CN115583802B - 一种卤化物钙钛矿薄膜及其制备方法、装置 - Google Patents
一种卤化物钙钛矿薄膜及其制备方法、装置 Download PDFInfo
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- CN115583802B CN115583802B CN202211294779.3A CN202211294779A CN115583802B CN 115583802 B CN115583802 B CN 115583802B CN 202211294779 A CN202211294779 A CN 202211294779A CN 115583802 B CN115583802 B CN 115583802B
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- halide perovskite
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- heat conducting
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- 150000004820 halides Chemical class 0.000 title claims abstract description 123
- 238000002360 preparation method Methods 0.000 title abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 106
- 239000000758 substrate Substances 0.000 claims abstract description 97
- 239000002904 solvent Substances 0.000 claims abstract description 62
- 239000002243 precursor Substances 0.000 claims abstract description 35
- 239000010408 film Substances 0.000 claims description 106
- 239000010409 thin film Substances 0.000 claims description 39
- -1 halogen anion Chemical group 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 28
- 238000003860 storage Methods 0.000 claims description 25
- 150000001768 cations Chemical class 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- JCOZRYLPDMUROC-UHFFFAOYSA-N [N].CNC=O Chemical compound [N].CNC=O JCOZRYLPDMUROC-UHFFFAOYSA-N 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- BAVYZALUXZFZLV-UHFFFAOYSA-N mono-methylamine Natural products NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- BJMBNXMMZRCLFY-UHFFFAOYSA-N [N].[N].CN(C)C=O Chemical compound [N].[N].CN(C)C=O BJMBNXMMZRCLFY-UHFFFAOYSA-N 0.000 claims description 4
- NCMHKCKGHRPLCM-UHFFFAOYSA-N caesium(1+) Chemical compound [Cs+] NCMHKCKGHRPLCM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims description 3
- ABFQGXBZQWZNKI-UHFFFAOYSA-N 1,1-dimethoxyethanol Chemical compound COC(C)(O)OC ABFQGXBZQWZNKI-UHFFFAOYSA-N 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- OTYYBJNSLLBAGE-UHFFFAOYSA-N CN1C(CCC1)=O.[N] Chemical compound CN1C(CCC1)=O.[N] OTYYBJNSLLBAGE-UHFFFAOYSA-N 0.000 claims description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 2
- 229910001431 copper ion Inorganic materials 0.000 claims description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims description 2
- 229910001419 rubidium ion Inorganic materials 0.000 claims description 2
- 229910001432 tin ion Inorganic materials 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 13
- 238000007711 solidification Methods 0.000 abstract description 10
- 230000008023 solidification Effects 0.000 abstract description 10
- 230000001276 controlling effect Effects 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 19
- 238000000576 coating method Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 238000007639 printing Methods 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 6
- 230000008025 crystallization Effects 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 239000012296 anti-solvent Substances 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 238000004528 spin coating Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000010345 tape casting Methods 0.000 description 4
- 238000011049 filling Methods 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical compound [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 description 3
- LLWRXQXPJMPHLR-UHFFFAOYSA-N methylazanium;iodide Chemical compound [I-].[NH3+]C LLWRXQXPJMPHLR-UHFFFAOYSA-N 0.000 description 3
- 238000000935 solvent evaporation Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910021419 crystalline silicon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- QHJPGANWSLEMTI-UHFFFAOYSA-N aminomethylideneazanium;iodide Chemical compound I.NC=N QHJPGANWSLEMTI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- XQPRBTXUXXVTKB-UHFFFAOYSA-M caesium iodide Chemical compound [I-].[Cs+] XQPRBTXUXXVTKB-UHFFFAOYSA-M 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001548 drop coating Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3447—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a halide
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3441—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising carbon, a carbide or oxycarbide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Chemically Coating (AREA)
Abstract
Description
序号 | 结晶情况 |
实施例1 | 卤化物钙钛矿结晶 |
实施例2 | 卤化物钙钛矿结晶 |
实施例3 | 卤化物钙钛矿结晶 |
对比例1 | 卤化物钙钛矿未结晶 |
对比例2 | 卤化物钙钛矿未结晶 |
对比例3 | 卤化物钙钛矿未结晶 |
对比例4 | 卤化物钙钛矿未结晶 |
对比例5 | 卤化物钙钛矿结晶 |
Claims (10)
Priority Applications (1)
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CN202211294779.3A CN115583802B (zh) | 2022-10-21 | 2022-10-21 | 一种卤化物钙钛矿薄膜及其制备方法、装置 |
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CN202211294779.3A CN115583802B (zh) | 2022-10-21 | 2022-10-21 | 一种卤化物钙钛矿薄膜及其制备方法、装置 |
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CN115583802A CN115583802A (zh) | 2023-01-10 |
CN115583802B true CN115583802B (zh) | 2024-05-17 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116456790B (zh) * | 2023-06-19 | 2023-09-12 | 北京曜能科技有限公司 | 钙钛矿薄膜制备方法及钙钛矿太阳能电池、叠层电池 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106811794A (zh) * | 2017-03-03 | 2017-06-09 | 苏州协鑫纳米科技有限公司 | 用于钙钛矿晶体的结晶生长板、结晶釜及结晶装置 |
CN108026639A (zh) * | 2015-08-20 | 2018-05-11 | 香港科技大学 | 有机-无机钙钛矿材料及其光电器件的近空间升华制备 |
CN108569719A (zh) * | 2017-03-14 | 2018-09-25 | 韩国化学研究院 | 多孔性金属卤化物膜、其制备方法及利用其的钙钛矿结构的有机金属卤化物的制备方法 |
CN110581223A (zh) * | 2018-06-11 | 2019-12-17 | 湖北万度光能有限责任公司 | 太阳能电池的生产方法 |
CN113788629A (zh) * | 2021-08-19 | 2021-12-14 | 华中科技大学 | 一种高质量卤化物钙钛矿薄膜的制备方法 |
WO2022172869A1 (ja) * | 2021-02-15 | 2022-08-18 | 株式会社カネカ | ペロブスカイト薄膜系太陽電池の製造方法 |
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- 2022-10-21 CN CN202211294779.3A patent/CN115583802B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108026639A (zh) * | 2015-08-20 | 2018-05-11 | 香港科技大学 | 有机-无机钙钛矿材料及其光电器件的近空间升华制备 |
CN106811794A (zh) * | 2017-03-03 | 2017-06-09 | 苏州协鑫纳米科技有限公司 | 用于钙钛矿晶体的结晶生长板、结晶釜及结晶装置 |
CN108569719A (zh) * | 2017-03-14 | 2018-09-25 | 韩国化学研究院 | 多孔性金属卤化物膜、其制备方法及利用其的钙钛矿结构的有机金属卤化物的制备方法 |
CN110581223A (zh) * | 2018-06-11 | 2019-12-17 | 湖北万度光能有限责任公司 | 太阳能电池的生产方法 |
WO2022172869A1 (ja) * | 2021-02-15 | 2022-08-18 | 株式会社カネカ | ペロブスカイト薄膜系太陽電池の製造方法 |
CN113788629A (zh) * | 2021-08-19 | 2021-12-14 | 华中科技大学 | 一种高质量卤化物钙钛矿薄膜的制备方法 |
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Effective date of registration: 20240706 Address after: Building B409-20, 4th Floor, Building 1, Optoelectronic Innovation Park, No.1 Hanyang Road, Donghu New Technology Development Zone, Wuhan City, Hubei Province, China (Free Trade Zone Wuhan Area) Patentee after: Hubei Wan Guang Light Co.,Ltd. Country or region after: China Address before: South area of main factory building 2, No. 4, Guandong Science and Technology Industrial Park, Donghu New Technology Development Zone, Wuhan City, Hubei Province 430000 Patentee before: Wuhan Wandu Optical Energy Research Institute Co.,Ltd. Country or region before: China |