CN115844785A - 植物染发剂及其制备方法 - Google Patents
植物染发剂及其制备方法 Download PDFInfo
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- CN115844785A CN115844785A CN202211669508.1A CN202211669508A CN115844785A CN 115844785 A CN115844785 A CN 115844785A CN 202211669508 A CN202211669508 A CN 202211669508A CN 115844785 A CN115844785 A CN 115844785A
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- agent
- plant
- hair
- hair dye
- extract
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- 239000000419 plant extract Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000284 extract Substances 0.000 claims abstract description 27
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Abstract
本发明公开了一种植物染发剂,包括A剂和B剂,A剂含有植物提取物,植物提取物为拳参水提物或拳参水提物与其他植物水提物的组合,B剂含有亚铁盐。据此,发明人还建立了相应产品的制备方法。本发明的植物染发剂中主要成分植物提取物用水进行提取,不存在有机溶剂残留的问题,因此所得植物染发剂产品更环保、更安全。此外,研究证实,本发明植物染发剂具有容易上色,提高染发色牢度,染发颜色自然,不易褪色等特点;而且拳参具有清热解毒、消肿、止血等功效,有利于减轻染发剂对头皮的刺激。应用该植物染发剂仅需根据发质进行
Description
技术领域
本发明属于化妆品技术领域,尤其涉及一种植物染发剂及其制备方法。
背景技术
目前不仅仅是老年人有白发,随着当代生活节奏的加快,各方面的压力以及不良生活习惯导致越来越多中青年人出现了大量白发。然而,市场上染发剂主流产品为化学染发剂,化学染发剂主要采用对苯二胺、苯二酚类或其衍生物经双氧水氧化而显色,此外还可能含有铅、汞、镉、镍等重金属。研究表明,该类化学染发剂对头皮有一定的损害,毒性大,容易导致皮炎,皮肤过敏等皮肤疾病,其中有些化学成分还会引起细胞突变,长期使用甚至引发癌症,危害人类健康。
植物染发剂以植物色素为主要染色原料,相对于化学染发剂,植物染发剂对环境的污染性更小,更加环保;同时,植物原料对头发造成原发性的刺激或伤害较小,对于产生皮肤过敏以及皮肤疾病的可能性也较小,添加不同的植物成分还可以使制备的染发剂同时具备染发、养发、护发等的功能;除此以外,天然植物染发剂可使头发具有更自然的色泽。然而,目前许多植物染发剂仍存在易褪色、植物提取过程中有机溶剂残留等问题。因此,亟需开发一种新型环保、不易褪色的天然植物染发剂。
拳参为蓼科植物拳参Polygonum bistortaL.的干燥根茎,始载于《本草图经》。具有清热解毒、消肿、止血之功效,主治赤痢热泻、肺热咳嗽、痈肿瘰疬、口舌生疮、血热吐衄、痔疮出血、蛇虫咬伤(参考文献:[1]王皓南,詹志来,刘大会,黄必胜,黄璐琦,杜鸿志.拳参本草再考证及其临床应用进展[J].中成药,2022,44(08):2607-2612.)。目前暂未见拳参用于染发的报道。
发明内容
本发明要解决的技术问题是提供一种植物染发剂及其制备方法,该染发剂产品具有无溶剂残留、染色色牢度高、不易褪色和安全环保等优点。
为解决上述技术问题,本发明采用以下技术方案:
拳参在染发方面的应用。
植物染发剂,含有拳参水提物。
上述植物染发剂,包括A剂和B剂,A剂含有植物提取物,植物提取物为拳参水提物或拳参水提物与其他植物水提物的组合,B剂含有亚铁盐。
其他植物水提物为五倍子水提物、石榴皮水提物、杨梅树皮水提物之一或其组合。
亚铁盐为硫酸亚铁、氯化亚铁、碳酸亚铁、七水合硫酸亚铁之一或其组合。
A剂还含有还原剂、碱剂、增稠剂、固色物质、香精、金属螯合剂;还原剂为硫代硫酸钠、亚硫酸钠、半胱氨酸、巯基乙酸、异抗坏血酸钠、L-抗坏血酸之一或其组合;碱剂为一乙醇胺、二乙醇胺、三乙醇胺、氢氧化钠、氢氧化钾、碳酸钠、碳酸氢钠之一或其组合;增稠剂为羧甲基纤维素、羧甲基纤维素钠、甲基纤维素、羟乙基纤维素、***胶、羟丙基纤维素、羟丙基甲基纤维素、黄原胶之一或其组合;固色物质为没食子酸、单宁酸之一或其组合;金属螯合剂为EDTA二钠盐、EDTA四钠盐之一或其组合。
B剂制备按以下进行操作:将十八醇,十六醇,二十烷基三甲基氯化铵,单硬脂酸甘油酯,聚二甲基硅氧烷,融化后搅拌成白色半固体,加水继续加热/>不断搅拌乳化成为半透明膏状,冷却至40℃左右加入香精,再加入亚铁盐不断搅拌均匀,膏体由半透明变为乳白色。
附图说明
图2是未经染色自然白发及应用各实施例染发剂染发后的效果图。
图3是各实施案例所染头发与自然黑发的色差值结果图,图中:△E1为与女性自然黑发的色差值,△E2为与男性自然黑发的色差值,色差值越小,表明两者颜色越接近。
具体实施方式
实施例1
按表1的配方配制植物染发剂的A剂,其中植物提取物溶液是由拳参、石榴皮、五倍子提取物溶液混合而成(体积比为4:3:3)
表1实施例1A剂配方
按表2的配方配制植物染发剂的B剂
表2实施例1B剂配方
A剂的制备方法如下:取植物提取物液,相继加入五水合硫代硫酸钠、亚硫酸钠、EDTA-2Na、三乙醇胺、L-半胱氨酸和异抗坏血酸钠,振摇使溶解,再加入没食子酸,用0.1mol/L盐酸溶液调节pH到8,加入香精,最后加入羧甲纤维素钠,边加边搅拌直至粘稠。
B剂的制备方法如下:将十八醇、十六醇、二十烷基三甲基氯化铵、单硬脂酸甘油酯、聚二甲基硅氧烷在下融化,搅拌均匀后加水继续加热15-20min,不断搅拌乳化成为半透明膏状,冷却至40℃左右加入香精,再加入七水合硫酸亚铁不断搅拌均匀,膏体半透明变为乳白色。
本实施例的植物染发剂的使用方法:将A剂涂抹于头发上,用保鲜膜包裹,在50℃下保持30min;之后将头发表面多余A剂清理擦拭干净,直接将B剂涂抹于头发上并用保鲜膜包裹,在50℃下保持20min进行显色,之后进行清洗即可。
实施例2
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,实施例2的A剂中植物提取物溶液是由拳参、石榴皮、五倍子提取物溶液混合而成(体积比为8:1:11)。
实施例3
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,实施例3的A剂中植物提取物溶液是由拳参、石榴皮、五倍子提取物溶液混合而成(体积比为12:1:7)。
实施例4
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,实施例4的A剂中植物提取物溶液是杨梅树皮提取物溶液。
实施例5
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,实施例5的A剂中植物提取物溶液是石榴皮提取物溶液。
实施例6
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,实施例6的A剂中植物提取物溶液是五倍子提取物溶液。
实施例7
配方成分(见表1、表2)、制法、用法与实施例1基本相同。不同的是,与实施例1不同的是,实施例7的A剂中植物提取物溶液是由拳参、杨梅树皮提取物溶液混合而成(体积比为1:1)。
采用全自动测色色差仪对头发样品进行测定,获取色差相关参数,从而对染发效果进行评价。每个样品测定三次,取平均值,分别记录各样品的色差参数L*、a*、b*、C*、h。L代表亮度,其值越大代表样品越亮(如L=100为白色,L=50为灰色,L=0为黑色);a代表红绿值,+a表示偏红的程度,-a表示偏绿的程度;b代表黄蓝值,+b表示偏黄的程度,-b表示偏蓝的程度;C表示饱和度,即纯度和彩度值,指色彩中色素的含量、色彩的鲜艳程度,其值越大表示颜色越鲜艳;h代表色相,表示0-360°范围的颜色角,其数值反映有色物质所属的颜色种类,如颜色角在0-90°之间则为红色、橙色和黄色,90-180°之间则为黄色、黄绿色和绿色,180-270°之间为绿色、青色和蓝色,270-360°为蓝色、紫色、洋红色和红色(参考文献:[2]丁芸.核桃青皮的活性成分提取及染色性能研究[D];新疆大学,2016.[3]高莉红.姜黄素的合成、染发及其染发机理研究[D];江南大学,2013.)。取25岁女性未经烫染的黑发、20岁男性未经烫染的黑发及自然白发作为对照,测三组平行数据后与实施案例进行色差对比。同时利用头发洗涤前后的色差(ΔE)对染发后的水洗牢固度进行评价,色差(ΔE)按式(1)进行计算。
△E* =[(Ln* - L0*)2 + (an* - a0*)2 + (bn* - b0*)2]1/2 (1)
其中L0*、a0*、b0*为染发后头发初次洗涤前的颜色特征值,Ln*、an*、bn*为染发后头发洗涤n次后的颜色特征值。
表3实施例1~7植物染发剂的染发效果
注:△E1为实施例与女性自然黑发的色差值;△E2为实施例与男性自然黑发的色差值;△E3表示实施例与自然白发的色差值。△E越小,表明两者的颜色越接近。
实施例染发后的效果,由表3和图3可知,相对于仅含石榴皮、五倍子或杨梅树皮提取物的植物染发剂(实例/>),含拳参提取物的植物染发剂(实施例/>)与自然黑发之间的色差值(△E1和△E2)较小,且与自然白发间的色差值(△E3)较大,说明实施例/>上色效果好且发色接近自然黑色。
实施例染发后的水洗牢固度见图4,相对于仅含石榴皮、五倍子或杨梅树皮提取物的植物染发剂(实例/>),含拳参提取物的植物染发剂(实施例/>)经过多次洗涤后的头发与未洗涤前的头发的色差值(ΔE)更小,说明通过将拳参提取物加入五倍子及石榴皮提取物中进行复配,可提高染发后的水洗牢固度。
实验结果表明,本发明植物染发剂能将头发染成黑色,且发色接近天然黑发,还具有耐洗色牢度高、不易褪色等优点。并且,本发明中色素来源天然,染发剂所含的拳参或杨梅树皮提取物具有抗氧化、抗炎、消肿等功效,对头皮和头发能够起到保护作用,同时有一定的抗菌效果,能提高染发剂的防腐性能。此外,本发明染发剂中的植物提取物用水进行提取,不存在有机溶剂残留的问题,具有安全环保的优点。
Claims (10)
1.拳参在染发方面的应用。
2.一种植物染发剂,其特征在于含有拳参水提物。
3.根据权利要求2所述的植物染发剂,其特征在于包括A剂和B剂,A剂含有植物提取物,植物提取物为拳参水提物或拳参水提物与其他植物水提物的组合,B剂含有亚铁盐。
4.根据权利要求3所述的植物染发剂,其特征在于:所述其他植物水提物为五倍子水提物、石榴皮水提物、杨梅树皮水提物之一或其组合。
5.根据权利要求3所述的植物染发剂,其特征在于:所述亚铁盐为硫酸亚铁、氯化亚铁、碳酸亚铁、七水合硫酸亚铁之一或其组合。
6.根据权利要求3所述的植物染发剂,其特征在于:所述A剂还含有还原剂、碱剂、增稠剂、固色物质、香精、金属螯合剂;所述还原剂为硫代硫酸钠、亚硫酸钠、半胱氨酸、巯基乙酸、异抗坏血酸钠、L-抗坏血酸之一或其组合;所述碱剂为一乙醇胺、二乙醇胺、三乙醇胺、氢氧化钠、氢氧化钾、碳酸钠、碳酸氢钠之一或其组合;所述增稠剂为羧甲基纤维素、羧甲基纤维素钠、甲基纤维素、羟乙基纤维素、***胶、羟丙基纤维素、羟丙基甲基纤维素、黄原胶之一或其组合;所述固色物质为没食子酸、单宁酸之一或其组合;所述金属螯合剂为EDTA二钠盐、EDTA四钠盐之一或其组合。
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