CN115897283A - Dustproof and flame-retardant wallpaper and preparation method thereof - Google Patents
Dustproof and flame-retardant wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN115897283A CN115897283A CN202211559088.1A CN202211559088A CN115897283A CN 115897283 A CN115897283 A CN 115897283A CN 202211559088 A CN202211559088 A CN 202211559088A CN 115897283 A CN115897283 A CN 115897283A
- Authority
- CN
- China
- Prior art keywords
- flame
- dustproof
- wallpaper
- retardant
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000003063 flame retardant Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 241000196252 Ulva Species 0.000 claims abstract description 30
- 239000002131 composite material Substances 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 150000001413 amino acids Chemical class 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 21
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 238000000926 separation method Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 30
- 239000006228 supernatant Substances 0.000 claims description 24
- 238000005507 spraying Methods 0.000 claims description 16
- 230000003449 preventive effect Effects 0.000 claims description 11
- 239000004475 Arginine Substances 0.000 claims description 10
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 10
- 230000007935 neutral effect Effects 0.000 claims description 10
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 9
- 239000004472 Lysine Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 7
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 6
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims description 6
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 3
- 229920001284 acidic polysaccharide Polymers 0.000 description 16
- 150000004805 acidic polysaccharides Chemical class 0.000 description 16
- 239000002585 base Substances 0.000 description 12
- 239000000428 dust Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 5
- 239000005017 polysaccharide Substances 0.000 description 5
- 150000004804 polysaccharides Chemical class 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002795 guanidino group Chemical group C(N)(=N)N* 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
- 241000195628 Chlorophyta Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 241000196253 Ulva prolifera Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
The invention relates to the technical field of decorative materials, and provides dustproof and flame-retardant wallpaper and a preparation method thereof. The wallpaper is treated by dustproof and flame-retardant treatment liquid. The dustproof and flame-retardant treatment liquid is prepared by heating and extracting enteromorpha powder by using an alkaline composite extracting solution, then carrying out centrifugal separation, adding an auxiliary agent into supernate and adjusting the pH value. The composite extracting solution comprises basic amino acid, quaternary ammonium base and deionized water. The wallpaper prepared by the method disclosed by the invention has good flame retardant property and good dustproof property.
Description
Technical Field
The invention relates to the technical field of decorative materials, and provides dustproof and flame-retardant wallpaper and a preparation method thereof.
Background
The wallpaper is a common interior decoration material and is widely used for interior wall decoration of houses, offices, hotels and restaurants. However, most wallpaper on the market is easy to burn, and in recent years, indoor fire frequently occurs, and the application of wallpaper is accompanied with a great potential safety hazard. Along with the above, the demand of the flame-retardant wallpaper is increasingly urgent, and the flame-retardant wallpaper has a wide application prospect.
Enteromorpha is a marine chlorophyta plant, and has flame retardancy. The enteromorpha can be rapidly propagated and even abused to cause disasters when external conditions are appropriate, and the harmless treatment and the resource utilization of the enteromorpha have important significance. In the prior art, a treatment solution containing enteromorpha polysaccharide is obtained by a hot water extraction method, and a good effect is achieved by performing flame retardant finishing on cotton fabrics. Similarly, the flame retardant property of the wallpaper can be improved by treating the wallpaper with the enteromorpha polysaccharide extract.
It is known that enteromorpha polysaccharide obtained by hot water extraction method includes neutral polysaccharide and acidic polysaccharide, while acidic polysaccharide can be extracted specifically by alkali liquor extraction method. Because the acidic polysaccharide contains glucuronic acid and the ring of the acidic polysaccharide contains carboxyl, when the acidic polysaccharide is heated, the carboxyl can not only generate dehydration reaction with hydroxyl to generate water, but also generate decarboxylation reaction to generate carbon dioxide, which is beneficial to diluting the concentration of combustible gas and can play a role in inhibiting combustion in the initial stage, so the acidic polysaccharide has better flame retardant effect than neutral polysaccharide. Therefore, the acidic polysaccharide can be selectively extracted by an alkali liquor extraction method for flame retardance of the wallpaper.
However, since acidic polysaccharide has negative charges and dust in the air generally has positive charges, the acidic polysaccharide can attract and adhere the dust to wallpaper through electrostatic action, so that the wallpaper is easily stained with dust, and the application of the acidic polysaccharide in flame retardation of wallpaper is limited.
Disclosure of Invention
In order to overcome the defect that wallpaper after flame retardant treatment by using an enteromorpha acidic polysaccharide extracting solution is easy to be contaminated with dust, the invention provides the dustproof and flame retardant wallpaper and the preparation method thereof, and aims to enable the wallpaper to have good dustproof capability while improving the flame retardant property of the wallpaper by using the enteromorpha acidic polysaccharide extracting solution.
In order to achieve the purpose, the invention relates to the following specific technical scheme:
firstly, the invention provides a preparation method of dustproof and flame-retardant wallpaper, which comprises the following preparation steps:
(1) Adding enteromorpha powder into the composite extracting solution, heating and extracting for a certain time, and carrying out centrifugal separation while the solution is hot to obtain supernatant;
(2) Adding an auxiliary agent into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment solution;
(3) And spraying the treating fluid on the surface of the wallpaper, fully wetting the wallpaper, and drying to obtain the dustproof and flame-retardant wallpaper.
Wherein the composition of the compound extracting solution comprises basic amino acid, quaternary ammonium base and deionized water.
Preferably, the basic amino acid is one of lysine, arginine and histidine.
Preferably, the quaternary ammonium base is tetramethylammonium hydroxide.
Preferably, in the composite extracting solution, the concentration of the basic amino acid is 0.2 to 0.3mol/L, and the concentration of the quaternary ammonium base is 0.8 to 1.2mol/L.
Basic amino acids are amino acids with more basic than acidic groups, such as lysine, arginine, histidine. Wherein lysine contains 2 amino groups and 1 carboxyl group, arginine contains 1 amino group, 1 basic guanidino group and 1 carboxyl group, and histidine contains 1 amino group, 1 basic imidazolyl group and 1 carboxyl group. The quaternary ammonium base has the general formula R 4 NOH, wherein R are the same or different hydrocarbyl groups, the quaternary ammonium base having a strong basicity. When R is methyl, it is the simplest quaternary ammonium base, i.e., tetramethylammonium hydroxide.
Basic amino acids and quaternary ammonium bases are not only basic but also have a positive charge. Based on the method, alkaline amino acid, quaternary ammonium base and deionized water are adopted to form a composite extracting solution, and enteromorpha prolifera powder is extracted. In the compound extracting solution, even if the basic amino acid consumes partial alkali through the reaction of carboxyl and quaternary ammonium hydroxide, the mole number of the quaternary ammonium hydroxide is greatly higher than that of the basic amino acid, and the amino (guanidino or imidazolyl) of the basic amino acid can provide an alkaline environment, so that the compound extracting solution shows obvious alkalinity, and the acidic polysaccharide in the enteromorpha can be selectively extracted. Furthermore, compared with the common alkali liquor extraction method (taking sodium hydroxide solution as an extracting solution) in the prior research, the supernatant obtained after the extraction and centrifugation of the invention not only contains acidic polysaccharide, but also contains components in the composite extracting solution, and as the basic amino acid part and the quaternary ammonium base part both have positive charges, the surface of the wallpaper is positively charged, and dust in the air is also positively charged, so that the dust can be prevented from being adsorbed on the wallpaper through electrostatic repulsion, and the wallpaper is endowed with good dustproof capability. Furthermore, nitrogen-containing groups are introduced in the use of the basic amino acid and the quaternary ammonium base, and the generated gas can absorb heat, dilute oxygen and promote the expansion of a carbon layer during combustion, so that the carbon layer and the acidic polysaccharide can play a role in flame retardance, and the flame retardant effect of the wallpaper can be further improved.
The particle size of the enteromorpha powder is preferably 80-120 meshes, and the fresh enteromorpha is taken as a raw material, and the preparation process comprises the steps of cleaning, drying and crushing.
Preferably, the addition amount of the enteromorpha powder is 2 to 4 percent of the mass of the composite extracting solution.
Preferably, the heating temperature in the step (1) is 80 to 90 ℃ and the time is 2 to 4 hours.
Preferably, the rotation speed of the centrifugal separation in the step (1) is 4000 to 5000r/min, and the time is 10 to 15min.
The kind of the auxiliary agent can be selected according to the situation, and includes but is not limited to a mildew preventive. The addition amount of the mildew preventive is 0.2 to 0.4 percent of the mass of the supernatant.
Preferably, the spraying amount of the treatment liquid is 0.5 to 1.5 times of the mass of the wallpaper.
The invention also provides the dustproof and flame-retardant wallpaper prepared by the preparation method. The wallpaper is treated by dustproof and flame-retardant treatment liquid. The dustproof and flame-retardant treatment liquid is prepared by heating and extracting enteromorpha powder by using an alkaline composite extracting solution, then carrying out centrifugal separation, adding an auxiliary agent into supernate and adjusting the pH value. The composite extracting solution comprises basic amino acid, quaternary ammonium base and deionized water.
The invention provides dustproof and flame-retardant wallpaper and a preparation method thereof, and the excellent effects are as follows: the wallpaper prepared by the method disclosed by the invention has good flame retardant property and good dustproof property.
Detailed Description
The following examples 1-2, in which lysine was used as a basic amino acid, examples 3-4, and examples 5-6, in which arginine was used as a basic amino acid, further illustrate the technical aspects of the present invention.
Various substitutions and alterations can be made by those skilled in the art and by conventional means without departing from the spirit of the method of the invention described above.
Example 1
(1) Adding enteromorpha powder of 80-120 meshes into the composite extracting solution, heating to 90 ℃, extracting for 4h, and performing centrifugal separation at 4500r/min for 12min to obtain supernatant; the adding amount of the enteromorpha powder is 4 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating liquid on the surface of wallpaper to fully wet the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the compound extract is composed of lysine, tetramethyl ammonium hydroxide and deionized water. The concentration of lysine was 0.2mol/L and the concentration of tetramethylammonium hydroxide was 0.8mol/L.
Example 2
(1) Adding enteromorpha powder of 80 to 120 meshes into the composite extracting solution, heating to 80 ℃, extracting for 2h, and performing centrifugal separation at 4500r/min for 12min to obtain supernatant; the adding amount of the enteromorpha powder is 2 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating liquid on the surface of wallpaper to fully wet the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the compound extract is composed of lysine, tetramethyl ammonium hydroxide and deionized water. The concentration of lysine was 0.3mol/L and the concentration of tetramethylammonium hydroxide was 1.2mol/L.
Example 3
(1) Adding enteromorpha powder of 80-120 meshes into the composite extracting solution, heating to 90 ℃, extracting for 4h, and performing centrifugal separation at 4500r/min for 12min to obtain supernatant; the adding amount of the enteromorpha powder is 4 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating fluid on the surface of the wallpaper, fully wetting the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the composite extracting solution consists of arginine, tetramethyl ammonium hydroxide and deionized water. The concentration of arginine is 0.2mol/L, and the concentration of tetramethyl ammonium hydroxide is 0.8mol/L.
Example 4
(1) Adding enteromorpha powder of 80 to 120 meshes into the composite extracting solution, heating to 80 ℃, extracting for 2h, and carrying out centrifugal separation for 12min at a speed of 4500r/min to obtain supernatant; the adding amount of the enteromorpha powder is 2 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating liquid on the surface of wallpaper to fully wet the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the compound extract is composed of arginine, tetramethyl ammonium hydroxide and deionized water. The concentration of arginine is 0.3mol/L, and the concentration of tetramethylammonium hydroxide is 1.2mol/L.
Example 5
(1) Adding enteromorpha powder of 80 to 120 meshes into the composite extracting solution, heating to 90 ℃, extracting for 4 hours, and carrying out centrifugal separation for 12 minutes at a speed of 4500r/min to obtain supernatant; the adding amount of the enteromorpha powder is 4 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating fluid on the surface of the wallpaper, fully wetting the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the compound extract consists of histidine, tetramethylammonium hydroxide and deionized water. The concentration of histidine is 0.2mol/L and the concentration of tetramethylammonium hydroxide is 0.8mol/L.
Example 6
(1) Adding enteromorpha powder of 80 to 120 meshes into the composite extracting solution, heating to 80 ℃, extracting for 2h, and performing centrifugal separation at 4500r/min for 12min to obtain supernatant; the adding amount of the enteromorpha powder is 2 percent of the mass of the composite extracting solution;
(2) Adding a mildew inhibitor into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid; the addition amount of the mildew preventive is 0.3 percent of the mass of the supernatant;
(3) Spraying the treating fluid on the surface of the wallpaper, fully wetting the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper; the spraying amount of the treatment liquid is 1 time of the mass of the wallpaper;
the compound extract consists of histidine, tetramethylammonium hydroxide and deionized water. The concentration of histidine was 0.3mol/L and the concentration of tetramethylammonium hydroxide was 1.2mol/L.
Comparative example 1
And extracting the enteromorpha powder by adopting a 1.2mol/L sodium hydroxide solution, wherein other preparation conditions are consistent with those of the example 6.
In the above examples and comparative examples, the wallpaper used was 2 kg/5.3 m in size 2 (i.e. an area per roll of 5.3m 2 Mass 2 kg); the mildew preventive used is mildew preventive ATE9277.
And (3) performance testing:
(1) The wallpaper prepared in examples 1-6 and comparative example 1 was subjected to a vertical burning performance test with reference to GB/T5455-2014 standard, and the after burning time, smoldering time and damage length are obtained and are shown in Table 1; it can be seen that: the wallpapers prepared in examples 1-6 and comparative example 1 can achieve good flame retardant effect, wherein the wallpaper has the best flame retardant property when the basic amino acid adopts arginine; the flame retardant property of the wallpaper prepared in example 6 is slightly better than that of comparative example 1, because the components in the composite extracting solution and the acidic polysaccharide in the example play a flame retardant role together, the flame retardant effect can be improved to a certain extent.
(2) Respectively cutting 20cm multiplied by 20cm samples of the wallpaper prepared in the examples 1-6 and the wallpaper prepared in the comparative example 1, placing the wallpaper in the same outdoor place, vertically placing the wallpaper, respectively placing the wallpaper in a sealed box (30 cm multiplied by 30 cm) provided with a fan after 7 days, enabling the plane of the wallpaper to be opposite to the fan, starting the fan to blow the wallpaper, enabling dust adsorbed on the surface of the wallpaper to fall off, and testing the concentration of PM2.5 and the concentration of PM10 in the box by using a dust detector after 60min of blowing, wherein the concentrations are shown in table 1; it can be seen that: the dustproof performance of the wallpaper prepared in the embodiment is obviously better than that of the wallpaper prepared in the comparative example 1, because the embodiment uses the basic amino acid and the quaternary ammonium base with positive charges, the surface of the wallpaper after being dried is positively charged, and dust in the air is also positively charged, so that the dust can be prevented from being adsorbed on the wallpaper through electrostatic repulsion.
Table 1:
Claims (9)
1. the preparation method of the dustproof and flame-retardant wallpaper is characterized by comprising the following preparation steps of:
(1) Adding enteromorpha powder into the composite extracting solution, heating and extracting for a certain time, and carrying out centrifugal separation while the solution is hot to obtain supernatant;
(2) Adding an auxiliary agent into the supernatant, and adjusting the pH to be neutral to obtain a dustproof and flame-retardant treatment liquid;
(3) Spraying the treating fluid on the surface of the wallpaper, fully wetting the wallpaper, and drying to obtain dustproof and flame-retardant wallpaper;
wherein the composition of the compound extracting solution comprises basic amino acid, quaternary ammonium base and deionized water; and the concentration of the basic amino acid in the composite extracting solution is 0.2 to 0.3mol/L, and the concentration of the quaternary ammonium base is 0.8 to 1.2mol/L.
2. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the basic amino acid is one of lysine, arginine and histidine.
3. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the quaternary ammonium base is tetramethyl ammonium hydroxide.
4. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the addition amount of the enteromorpha powder is 2 to 4 percent of the mass of the composite extracting solution.
5. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the heating temperature in the step (1) is 80 to 90 ℃, and the time is 2 to 4 hours.
6. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the rotation speed of centrifugal separation in the step (1) is 4000-5000 r/min, and the time is 10-15min.
7. The method for preparing the dustproof and flame-retardant wallpaper according to claim 1, characterized in that: such adjuvants include, but are not limited to, mold inhibitors; the addition amount of the mildew preventive is 0.2 to 0.4 percent of the mass of the supernate.
8. The preparation method of the dustproof and flame-retardant wallpaper according to claim 1, which is characterized in that: the spraying amount of the treatment liquid is 0.5 to 1.5 times of the mass of the wallpaper.
9. The dustproof and flame-retardant wallpaper prepared by the preparation method according to any one of claims 1 to 8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211559088.1A CN115897283A (en) | 2022-12-06 | 2022-12-06 | Dustproof and flame-retardant wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211559088.1A CN115897283A (en) | 2022-12-06 | 2022-12-06 | Dustproof and flame-retardant wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115897283A true CN115897283A (en) | 2023-04-04 |
Family
ID=86470950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211559088.1A Pending CN115897283A (en) | 2022-12-06 | 2022-12-06 | Dustproof and flame-retardant wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115897283A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015062730A1 (en) * | 2013-10-31 | 2015-05-07 | Schaefer Kalk Gmbh & Co. Kg | Article with low flammability |
| CN105839450A (en) * | 2016-04-12 | 2016-08-10 | 陈长胜 | Papermaking method using enteromorpha |
| CN106917479A (en) * | 2015-12-28 | 2017-07-04 | 上海倡想智能科技有限公司 | A kind of new wall paper |
| CN111910444A (en) * | 2020-08-12 | 2020-11-10 | 陈兵 | Wallpaper with flame-retardant adsorption performance |
| JP2022094092A (en) * | 2020-12-14 | 2022-06-24 | 凸版印刷株式会社 | Decorative sheet |
-
2022
- 2022-12-06 CN CN202211559088.1A patent/CN115897283A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015062730A1 (en) * | 2013-10-31 | 2015-05-07 | Schaefer Kalk Gmbh & Co. Kg | Article with low flammability |
| CN106917479A (en) * | 2015-12-28 | 2017-07-04 | 上海倡想智能科技有限公司 | A kind of new wall paper |
| CN105839450A (en) * | 2016-04-12 | 2016-08-10 | 陈长胜 | Papermaking method using enteromorpha |
| CN111910444A (en) * | 2020-08-12 | 2020-11-10 | 陈兵 | Wallpaper with flame-retardant adsorption performance |
| JP2022094092A (en) * | 2020-12-14 | 2022-06-24 | 凸版印刷株式会社 | Decorative sheet |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109629234B (en) | Preparation method of silazane and dopamine synergistic flame-retardant super-hydrophobic coating | |
| CN108642962B (en) | High-temperature-resistant halogen-free paper flame retardant | |
| CN102719154B (en) | Flame-retardant heat-insulating coating and preparation method thereof | |
| CN115897283A (en) | Dustproof and flame-retardant wallpaper and preparation method thereof | |
| CN111926934A (en) | Preparation method of composite flame retardant for fireproof heat-insulation decorative board | |
| CN108948932B (en) | Heat-preservation and heat-insulation coating and preparation method thereof | |
| CN108453853A (en) | A kind of high fire-retardance timber | |
| CN111826021B (en) | Organic gel for removing polyacrylic resin on surface of mural based on nano calcium hydroxide and preparation method thereof | |
| WO2021175065A1 (en) | Organic-inorganic hybrid fireproof coating and preparation method therefor | |
| CN116426174B (en) | Preparation method of high-flame-retardance high-weather-resistance stone-like coating | |
| CN114703667B (en) | Method for preparing flame-retardant cotton fabric based on attapulgite layer-by-layer self-assembly technology | |
| CN113117281B (en) | Basalt three-phase foam extinguishing agent and preparation method thereof | |
| CN114058083A (en) | Zirconium-based magnesium hydroxide and preparation method and application thereof | |
| CN108059898B (en) | Environment-friendly building fireproof coating and preparation method thereof | |
| CN113621258B (en) | Fireproof flame-retardant ecological coating and preparation method thereof | |
| CN114621619A (en) | Fireproof flame-retardant waterproof building coating and preparation method and product thereof | |
| CN114605874A (en) | Reinforced alkali-resistant permeable primer and preparation method thereof | |
| CN116904165B (en) | Environment-friendly dust inhibitor and application thereof in mine | |
| CN115873456B (en) | Water-based high-temperature-resistant coating and preparation method thereof | |
| CN111395674A (en) | Building wall surface structure and preparation method thereof | |
| CN114891373B (en) | Preparation method of transparent inorganic nano self-cleaning coating | |
| CN104327616B (en) | Glass-wool inorganic heat-insulating coating | |
| CN103351882A (en) | Liquid efficient fire retardation agent and preparation method thereof | |
| CN117965094A (en) | Environment-friendly efficient flame-retardant inorganic coating and preparation method thereof | |
| CN118271885B (en) | Fireproof coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |