CN115959356A - Explosion-proof glass wine bottle and production method thereof - Google Patents
Explosion-proof glass wine bottle and production method thereof Download PDFInfo
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- CN115959356A CN115959356A CN202211710109.5A CN202211710109A CN115959356A CN 115959356 A CN115959356 A CN 115959356A CN 202211710109 A CN202211710109 A CN 202211710109A CN 115959356 A CN115959356 A CN 115959356A
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- 239000011521 glass Substances 0.000 title claims abstract description 80
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 107
- 239000000155 melt Substances 0.000 claims description 25
- 239000003963 antioxidant agent Substances 0.000 claims description 23
- 239000004611 light stabiliser Substances 0.000 claims description 20
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 17
- 230000003078 antioxidant effect Effects 0.000 claims description 17
- 235000013361 beverage Nutrition 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 14
- 239000004014 plasticizer Substances 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 229910021532 Calcite Inorganic materials 0.000 claims description 9
- 239000006004 Quartz sand Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 9
- 229960002594 arsenic trioxide Drugs 0.000 claims description 9
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003610 charcoal Substances 0.000 claims description 9
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 9
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000010446 mirabilite Substances 0.000 claims description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000007822 coupling agent Substances 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 235000017550 sodium carbonate Nutrition 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- GCDUWJFWXVRGSM-UHFFFAOYSA-N 2-[2-(2-heptanoyloxyethoxy)ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCC GCDUWJFWXVRGSM-UHFFFAOYSA-N 0.000 claims description 5
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- 230000017105 transposition Effects 0.000 claims description 5
- 239000012943 hotmelt Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- -1 dipentaerythritol ester Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000003086 colorant Substances 0.000 abstract description 6
- 238000004880 explosion Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000012634 fragment Substances 0.000 description 6
- 238000005728 strengthening Methods 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 4
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 241001391944 Commicarpus scandens Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- RPGCQRYGRLCEAH-UHFFFAOYSA-N 2-[2-[2-[2-(6-methylheptanoyloxy)ethoxy]ethoxy]ethoxy]ethyl 6-methylheptanoate Chemical compound C(CCCCC(C)C)(=O)OCCOCCOCCOCCOC(CCCCC(C)C)=O RPGCQRYGRLCEAH-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
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- Containers Having Bodies Formed In One Piece (AREA)
Abstract
The invention discloses an explosion-proof glass wine bottle which comprises an explosion-proof glass wine bottle body, wherein the explosion-proof glass wine bottle body consists of an inner layer, an outer layer and a bottom layer, the bottom layer is arranged at the lower ends of the inner layer and the outer layer, the outer layer is arranged on the outer side of the inner layer, a reinforcing groove is formed between the inner layer and the outer layer, a reinforcing layer is filled in the reinforcing groove, and the reinforcing layer is of a net structure and is formed by twisting PVB reinforcing wires. The anti-explosion glass wine bottle body comprises an inner layer, an outer layer, a reinforcing layer and a bottom layer, wherein the reinforcing layer is arranged in a reinforcing groove between the inner layer and the outer layer, the reinforcing layer is net-shaped and is formed by twisting PVB reinforcing wires, a porous structure is formed on the surface of the net-shaped reinforcing layer, so that the net-shaped reinforcing layer is more tightly connected with the inner layer and the outer layer, the structural strength is higher, the reinforcing layer can absorb impact energy, and the problem that glass broken pieces splash after a glass bottle is broken is solved. Meanwhile, the reinforcing layer made of PVB material can be adjusted to different colors by adding coloring agent, so that the special wine can be shielded and stored conveniently.
Description
Technical Field
The invention relates to the technical field of glass wine bottles, in particular to an explosion-proof glass wine bottle and a production method thereof.
Background
The glass wine bottle is a container for containing alcohol, which is mainly made of glass, and the alcohol is a solvent which has strong reaction capability on metals such as lead, aluminum and the like, so that the introduction of the substances is avoided as much as possible, and the glass wine bottle is required to be used.
The existing glass wine bottle has insufficient explosion-proof performance, the wine bottle is easy to break when being extruded, impacted and dropped by external force, the broken wine bottle forms a plurality of glass fragments and is scattered towards the periphery, and the scattered glass fragments are easy to cause personal injury, so that the explosion-proof glass wine bottle and the production method thereof are provided.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an explosion-proof glass wine bottle and a production method thereof, and solves the problems that: the explosion-proof performance of current glass beverage bottle is not enough, easily causes the beverage bottle to break when receiving external force extrusion, striking, dropping, and the beverage bottle after breaking forms a plurality of glass fragments and to scattering all around towards, scatters the glass fragment after towards and easily causes personnel injured's problem.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the utility model provides an explosion-proof glass beverage bottle, includes, explosion-proof glass beverage bottle body comprises inlayer, skin and bottom, and inlayer and outer lower extreme are arranged in to the bottom, and the inlayer outside is arranged in to the skin, and is formed with the strengthening groove between inlayer and the skin, and the strengthening groove intussuseption is filled with the enhancement layer, the enhancement layer is network structure and is formed by the PVB reinforcing wire transposition, forms a plurality of in the enhancement layer and strengthens the chamber and strengthen the section.
As a further preferable mode of the invention, the reinforcing layer is in hot-melt connection with the inner layer, and a plurality of reinforcing particles are uniformly arranged on the surface of the inner layer and in the reinforcing cavity.
In a further preferred embodiment of the present invention, the reinforcing particles have a polygonal structure.
As a further preferred embodiment of the present invention, the method comprises the following steps:
s1: inner layer and bottom layer for making explosion-proof glass wine bottle
Mixing quartz sand, soda, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder according to a mass ratio at 1400-1550 ℃ and melting to obtain a melt;
respectively injecting the melts into the molds of the inner layer and the bottom layer for cooling and molding;
the inner layer is connected with the bottom layer in a hot melting way to prepare a primary bottle body with a reinforcing groove on the surface;
s2: making the reinforcing layer
Weighing PVB resin, a plasticizer, an antioxidant, a light stabilizer, a binding power regulator and a coupling agent according to a proportion, mixing and extruding to prepare a strip-shaped PVB reinforcing wire;
putting the reinforcing wires in a stranding machine for stranding to prepare a reticular reinforcing layer;
s3: bonding reinforced layer
Heating the primary bottle body prepared in the step S1, then attaching the reinforcing layer prepared in the step S2 to the surface of the primary bottle body and bonding the reinforcing layer, continuously heating the primary bottle body, grinding PVB reinforcing wires into powder, and uniformly spraying the powder on the surface of the primary bottle body through a spraying machine to prepare a glass bottle body with the reinforcing layer;
s4: making the outer layer
And (3) placing the glass bottle body with the reinforcing layer prepared in the step (S3) into a mould, injecting the melt prepared in the step (S1), and attaching the melt to the surface of the glass bottle body with the reinforcing layer to form an outer layer to prepare the explosion-proof glass wine bottle.
In a further preferred embodiment of the present invention, the light stabilizer is one of a benzotriazole light stabilizer and a hindered amine light stabilizer.
In a further preferred embodiment of the present invention, the antioxidant is a mixture of a hindered phenol antioxidant and a phosphite antioxidant.
As a further preferred mode of the present invention, the plasticizer is one or a combination of more of triethylene glycol diisocaprylate, triethylene glycol di-n-heptanoate, tetraethylene glycol diisocaprylate, dibutyl sebacate and dipentaerythritol.
(III) advantageous effects
The invention provides an explosion-proof glass wine bottle and a production method thereof. The method has the following beneficial effects:
according to the invention, the anti-explosion glass wine bottle body consists of the inner layer, the outer layer, the reinforcing layer and the bottom layer, the reinforcing layer is arranged in the reinforcing groove between the inner layer and the outer layer, the reinforcing layer is net-shaped and is formed by twisting PVB reinforcing wires, a porous structure is formed on the surface of the net-shaped reinforcing layer, so that the net-shaped reinforcing layer is more tightly connected with the inner layer and the outer layer, the structural strength is higher, the reinforcing layer can absorb impact energy, and the problem that broken glass pieces splash after the glass bottle is broken is solved. Meanwhile, the reinforcing layer made of PVB material can be adjusted to different colors by adding coloring agent, so that the special wine can be shielded and stored conveniently.
Drawings
FIG. 1 is a block diagram of an explosion-proof glass wine bottle of the present invention;
FIG. 2 is a view of the internal structure of the blast-resistant glass wine bottle of the present invention;
FIG. 3 is a block diagram of the explosion proof layer of the present invention;
fig. 4 is an enlarged view of a in fig. 3.
In the figure: 1. an inner layer; 2. a reinforcing layer; 3. a reinforcing groove; 4. an outer layer; 5. a bottom layer; 6. PVB reinforcing wires; 7. a reinforcement section; 8. a reinforcement cavity; 9. the particles are reinforced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
Referring to fig. 1-4, an embodiment of the invention provides a technical solution: the utility model provides an explosion-proof glass beverage bottle, includes, explosion-proof glass beverage bottle body comprises inlayer 1, outer 4 and bottom 5, and inlayer 1 and outer 4's lower extreme is arranged in to bottom 5, and the inlayer 1 outside is arranged in to outer 4, and is formed with between inlayer 1 and the outer 4 and strengthens groove 3, and 3 intussuseption in the strengthening groove are filled with enhancement layer 2, and enhancement layer 2 is network structure and is formed by 6 transposition of PVB reinforcing wire, forms a plurality of in the enhancement layer 2 and strengthens chamber 8 and enhancement section 7.
In a further improvement, the reinforcing layer 2 is in hot-melt connection with the inner layer 1, and a plurality of reinforcing particles 9 are uniformly arranged on the surface of the inner layer 1 and in the reinforcing cavity 8.
Further improved, the reinforcing particles 9 are of polygonal configuration.
In a further development, the method comprises the following method steps:
s1: inner layer 1 and bottom layer 5 for making explosion-proof glass wine bottle
Mixing and melting quartz sand, soda ash, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder at 1550 ℃ according to the mass ratio of (0.05): 5.5:1.2:3, preparing a melt;
respectively injecting the melts into the molds of the inner layer 1 and the bottom layer 5 for cooling and molding;
the inner layer 1 is connected with the bottom layer 5 in a hot melting way to prepare a primary bottle body with a reinforcing groove 3 on the surface;
s2: manufacture of the reinforcing layer 2
The PVB resin, the plasticizer, the antioxidant, the light stabilizer, the adhesive force regulator and the coupling agent are weighed, mixed and extruded according to the proportion, wherein the proportion of the PVB resin, the plasticizer, the antioxidant, the light stabilizer, the adhesive force regulator and the coupling agent is 68: 0.005, wherein the PVB resin has a hydroxyl content of 17wt%; viscosity at 20 ℃ was 220cp; under the condition of the test temperature of 140 ℃ and the load of 20kg, the melt index of the PVB resin is 1.0g/10min, and a strip-shaped PVB reinforcing wire 6 is prepared;
putting the reinforcing wires into a stranding machine for stranding to prepare a reticular reinforcing layer 2;
s3: laminated reinforcing layer 2
Heating the primary bottle body prepared in the step (S1) at 50 ℃, then attaching the reinforcing layer 2 prepared in the step (S2) to the surface of the primary bottle body and bonding the reinforcing layer with the primary bottle body, continuously heating the primary bottle body at 30 ℃, and reducing the temperature by 10 ℃ per minute until the heater is turned off; when the temperature is continuously reduced to 20 ℃, the PVB reinforcing wire 6 is ground into powder and then is uniformly sprayed on the surface of the primary bottle body through a spraying machine, so that the glass bottle body with the reinforcing layer 2 is prepared;
s4: making the outer layer 4
And (4) placing the glass bottle body with the reinforcing layer 2 prepared in the step (S3) into a mould, injecting the melt prepared in the step (S1), and attaching the melt to the surface of the glass bottle body with the reinforcing layer 2 to form an outer layer 4 to prepare the explosion-proof glass wine bottle.
In a further improvement, the light stabilizer is a benzotriazole light stabilizer.
In a further improvement, the antioxidant is a mixture of hindered phenol antioxidants and phosphite antioxidants.
In a further improvement, the plasticizer is one or more of triethylene glycol diisocaprylate, triethylene glycol di-n-heptanoate, tetraethylene glycol diisocaprylate, dibutyl sebacate and dipentaerythritol ester.
Example two
The utility model provides an explosion-proof glass beverage bottle, includes, explosion-proof glass beverage bottle body comprises inlayer 1, outer 4 and bottom 5, and inlayer 1 and outer 4's lower extreme is arranged in to bottom 5, and the inlayer 1 outside is arranged in to outer 4, and is formed with between inlayer 1 and the outer 4 and strengthens groove 3, and 3 intussuseption in the strengthening groove are filled with enhancement layer 2, and enhancement layer 2 is network structure and is formed by 6 transposition of PVB reinforcing wire, forms a plurality of in the enhancement layer 2 and strengthens chamber 8 and enhancement section 7.
In a further improvement, the reinforcing layer 2 is in hot-melt connection with the inner layer 1, and a plurality of reinforcing particles 9 are uniformly arranged on the surface of the inner layer 1 and in the reinforcing cavity 8.
Further improved, the reinforcing particles 9 are of polygonal configuration.
In a further development, the method comprises the following method steps:
s1: inner layer 1 and bottom layer 5 for making explosion-proof glass wine bottle
Mixing and melting quartz sand, soda ash, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder at 1400 ℃, wherein the ratio of the quartz sand, the soda ash, the calcite, the charcoal, the white arsenic, the mirabilite, the copper sulfate, the aluminum oxide and the potassium dichromate is 80: 4.5:1.33:3.55, preparing a melt;
respectively injecting the melts into the molds of the inner layer 1 and the bottom layer 5 for cooling and molding;
the inner layer 1 is connected with the bottom layer 5 in a hot melting way to prepare a primary bottle body with a reinforcing groove 3 on the surface;
s2: manufacture of the reinforcing layer 2
The PVB resin, the plasticizer, the antioxidant, the light stabilizer, the adhesive force regulator and the coupling agent are weighed according to the proportion and are mixed and extruded, and the ratio of the PVB resin to the plasticizer to the antioxidant to the light stabilizer to the adhesive force regulator to the coupling agent is (88.2): 0.007 where the PVB resin had a hydroxyl content of 15wt%; viscosity at 20 ℃ was 150cp; under the condition of the test temperature of 140 ℃ and the load of 20kg, the melt index of the PVB resin is 0.8g/10min, and a strip-shaped PVB reinforcing wire 6 is prepared;
putting the reinforcing wires into a stranding machine for stranding to prepare a reticular reinforcing layer 2;
s3: bonding reinforced layer 2
Heating the primary bottle body prepared in the step (S1) at the temperature of 30 ℃, then attaching the reinforcing layer 2 prepared in the step (S2) to the surface of the primary bottle body and bonding the reinforcing layer, continuously heating the primary bottle body at the temperature of 20 ℃, and reducing the temperature by 5 ℃ per minute until the heater is turned off; when the temperature is continuously reduced to 5 ℃, the PVB reinforcing wire 6 is ground into powder and then is uniformly sprayed on the surface of the primary bottle body through a spraying machine, so as to prepare the glass bottle body with the reinforcing layer 2;
s4: making the outer layer 4
And (4) placing the glass bottle body with the reinforcing layer 2 prepared in the step (S3) into a mould, injecting the melt prepared in the step (S1), and attaching the melt to the surface of the glass bottle body with the reinforcing layer 2 to form an outer layer 4 to prepare the explosion-proof glass wine bottle.
In a further improvement, the light stabilizer is a benzotriazole light stabilizer.
In a further improvement, the antioxidant is a mixture of hindered phenol antioxidants and phosphite antioxidants.
In a further improvement, the plasticizer is one or more of triethylene glycol diisocaprylate, triethylene glycol di-n-heptanoate, tetraethylene glycol diisocaprylate, dibutyl sebacate and dipentaerythritol ester.
EXAMPLE III
The utility model provides an explosion-proof glass beverage bottle, includes, explosion-proof glass beverage bottle body comprises inlayer 1, outer 4 and bottom 5, and inlayer 1 and outer 4's lower extreme is arranged in to bottom 5, and the inlayer 1 outside is arranged in to outer 4, and is formed with between inlayer 1 and the outer 4 and strengthens groove 3, and the intussuseption of strengthening groove 3 is filled with enhancement layer 2, and enhancement layer 2 is network structure and is formed by 6 transposition of PVB reinforcing wire.
In a further improvement, the reinforcing layer 2 is connected to the inner layer 1 by thermal fusion.
In a further development, the method comprises the following method steps:
s1: inner layer 1 and bottom layer 5 for making explosion-proof glass wine bottle
Mixing and melting quartz sand, soda ash, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder at 1400 ℃, wherein the ratio of the quartz sand, the soda ash, the calcite, the charcoal, the white arsenic, the mirabilite, the copper sulfate, the aluminum oxide and the potassium dichromate is 80: 4.5:1.33: 3.55;
respectively injecting the melts into the molds of the inner layer 1 and the bottom layer 5 for cooling and molding;
the inner layer 1 is connected with the bottom layer 5 in a hot melting way to prepare a primary bottle body with a reinforcing groove 3 on the surface;
s2: manufacture of the reinforcing layer 2
The PVB resin, the plasticizer, the antioxidant, the light stabilizer, the adhesive force regulator and the coupling agent are weighed according to the proportion and are mixed and extruded, and the ratio of the PVB resin to the plasticizer to the antioxidant to the light stabilizer to the adhesive force regulator to the coupling agent is (88.2): 0.007 where the PVB resin had a hydroxyl content of 15wt%; viscosity at 20 ℃ was 150cp; under the condition of the test temperature of 140 ℃ and the load of 20kg, the melt index of the PVB resin is 0.8g/10min, and a strip-shaped PVB reinforcing wire 6 is prepared;
putting the reinforcing wires into a stranding machine for stranding to prepare a reticular reinforcing layer 2;
s3: laminated reinforcing layer 2
Heating the primary bottle body prepared in the step (S1) to 30 ℃, and then attaching the reinforcing layer 2 prepared in the step (S2) to the surface of the primary bottle body and bonding the reinforcing layer to the surface of the primary bottle body to prepare a glass bottle body with the reinforcing layer 2;
s4: making the outer layer 4
And (4) placing the glass bottle body with the reinforcing layer 2 prepared in the step (S3) into a mould, injecting the melt prepared in the step (S1), and attaching the melt to the surface of the glass bottle body with the reinforcing layer 2 to form an outer layer 4 to prepare the explosion-proof glass wine bottle.
In a further improvement, the light stabilizer is a benzotriazole light stabilizer.
In a further improvement, the antioxidant is a mixture of hindered phenol antioxidants and phosphite antioxidants.
In a further refinement, the plasticizer is a combination of triethylene glycol di-n-heptanoate, tetraethylene glycol di-iso-octanoate and dibutyl sebacate.
Example four
The utility model provides an explosion-proof glass beverage bottle, includes explosion-proof glass beverage bottle body, and explosion-proof glass beverage bottle body comprises inlayer 1, skin 4 and bottom 5, and inlayer 1 and skin 4's lower extreme is arranged in to bottom 5, and the inlayer 1 outside is arranged in to skin 4.
In a further development, the method comprises the following method steps:
s1: inner layer 1 and bottom layer 5 for making explosion-proof glass wine bottle
Mixing and melting quartz sand, soda ash, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder at 1400 ℃, wherein the ratio of the quartz sand, the soda ash, the calcite, the charcoal, the white arsenic, the mirabilite, the copper sulfate, the aluminum oxide and the potassium dichromate is 80: 4.5:1.33:3.55, preparing a melt;
respectively injecting the melts into the molds of the inner layer 1 and the bottom layer 5 for cooling and molding;
the inner layer 1 is connected with the bottom layer 5 in a hot melting way to obtain a primary bottle body;
s2: making the outer layer 4
And (4) placing the primary bottle body prepared in the step (S1) into a mold, and injecting the melt prepared in the step (S1) to form an outer layer 4, so as to prepare the explosion-proof glass wine bottle.
Application test:
the glass wine bottles prepared in the four examples were placed at heights of 1m, 2m, 3m, and 4m, respectively, and subjected to a drop test, and whether or not to break and a broken piece splashing range (the splashing range is the maximum radius of the piece splashing) were measured, with the results shown in the following table:
| 1m | 2m | 3m | 4m | |
| example one | Is not broken | Is not broken | Crushing/0.8 m | 1.3m of crushed |
| Example two | Is not broken | Is not broken | Crushing/1.2 m | 2.05m of crushing |
| EXAMPLE III | Is not broken | 1.1m of crushed | Crushing/1.8 m | 2.2m of crushing |
| Example four (comparative) | Crushing/0.8 m | 1.6m of crushed | 2.3m crushing | Crushing/3 m |
The tests show that the anti-popping glass wine bottles made in examples 1-2 have a small splashing range in the four height drop test, with the glass wine bottle made in example 1 being the best.
1, inner layer of the invention; 2. a reinforcing layer; 3. a reinforcing groove; 4. an outer layer; 5. a bottom layer; 6. PVB reinforcing wires; 7. a reinforcement section; 8. a reinforcement cavity; 9. the invention solves the problems that the anti-explosion performance of the existing glass wine bottle is not enough, the wine bottle is easy to break when being extruded, impacted and dropped by external force, the broken wine bottle forms a plurality of glass fragments and is scattered towards the periphery, and the scattered glass fragments are easy to cause personal injury. Meanwhile, the reinforcing layer 2 made of PVB material can be adjusted to different colors by adding coloring agent, so that the special wine can be shielded and stored conveniently.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (7)
1. The utility model provides an explosion-proof glass beverage bottle, includes, explosion-proof glass beverage bottle body, its characterized in that: explosion-proof glass beverage bottle body comprises inlayer (1), skin (4) and bottom (5), and the lower extreme of inlayer (1) and skin (4) is arranged in bottom (5), and inlayer (1) outside is arranged in skin (4), and is formed with between inlayer (1) and skin (4) and strengthens groove (3), and it is filled with enhancement layer (2) to strengthen groove (3) intussuseption, enhancement layer (2) are network structure and are formed by PVB enhancement silk (6) transposition, form a plurality of in enhancement layer (2) and strengthen chamber (8) and enhancement section (7).
2. An explosion-proof glass wine bottle as defined in claim 1, wherein: the reinforcing layer (2) is in hot-melt connection with the inner layer (1), and a plurality of reinforcing particles (9) are uniformly arranged on the surface of the inner layer (1) and in the reinforcing cavity (8).
3. An explosion-proof glass wine bottle as defined in claim 2, wherein: the reinforcing particles (9) are of polygonal structure.
4. The method for producing an explosion-proof glass wine bottle as defined in claim 1, wherein: the method comprises the following steps:
s1: inner layer (1) and bottom layer (5) for making explosion-proof glass wine bottle
Mixing quartz sand, soda ash, calcite, charcoal, white arsenic, mirabilite, copper sulfate, aluminum oxide and potassium dichromate powder according to a mass ratio at 1400-1550 ℃ for melting to obtain a melt;
respectively injecting the melts into the molds of the inner layer (1) and the bottom layer (5) for cooling and molding;
the inner layer (1) is connected with the bottom layer (5) in a hot melting way to prepare a primary bottle body with a reinforcing groove (3) on the surface;
s2: manufacture of the reinforcing layer (2)
The PVB resin, the plasticizer, the antioxidant, the light stabilizer, the bonding force regulator and the coupling agent are weighed according to the proportion, mixed and extruded to prepare a strip-shaped PVB reinforcing wire (6);
putting the reinforcing wires into a stranding machine for stranding to prepare a reticular reinforcing layer (2);
s3: bonding enhanced layer (2)
Heating the primary bottle body prepared in the step S1, then attaching the reinforcing layer (2) prepared in the step S2 to the surface of the primary bottle body and bonding the reinforcing layer, continuously heating the primary bottle body, grinding PVB reinforcing wires (6) into powder, and uniformly spraying the powder on the surface of the primary bottle body through a spraying machine to prepare the glass bottle body with the reinforcing layer (2);
s4: making outer layer (4)
And (4) placing the glass bottle body with the reinforcing layer (2) prepared in the step (S3) into a mold, injecting the melt prepared in the step (S1), and attaching the melt to the surface of the glass bottle body with the reinforcing layer (2) to form an outer layer (4) to prepare the explosion-proof glass wine bottle.
5. The method for producing an explosion-proof glass wine bottle as defined in claim 4, wherein: the light stabilizer is one of benzotriazole light stabilizer and hindered amine light stabilizer.
6. The method for producing an explosion-proof glass wine bottle as defined in claim 4, wherein: the antioxidant is a mixture of hindered phenol antioxidant and phosphite antioxidant.
7. The method for producing an explosion-proof glass wine bottle as defined in claim 4, wherein: the plasticizer is one or a combination of triethylene glycol diisocaprylate, triethylene glycol di-n-heptanoate, tetraethylene glycol diisocaprylate, dibutyl sebacate and dipentaerythritol ester.
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| CN115959356B CN115959356B (en) | 2023-12-22 |
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| CN211281906U (en) * | 2019-12-16 | 2020-08-18 | 广州市亿晶玻璃有限公司 | High internal stress anti-rupture glass bottle |
| CN217171350U (en) * | 2021-11-30 | 2022-08-12 | 烟台新中萃玻璃包装有限公司 | Explosion-proof wine bottle |
| CN217706674U (en) * | 2022-06-23 | 2022-11-01 | 重庆万恒玻璃有限公司 | High-grade glass wine bottle with colored glaze |
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| US4486378A (en) * | 1980-05-07 | 1984-12-04 | Toyo Seikan Kaisha Ltd. | Plastic bottles and process for preparation thereof |
| US4486378B1 (en) * | 1980-05-07 | 1990-07-03 | Toyo Seikan Kaisha Ltd | |
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| CN115959356B (en) | 2023-12-22 |
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