar.
Background
The mortar which is smeared on the surfaces of buildings, building components and base materials and has the function of protecting the base layer and meeting the use requirement is called as plastering mortar. The plastering mortar can be classified into general plastering mortar, decorative mortar and plastering mortar having some special functions according to different functions of the plastering mortar. The plastering mortar is required to have good workability, is easy to smear into a uniform and flat thin layer, and is convenient for construction; the adhesive force is high, so that the adhesive is not easy to crack or fall off; when the mortar is in a humid environment or in a part which is easy to be acted by external force, the mortar should also have higher water resistance and strength.
With the acceleration of the urban process, the building house industry is vigorously developed, and the building industry still keeps a high growth speed. Thus, the demands and requirements of the construction engineering for the finishing mortar are increasing. For wet sites, coastal areas, buildings are prone to corrosion. Therefore, there is a need to develop a finishing mortar having good corrosion resistance to protect the building.
Disclosure of Invention
The invention aims to provide a preparation method of novel polymer surface mortar, which aims to solve the problems in the prior art.
In order to solve the technical problems, the invention provides the following technical scheme:
the novel polymer plastering mortar mainly comprises the following components in parts by mass: 20-30 parts of cement, 10-15 parts of modified basalt fiber, 10-15 parts of fly ash, 10-15 parts of polymer emulsion and 5-7 parts of pure water.
As optimization, the modified basalt fiber is prepared by basalt fiber and photoinitiated organic silicon polyester reaction.
As optimization, the photoinitiated organic silicon polyester is prepared by reacting 3-aminopropyl trimethoxy silane with 4-chlorobenzophenone to prepare photoinitiated silane, and the photoinitiated silane is prepared by reacting polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane.
The polymer emulsion is prepared by using soft monomer, hard monomer and allyl triethoxysilane as monomers, emulsifying the monomers by using an emulsifying agent, and initiating polymerization by using an initiator.
The preparation method of the novel polymer plastering mortar mainly comprises the following preparation steps:
(1) Uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.1-0.2 in a nitrogen atmosphere, adding p-toluenesulfonic acid which is 0.004-0.006 times of the mass of the polyethylene glycol PEG400, stirring at 90-100 ℃ for reaction for 20-30 min at 300-500 r/min, heating to 150-160 ℃ for continuous stirring for reaction for 6-8 h, cooling to room temperature, and standing at 50-60 ℃ for 3-4 h at 10-20 Pa to obtain photoinitiated organosilicon polyester;
(2) Uniformly mixing basalt fibers, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to a mass ratio of 1:2-3:12-16:4-6, stirring for 60-80 min at 20-30 ℃ and 600-800 r/min, filtering, washing for 3-5 times with absolute ethyl alcohol, and drying for 6-8 h at 60-70 ℃ to obtain modified basalt fibers;
(3) Uniformly mixing a soft monomer, a hard monomer, allyl triethoxysilane, an emulsifier and pure water according to a mass ratio of 1:1:0.2-0.3:0.06-0.08:4-5 to prepare a monomer emulsion; uniformly mixing a thermal initiator and pure water according to a mass ratio of 1:30-40 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:20-30 to prepare an emulsion base solution, dropwise adding a monomer emulsion with a mass 1.2-1.4 times of that of the emulsion base solution and a heat initiation solution with a mass 0.6-0.7 times of that of the emulsion base solution at a uniform speed within 50-60 min under the stirring condition of 300-500 r/min at the temperature of 80-85 ℃, keeping the temperature unchanged for continuous reaction for 2-3 hours after the dropwise adding, and concentrating at the temperature of 30-40 ℃ at the pressure of 50-100 Pa until the water content is 40-42%, thus preparing a polymer emulsion;
(4) Weighing 20-30 parts of cement, 10-15 parts of modified basalt fiber, 10-15 parts of fly ash, 10-15 parts of polymer emulsion and 5-7 parts of pure water according to parts by mass; mixing cement, modified basalt fiber and fly ash uniformly to prepare powder, mixing polymer emulsion and pure water uniformly to prepare liquid material, pouring the dry material into the liquid material, and stirring at 20-30 ℃ for 3-4 min at 600-800 r/min to obtain the novel polymer plastering mortar.
As an optimization, the preparation method of the photoinitiated silane in the step (1) comprises the following steps: uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:8-10, adding triethylamine with the mass of 0.04-0.06 times that of the 3-aminopropyl trimethoxy silane, stirring for 3-5 min at the temperature of 0-5 ℃ and 300-500 r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar weight of 3-aminopropyl trimethoxy silane, stirring for 50-60 min at the temperature of 0-5 ℃ and 300-500 r/min, standing for 20-24 h at room temperature, and drying for 6-8 h at the temperature of 10-20 ℃ and 50-100 Pa.
And (3) optimally, the basalt fiber in the step (2) has the diameter of 10-15 mu m and the length of 8-12 mm.
As optimization, the soft monomer in the step (3) is one or more of ethyl acrylate, butyl acrylate and isooctyl acrylate; the hard monomer is one or more of vinyl acetate, styrene, acrylonitrile, methyl methacrylate and acrylamide; the emulsifier is OP-10 emulsifier; the thermal initiator is ammonium persulfate; the water content refers to the mass fraction of pure water in the polymer emulsion.
As optimization, the cement in the step (4) is PO42.5 ordinary Portland cement; the fly ash is 800-1000 meshes of fly ash.
Compared with the prior art, the invention has the following beneficial effects:
when the novel polymer plastering mortar is prepared, basalt fibers and photoinitiated organic silicon polyester are reacted to prepare modified basalt fibers; mixing and stirring cement, modified basalt fiber, fly ash, polymer emulsion and pure water to obtain the novel polymer plastering mortar.
Firstly, 3-aminopropyl trimethoxy silane and 4-chlorobenzophenone react to prepare photoinitiated silane, polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane react to prepare photoinitiated organosilicon polyester, the photoinitiated organosilicon polyester has photoinitiated performance, photoinitiated groups can initiate polymerization of free radical unsaturated bonds under irradiation of sunlight or artificial ultraviolet lamps to form a crosslinked network, so that the bonding performance and corrosion resistance are improved, the photoinitiated organosilicon polyester is used for modifying basalt fibers, the dispersibility is improved, hydrolysis of the photoinitiated organosilicon polyester can be caused under the conditions of hydration and heating of cement or insolation, a large number of silicon hydroxyl chain segments can be combined with inorganic components, the structure is more compact and firm, and the bonding performance and corrosion resistance are further improved.
Secondly, emulsifying soft monomers, hard monomers and allyl triethoxysilane serving as monomers by using an emulsifying agent, initiating polymerization by using an initiator to prepare polymer emulsion, and reacting to prepare the polymer emulsion; allyl triethoxysilane is added in the preparation process of the polymer emulsion, so that the polymer emulsion and an inorganic interface can be well combined with each other, and the combined inorganic components are subjected to surface coverage and hydrophobic protection, so that the adhesive property and the corrosion resistance are improved.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
In order to more clearly illustrate the method provided by the invention, the following examples are used for describing the detailed description, and the test methods of each index of the novel polymer finishing mortar prepared in the following examples are as follows:
adhesive properties: the materials obtained in each example and comparative example are coated on a test board and are exposed to sunlight for 5min, then are placed in a room for standing for 24h to be solidified into a paint film with the thickness of 0.5mm, according to the specification of GBT 9755-2014, a scribing test adhesion method is adopted, a single-blade cutter is used for horizontally cutting 3 channels on the test board coated with the paint film, then the same cutting is carried out for 3 channels in the direction vertical to the horizontal direction, the distance between each channel is 3mm, the grid number is 4, then an adhesive tape tearing experiment is carried out, and the adhesion grade is recorded.
Corrosion resistance: the materials obtained in each example and comparative example are coated on a polytetrafluoroethylene plate and are exposed to sunlight for 5min, then are placed indoors for standing for 24h to be solidified into a paint film with the thickness of 0.5mm, the paint film is immersed in hydrochloric acid solution with the PH of 1 after being stripped, and then is placed at the temperature of 30 ℃ for 72h, and the materials are weighed again after being washed and dried, and the quality difference before and after calculation is recorded as the corrosion amount.
Example 1
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:8, adding triethylamine with the mass of 0.04 times that of the 3-aminopropyl trimethoxy silane, stirring at 0 ℃ for 5min at 300r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar weight as the 3-aminopropyl trimethoxy silane, stirring at 0 ℃ for 60min at 300r/min, standing at room temperature for 24h, and drying at 10 ℃ for 8h at 50Pa to obtain photoinitiated silane; uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.1 in a nitrogen atmosphere, adding p-toluenesulfonic acid with the mass of 0.004 times that of the polyethylene glycol PEG400, stirring at 90 ℃ and 300r/min for reaction for 30min, heating to 150 ℃ for continuous stirring for reaction for 8h, cooling to room temperature, and standing at 50 ℃ and 10Pa for 4h to obtain photoinitiated organic silicon polyester;
(2) Uniformly mixing basalt fiber with the diameter of 10 mu m and the length of 8mm, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to the mass ratio of 1:2:12:4, stirring for 80min at 20 ℃ and 600r/min, filtering, washing 3 times with absolute ethyl alcohol, and drying at 60 ℃ for 8 hours to obtain modified basalt fiber;
(3) Uniformly mixing ethyl acrylate, methyl methacrylate, allyl triethoxysilane, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.2:0.06:4 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:300 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:20 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.2 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.6 times of that of the emulsified base solution at a uniform speed within 50min under the stirring condition of 300r/min at the temperature of 80 ℃, keeping the temperature unchanged for continuous reaction for 3 hours after the dropwise adding, and concentrating at the temperature of 30 ℃ under the pressure of 50Pa until the water content is 40%, thus preparing polymer emulsion;
(4) Weighing 20 parts of PO42.5 ordinary Portland cement, 10 parts of modified basalt fiber, 10 parts of 800-mesh fly ash, 10 parts of polymer emulsion and 5 parts of pure water according to parts by mass; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 20 ℃ and 600r/min for 4min to obtain the novel polymer plastering mortar.
Example 2
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:9, adding triethylamine with the mass of 0.05 times that of the 3-aminopropyl trimethoxy silane, stirring at 2.5 ℃ for 4min at 400r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar amount of the 3-aminopropyl trimethoxy silane, stirring at 2.5 ℃ for 55min at 400r/min, standing at room temperature for 22h, and drying at 15 ℃ at 75Pa for 7h to obtain photoinitiated silane; uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.15 in a nitrogen atmosphere, adding p-toluenesulfonic acid with the mass of 0.005 times that of the polyethylene glycol PEG400, stirring at 95 ℃ and 400r/min for reaction for 25min, heating to 155 ℃ for continuous stirring for reaction for 7h, cooling to room temperature, and standing at 55 ℃ and 15Pa for 3.5h to obtain photoinitiated organic silicon polyester;
(2) Uniformly mixing basalt fiber with the diameter of 12 mu m and the length of 10mm, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to the mass ratio of 1:2.5:14:5, stirring for 70min at 25 ℃ and 700r/min, filtering, washing for 4 times by using absolute ethyl alcohol, and drying for 7h at 65 ℃ to obtain modified basalt fiber;
(3) Uniformly mixing ethyl acrylate, methyl methacrylate, allyl triethoxysilane, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.25:0.07:4.5 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:35 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:25 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.3 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.65 times of that of the emulsified base solution at a uniform speed within 55min under the stirring condition of 400r/min at the temperature of 82.5 ℃, keeping the temperature unchanged for continuous reaction for 2.5h after the dropwise adding, and concentrating at the temperature of 35 ℃ and under the pressure of 75Pa until the water content is 41%, thereby preparing polymer emulsion;
(4) Weighing 25 parts of PO42.5 ordinary Portland cement, 12 parts of modified basalt fiber, 12 parts of 900-mesh fly ash, 12 parts of polymer emulsion and 6 parts of pure water according to parts by mass; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 25 ℃ and 700r/min for 3.5min to obtain the novel polymer plastering mortar.
Example 3
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:10, adding triethylamine with the mass of 0.06 times that of the 3-aminopropyl trimethoxy silane, stirring at 5 ℃ for 3min at 500r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar weight as the 3-aminopropyl trimethoxy silane, stirring at 5 ℃ for 50min at 500r/min, standing for 20h at room temperature, and drying at 100Pa for 6h at 20 ℃ to obtain photoinitiated silane; uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.2 in a nitrogen atmosphere, adding p-toluenesulfonic acid with the mass of 0.006 times that of the polyethylene glycol PEG400, stirring at 100 ℃ and 500r/min for reaction for 20min, heating to 160 ℃ for continuous stirring for reaction for 6h, cooling to room temperature, and standing at 60 ℃ and 20Pa for 3h to obtain photoinitiated organic silicon polyester;
(2) Uniformly mixing basalt fiber with the diameter of 15 mu m and the length of 12mm, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to the mass ratio of 1:3:16:6, stirring for 60min at 30 ℃ and 800r/min, filtering, washing for 5 times by using absolute ethyl alcohol, and drying for 6h at 70 ℃ to obtain modified basalt fiber;
(3) Uniformly mixing ethyl acrylate, methyl methacrylate, allyl triethoxysilane, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.3:0.08:5 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:40 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:30 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.4 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.7 times of that of the emulsified base solution at a uniform speed within 60 minutes under the stirring condition of 500r/min at the temperature of 85 ℃, keeping the temperature unchanged for continuous reaction for 2 hours after the dropwise adding, and concentrating at the temperature of 40 ℃ under the pressure of 100Pa until the water content is 42%, thus preparing polymer emulsion;
(4) Weighing 30 parts of PO42.5 ordinary Portland cement, 12 parts of modified basalt fiber, 15 parts of 1000-mesh fly ash, 15 parts of polymer emulsion and 7 parts of pure water according to parts by weight; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 30 ℃ and 800r/min for 3min to obtain the novel polymer plastering mortar.
Comparative example 1
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing polyethylene glycol PEG400 and allyltrimethoxysilane according to a molar ratio of 1.5:1.15 in a nitrogen atmosphere, adding p-toluenesulfonic acid with the mass of 0.005 times that of the polyethylene glycol PEG400, stirring at 95 ℃ and 400r/min for reaction for 25min, heating to 155 ℃ for continuous stirring for reaction for 7h, cooling to room temperature, and standing at 55 ℃ and 15Pa for 3.5h to obtain the organosilicon polyester;
(2) Uniformly mixing basalt fiber with the diameter of 12 mu m and the length of 10mm, organic silicon polyester, absolute ethyl alcohol and pure water according to the mass ratio of 1:2.5:14:5, stirring for 70min at 25 ℃ and 700r/min, filtering, washing for 4 times with absolute ethyl alcohol, and drying for 7h at 65 ℃ to obtain modified basalt fiber;
(3) Uniformly mixing ethyl acrylate, methyl methacrylate, allyl triethoxysilane, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.25:0.07:4.5 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:35 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:25 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.3 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.65 times of that of the emulsified base solution at a uniform speed within 55min under the stirring condition of 400r/min at the temperature of 82.5 ℃, keeping the temperature unchanged for continuous reaction for 2.5h after the dropwise adding, and concentrating at the temperature of 35 ℃ and under the pressure of 75Pa until the water content is 41%, thereby preparing polymer emulsion;
(4) Weighing 25 parts of PO42.5 ordinary Portland cement, 12 parts of modified basalt fiber, 12 parts of fly ash, 12 parts of polymer emulsion and 6 parts of pure water according to parts by mass; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 25 ℃ and 700r/min for 3.5min to obtain the novel polymer plastering mortar.
Comparative example 2
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing ethyl acrylate, methyl methacrylate, allyl triethoxysilane, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.25:0.07:4.5 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:35 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:25 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.3 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.65 times of that of the emulsified base solution at a uniform speed within 55min under the stirring condition of 400r/min at the temperature of 82.5 ℃, keeping the temperature unchanged for continuous reaction for 2.5h after the dropwise adding, and concentrating at the temperature of 35 ℃ and under the pressure of 75Pa until the water content is 41%, thereby preparing polymer emulsion;
(2) Weighing 25 parts of PO42.5 ordinary Portland cement, 12 parts of basalt fiber, 12 parts of fly ash, 12 parts of polymer emulsion and 6 parts of pure water according to parts by mass; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 25 ℃ and 700r/min for 3.5min to obtain the novel polymer plastering mortar.
Comparative example 3
The preparation method of the novel polymer surface mortar comprises the following preparation steps:
(1) Uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:9, adding triethylamine with the mass of 0.05 times that of the 3-aminopropyl trimethoxy silane, stirring at 2.5 ℃ for 4min at 400r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar amount of the 3-aminopropyl trimethoxy silane, stirring at 2.5 ℃ for 55min at 400r/min, standing at room temperature for 22h, and drying at 15 ℃ at 75Pa for 7h to obtain photoinitiated silane; uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.15 in a nitrogen atmosphere, adding p-toluenesulfonic acid with the mass of 0.005 times that of the polyethylene glycol PEG400, stirring at 95 ℃ and 400r/min for reaction for 25min, heating to 155 ℃ for continuous stirring for reaction for 7h, cooling to room temperature, and standing at 55 ℃ and 15Pa for 3.5h to obtain photoinitiated organic silicon polyester;
(2) Uniformly mixing basalt fiber with the diameter of 12 mu m and the length of 10mm, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to the mass ratio of 1:2.5:14:5, stirring for 70min at 25 ℃ and 700r/min, filtering, washing for 4 times by using absolute ethyl alcohol, and drying for 7h at 65 ℃ to obtain modified basalt fiber;
(3) Uniformly mixing ethyl acrylate, methyl methacrylate, OP-10 emulsifier and pure water according to the mass ratio of 1:1:0.07:4.5 to prepare monomer emulsion; uniformly mixing ammonium persulfate and pure water according to a mass ratio of 1:35 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:25 to prepare an emulsified base solution, dropwise adding monomer emulsion with the mass 1.3 times of that of the emulsified base solution and a thermal initiation solution with the mass 0.65 times of that of the emulsified base solution at a uniform speed within 55min under the stirring condition of 400r/min at the temperature of 82.5 ℃, keeping the temperature unchanged for continuous reaction for 2.5h after the dropwise adding, and concentrating at the temperature of 35 ℃ and under the pressure of 75Pa until the water content is 41%, thereby preparing polymer emulsion;
(4) Weighing 25 parts of PO42.5 ordinary Portland cement, 12 parts of modified basalt fiber, 12 parts of fly ash, 12 parts of polymer emulsion and 6 parts of pure water according to parts by mass; uniformly mixing PO42.5 ordinary Portland cement, modified basalt fiber and fly ash to prepare powder, uniformly mixing polymer emulsion and pure water to prepare liquid material, pouring the dry material into the liquid material, and stirring at 25 ℃ and 700r/min for 3.5min to obtain the novel polymer plastering mortar.
Effect example
The following table 1 shows the results of performance analysis of the adhesion performance and corrosion resistance performance of the novel polymer coating mortars of examples 1 to 3 and comparative examples 1 to 4 according to the present invention.
TABLE 1
From the comparison of experimental data of examples 1-3 and comparative examples 1-4 in Table 1, it can be found that the novel polymer plastering mortar prepared by the invention has good bonding performance and corrosion resistance.
From comparison of experimental data of examples 1, 2 and 3 and comparative example 1, examples 1, 2 and 3 have high adhesive force and low corrosion amount compared with comparative example 1, which shows that photoinitiated silane is added to introduce photoinitiated groups, and sunlight or artificial ultraviolet lamp irradiation can cause the photoinitiated groups to initiate polymerization of free radical unsaturated bonds to form a crosslinked network during coating use, so that the adhesive property and corrosion resistance are improved; from comparison of experimental data of examples 1, 2 and 3 and comparative example 2, the examples 1, 2 and 3 have high adhesive force and low corrosion amount compared with comparative example 2, which shows that the photoinitiated organosilicon polyester is used for modifying basalt fiber, so that dispersibility is improved, photoinitiated performance is achieved, hydrolysis of the photoinitiated organosilicon polyester can be caused under the conditions of hydration and heating of cement or sun exposure, a large number of silicon hydroxyl chain segments can be formed to be combined with inorganic components, and the structure is more compact and firm, so that bonding performance and corrosion resistance are improved; from comparison of experimental data of examples 1, 2 and 3 and comparative example 3, the examples 1, 2 and 3 have high adhesive force and low corrosion amount compared with comparative example 3, which indicates that the allyl triethoxysilane is added in the preparation process of the polymer emulsion, so that the polymer emulsion and an inorganic interface can be well combined with each other, and the combined inorganic composition is subjected to surface coverage and hydrophobic protection, so that the adhesive property and the corrosion resistance are improved.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (5)
1. The preparation method of the novel polymer plastering mortar is characterized by mainly comprising the following preparation steps:
(1) Uniformly mixing polyethylene glycol PEG400, allyl trimethoxy silane and photoinitiated silane according to a molar ratio of 1.5:1:0.1-0.2 in a nitrogen atmosphere, adding p-toluenesulfonic acid which is 0.004-0.006 times of the mass of the polyethylene glycol PEG400, stirring at 90-100 ℃ for reaction for 20-30 min at 300-500 r/min, heating to 150-160 ℃ for continuous stirring for reaction for 6-8 h, cooling to room temperature, and standing at 50-60 ℃ for 3-4 h at 10-20 Pa to obtain photoinitiated organosilicon polyester;
(2) Uniformly mixing basalt fibers, photoinitiated organic silicon polyester, absolute ethyl alcohol and pure water according to a mass ratio of 1:2-3:12-16:4-6, stirring for 60-80 min at 20-30 ℃ and 600-800 r/min, filtering, washing for 3-5 times with absolute ethyl alcohol, and drying for 6-8 h at 60-70 ℃ to obtain modified basalt fibers;
(3) Uniformly mixing a soft monomer, a hard monomer, allyl triethoxysilane, an emulsifier and pure water according to a mass ratio of 1:1:0.2-0.3:0.06-0.08:4-5 to prepare a monomer emulsion; uniformly mixing a thermal initiator and pure water according to a mass ratio of 1:30-40 to prepare a thermal initiation solution; uniformly mixing an OP-10 emulsifier and pure water according to a mass ratio of 1:20-30 to prepare an emulsion base solution, dropwise adding a monomer emulsion with a mass 1.2-1.4 times of that of the emulsion base solution and a heat initiation solution with a mass 0.6-0.7 times of that of the emulsion base solution at a uniform speed within 50-60 min under the stirring condition of 300-500 r/min at the temperature of 80-85 ℃, keeping the temperature unchanged for continuous reaction for 2-3 hours after the dropwise adding, and concentrating at the temperature of 30-40 ℃ at the pressure of 50-100 Pa until the water content is 40-42%, thus preparing a polymer emulsion;
(4) Weighing 20-30 parts of cement, 10-15 parts of modified basalt fiber, 10-15 parts of fly ash, 10-15 parts of polymer emulsion and 5-7 parts of pure water according to parts by mass; mixing cement, modified basalt fiber and fly ash uniformly to prepare powder, mixing polymer emulsion and pure water uniformly to prepare liquid material, pouring the dry material into the liquid material, and stirring at 20-30 ℃ for 3-4 min at 600-800 r/min to obtain the novel polymer plastering mortar.
2. The method for preparing a novel polymer finishing mortar according to claim 1, wherein the method for preparing photoinitiated silane in step (1) comprises the following steps: uniformly mixing 3-aminopropyl trimethoxy silane and methylene dichloride according to the mass ratio of 1:8-10, adding triethylamine with the mass of 0.04-0.06 times that of the 3-aminopropyl trimethoxy silane, stirring for 3-5 min at the temperature of 0-5 ℃ and 300-500 r/min, continuously stirring, adding 4-chlorobenzophenone with the same molar weight of 3-aminopropyl trimethoxy silane, stirring for 50-60 min at the temperature of 0-5 ℃ and 300-500 r/min, standing for 20-24 h at room temperature, and drying for 6-8 h at the temperature of 10-20 ℃ and 50-100 Pa.
3. The method for preparing the novel polymer finishing mortar according to claim 1, wherein the basalt fiber in the step (2) has a diameter of 10-15 μm and a length of 8-12 mm.
4. The method for preparing a novel polymer finishing mortar according to claim 1, wherein the soft monomer in the step (3) is one or more of ethyl acrylate, butyl acrylate and isooctyl acrylate; the hard monomer is one or more of vinyl acetate, styrene, acrylonitrile, methyl methacrylate and acrylamide; the emulsifier is OP-10 emulsifier; the thermal initiator is ammonium persulfate; the water content refers to the mass fraction of pure water in the polymer emulsion.
5. The method for preparing a novel polymer finishing mortar according to claim 1, wherein the cement in the step (4) is PO42.5 portland cement; the fly ash is 800-1000 meshes of fly ash.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226531A (en) * | 1998-01-20 | 1999-08-25 | 株式会社日本触媒 | Cement additive and cement composition using same |
| CN111676596A (en) * | 2019-03-11 | 2020-09-18 | 德国昕特玛有限公司 | Latex bonded textile fiber structures for architectural applications |
| KR102269957B1 (en) * | 2020-12-09 | 2021-06-29 | 바론건설 주식회사 | Water inseparable polymer cement mortar and its mixer and concrete structure repair and reinforcement method using the same |
| CN114539888A (en) * | 2022-02-27 | 2022-05-27 | 上谷新材料(苏州)有限公司 | Strippable dual-curing coating and preparation method thereof |
| CN116102307A (en) * | 2022-12-01 | 2023-05-12 | 中南大学 | Mortar for airport assembly type runway slurry technology |
-
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226531A (en) * | 1998-01-20 | 1999-08-25 | 株式会社日本触媒 | Cement additive and cement composition using same |
| CN111676596A (en) * | 2019-03-11 | 2020-09-18 | 德国昕特玛有限公司 | Latex bonded textile fiber structures for architectural applications |
| KR102269957B1 (en) * | 2020-12-09 | 2021-06-29 | 바론건설 주식회사 | Water inseparable polymer cement mortar and its mixer and concrete structure repair and reinforcement method using the same |
| CN114539888A (en) * | 2022-02-27 | 2022-05-27 | 上谷新材料(苏州)有限公司 | Strippable dual-curing coating and preparation method thereof |
| CN116102307A (en) * | 2022-12-01 | 2023-05-12 | 中南大学 | Mortar for airport assembly type runway slurry technology |
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