CN115363035A - Rain wash resistant herbicide composition and application thereof - Google Patents
Rain wash resistant herbicide composition and application thereof Download PDFInfo
- Publication number
- CN115363035A CN115363035A CN202110552501.0A CN202110552501A CN115363035A CN 115363035 A CN115363035 A CN 115363035A CN 202110552501 A CN202110552501 A CN 202110552501A CN 115363035 A CN115363035 A CN 115363035A
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- CN
- China
- Prior art keywords
- herbicide
- mass ratio
- herbicidal composition
- application
- fluroxypyr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
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Abstract
The application provides a herbicide composition resistant to rain wash and application thereof. The herbicide composition comprises a herbicide A, a herbicide B and a herbicide C, wherein the herbicide A is one of halauxifen-ethyl and halauxifen-ethyl, the herbicide B is at least one of triclopyr and fluroxypyr, and the herbicide C comprises at least one of atrazine, ametryn, terbuthylazine and diuron.
Description
Technical Field
The application relates to the technical field of herbicides, in particular to a rain wash-resistant herbicide composition and application thereof.
Background
The weeds are one of three pests in agricultural production, and can compete with crops for a growth space, so that the normal growth of the crops is influenced, the yield is reduced, great loss is caused to the agricultural production, and the yield reduction of the crops caused by the weeds in China is more than 10%. Weeds have a overgrowing habit, and if the weeds are not prevented and controlled in time, the urban attractiveness and road traffic safety are affected.
The current methods of weed control are primarily the application of herbicides, also known as herbicides, a class of substances used to kill or inhibit the growth of plants. At present, the herbicide is widely used for preventing and treating harmful plants such as weeds, miscellaneous irrigation, miscellaneous trees and the like in farmlands, orchards, flower nursery gardens, grasslands, non-cultivated lands, railway lines, riverways, reservoirs, warehouses and the like. The herbicide has the characteristics of good effect, high efficiency, low cost, simplicity, convenience, feasibility and the like, and contributes greatly to stable, rapid and healthy development of agriculture.
However, the existing herbicide has poor rain erosion resistance in the application process, and if the existing herbicide encounters rain in a short time after application, the weeding effect is affected. Since the weeding in uncultivated areas and orchards belongs to the weeding peak period within 6-9 months, more rainwater exists at the time, and if rainfall occurs within 6 hours after application, the weeding effect is often greatly influenced and is difficult to play a role in weeding; on the other hand, the difficulty of controlling aged and aged weeds is high. The time of emergence of weeds is often uneven, so long-acting weed control is difficult to realize, and particularly in non-cultivated land, orchard and other areas, the difficulty in preventing and killing weeds is greater due to the management requirements and cost limiting factors; in addition, the existing herbicide has narrow weed control spectrum and poor weeding effect.
Disclosure of Invention
In order to improve the above problems, the present application provides a rainwash-resistant herbicide composition which has an excellent effect on controlling older weeds, aged weeds, and malignant weeds, is less affected by rainwash, and is particularly suitable for weed control in non-cultivated lands and orchards.
The present application provides a rainwash-resistant herbicide composition comprising herbicidal active ingredients: herbicide A, herbicide B and herbicide C,
the herbicide A is: at least one of chlorofluoropyridine ester and chlorofluoropyridine ester;
the herbicide B is: at least one of triclopyr and fluroxypyr; and
the herbicide C is: at least one of atrazine, ametryn, terbuthylazine and diuron;
wherein the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.05-4) to (1-25) to (2-30), and within the ratio range, the weeding active ingredients have a synergistic effect.
When the herbicide A is halauxifen-methyl and the herbicide B is triclopyr, the mass ratio of the herbicide C to atrazine to ametryn to terbuthylazine to diuron is (0.05-3) - (2-25) - (2-30), such as (0.1-1.5) - (5-18) - (3-25), and further such as (0.2-0.6) - (6-12) - (4-20).
When the herbicide A is fluroxypyr and the herbicide B is triclopyr, the mass ratio of the herbicide C to atrazine to ametryn to terbuthylazine to diuron is (0.1-4) to (2-25) to (2-30), for example, the mass ratio is (0.3-3) to (5-18) to (3-25), and further for example, the mass ratio is (0.6-1.5) to (6-12) to (4-20).
When the herbicide A is halauxifen-methyl and the herbicide B is fluroxypyr, the mass ratio of the herbicide C atrazine to ametryn to terbuthylazine to diuron is (0.05-3) to (1-10) to (2-30), such as the mass ratio of (0.1-1.5) to (2-8) to (3-25), and further such as the mass ratio of (0.2-0.6) to (3-5) to (4-20).
When the herbicide A is fluroxypyr and the herbicide B is fluroxypyr, the mass ratio of the herbicide C atrazine, ametryn, terbuthylazine and diuron is (0.1-4) to (1-10) to (2-30), for example, the mass ratio is (0.3-3) to (2-8) to (3-25), and further for example, the mass ratio is (0.6-1.5) to (3-5) to (4-20).
When the herbicide A is halauxifen-methyl and the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glufosinate ammonium in the mass ratio of (0.05-3) to (2-25) to (2-30) to (15-40), for example, in the mass ratio of (0.1-1.5) to (5-18) to (3-25) to (20-35), and further for example, in the mass ratio of (0.2-0.6) to (6-12) to (4-20) to (25-30).
When the herbicide A is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glufosinate-ammonium in a mass ratio of (0.1-4) to (2-25) to (2-30) to (15-40), such as (0.3-3) to (5-18) to (3-25) to (20-35), and such as (0.6-1.5) to (6-12) to (4-20) to (25-30).
When the herbicide A is halauxifen-methyl and the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glufosinate in a mass ratio of (0.05-3), (1-10), (2-30), (15-40), such as (0.1-1.5), (2-8), (3-25), (20-35), and such as (0.2-0.6), (3-5), (4-20) and (25-30).
When the herbicide A is fluroxypyridine ester and the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glufosinate-ammonium in the mass ratio of (0.1-4) to (1-10) to (2-30) to (15-40), for example, in the mass ratio of (0.3-3) to (2-8) to (3-25) to (20-35), and further for example, in the mass ratio of (0.6-1.5) to (3-5) to (4-20) to (25-30).
When the herbicide A is halauxifen-methyl and the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glyphosate in a mass ratio of (0.05-3) to (2-25) to (2-30) to (30-80), such as (0.1-1.5) to (5-18) to (3-25) to (40-60), and further such as (0.2-0.6) to (6-12) to (4-20) to (45-55).
When the herbicide A is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glyphosate, the mass ratio of which is (0.1-4) to (2-25) to (2-30) to (30-80), such as (0.3-3) to (5-18) to (3-25) to (40-60), and such as (0.6-1.5) to (6-12) to (4-20) to (45-55).
When the herbicide A is halauxifen-methyl and the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glyphosate in a mass ratio of (0.05-3) to (1-10) to (2-30) to (30-80), such as a mass ratio of (0.1-1.5) to (2-8) to (3-25) to (40-60), and further such as a mass ratio of (0.2-0.6) to (3-5) to (4-20) to (45-55).
When the herbicide A is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine and diuron, and the herbicide D is glyphosate, wherein the mass ratio of the glyphosate is (0.1-4) to (1-10) to (2-30) to (30-80), for example, the mass ratio of the glyphosate is (0.3-3) to (2-8) to (3-25) to (40-60), and further for example, the mass ratio of the glyphosate is (0.6-1.5) to (3-5) to (4-20) to (45-55).
When the herbicidal composition comprises herbicide a, herbicide B and herbicide C, the effective amount of the herbicidal composition is 10 to 500g (a.i.)/ha, such as 20 to 450g (a.i.)/ha or 30 to 400g (a.i.)/ha, it is understood that the above-mentioned ratios are merely examples, and in one embodiment of the present application, other ratios, such as 300g (a.i.)/ha, may be used in the range of the content of the herbicidal composition in the formulation.
When the herbicidal composition includes the herbicide a, the herbicide B, the herbicide C, and the herbicide D is glufosinate, the effective amount of the herbicidal composition is 200 to 900g (a.i.) ha, for example 300 to 850g (a.i.) ha or 450 to 750g (a.i.) ha.
When the herbicidal composition comprises herbicide a, herbicide B, herbicide C and herbicide D, and the herbicide D is glyphosate, the effective amount of the herbicidal composition is 500 to 1500g (a.i.)/ha, for example 600 to 1200g (a.i.)/ha or 700 to 1100g (a.i.)/ha.
The application also provides a preparation containing the herbicide composition, the mass percentage of the herbicide active ingredient is 1-85%, the preparation can be any agriculturally acceptable preparation, preferably wettable powder and oil suspending agent, and more preferably oil suspending agent.
The application also provides the application of the herbicide composition, and the herbicide composition is used for controlling weeds in non-cultivated lands and/or orchards.
Has the advantages that:
according to the rain-wash-resistant herbicide composition, the herbicide A, the herbicide B and the herbicide C are compounded according to a specific proportion, so that the composition has a synergistic effect, is wide in weed control spectrum, is good in effects on/resistance to fluorochloropyridinate, triclopyr and fluorochloropyr weeds, is also good in quick-acting performance on large-age weeds, and is long in lasting period. In addition, the herbicide composition provided by the application is resistant to rain wash, the defect that atrazine, ametryn, diuron and terbuthylazine are not resistant to rain is overcome, and adverse effects on the environment are reduced.
Detailed Description
Definition and description of terms:
the orchard in the application refers to a garden for planting fruit trees, also called a fruit tree garden, and includes, but is not limited to, fields such as oranges, apples, pear trees, peaches, plums, apricots and the like.
The non-cultivated land in the present application refers to a region where crops are not planted, including but not limited to the front and back of a house, a railway, a highway, a warehouse, forest fire prevention, ditch edge, roadside, wasteland, forest land and the like.
At present, the halauxifen-methyl is commonly used for preventing and killing broadleaf weeds in wheat fields and is ineffective to gramineous weeds. The fluroxypyr-meptyl is mainly researched, developed and applied on rice at present, stem and leaf treatment can effectively prevent and kill barnyard grass, broad-leaved weeds and annual sedge, but has obvious selectivity on weeds, and has poor effects on Euphorbia lathyris, ludwigia prostrata, ribes nigrum and perennial sedge including scirpus planiculmis, iris lactea, cyperus aquatica, boea felterrata and water chestnut and the like.
Atrazine, a herbicide selectively absorbed pre-and post-emergence. The root absorption is the main one, the stem and leaf absorption is little, and the stem and leaf are quickly conducted to plant meristems and leaf parts to interfere photosynthesis and cause the death of weeds. It is known that it is applied to control broadleaf weeds and grassy weeds in corn, sorghum, sugarcane and the like, but the efficacy of it is seriously affected by drought, rainfall and the like.
Ametryn, a selective systemic herbicide, belongs to a typical photosynthesis inhibitor. Are known to be applied in sugarcane, citrus, corn, soybean, potato, pea, carrot fields to control annual weeds.
Terbuthylazine, which is absorbed mainly by the roots of plants, is used for controlling most weeds and is applied before emergence. It is known that it is applied to crop fields such as corn, wheat, barley, potato, pea, sorghum, and citrus to control various weeds, and also to selectively control citrus, corn, and vineyard weeds.
Diuron, which is a substituted urea herbicide, has a systemic conduction effect and a certain contact action. After the medicament is absorbed by the root system or the leaves of the plant, photosynthesis is inhibited, so that the leaves are green, the leaf tips and the edges are faded, and the plants die due to lack of nutrition. It is known to be applied to crops such as cotton, soybean, tomato, tobacco, strawberry, grape, orchards, rubber gardens, etc. to control annual grassy weeds and certain broadleaf weeds such as Echinochloa crusgalli, crab grass, green bristlegrass, wild amaranth, cyperus rotundus, chenopodium quinoa, etc.
Wherein atrazine, ametryn, diuron and terbuthylazine all belong to photosystem II inhibitors (PS II inhibitors).
Glufosinate-ammonium belongs to a non-conductive contact herbicide, and is used for preventing and controlling weeds by inhibiting glutamine synthetase, so that the nitrogen metabolism in plants is disturbed, nitrogen accumulation poisoning is caused, the synthesis and photosynthesis of chloroplasts are hindered, and finally the plants die. With years of use, resistant weeds are also gradually reported.
The glyphosate, including various salts thereof, belongs to an organic phosphine systemic conduction type biocidal herbicide, is a systemic conduction type herbicide, has a broad weed control spectrum, but due to single use for a long time, a plurality of common weeds have been found to generate resistance to the glyphosate in the world, and common malignant weed resistant erigeron breviscapus, resistant eleusine indica and related tolerant weeds cannot be effectively killed.
When the herbicides are combined together according to the compounding proportion, the application can achieve an obvious synergistic effect and is resistant to rain wash, and the following is a specific compounding scheme.
First, the present application provides a herbicidal composition comprising herbicidally active ingredients: herbicide A, herbicide B and herbicide C,
the herbicide A is: at least one of chlorofluoropyridine ester and chlorofluoropyridine ester;
the herbicide B is: at least one of triclopyr and fluroxypyr; and
the herbicide C is: at least one of atrazine, ametryn, terbuthylazine and diuron;
wherein the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.05-4) to (1-25) to (2-30).
In some embodiments, the herbicide a is halauxifen, the herbicide B is triclopyr, and the herbicide C is atrazine, ametryn, terbuthylazine, diuron in a mass ratio of (0.05-3) to (2-25) to (2-30), such as in a mass ratio of (0.1-1.5) to (5-18) to (3-25), and further such as in a mass ratio of (0.2-0.6) to (6-12) to (4-20).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is triclopyr, and the herbicide C is atrazine, ametryn, terbuthylazine, diuron in a mass ratio of (0.1-4) to (2-25) to (2-30), such as in a mass ratio of (0.3-3) to (5-18) to (3-25), and further such as in a mass ratio of (0.6-1.5) to (6-12) to (4-20).
In some embodiments, the herbicide a is halauxifen, the herbicide B is fluroxypyr, and the herbicide C is atrazine, ametryn, terbuthylazine, diuron in a mass ratio of (0.05-3) to (1-10) to (2-30), such as in a mass ratio of (0.1-1.5) to (2-8) to (3-25), and further such as in a mass ratio of (0.2-0.6) to (3-5) to (4-20).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is a fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron in a mass ratio of (0.1-4) to (1-10) to (2-30), e.g., in a mass ratio of (0.3-3) to (2-8) to (3-25), and further e.g., in a mass ratio of (0.6-1.5) to (3-5) to (4-20).
In some embodiments, the herbicide a is halauxifen, the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glufosinate in a mass ratio of (0.05-3) to (2-25) to (2-30) to (15-40), such as in a mass ratio of (0.1-1.5) to (5-18) to (3-25) to (20-35), and such as in a mass ratio of (0.2-0.6) to (6-12) to (4-20) to (25-30).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glufosinate in a mass ratio of (0.1-4) to (2-25) to (2-30) to (15-40), such as in a mass ratio of (0.3-3) to (5-18) to (3-25) to (20-35), such as in a mass ratio of (0.6-1.5) to (6-12) to (4-20) to (25-30).
In some embodiments, the herbicide a is halauxifen, the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glufosinate in a mass ratio of (0.05-3) to (1-10) to (2-30) to (15-40), such as in a mass ratio of (0.1-1.5) to (2-8) to (3-25) to (20-35), such as in a mass ratio of (0.2-0.6) to (3-5) to (4-20) to (25-30).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, the herbicide D is glufosinate-ammonium in a mass ratio of (0.1-4) to (1-10) to (2-30) to (15-40), e.g., in a mass ratio of (0.3-3) to (2-8) to (3-25) to (20-35), further e.g., in a mass ratio of (0.6-1.5) to (3-5) to (4-20) to (25-30).
In some embodiments, the herbicide a is halauxifen, the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glyphosate in a mass ratio of (0.05-3), (2-25), (2-30), (30-80), e.g., in a mass ratio of (0.1-1.5), (5-18), (3-25), (40-60), e.g., in a mass ratio of (0.2-0.6), (6-12), (4-20), (45-55).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is triclopyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glyphosate in a mass ratio of (0.1-4) to (2-25) to (2-30) to (30-80), e.g., in a mass ratio of (0.3-3) to (5-18) to (3-25) to (40-60), e.g., in a mass ratio of (0.6-1.5) to (6-12) to (4-20) to (45-55).
In some embodiments, the herbicide a is halauxifen, the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, and the herbicide D is glyphosate in a mass ratio of (0.05-3) to (1-10) to (2-30) to (30-80), such as in a mass ratio of (0.1-1.5) to (2-8) to (3-25) to (40-60), such as in a mass ratio of (0.2-0.6) to (3-5) to (4-20) to (45-55).
In some embodiments, the herbicide a is a fluroxypyr, the herbicide B is fluroxypyr, the herbicide C is atrazine, ametryn, terbuthylazine, diuron, the herbicide D is glyphosate in a mass ratio of (0.1-4) to (1-10) to (2-30) to (30-80), e.g., in a mass ratio of (0.3-3) to (2-8) to (3-25) to (40-60), e.g., in a mass ratio of (0.6-1.5) to (3-5) to (4-20) to (45-55).
Throughout this application, the mass ratio of herbicide a, herbicide B to herbicide C, or herbicide a, herbicide B, herbicide C to herbicide D, represents a ratio of the mass of the three/four components, and the range of the respective ratios includes all mass ratios that fall within the range of the ratios of this application, multiplied or divided by any coefficient, such as 90: (0.05 to 4): (1-20). Without being limited to the listed examples, other mass ratios are within the scope of the present application as long as the mass ratios of the three substances are multiplied or divided by any coefficient.
In some embodiments, the herbicidal composition comprises herbicide a, herbicide B and herbicide C, and the effective amount of the herbicidal composition is 10 to 500g (a.i.)/ha, such as 20 to 450g (a.i.)/ha or 30 to 400g (a.i.)/ha, it being understood that the above-mentioned ratios are merely examples, and in one embodiment of the present application, the herbicidal composition may be used in other effective amounts within the range of the amount in the formulation, such as 300g (a.i.)/ha.
In some embodiments, the herbicidal composition comprises herbicide a, herbicide B, herbicide C, and herbicide D.
When the herbicide D is glufosinate-ammonium, the effective amount of the herbicidal composition is 200 to 900g (a.i.)/ha, such as 300 to 850g (a.i.)/ha or 450 to 750g (a.i.)/ha, it being understood that the above-mentioned ratios are merely examples, and in one embodiment of the present application, other effective amounts may be used in the range of the amount of the herbicidal composition in the formulation, such as 450g (a.i.)/ha;
when the herbicide D is glyphosate, the effective amount of the herbicidal composition is 500 to 1500g (a.i.)/ha, such as 600 to 1200g (a.i.)/ha or 700 to 1100g (a.i.)/ha, it being understood that the above ratios are merely examples, and in one embodiment of the present application, other effective amounts, such as 1100g (a.i.)/ha, may be used in the range of the amount of the herbicidal composition in the formulation.
The application also provides a preparation containing the herbicide composition, the mass percentage of the herbicide active ingredient is 1-85%, the preparation can be any agriculturally allowable dosage form, and on the basis of the herbicide composition, the preparation can be wettable powder or oil suspending agent in consideration of improvement of rain wash resistance.
In some embodiments, the herbicidal composition is present in the formulation in an amount of 1% to 85% by weight, e.g., 1%, 10%, 20%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, etc., it being understood that these proportions are exemplary only and that in other embodiments of the present application, the herbicidal composition may be present in the formulation in other ranges, e.g., 5%.
Wherein, the wettable powder comprises the following auxiliary materials: naphthalene sulfonate, sodium dodecyl sulfate, lignosulfonate, white carbon black and kaolin.
The auxiliary materials of the oil suspending agent comprise: vegetable oil and its derivatives (methyl oleate), calcium dodecylbenzene sulfonate, castor oil polyoxyethylene ether, polycarboxylate, alkylphenol polyoxyethylene ether, and organic bentonite.
In some embodiments, the herbicidal composition comprises herbicide a, herbicide B, and herbicide C.
When the herbicide composition is prepared into an oil suspending agent, the mass percent of the herbicide A, B and C is 1-45% of the total mass of the oil suspending agent.
When the herbicide composition is prepared into wettable powder, the mass percentage of the herbicide A, B and C is 1-85% of the total mass of the wettable powder.
In some embodiments, the herbicidal composition comprises herbicide a, herbicide B, herbicide C, and herbicide D, which is glyphosate.
When the herbicide composition is prepared into an oil suspending agent, the mass percent of the herbicides A, B, C and D is 35-45% of the total mass of the oil suspending agent.
When the herbicide composition is prepared into wettable powder, the mass percentage of the herbicides A, B, C and D is 35-85%, for example 38-75%, based on the total mass of the wettable powder.
In some embodiments, the herbicidal composition comprises herbicide a, herbicide B, herbicide C, and herbicide D, which is glufosinate.
When the herbicide composition is prepared into an oil suspending agent, the mass percent of the herbicides A, B, C and D is 1-45% of the total mass of the oil suspending agent.
When the herbicide composition is prepared into wettable powder, the mass percentage of the herbicides A, B, C and D is 1-85%, such as 26-75%, based on the total mass of the wettable powder.
The application also provides the application of the herbicide composition, and the herbicide composition is used for controlling weeds in non-cultivated lands and/or orchards.
The technical solution of the present application will be described in detail below with reference to examples.
Examples
In order to make the purpose, technical solution and advantages of the present application more concise and clear, the present application is described with the following specific examples, but the present application is by no means limited to these examples. The following description is of the preferred embodiment of the present application and is provided for the purpose of illustration only and should not be construed as limiting the scope of the invention. It should be understood that any modification, equivalent replacement or improvement made within the spirit and principle of the present application is included in the protection scope of the present application. Therefore, the protection scope of the present patent shall be subject to the appended claims.
In these examples, all percentages are by weight unless otherwise indicated.
The proportion of each embodiment is as follows:
the present application provides a total of 608 examples of herbicidal compositions, the specific proportions of herbicide a, herbicide B, herbicide C and herbicide D in each example are detailed in table 1 below:
table 1 formulation tables for herbicidal compositions of examples 1 to 608
Comparative example
A total of 40 comparative examples are provided herein, each having a formulation as detailed in table 2 below:
table 2 formulation tables of the herbicidal compositions of comparative example 1 to comparative example 40
Test example 1: field effective period test 1 (Fluoropicolinate + triclopyr + PS II inhibitor)
1.1. Reagent to be tested: as shown in table 1, the three-element compound herbicide prepared in example 1 to example 120 contains halauxifen, triclopyr and ametryn or atrazine or terbuthylazine or diuron in different proportions. As shown in Table 2, the two-element and three-element compound herbicide prepared by different combinations and proportions of the halauxifen, the triclopyr, the ametryn or the atrazine or the terbuthylazine or the diuron and the prometryn in the comparative examples 1 to 13 and the comparative example 23.
1.2. Control agents: see table 3 below for details:
TABLE 3 control agent information sheet involved in field efficacy test
1.3. Target weeds: 8-10 branch bermudagrass, 4-5 tillering eleusine indica, 10-15 leaf stage purslane, 10-15 leaf stage chenopodium album, and the like.
1.4. The test method comprises the following steps: the test is carried out in a citrus orchard in the Wuming district of Nanning city, guangxi province, the test land is red loam, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. Each treatment was repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were identical for each treated area except that the herbicidal composition/control was applied according to the above protocol.
After spraying the herbicide composition/control agent on each treatment area for 10, 20, 40 and 60 days, 4 points of each treatment area are randomly sampled, and the area of each sample is 0.5m 2 And weighing the fresh weight of the overground part of the 4 kinds of target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the total fresh weight control effect of the 4 kinds of target weeds, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
table 4 total fresh weight control in field (%) -after varying time of herbicidal compositions of fluroxypyr-meptyl + atrazine + triclopyr
As can be seen from table 4, in terms of quick-acting property and effective duration of common weeds, as can be seen from comparison among examples 1 to 30, comparative example 1, comparative example 2 and comparative example 6, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-component and binary-component herbicides. As can be seen from comparison between examples 1 to 30 and comparative examples 10 and 23, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property after 10 days, thoroughness property after 20 days, and effective duration after 40 days and 60 days after application, compared with other formulation ratios.
TABLE 5 Total fresh weight control in the field (%) -after various times of herbicidal composition of Fluoropicolide + ametryn + Trifluoxyacetic acid
As can be seen from table 5, in terms of quick-acting property and effective period of common weeds, it can be seen from comparison among examples 31 to 60, comparative examples 1, 3 and 7 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-component and binary complex herbicidal active ingredients. As can be seen from comparison between examples 31 to 60 and comparative examples 11 and 23, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, compared with other combination ratios.
TABLE 6 Total fresh weight control in the field (%) -after herbicidal composition of Fluoropicolide + terbuthylazine + Trifluroxypyr for different times
As can be seen from Table 6, on the quick-acting property and the lasting period of common weeds, the ternary compound herbicidal composition provided by the embodiment of the application is obviously superior to the single-component and binary compounds of the active ingredients of various herbicides as can be seen from the comparison among the examples 61 to 90, the comparative examples 1, 4 and 8. As can be seen from comparison between examples 61 to 90 and comparative examples 12 and 23, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in the quick-acting property 10 days after application, the thoroughness 20 days after application, and the effective duration 40 days and 60 days after application, compared with other combination ratios.
Table 7 total field fresh weight control effect (%) (in%) at different times after herbicidal compositions of halauxifen + diuron + triclopyr
As can be seen from table 7, in terms of quick-acting property and effective duration of common weeds, it can be seen from comparison among examples 91 to 120, comparative examples 1, 5 and 9 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-component and binary-component herbicides of various herbicidal active ingredients. As can be seen from comparison between examples 91 to 120 and comparative examples 13 and 23, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in the quick-acting property 10 days after application, the thoroughness property 20 days after application, and the effective duration 40 days and 60 days after application, compared with other combination ratios.
Test example 2: field duration test 1 (Fluoropicolide + Fluoroglycofen + PS II inhibitor)
2.1. Reagent to be tested: as shown in table 1, the three-element compound herbicide prepared in example 121 to example 240 contains fluroxypyr, fluroxypyr and ametryn or atrazine or terbuthylazine or diuron in different proportions. As shown in Table 2, the three-element and two-element compound herbicide prepared from the fluorochloropyridine ester, fluroxypyr and ametryn or atrazine or terbuthylazine or diuron in different combinations and proportions in comparative examples 2 to 5, 25 to 33 and 39.
2.2. Control agents: see table 8 below for details:
TABLE 8 control agent information Table involved in field drug effect test
2.3. Target weeds: setaria viridis at 8-10 leaf stage, conyza canadensis at 10-12 leaf stage, amaranthus deltoides at 10-12 leaf stage, solanum nigrum at 10-12 leaf stage, etc.
2.4. The test method comprises the following steps: the test is performed in south-ning City of Guangxi provinceThe test is carried out in a citrus orchard in the Wuming area, the test land is red loam, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. The treatment doses are referred to tables 9 to 12, and each treatment is repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were identical for each treated area except that the herbicidal composition/control was applied according to the above protocol.
After spraying the herbicide composition/control agent on each treatment area for 10, 20, 40 and 60 days, 4 points of each treatment area are randomly sampled, and the area of each sample is 0.5m 2 And weighing the fresh weight of the overground part of the 4 kinds of target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the total fresh weight control effect of the 4 kinds of target weeds, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 9 Total fresh weight control in the field at various times after herbicidal composition of Fluoropicolide + Atrazine + Fluroxypyr (%)
As can be seen from table 9, in terms of quick-acting performance and effective duration of common weeds, it can be seen from comparison among examples 121 to 150, comparative examples 2, 25 and 26 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between example 121 and example 150 and comparative examples 30 and 39, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, as compared with other formulation ratios.
TABLE 10 Total fresh weight control in the field at various times after herbicidal compositions of Fluoropicolide + ametryn + Fluroxypyr (%)
As can be seen from table 10, on the quick-acting property and the lasting period of common weeds, as can be seen from comparison among examples 151 to 180, comparative examples 3, 25 and 27, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between examples 151 to 180 and comparative examples 31 and 39, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, as compared with other formulation ratios.
Table 11 total fresh weight control in field (%), at different times after herbicidal compositions fluroxypyridine ester + terbuthylazine + fluroxypyr
As can be seen from table 11, in terms of quick-acting property and effective period of common weeds, it can be seen from comparison among examples 181-210, comparative examples 4, 25 and 28 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between examples 181-210 and comparative examples 32 and 39, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, as compared with other formulation ratios.
TABLE 12 Total fresh weight control in field (%) -at different times after herbicidal composition of halauxifen + diuron + fluroxypyr
As can be seen from table 12, on the quick-acting property and the lasting period of common weeds, as can be seen from comparison among examples 211 to 240, comparative example 5, comparative example 25 and comparative example 29, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex of each herbicidal active ingredient. As can be seen from comparison between examples 211 to 240 and comparative examples 33 and 39, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, as compared with other formulation ratios.
Test example 3: field Effect test 1 (Fluroxypyridyl ester + triclopyr + PS II inhibitor)
3.1. Reagent to be tested: (Table 1) the fluroxypyr, the triclopyr and the ametryn or the atrazine or the terbuthylazine or the diuron prepared in the examples 241 to 360 are ternary compound herbicides with different mixture ratios. (Table 2) the fluroxypyr, the triclopyr and ametryn or atrazine or terbuthylazine or diuron prepared by the comparative examples 6 to 9, 14 to 22 and 24 are ternary and binary compound herbicides with different combinations and proportions.
3.2. Control agents: see table 13 below for details:
TABLE 13 control agent information sheet involved in field efficacy test
3.3. Target weeds: 5-10 tillering barnyard grass, 6-9 hispid arthraxon, 12-15 leaf-stage Amaranthus retroflexus, 3 branch broad-leaved Fengfeng grass and the like.
3.4. The test method comprises the following steps: the test is carried out in a citrus orchard in the Wuming district of Nanning city, guangxi province, the test land is red loam, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. The treatment doses are shown in tables 14-17, and each treatment is repeated 4 times, and each treatment area is 30m 2 Diluting with water to spray amount of 40L per mu, and using water as blank instead of herbicidal compositionTreatments, trial treatments were arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were identical for each treated area except that the herbicidal composition/control was applied according to the above protocol.
After spraying the herbicide composition/control agent on each treatment area for 10, 20, 40 and 60 days, 4 points of each treatment area are randomly sampled, and the area of the sample is 0.5m 2 And weighing the fresh weight of the overground part of the 4 kinds of target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the total fresh weight control effect of the 4 kinds of target weeds, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 14 Total fresh weight control in field (%) > at different times after herbicidal composition of Fluroxypyridyl ester + Atrazine + Trichloropyric acid
As can be seen from table 14, in terms of quick-acting property and effective duration of common weeds, it can be seen from comparison among examples 241 to 270, comparative example 6, comparative example 14 and comparative example 15 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-component and binary complex herbicidal active ingredients. As can be seen from comparison between examples 241 to 270, and comparative examples 19 and 24, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, compared with other combination ratios.
TABLE 15 Total fresh weight control in the field at various times after herbicidal compositions of fluroxypyr, ametryn, triclopyr (%)
As can be seen from table 15, on the quick-acting property and the lasting period of common weeds, as can be seen from comparison among examples 271 to 300, comparative example 7, comparative example 14 and comparative example 16, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-component and binary complex herbicides. As can be seen from comparison between examples 271 to 300 and comparative examples 20 and 24, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, as compared with other formulation ratios.
TABLE 16 Total fresh weight control in field (%) > at different times after herbicidal composition of fluroxypyr, terbuthylazine and triclopyr
As can be seen from table 16, on the quick-acting property and the lasting period of common weeds, as can be seen from comparison among examples 301 to 330, comparative example 8, comparative example 14 and comparative example 17, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex of each herbicidal active ingredient. As can be seen from comparison between examples 301 to 330 and comparative examples 21 and 24, the herbicidal composition provided by the present application has significantly superior effects in the quick-acting property 10 days after application, the thoroughness property 20 days after application, and the effective duration 40 days and 60 days after application, compared with other formulation ratios.
TABLE 17 Total fresh weight control in field (%) > at different times after herbicidal composition of fluroxypyr, diuron, triclopyr
As can be seen from table 17, in terms of quick-acting property and effective period of common weeds, it can be seen from comparison among examples 331 to 360, comparative examples 9, 14 and 18 that the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between examples 331 to 360 and comparative examples 22 and 24, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in the quick-acting property 10 days after application, the thoroughness 20 days after application, and the effective duration 40 days and 60 days after application, compared with other combination ratios.
Test example 4: duration of field test 1 (fluroxypyr, PS II inhibitor)
4.1. Reagent to be tested: in table 1, the fluroxypyr and the ametryn or the atrazine or the terbuthylazine or the diuron prepared in the examples 361 to 480 are ternary compound herbicides with different mixture ratios. (Table 2) ternary and binary compound herbicides of different combinations and proportions of fluroxypyr, ametryn or atrazine or terbuthylazine or diuron prepared in comparative examples 15 to 18, 26 to 29, 34 to 38 and 40.
4.2. Control agents: see table 18 below for details:
TABLE 18 control drug information Table involved in field drug effect test
4.3. Target weeds: sorghum halepense in 12-leaf stage, nit grass in 13-15-leaf stage, copperleaf herb in 8-12-leaf stage, pokeberry root in 10-13-leaf stage and the like.
4.4. The test method comprises the following steps: the test is carried out in a citrus orchard in the Wuming district of Nanning city, guangxi province, the test land is red loam, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. The treatment doses are shown in tables 19-22, and each treatment is repeated 4 times, and each treatment area is 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were otherwise identical for each treatment area except that the herbicidal composition/control was applied according to the protocol described above.
After spraying the herbicide composition/control agent on each treatment area for 10, 20, 40 and 60 days, 4 points of each treatment area are randomly sampled, and the area of each sample is 0.5m 2 Weighing the fresh weight of the overground part of the 4 kinds of target weeds in each treatment area, and controlling the effect by the total fresh weight of the 4 kinds of target weedsEvaluating the control effect of the medicament on the target weeds, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 19 Total fresh weight control in field (%) > at different times after herbicidal composition of fluroxypyridine + atrazine + fluroxypyr
As can be seen from table 19, in the quick action and the lasting period of the common weeds, the ternary complex herbicidal composition provided by the examples of the present application is obviously superior to the single-component and binary-component herbicides of the respective herbicidal active ingredients, as can be seen from the comparison among the examples 361 to 390, the comparative examples 15, the comparative examples 26 and the comparative examples 34. As can be seen from comparison between examples 331-360 and comparative examples 35 and 40, the herbicidal composition provided by the present application has significantly superior effects on the quick action 10 days after application, the thoroughness 20 days after application, and the effective duration 40 days and 60 days after application, compared with other formulation ratios.
TABLE 20 Total fresh weight control in field (%), at various times after herbicidal composition of fluroxypyridine ester + ametryn + fluroxypyr
As can be seen from table 20, in terms of quick action and effective duration of common weeds, it can be seen from comparison among examples 391-420, comparative examples 16, 27 and 34 that the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between examples 391 to 420 and comparative examples 36 and 40, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects compared to other combination ratios in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application.
TABLE 21 fresh weight control in field at different times after herbicidal composition of fluroxypyridine + terbuthylazine + fluroxypyr (%)
As can be seen from table 21, on the quick-acting property and the lasting period of common weeds, as can be seen from comparison among examples 421 to 450, comparative examples 17, 28 and 34, the ternary complex herbicidal composition provided by the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients. As can be seen from comparison between examples 421 to 450 and comparative examples 37 and 40, the combination ratio of the effective components of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property after 10 days, thoroughness after 20 days, and effective duration after 40 days and 60 days after application, compared with other combination ratios.
TABLE 22 fresh weight control in field at various times after herbicidal composition of fluroxypyridine ester + diuron + fluroxypyr (%)
As can be seen from Table 22, the ternary complex herbicidal composition provided by the examples of the application is obviously superior to the single-component and binary complex herbicidal active ingredients in comparison with comparative example 18, comparative example 29 and comparative example 34 in the quick-acting property and the lasting period of the common weeds. As can be seen from comparison between examples 451 to 480 and comparative examples 38 and 40, the formulation ratio of each active ingredient of the herbicidal composition provided by the present application has significantly superior effects in terms of quick-acting property 10 days after application, thoroughness 20 days after application, and effective duration 40 days and 60 days after application, compared with other formulation ratios.
Test example 5: control of resistant/tolerant weeds (Fluoropicolinate + Trichloropicolinic acid + PS II inhibitor)
5.1. Reagent to be tested: (Table 1) the three-element compound herbicide prepared in the examples 1 to 120 comprises the halauxifen, the triclopyr and the atrazine or the terbuthylazine or the diuron in different proportions. (Table 2) the three-element and two-element compound herbicide prepared from the fluroxypyr, the triclopyr, the ametryn or the atrazine or the terbuthylazine or the diuron prepared in comparative examples 1 to 13 and 23 in different combinations and proportions.
5.2. Control agents: see Table 3
5.3. Target weeds: 8 to 10 branches of veronica officinalis and 10 leaves of 1-heartleaf shepherd's purse.
5.4. The test method comprises the following steps: the test is carried out on the barren land of the complex city in Henan province, and the test land is yellow brown soil with smooth topography. The test field has no other herbicide before and after the test, and has stable weed populationAnd the distribution is uniform. The respective treatment doses are shown in tables 25 to 26, and each treatment was repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were otherwise identical for each treatment area except that the herbicidal composition/control was applied according to the above protocol.
After spraying the herbicide composition/control agent for 35 days in each treatment area, 4 points in each treatment area were randomly sampled to obtain a sample area of 0.5m 2 And weighing the fresh weight of the overground part of the target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the control effect of the fresh weight of the target weeds, and calculating the control effect of the fresh weight according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 23 field fresh weight control Effect (%) -35 days after application of the Fluoropicolide + Atrazine + Trifluopicolide herbicidal composition
As can be seen from table 23, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
TABLE 24 field fresh weight control Effect (%)
As can be seen from table 24, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 25 fresh weight control in field 35 days after application of the herbicidal compositions Fluoropicolide + terbuthylazine + triclopyr (%)
As can be seen from table 25, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to the single-component and binary complex herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 26 field fresh weight control Effect (%) -35 days after application of the Fluoropicolide + diuron + Trifluoxyacetic acid herbicidal composition
As can be seen from table 26, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 6: antagonistic/resistant weed control (Fluoropicolinate + Fluroxypyr + PS II inhibitor)
6.1. Reagent to be tested: (Table 1) the three-element compound herbicide of fluroxypyr, fluroxypyr and ametryn or atrazine or terbuthylazine or diuron prepared in examples 121 to 240 in different proportions. (Table 2) the three-element and two-element compound herbicide prepared by different combinations and proportions of the fluroxypyr, the ametryn or the atrazine or the terbuthylazine or the diuron in the comparative examples 2 to 5, the comparative examples 25 to 33 and the comparative example 39.
6.2. Control agents: see table 8.
6.3. Target weeds: 9-12 leaf stage caraway and 8-13 leaf stage Chenopodium album L.
6.4. The test method comprises the following steps: the test is carried out on the barren lands of the seas and the west in Qinghai province, the test lands are chestnut calcium soil, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. Each treatment was repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. Remove and pressThe other conditions were completely consistent for each treatment area except for the application of the herbicidal composition/control.
After spraying the herbicide composition/control agent for 35 days in each treatment area, 4 points in each treatment area were randomly sampled to obtain a sample area of 0.5m 2 And weighing the fresh weight of the overground part of the target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the control effect of the fresh weight of the target weeds, and calculating the control effect of the fresh weight according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 27 fresh weight control in field 35 days after herbicidal Fluoropicolide + Atrazine + Fluroxypyr compositions (%)
As can be seen from table 27, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 28 fresh weight control in field 35 days after herbicidal composition Fluoropicolide + ametryn + Fluroxypyr (%)
As can be seen from table 28, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to the single-component and binary complex herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
TABLE 29 fresh weight control in field 35 days after herbicidal Fluoropicolide + terbuthylazine + Fluroxypyr composition application (%)
As can be seen from table 29, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 30 field fresh weight control Effect (%) -35 days after herbicidal composition of Fluoropicolide + diuron + Fluroxypyr
As can be seen from table 30, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 7: antagonistic/resistant weed control (fluroxypyr + triclopyr + PS II inhibitor)
7.1. Reagent to be tested: (Table 1) the three-element compound herbicide of fluroxypyr, triclopyr and ametryn or atrazine or terbuthylazine or diuron prepared in examples 241 to 360 in different proportions. (Table 2) the fluroxypyr, the triclopyr and ametryn or atrazine or terbuthylazine or diuron prepared by the comparative examples 6 to 9, 14 to 22 and 24 are ternary and binary compound herbicides with different combinations and proportions.
7.2. Control agents: see table 13.
7.3. Target weeds: 5 tillering Iris pallida, 3-5 tillering scirpus planiculmis.
7.4. The test method comprises the following steps: the test is carried out on a wasteland in the Almony region of Heilongjiang province, the test land is black loam, the upper stubble is rice, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. Each treatment was repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Lingnong, and adopts a stem and leaf spraying method. The conditions were identical for each treated area except that the herbicidal composition/control was applied according to the above protocol.
After spraying the herbicide composition/control agent for 35 days in each treatment area, 4 points in each treatment area were randomly sampled to obtain a sample area of 0.5m 2 And weighing the above-ground fresh weight of the target weeds in each treatment area to targetEvaluating the control effect of the agent on the target weeds according to the fresh weight control effect of the target weeds, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 31 field fresh weight control efficacy (%) (35 days after herbicidal compositions of fluroxypyr, atrazine, triclopyr
As can be seen from table 31, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 32 fresh weight control in field 35 days after herbicidal composition of Fluroxypyridyl ester + ametryn + triclopyr (%)
As can be seen from table 32, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to the single-component and binary complex herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 33 field fresh weight control effect (%) 35 days after herbicidal composition of fluroxypyridine ester + terbuthylazine + triclopyr
As can be seen from table 33, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 34 field fresh weight control effect (%) 35 days after herbicidal composition of fluroxypyr, diuron, triclopyr
As can be seen from table 34, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
Test example 8: antagonistic/resistant weed control (fluroxypyr + PS II inhibitor)
8.1. Reagent to be tested: (Table 1) the fluroxypyr, the fluroxypyr and the ametryn or the atrazine or the terbuthylazine or the diuron prepared in the examples 361 to 480 are ternary compound herbicides with different mixture ratios. (Table 2) three-element and two-element compound herbicides with different combinations and proportions of fluroxypyr, ametryn, atrazine, terbuthylazine or diuron prepared by comparative example 15 to comparative example 18, comparative example 26 to comparative example 29, comparative example 34 to comparative example 38 and comparative example 40.
8.2. Control agents: see table 18.
8.3. Target weeds: 10-15 leaf period felt of boehmeria, 13-16 leaf period yellow croaker.
8.4. The test method comprises the following steps: the test is carried out in a wasteland in Changsha county of Hunan province, the test land is chestnut calcium soil, and the terrain is smooth. Other herbicides are not applied before and after the test, and the weed population stability and uniform distribution are realized. Each treatment was repeated 4 times with a treatment area of 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Lingnong, and adopts a stem and leaf spraying method. The conditions were otherwise identical for each treatment area except that the herbicidal composition/control was applied according to the above protocol.
After each treatment area was sprayed with the herbicidal composition/control agent for 35 days, 4-point random sampling was conducted on each treatment area at an area of 0.5m 2 And weighing the fresh weight of the overground part of the target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the control effect of the fresh weight of the target weeds, and calculating the control effect of the fresh weight according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 35 fresh weight control Effect (%) in the field 35 days after herbicidal composition of Fluroxypyridyl ester + Atrazine + Fluroxypyr
As can be seen from table 35, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 36 fresh weight control in field 35 days after herbicidal composition of fluroxypyr, ametryn + fluroxypyr (%)
As can be seen from table 36, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 37 fresh weight control in field 35 days after herbicidal composition of fluroxypyridine ester + terbuthylazine + fluroxypyr (%)
As can be seen from table 37, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
TABLE 38 fresh weight control in field 35 days after herbicidal composition of fluroxypyridine ester + diuron + fluroxypyr (%)
As can be seen from table 38, the ternary complex herbicidal composition provided in the examples of the present application is significantly superior to single-agent and binary complex herbicidal active ingredients in the control of resistant/tolerant weeds. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 9: rain erosion test (Fluoropicolinate + Trifluroxypyr + PS II inhibitor)
9.1. Reagent to be tested: (Table 1) the three-element compound herbicide prepared in the examples 1 to 120 comprises the halauxifen, the triclopyr and the atrazine or the terbuthylazine or the diuron in different proportions. (Table 2) the three-element and two-element compound herbicide prepared in different combinations and proportions of the halauxifen, the triclopyr and the ametryn or the atrazine or the terbuthylazine or the diuron in the comparative examples 1 to 13 and the comparative example 23.
9.2. Control agents: refer to table 3.
9.3. Target weeds: 7-8 leaf period of Veronica officinalis L.
9.4. The test method comprises the following steps: the method is carried out according to a potted plant stem and leaf treatment method of NY/T1155.4-2006, quantitative soil is filled in plastic pots with the height of 8cm and the diameter of 9cm, speedwell seeds are dibbled in the plastic pots, 15 seeds are sown in each plastic pot, the plastic pots are cultured in an artificial climate chamber, redundant plants are pulled out after emergence of seedlings, only 8 plants are reserved in each plastic pot, when weeds grow to 7-8 leaf stages, spraying treatment is carried out on a walking type spraying tower, water treatment is set as blank control, and the treatment is repeated for 8 times. After the liquid medicine is naturally dried, each treatment is divided into 2 parts, and each part is repeated for 4 times. After 4 hours of pesticide application, one part is simulated with a walking spray tower for artificial rainfall for 20 minutes, the other part is not treated, and after the target weed leaf water drops are dried in the air, the target weeds are moved into a greenhouse for observation.
After spraying the herbicidal composition/control agent for 35 days in each treatment area, the fresh weight of the aerial parts was weighed. Evaluating the control effect of the medicament on the target weeds by using the fresh weight control effect, and calculating the fresh weight control effect according to the following formula:
the results are detailed in the following table:
table 39 fresh weight control effect in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 39, the ternary complex herbicidal composition provided by the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in terms of rainfastness. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
Table 40 fresh weight control in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 40, the ternary complex herbicidal composition provided by the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 41 fresh weight control effect in room 35 days after application of control agent/herbicidal composition to each treated area (%)
As can be seen from table 41, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
TABLE 42 fresh weight control in the room 35 days after application of control/herbicidal composition to each treatment area (%)
As can be seen from table 42, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in rainwash resistance. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 10: rain erosion test (Fluoropicolide + Fluroxypyr + PS II inhibitor)
10.1. Reagent to be tested: (Table 1) the three-element compound herbicide prepared from the fluroxypyr, the fluroxypyr and the atrazine or the terbuthylazine or the diuron in different proportions in the examples 121 to 240. (Table 2) the three-element and two-element compound herbicide prepared by different combinations and proportions of the fluroxypyr, the ametryn or the atrazine or the terbuthylazine or the diuron in the comparative examples 2 to 5, the comparative examples 25 to 33 and the comparative example 39.
10.2. Control agents: refer to table 8.
10.3. Target weeds: and (4) caraway anise.
10.4. The test method comprises the following steps: the method is carried out according to the method for treating stem leaves of a pot plant of NY/T1155.4-2006, quantitative soil is filled in plastic pots with the height of 8cm and the diameter of 9cm, caraway anisole seeds are dibbled in the plastic pots, 15 seeds are sowed in each plastic pot, the plastic pots are cultured in an artificial climate chamber, redundant plants are pulled out after emergence of seedlings, only 8 plants are reserved in each plastic pot, when weeds grow to 7-8 leaf stages, spraying treatment is carried out on a walking type spraying tower, water treatment is set as blank control, and the treatment is repeated for 8 times. After the liquid medicine is naturally dried, each treatment is divided into 2 parts, and each part is repeated for 4 times. After 4 hours of pesticide application, one part is simulated artificial rainfall by using a walking type spray tower, the other part is not treated, and after the target weed leaf water drops are dried in the air, the target weeds are moved into a greenhouse for observation.
After spraying the herbicidal composition/control agent for 35 days in each treatment area, the fresh weight of the aerial parts was weighed. Evaluating the control effect of the medicament on the target weeds by using the fresh weight control effect, and calculating the fresh weight control effect according to the following formula:
the results are detailed in the following table:
table 43 fresh weight control in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 43, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 44 indoor fresh weight control effect (%) (35 days after application of control/herbicidal composition to each treatment area)
As can be seen from table 44, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in rainwash resistance. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
Table 45 fresh weight control effect in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 45, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 46 fresh weight control effect in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 46, the ternary complex herbicidal composition provided by the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 11: rain erosion test (Fluroxypyridyl ester + triclopyr + PS II inhibitor)
11.1. Reagent to be tested: as shown in table 1, the three-element compound herbicide prepared in examples 241 to 360 comprises fluroxypyr, triclopyr and ametryn or atrazine or terbuthylazine or diuron in different proportions. As shown in Table 2, the fluroxypyr, the triclopyr and ametryn or atrazine or terbuthylazine or diuron prepared in comparative examples 6 to 9, 14 to 22 and 24 are ternary and binary compound herbicides in different combinations and proportions.
11.2. Control agents: see table 13 for details.
11.3. Target weeds: scirpus planiculmis at 5-6 leaf stage.
11.4. The test method comprises the following steps: the method is carried out according to the potted stem and leaf treatment method of NY/T1155.4-2006, quantitative soil is filled in plastic pots with the height of 8cm and the diameter of 9cm, scirpus planiculmis seeds are dibbled in the plastic pots, 15 seeds are sowed in each plastic pot, the scirpus planiculmis are cultured in an artificial climate chamber, redundant plants are pulled out after seedling emergence, only 8 plants are reserved in each plastic pot, when weeds grow to 7-8 leaf stages, spraying treatment is carried out on a walking type spraying tower, and water treatment is set as blank control and is repeated for 8 times. After the liquid medicine is naturally dried, each treatment is divided into 2 parts, and each part is repeated for 4 times. After 4 hours of pesticide application, one part is simulated artificial rainfall by using a walking type spray tower, the other part is not treated, and after the target weed leaf water drops are dried in the air, the target weeds are moved into a greenhouse for observation.
After spraying the herbicidal composition/control agent for 35 days in each treatment area, the fresh weight of the aerial parts was weighed. Evaluating the control effect of the medicament on the target weeds by the fresh weight control effect, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
table 47 fresh weight control in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 47, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 48 fresh weight control effect in house 35 days after application of control agent/herbicidal composition to each treated area (%)
As can be seen from table 48, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 49 fresh weight control effect in house 35 days after application of control agent/herbicidal composition to each treated area (%)
As can be seen from table 49, the ternary complex herbicidal composition provided by the embodiments of the present application is significantly superior to single agents and binary complexes of the respective herbicidal active ingredients in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 50 fresh weight control effect in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 50, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 12: rain erosion test (fluroxypyridine ester + fluroxypyr + PS II inhibitor)
12.1. Reagent to be tested: as shown in Table 1, the fluroxypyr and the ametryn or the atrazine or the terbuthylazine or the diuron prepared in the examples 361 to 480 are ternary compound herbicides with different mixture ratios. As shown in Table 2, the three-element and two-element compound herbicides in different combinations and proportions of the fluroxypyr, the ametryn, the atrazine, the terbuthylazine or the diuron prepared in comparative examples 15 to 18, 26 to 29, 34 to 38 and 40.
12.2. Control agents: see table 18 for details.
12.3. Target weeds: 5-6 leaf stage HUANGHUASHUILONG.
12.4. The test method comprises the following steps: the method is carried out according to a potted plant stem and leaf treatment method of NY/T1155.4-2006, quantitative soil is filled in plastic pots with the height of 8cm and the diameter of 9cm, yellow croaker seeds are dibbled in the plastic pots, 15 seeds are sown in each plastic pot, the plastic pots are cultured in an artificial climate chamber, redundant plants are pulled out after emergence of seedlings, only 8 plants are reserved in each plastic pot, when weeds grow to 7-8 leaf stages, spraying treatment is carried out on a walking type spraying tower, water treatment is set as blank control, and the treatment is repeated for 8 times. After the liquid medicine is naturally dried, each treatment is divided into 2 parts, and each part is repeated for 4 times. After 4 hours of pesticide application, one part is simulated artificial rainfall by using a walking type spray tower, the other part is not treated, and after the target weed leaf water drops are dried in the air, the target weeds are moved into a greenhouse for observation.
After spraying the herbicidal composition/control agent for 35 days in each treatment area, the fresh weight of the aerial parts was weighed. Evaluating the control effect of the medicament on the target weeds by using the fresh weight control effect, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
TABLE 51 fresh weight control Effect (%) indoor 35 days after application of control agent/herbicidal composition to each treated area
As can be seen from table 51, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
Table 52 fresh weight control effect in the room 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 52, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in terms of rainfastness. Moreover, as can be seen from comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a significantly excellent effect compared with other compounding ratios.
TABLE 53 fresh weight control in the house 35 days after application of control/herbicidal composition to each treated area (%)
As can be seen from table 53, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in rainwash resistance. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Table 54 indoor fresh weight control effect (%) 35 days after application of control/herbicidal composition drugs to each treated area
As can be seen from table 54, the ternary complex herbicidal composition provided in the embodiments of the present application is significantly superior to single agents and binary complexes of each herbicidal active ingredient in rainwash resistance. Moreover, as can be seen from the comparison of the data of the examples and the comparative examples, the compounding ratio of each effective component of the herbicidal composition provided by the application has a remarkably excellent effect compared with other compounding ratios.
Test example 13: combined test with glufosinate-ammonium
13.1. Reagent to be tested: as shown in table 1, examples 481 to 512, and examples 545 to 576, the example prepares a quaternary built herbicide of fluroxypyr or fluroxypyr, triclopyr or fluroxypyr, ametryn or terbuthylazine or diuron and glufosinate in different proportions.
13.2. Control agents: see table 55 below for details:
TABLE 55 control drug information Table related to field drug effect test
13.3. Target weeds: more than 10 tillers of glufosinate-ammonium-resistant eleusine indica.
13.4. The test method comprises the following steps: the test is carried out in a flower and tree field in the Jiangmen city of Guangdong province, the test field is red loam, and the terrain is smooth. The test field has used glufosinate-ammonium for 12 years all the year round, and has higher resistance to glufosinate-ammonium and is almost ineffective when used alone. Each treatment was repeated 4 times, each treatment area being 30m 2 The application is carried out by diluting with water until the spray quantity per mu is 40L, and replacing the weeding composition with water as blank treatment, and the test treatments are arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Linong, and adopts a stem leaf spraying method. The conditions were otherwise identical for each treatment area except that the herbicidal composition/control was applied according to the protocol described above.
After spraying the herbicide composition/control agent for 35 days, 4 points of each treatment area are randomly sampled, and the area of the sample is 1m 2 Weighing the above-ground fresh weight of the target weeds in each treatment area, and weighing the target weedsEvaluating the control effect of the agent on the target weeds according to the fresh weight control effect of the grass, and calculating the fresh weight control effect according to the following formula:
the results of the field efficacy test are detailed in the following table:
table 56 fresh weight control in field 35 days after application of control/fluroxypyridine ester + triclopyr + atrazine or ametryn or terbuthylazine or diuron + glufosinate herbicidal composition to each treatment area (%)
As can be seen from table 56, the herbicidal compositions containing glufosinate provided in the examples of the present application are effective against old age resistant goosegrass.
Table 57 field fresh weight control effect (%) -35 days after application of control/herbicidal composition to each treatment area
As can be seen from table 57, the herbicidal compositions containing glufosinate provided in the examples of the present application are effective against old age resistant goosegrass.
Table 58 fresh weight control in field 35 days after application of control/fluroxypyridine ester + fluroxypyr + atrazine or ametryn or terbuthylazine or diuron + glufosinate herbicidal composition to each treatment area (%)
As can be seen from table 58, the herbicidal compositions containing glufosinate provided in the examples of the present application are effective against old age resistant goosegrass.
Table 59 fresh weight control in field 35 days after control/fluroxypyr, atrazine, terbuthylazine, diuron, glufosinate herbicide composition application in each treatment area (%)
As can be seen from table 59, the herbicidal compositions containing glufosinate provided in the examples of the present application are effective against old age resistant goosegrass.
Test example 14: combined test with glyphosate
14.1. Reagent to be tested: as shown in table 1, examples 513 to 544, examples 577 to 608, and quaternary built herbicides of different proportions of fluroxypyr or fluroxypyr, triclopyr or fluroxypyr, ametryn or atrazine or terbuthylazine or diuron prepared in the examples and glyphosate.
14.2. Control agents: see table 60 below for details:
TABLE 60 control agent information Table involved in field drug effect test
14.3. Target weeds: 30-50 cm glyphosate-resistant erigeron breviscapus.
14.4. The test method comprises the following steps: the test is carried out between rows of seedlings in Lujiang county of Anhui province, the test field is red loam, and the terrain is smooth. Test ofGlufosinate has been used for 12 years throughout the year, has a high resistance to glufosinate, and is almost ineffective when used alone. Each treatment was repeated 4 times, each treatment area being 30m 2 The application was carried out by diluting with water to a spray volume of 40L per acre and replacing the herbicidal composition with water as a blank treatment, the test treatments being arranged in random blocks. The pesticide spraying device is an AGROLEX HD400 electric sprayer of Singapore Lingnong, and adopts a stem and leaf spraying method. The conditions were otherwise identical for each treatment area except that the herbicidal composition/control was applied according to the protocol described above.
After spraying the herbicidal composition/control agent for 35 days in each treatment area, 4-point random sampling was carried out in each treatment area with a sample area of 1m 2 And weighing the fresh weight of the overground part of the target weeds in each treatment area, evaluating the control effect of the medicament on the target weeds according to the control effect of the fresh weight of the target weeds, and calculating the control effect of the fresh weight according to the following formula:
the results of the field efficacy test are detailed in table 61 below:
table 61 fresh weight control in field 35 days after application of control/fluroxypyridine ester + triclopyr + atrazine or ametryn or terbuthylazine or diuron + glyphosate herbicidal composition to each treatment area (%)
As can be seen from table 61, the herbicidal compositions containing glyphosate provided in the examples of the present application are effective against the older resistant erigeron breviscapus.
Table 62 fresh weight control in field 35 days after application of control/fluroxypyridine ester + triclopyr + atrazine or ametryn or terbuthylazine or diuron + glyphosate herbicidal composition to each treatment area (%)
As can be seen from table 62, the herbicidal compositions containing glyphosate provided in the examples of the present application are effective against the older resistant erigeron breviscapus.
Table 63 fresh weight control in field 35 days after application of control/fluroxypyridine ester + fluroxypyr + atrazine or ametryn or terbuthylazine or diuron + glyphosate herbicidal composition to each treatment area (%)
As can be seen from table 63, the herbicidal compositions containing glyphosate provided in the examples of the present application are effective against the older resistant erigeron breviscapus.
Table 64 fresh weight control in field 35 days after application of control/fluroxypyridine ester + fluroxypyr + atrazine or ametryn or terbuthylazine or diuron + glyphosate herbicidal composition to each treatment area (%)
As can be seen from table 64, the herbicidal compositions containing glyphosate provided in the examples of the present application are effective against the older resistant erigeron breviscapus.
The rainwash-resistant herbicide composition and the application thereof provided by the application are described in detail above. The principle and the implementation of the present application are explained by applying specific examples, and the description of the above embodiments is only used to help understand the technical solution and the core idea of the present application; those of ordinary skill in the art will understand that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; such modifications or substitutions do not depart from the scope of the embodiments of the present application.
Claims (18)
1. A rainwash-resistant herbicide composition, characterized in that it comprises a herbicidally active ingredient comprising a herbicide A, a herbicide B and a herbicide C,
the herbicide A is: at least one of chlorofluoropyridine ester and chlorofluoropyridine ester;
the herbicide B is: at least one of triclopyr and fluroxypyr;
the herbicide C is: at least one of atrazine, ametryn, terbuthylazine and diuron;
wherein the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.05-4) to (1-25) to (2-30).
2. The herbicide composition as claimed in claim 1, wherein the herbicide A is halauxifen-ethyl, the herbicide B is triclopyr, and the mass ratio of the herbicide A, the herbicide B and the herbicide C is (0.05-3): (2-25): (2-30);
preferably, the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.1-1.5) to (5-18) to (3-25).
3. The herbicide composition as claimed in claim 1, wherein the herbicide A is fluroxypyr meptyl, the herbicide B is triclopyr, and the mass ratio of the herbicide A, the herbicide B and the herbicide C is (0.1-4): (2-25): (2-30);
preferably, the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.3-3) to (5-18) to (3-25).
4. A herbicide composition as claimed in claim 1, wherein the herbicide A is halauxifen-methyl, the herbicide B is fluroxypyr, and the mass ratio of the herbicide A, the herbicide B and the herbicide C is (0.05-3): (1-10): (2-30);
preferably, the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.1-1.5) to (2-8) to (3-25).
5. The herbicide composition as claimed in claim 1, wherein the herbicide A is fluroxypyr-meptyl, the herbicide B is fluroxypyr, and the mass ratio of the herbicide A, the herbicide B and the herbicide C is (0.1-4): (1-10): (2-30);
preferably, the mass ratio of the herbicide A to the herbicide B to the herbicide C is (0.3-3) to (2-8) to (3-25).
6. The herbicidal composition according to claim 1, wherein the herbicidally active ingredient further comprises a herbicide D, wherein the herbicide D is glufosinate or glyphosate.
7. A herbicide composition as claimed in claim 6, wherein the herbicide A is halauxifen-ethyl, the herbicide B is triclopyr, the herbicide D is glufosinate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C to the herbicide D is (0.05-3): (2-25): (2-30): (15-40);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.1-1.5), (5-18), (3-25) and (20-35).
8. A herbicide composition as claimed in claim 6, wherein the herbicide A is fluroxypyr meptyl, the herbicide B is triclopyr, the herbicide D is glufosinate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C to the herbicide D is (0.1-4): (2-25): (2-30): (15-40);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.3-3): 5-18): 3-25): 20-35.
9. A herbicide composition as claimed in claim 6, wherein the herbicide A is halauxifen-ethyl, the herbicide B is fluroxypyr, the herbicide D is glufosinate-ammonium, and the mass ratio of the herbicide A, the herbicide B, the herbicide C to the herbicide D is (0.05-3): 1-10): 2-30): 15-40;
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.1-1.5), (2-8), (3-25) and (20-35).
10. The herbicide composition as claimed in claim 6, wherein the herbicide A is fluroxypyr meptyl, the herbicide B is fluroxypyr, the herbicide D is glufosinate-ammonium, and the mass ratio of the herbicide A, the herbicide B, the herbicide C to the herbicide D is (0.1-4): (1-10): (2-30): (15-40);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.3-3): 2-8): 3-25): 20-35.
11. A herbicide composition as claimed in claim 6, wherein the herbicide A is halauxifen-ethyl, the herbicide B is triclopyr, the herbicide D is glyphosate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.05-3): 2-25): 2-30): 30-80;
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.1-1.5): 5-18): 3-25): 40-60.
12. A herbicide composition as claimed in claim 6, wherein the herbicide A is fluroxypyr meptyl, the herbicide B is triclopyr, the herbicide D is glyphosate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.1-4): (2-25): (2-30): (30-80);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.3-3): 5-18): 3-25): 40-60.
13. The herbicide composition as claimed in claim 6, wherein the herbicide A is halauxifen-ethyl, the herbicide B is fluroxypyr, the herbicide D is glyphosate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.05-3): (1-10): (2-30): (30-80);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.1-1.5): 2-8): 3-25): 40-60.
14. A herbicide composition as claimed in claim 6, wherein the herbicide A is fluroxypyr meptyl, the herbicide B is triclopyr, the herbicide D is glufosinate, and the mass ratio of the herbicide A, the herbicide B, the herbicide C to the herbicide D is (0.1-4): (1-10): (2-30): (30-80);
preferably, the mass ratio of the herbicide A, the herbicide B, the herbicide C and the herbicide D is (0.3-3), (2-8), (3-25) and (40-60).
15. A formulation comprising the herbicidal composition as claimed in any one of claims 1 to 14, wherein said herbicidally active component is present in an amount of 1% to 85% by weight of the formulation.
16. The preparation of claim 15, wherein the preparation is wettable powder and oil suspending agent.
17. Use of a herbicidal composition according to any one of claims 1 to 14, characterized in that it is used for controlling weeds in non-cultivated lands and/or orchards.
18. Use according to claim 17, characterized in that the herbicide composition is applied in a dose of 10 to 1100g (a.i.)/ha.
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Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101808520A (en) * | 2007-08-27 | 2010-08-18 | 陶氏益农公司 | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
CN102325454A (en) * | 2008-11-24 | 2012-01-18 | 陶氏益农公司 | Safening 6-(trisubstituted phenyl)-4-amino-2-pyridinecarboxylate herbicide injury on cereal crops |
CN102318632A (en) * | 2011-07-18 | 2012-01-18 | 广西田园生化股份有限公司 | Synergistic weeding composition containing fluroxypyr |
CN102763676A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Herbicide containing glufosinate |
CN103025168A (en) * | 2010-05-21 | 2013-04-03 | 拜耳知识产权有限责任公司 | Herbicidal agents for tolerant or resistant corn cultures |
CN104661524A (en) * | 2012-07-24 | 2015-05-27 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid |
CN104936449A (en) * | 2012-07-24 | 2015-09-23 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and certain ps ii inhibitors |
CN105813460A (en) * | 2013-12-12 | 2016-07-27 | 美国陶氏益农公司 | Selective weed control with halauxifen |
CN106172427A (en) * | 2016-06-30 | 2016-12-07 | 广西壮族自治区化工研究院 | A kind of Herbicidal combinations containing left-handed α terpineol |
CN106386813A (en) * | 2016-08-31 | 2017-02-15 | 四川利尔作物科学有限公司 | Herbicidal composition and application thereof |
CN107593714A (en) * | 2017-10-31 | 2018-01-19 | 青岛海知誉科技信息咨询有限公司 | Weeding composition containing chloropyridyl ester and triazine compound and application thereof |
CN109042668A (en) * | 2018-08-07 | 2018-12-21 | 安徽省银山药业有限公司 | A kind of mixed herbicide and its application of containing chlorine fluorine pyridine ester and fluroxypyr |
-
2021
- 2021-05-20 CN CN202110552501.0A patent/CN115363035A/en active Pending
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101808520A (en) * | 2007-08-27 | 2010-08-18 | 陶氏益农公司 | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
CN102325454A (en) * | 2008-11-24 | 2012-01-18 | 陶氏益农公司 | Safening 6-(trisubstituted phenyl)-4-amino-2-pyridinecarboxylate herbicide injury on cereal crops |
CN103025168A (en) * | 2010-05-21 | 2013-04-03 | 拜耳知识产权有限责任公司 | Herbicidal agents for tolerant or resistant corn cultures |
CN102318632A (en) * | 2011-07-18 | 2012-01-18 | 广西田园生化股份有限公司 | Synergistic weeding composition containing fluroxypyr |
CN102763676A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Herbicide containing glufosinate |
CN104661524A (en) * | 2012-07-24 | 2015-05-27 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid |
CN104936449A (en) * | 2012-07-24 | 2015-09-23 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and certain ps ii inhibitors |
CN105813460A (en) * | 2013-12-12 | 2016-07-27 | 美国陶氏益农公司 | Selective weed control with halauxifen |
CN106172427A (en) * | 2016-06-30 | 2016-12-07 | 广西壮族自治区化工研究院 | A kind of Herbicidal combinations containing left-handed α terpineol |
CN106386813A (en) * | 2016-08-31 | 2017-02-15 | 四川利尔作物科学有限公司 | Herbicidal composition and application thereof |
CN107593714A (en) * | 2017-10-31 | 2018-01-19 | 青岛海知誉科技信息咨询有限公司 | Weeding composition containing chloropyridyl ester and triazine compound and application thereof |
CN109042668A (en) * | 2018-08-07 | 2018-12-21 | 安徽省银山药业有限公司 | A kind of mixed herbicide and its application of containing chlorine fluorine pyridine ester and fluroxypyr |
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