CN115522389A - Emulsified oil removing agent for printing and dyeing processing - Google Patents
Emulsified oil removing agent for printing and dyeing processing Download PDFInfo
- Publication number
- CN115522389A CN115522389A CN202211251469.3A CN202211251469A CN115522389A CN 115522389 A CN115522389 A CN 115522389A CN 202211251469 A CN202211251469 A CN 202211251469A CN 115522389 A CN115522389 A CN 115522389A
- Authority
- CN
- China
- Prior art keywords
- oil removing
- removing agent
- glyceride
- water
- polyether polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 24
- 238000004043 dyeing Methods 0.000 title claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 150000008052 alkyl sulfonates Chemical class 0.000 claims abstract description 26
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 25
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- 125000005456 glyceride group Chemical group 0.000 claims abstract description 25
- 229920000570 polyether Polymers 0.000 claims abstract description 25
- 229920005862 polyol Polymers 0.000 claims abstract description 25
- 150000003077 polyols Chemical class 0.000 claims abstract description 25
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims description 8
- 239000013527 degreasing agent Substances 0.000 claims description 7
- 238000005237 degreasing agent Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000004753 textile Substances 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 5
- 239000004744 fabric Substances 0.000 abstract description 21
- 239000012535 impurity Substances 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses an emulsified oil removing agent for printing and dyeing processing, which relates to the technical field of printing and dyeing processing, and comprises the following components in percentage by weight: 37-42% of alkyl polyether polyol, 5-10% of alkyl sulfonate, 19-23% of glyceride, 3-7% of butyl ether and the balance of water. The emulsified oil remover comprises alkyl polyether polyol, wherein the HBL value of the emulsified oil remover is between 10 and 13, the emulsified oil remover has wide oil removing performance, almost all oil agents on fabrics are contained, and impurities contained in the fabrics can be fully emulsified and dispersed in water by matching with the dispersing and washing performance of glyceride and alkyl sulfonate, and can not be coagulated, polymerized and adhered to the fabrics and equipment even if more impurities are contained.
Description
Technical Field
The invention relates to the technical field of printing and dyeing processing, in particular to an emulsified oil removing agent for printing and dyeing processing.
Background
In the weaving process of the fabric, due to the improvement of the textile technology, the original fabric can be woven only by sizing and increasing the strength, part of enterprises at present change oiling to reduce friction to weave, and the oil on the fabric can generate impurity dirt agglomeration in the cylinder connecting process of printing and dyeing processing to influence the printing and dyeing effect.
The traditional printing and dyeing processing needs to remove sizing agent, machine oil and other impurities on the fabric, and all the traditional printing and dyeing processing uses a compound product of emulsifiers with corresponding HBL values and surfactants with dispersive washing power.
However, most spinning oil in the existing market adopts mixed oil, the HBL value of the mixed oil is widely distributed, and the oil removing agent products, such as NP, AEO and isomeric alcohol ether emulsifiers, are difficult to be fully emulsified and dispersed, so that oil stains suspended in water are easy to agglomerate and adhere to equipment and fabrics. Therefore, those skilled in the art have provided an emulsified oil removing agent for textile printing processing to solve the problems set forth in the background art described above.
Disclosure of Invention
The invention aims to provide an emulsified oil removing agent for printing and dyeing processing, which solves the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the emulsified oil removing agent for printing and dyeing processing comprises the following components in percentage by weight: 37-42% of alkyl polyether polyol, 5-10% of alkyl sulfonate, 19-23% of glyceride, 3-7% of butyl ether and the balance of water.
As a further scheme of the invention: the oil removing agent comprises the following components in percentage by weight: 37% of alkyl polyether polyol, 5% of alkyl sulfonate, 19% of glyceride, 3% of butyl ether and the balance of water.
As a still further scheme of the invention: the oil removing agent comprises the following components in percentage by weight: 42% of alkyl polyether polyol, 10% of alkyl sulfonate, 23% of glyceride, 7% of butyl ether and the balance of water.
As a still further scheme of the invention: the oil removing agent comprises the following components in percentage by weight: 40% of alkyl polyether polyol, 8% of alkyl sulfonate, 20% of glyceride, 5% of butyl ether and the balance of water.
As a still further scheme of the invention: the degreasing agent is prepared by the following method: weighing the alkyl polyether polyol, the alkyl sulfonate, the glyceride, the butyl ether and water according to the weight percentage for later use, respectively putting the alkyl polyether polyol, the alkyl sulfonate, the glyceride and the butyl ether into a stirrer, adding the water, fully stirring and uniformly mixing.
As a still further scheme of the invention: the stirring time is 2h.
Compared with the prior art, the invention has the beneficial effects that: the invention discloses an emulsified degreasing agent for printing and dyeing processing, which comprises alkyl polyether polyol, wherein the HBL value of the emulsified degreasing agent is between 10 and 13, the emulsified degreasing agent has wide degreasing performance, almost all the degreasing agent on a fabric is contained, impurities contained in the fabric can be fully emulsified and dispersed in water by matching with the dispersing and washing performance of glyceride and alkyl sulfonate, and the impurities cannot be condensed, polymerized and inversely adhered to the fabric and equipment even if more impurities are contained.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the embodiment of the present invention, the first and second,
example 1
An emulsified oil removing agent for printing and dyeing processing comprises the following components in percentage by weight: 37% of alkyl polyether polyol, 5% of alkyl sulfonate, 19% of glyceride, 3% of butyl ether and the balance of water.
Further, the oil removing agent is prepared by adopting the following method: weighing alkyl polyether polyol, alkyl sulfonate, glyceride, butyl ether and water according to the weight percentage for later use, respectively putting the alkyl polyether polyol, the alkyl sulfonate, the glyceride and the butyl ether into a stirrer, adding the water, fully stirring for 2 hours, and uniformly mixing.
Example 2
An emulsified oil removing agent for printing and dyeing processing comprises the following components in percentage by weight: 42% of alkyl polyether polyol, 10% of alkyl sulfonate, 23% of glyceride, 7% of butyl ether and the balance of water.
Further, the oil removing agent is prepared by adopting the following method: weighing alkyl polyether polyol, alkyl sulfonate, glyceride, butyl ether and water according to the weight percentage for later use, respectively putting the alkyl polyether polyol, the alkyl sulfonate, the glyceride and the butyl ether into a stirrer, adding the water, fully stirring for 2 hours, and uniformly mixing.
Example 3
An emulsified oil removal agent for printing and dyeing processing comprises the following components in percentage by weight: 40% of alkyl polyether polyol, 8% of alkyl sulfonate, 20% of glyceride, 5% of butyl ether and the balance of water.
Further, the oil removing agent is prepared by adopting the following method: weighing the alkyl polyether polyol, the alkyl sulfonate, the glyceride, the butyl ether and water in parts by weight for later use, respectively putting the alkyl polyether polyol, the alkyl sulfonate, the glyceride and the butyl ether into a stirrer, adding the water, fully stirring for 2 hours, and uniformly mixing.
Examples of the experiments
The impurities contained in the existing fabric comprise the following components: engine oil (HBL 12-13), spinning lubricating oil (HBL 10-13), inorganic impurities and oligomers.
Comparative example: the oil removing agent in the prior art comprises the following components: NP-10 (HBL 12-13), AEO-9 (HBL 12-13), alkyl sulfonate and butyl ether.
The experimental method comprises the following steps:
taking 2 parts of 10g of fabric containing mixed oil and ash, putting the fabric into dyeing cups, respectively adding 5ml of the oil removing agent in the comparative example and 5ml of the oil removing agent in the example 3 with the concentration of 1% and 0.2g of caustic soda flakes into the two dyeing cups, respectively adding 100ml of water, preserving the heat at 130 ℃ for 30min, cooling to 40 ℃, and observing residual liquid and cloth surfaces.
The experimental results are as follows:
the residual liquid using the oil removing agent in comparative example 1 was turbid, and the water surface had a large amount of floating oil, and the residual liquid using the oil removing agent in example 3 was slightly turbid, and the water surface had no floating oil;
the cloth surface treated by the oil removing agent in the comparative example has heavy oil stain, and the cloth surface treated by the oil removing agent in the example 3 is basically clean.
The experiments show that compared with the oil removal agent in the prior art, the oil removal agent disclosed by the invention has good emulsification and dispersion properties, the influence of oil on the fabric on printing and dyeing processing is reduced, and the problem of impurity agglomeration in a cylinder connecting process is reduced.
The emulsified oil remover comprises alkyl polyether polyol, wherein the HBL value of the emulsified oil remover is between 10 and 13, the emulsified oil remover has wide oil removing performance, almost all oil agents on fabrics are contained, and impurities contained in the fabrics can be fully emulsified and dispersed in water by matching with the dispersing and washing performance of glyceride and alkyl sulfonate, and can not be coagulated, polymerized and adhered to the fabrics and equipment even if more impurities are contained.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (6)
1. An emulsified degreasing agent for printing and dyeing processing is characterized in that: the oil removing agent comprises the following components in percentage by weight: 37-42% of alkyl polyether polyol, 5-10% of alkyl sulfonate, 19-23% of glyceride, 3-7% of butyl ether and the balance of water.
2. The emulsified oil removing agent for textile printing processing according to claim 1, wherein: the oil removing agent comprises the following components in percentage by weight: 37% of alkyl polyether polyol, 5% of alkyl sulfonate, 19% of glyceride, 3% of butyl ether and the balance of water.
3. The emulsified oil removing agent for textile printing processing according to claim 1, wherein: the oil removing agent comprises the following components in percentage by weight: 42% of alkyl polyether polyol, 10% of alkyl sulfonate, 23% of glyceride, 7% of butyl ether and the balance of water.
4. The emulsified oil removing agent for textile printing processing according to claim 1, wherein: the oil removing agent comprises the following components in percentage by weight: 40% of alkyl polyether polyol, 8% of alkyl sulfonate, 20% of glyceride, 5% of butyl ether and the balance of water.
5. The emulsified oil removing agent for textile printing processing according to claim 1, wherein: the degreasing agent is prepared by the following method: weighing the alkyl polyether polyol, the alkyl sulfonate, the glyceride, the butyl ether and water according to the weight percentage for later use, respectively putting the alkyl polyether polyol, the alkyl sulfonate, the glyceride and the butyl ether into a stirrer, adding the water, fully stirring and uniformly mixing.
6. The emulsified oil removing agent for textile printing processing according to claim 5, wherein: the stirring time is 2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211251469.3A CN115522389A (en) | 2022-10-13 | 2022-10-13 | Emulsified oil removing agent for printing and dyeing processing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211251469.3A CN115522389A (en) | 2022-10-13 | 2022-10-13 | Emulsified oil removing agent for printing and dyeing processing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115522389A true CN115522389A (en) | 2022-12-27 |
Family
ID=84700918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211251469.3A Pending CN115522389A (en) | 2022-10-13 | 2022-10-13 | Emulsified oil removing agent for printing and dyeing processing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115522389A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107067A (en) * | 1976-06-25 | 1978-08-15 | The Procter & Gamble Company | Detergent composition |
| US5712240A (en) * | 1996-04-25 | 1998-01-27 | Reckitt & Colman Inc. | Aqueous cleaning compositions providing water and oil repellency to fiber substrates |
| JPH1143872A (en) * | 1997-07-24 | 1999-02-16 | Miyoshi Oil & Fat Co Ltd | Scouring agent for textile fiber |
| CN103554468A (en) * | 2013-10-31 | 2014-02-05 | 淄博德信联邦化学工业有限公司 | Method for preparing nonionic surfactant polyether polyol |
| US20190233778A1 (en) * | 2016-10-12 | 2019-08-01 | Henkel Ag & Co. Kgaa | Detergent composition having a flow limit |
| CN111101374A (en) * | 2018-10-29 | 2020-05-05 | 葛江波 | Environment-friendly multipurpose oil-removing scouring agent and preparation method thereof |
| CN114621828A (en) * | 2021-03-29 | 2022-06-14 | 南通麦特隆新材料科技有限公司 | Degreasing agent for IC carrier plate through hole landfill and preparation method thereof |
-
2022
- 2022-10-13 CN CN202211251469.3A patent/CN115522389A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107067A (en) * | 1976-06-25 | 1978-08-15 | The Procter & Gamble Company | Detergent composition |
| US5712240A (en) * | 1996-04-25 | 1998-01-27 | Reckitt & Colman Inc. | Aqueous cleaning compositions providing water and oil repellency to fiber substrates |
| JPH1143872A (en) * | 1997-07-24 | 1999-02-16 | Miyoshi Oil & Fat Co Ltd | Scouring agent for textile fiber |
| CN103554468A (en) * | 2013-10-31 | 2014-02-05 | 淄博德信联邦化学工业有限公司 | Method for preparing nonionic surfactant polyether polyol |
| US20190233778A1 (en) * | 2016-10-12 | 2019-08-01 | Henkel Ag & Co. Kgaa | Detergent composition having a flow limit |
| CN111101374A (en) * | 2018-10-29 | 2020-05-05 | 葛江波 | Environment-friendly multipurpose oil-removing scouring agent and preparation method thereof |
| CN114621828A (en) * | 2021-03-29 | 2022-06-14 | 南通麦特隆新材料科技有限公司 | Degreasing agent for IC carrier plate through hole landfill and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20221227 |
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| RJ01 | Rejection of invention patent application after publication |