CN115301072A - Biological agent for pig house deodorization and preparation method thereof - Google Patents

Biological agent for pig house deodorization and preparation method thereof Download PDF

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CN115301072A
CN115301072A CN202210917540.0A CN202210917540A CN115301072A CN 115301072 A CN115301072 A CN 115301072A CN 202210917540 A CN202210917540 A CN 202210917540A CN 115301072 A CN115301072 A CN 115301072A
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extract
biological agent
ozone
solution
black soldier
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CN115301072B (en
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杜宗亮
容庭
邹兴昌
马现永
李贞明
邓盾
刘志昌
余苗
孟繁明
辛海云
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Guangdong Tianhe Muke Industrial Co ltd
Qingyuan Longfa Breeding Co ltd
Institute of Animal Science of Guangdong Academy of Agricultural Sciences
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Guangdong Tianhe Muke Industrial Co ltd
Qingyuan Longfa Breeding Co ltd
Institute of Animal Science of Guangdong Academy of Agricultural Sciences
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention belongs to the technical field of environmental protection, and discloses a biological preparation for deodorizing a pigsty, which contains black soldier fly larva intestinal extracts and poplar flower extracts; the weight ratio of the black soldier fly larva intestinal extract to the poplar flower extract is 1.1-10. The method has the advantages of quick response and long duration, and compared with the traditional scheme, the scheme has a better application prospect.

Description

Biological agent for pig house deodorization and preparation method thereof
Technical Field
The invention relates to the technical field of biology, in particular to a biological agent for deodorizing a pigsty.
Background
The invention relates to a Chinese patent ZL201811428762.6 proposed by courtyard et al; it discloses a complex lipid, which comprises the following components: barley pest lipid extract, citrus lipid extract, and black soldier fly lipid extract; barley pest lipid extract: citrus lipid extract: the weight ratio of the black soldier fly lipid extract is as follows: 6-10:2-6:1-3. It is used for reducing odorous gas such as ammonia gas and hydrogen sulfide in pig house.
Paragraph 125 of this document describes that the inhibitory effect of complex lipids on odorous gases was tested by measuring the odorous gas content after 24 hours.
In actual production, a method for controlling the odor with a small amount is needed in a farm in an instant manner.
Based on this, research and development work on the present project was developed.
The problem that the present scheme is to solve is: how to control the odor of the pigsty quickly and easily.
Disclosure of Invention
The invention aims to provide a biological agent for deodorizing a pigsty, the method has quick response and long duration, and compared with the traditional scheme, the scheme has better application prospect. In addition, the invention also discloses a preparation method of the preparation.
In order to achieve the purpose, the invention provides the following technical scheme: a biological preparation for deodorizing pigsty comprises intestinal extract of Hermetia illucens larvae and poplar flower extract; the weight ratio of the black soldier fly larva intestinal extract to the poplar flower extract is 1.1-10.
The biological preparation for deodorizing a pigsty further comprises an alcohol solution, and the black soldier fly larva intestinal extract and the poplar flower extract are dissolved in the alcohol solution.
In the above biological agent for hog house deodorization, the alcohol solution is an aqueous solution containing 20 to 40vol% of ethanol.
In the biological preparation for deodorizing a pigsty, the content of the black soldier fly larva intestinal extract and the poplar flower extract in the alcohol solution is 0.5-1wt%.
In the above biological agent for pig house deodorization, the alcohol solution is an ozone saturated solution.
Meanwhile, the invention also discloses a preparation method of the biological preparation for deodorizing the pigsty, which comprises the steps of adding water and alcohol into a mixing tank, and pumping the black soldier fly larva intestinal extract and the poplar flower extract into the mixing tank through a metering pump; during the stirring process, the ozone generator is started, and ozone is introduced into the solution.
In the above preparation method of the biological agent for pig house deodorization, the ozone is introduced for 1-5min.
Compared with the prior art, the invention has the beneficial effects that:
1. the previous research proves that the hermetia illucens oil extract can play a good antibacterial effect, the experiment is continuously researched on the basis, and the hermetia illucens oil extract can have a good effect in the aspect of controlling the odor for a long time by being compounded with the poplar flower extract.
2. There are 2 main reasons for using an alcohol solution, the first one is to promote the onset of spray evaporation and ozone; secondly, the dispersion effect of the grease substances in the solution is promoted; in addition, although studies have shown that low-concentration alcohol solutions do not provide a rapid bactericidal effect, the solution cannot deny its own bactericidal activity.
3. Ozone can promote the decomposition of ammonia gas into nitrogen gas and simultaneously promote the decomposition of hydrogen sulfide into sulfur dioxide.
Compared with the single use of ozone solution, the single use of black soldier fly larva intestinal extract and poplar flower extract, the effect of inhibiting the stink smell is quicker and more lasting.
Drawings
FIG. 1 is a view showing the structure of a pigsty according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Preparation of deodorant
Adding water and alcohol into a mixing tank, and pumping intestinal extract of hermetia illucens larvae and poplar flower extract into the mixing tank through a metering pump; starting an ozone generator during stirring, and introducing ozone into the solution; mixing for 3min;
an intestinal extract of hermetia illucens larvae prepared according to the method of example 1 of CN201910055164.7 in an amount of 0.5g;
0.5g of poplar flower extract (20 in specification, brown yellow powder, san sheng bio development limited, bachel city);
the alcohol concentration of the alcohol solution was 30vol%;
the total weight of the deodorant is 100g.
In the using process, the instant use is suggested.
Example 2
Preparation of deodorant
Adding water and alcohol into a mixing tank, and pumping intestinal extract of hermetia illucens larvae and poplar flower extract into the mixing tank through a metering pump; in the stirring process, starting an ozone generator, and introducing ozone into the solution; mixing for 3min;
an intestinal extract of hermetia illucens larvae prepared according to the method of example 1 of CN201910055164.7 in an amount of 0.1g;
0.9g of poplar flower extract (20 in specification, brown yellow powder, san sheng bio development limited, bachel city);
the alcohol concentration of the alcohol solution is 20vol%;
the total weight of the deodorant is 100g.
Example 3
Preparation of deodorant
Adding water and alcohol into a mixing tank, and pumping intestinal extract of hermetia illucens larvae and poplar flower extract into the mixing tank through a metering pump; starting an ozone generator during stirring, and introducing ozone into the solution; mixing for 3min;
an intestinal extract of hermetia illucens larvae prepared according to the method of example 1 of CN201910055164.7 in an amount of 0.9g;
0.1g of poplar flower extract (20 in specification, brown yellow powder, san sheng bio development limited, bachel city);
the alcohol concentration of the alcohol solution was 40vol%;
the total weight of the deodorant is 100g.
Comparative example 1
Adding water and alcohol into a mixing tank, starting stirring, starting an ozone generator during stirring, and introducing ozone into the solution; mixing time was 3min.
Comparative example 2
Adding water and alcohol into a mixing tank, and pumping intestinal extract of hermetia illucens larvae and poplar flower extract into the mixing tank through a metering pump; stirring was started for 3min.
An intestinal extract of hermetia illucens larvae prepared according to the method of example 1 of CN201910055164.7 in an amount of 0.5g;
0.5g of poplar flower extract (20, brown yellow powder, specifications of Sansheng biological development Co., ltd., baoji City);
the alcohol concentration of the alcohol solution was 30vol%;
the total weight of the deodorant is 100g.
Comparative example 3
Adding water and alcohol into a mixing tank, and pumping into intestinal extract of Hermetia illucens larvae through a metering pump; stirring was started for 3min.
An intestinal extract of hermetia illucens larvae prepared according to the method of example 1 of CN201910055164.7 in an amount of 1g;
the alcohol concentration of the alcohol solution was 30vol%;
the total weight of the deodorant is 100g.
Referring to fig. 1, the pigsty of the pigsty is a flat pigsty, the ground is a dropping board 1, the upper part of the ground is divided into a plurality of pigsties 2, and the lower part of the ground is a temporary excrement storage area 3; spray pipe 4 is all established to pig house top, fecaluria temporary storage area top, spray pipe connects to force (forcing) pump 5, the force (forcing) pump is connected to blending tank 6, be connected with ozone generator 7, measurement charge pump 8, alcohol filling pipe 9, water filling pipe 10 on the blending tank. The mixing tank is used for preparing the deodorant.
Experiment one, pig farm instant odor control
Selecting 5 flat-paved piggeries with the same breeding scale and similar day ages, and measuring the concentrations of hydrogen sulfide and ammonia gas above the piggeries and above a temporary storage area of excrement and urine before the start of testing; before starting spraying, the concentration error of hydrogen sulfide and ammonia gas in each tiled pigsty is within 10%, and if the concentration is lower than the preset concentration, the spraying is started after the concentration is increased to the error range.
After the experimental conditions are met, starting spraying, wherein the spraying amount above the pigsty is 3-5g/10 square meters; the spraying amount above the temporary storage area of the excrement and urine is 8-10g/10 square meters;
the experimental results are as follows:
TABLE 1 foul smell gas control Effect (unit: ppm) above the hog house
Figure BDA0003776290260000051
Figure BDA0003776290260000061
TABLE 2 odor control effectiveness (unit: ppm) above the fecal and urine holding area
Figure BDA0003776290260000062
Experimental two-pig farm lasting odor control
And continuously detecting the concentrations of hydrogen sulfide and ammonia gas above the pigsty and above the temporary storage area of excrement and urine on the basis of the first experiment, wherein the detection period is changed into 1-7day.
TABLE 3 foul smell gas control Effect (unit: ppm) above the hog house
Figure BDA0003776290260000063
TABLE 4 foul gas control effect (unit: ppm) above the fecal and urine buffer
Figure BDA0003776290260000071
And (4) conclusion:
the first experiment and the second experiment show that in the aspect of instant stink suppression, the black soldier fly larva intestinal extract compounded with the poplar flower extract is superior to the condition without ozone in the presence of ozone; the compounding effect within the preferred range of the invention has no obvious difference.
The best results of example 1 in terms of long-term odor inhibition;
the poplar flower extract is compounded by singly using ozone and singly using the black soldier fly larva intestinal extract, and the effect is obvious when the ozone is singly used, but the ozone is easy to dissipate.
Based on this, the user is advised to perform factory floor odor control according to the formula of the invention.

Claims (7)

1. A biological preparation for deodorizing a pigsty is characterized by comprising an intestinal extract of black soldier fly larvae and an extract of poplar flowers; the weight ratio of the black soldier fly larva intestinal extract to the poplar flower extract is 1.1-10.
2. The biological agent for deodorizing a pigsty according to claim 1, further comprising an alcohol solution, wherein the intestinal extract of hermetia illucens larvae and the extract of poplar flowers are dissolved in the alcohol solution.
3. The biological agent for hog house deodorization according to claim 2, wherein said alcohol solution is an aqueous solution containing 20-40vol% of ethanol.
4. The biological agent for hog house deodorization according to claim 2, wherein the content of black soldier fly larva intestinal extract and poplar flower extract in the alcoholic solution is 0.5-1wt%.
5. The biological agent for hog house deodorization according to claim 2, wherein said alcohol solution is an ozone-saturated solution.
6. A method for preparing the biological agent for deodorizing a pig house according to any one of claims 1 to 5, wherein water and alcohol are added to a mixing tank, and the intestinal extract of black soldier fly larvae and the extract of poplar flower are pumped in by a metering pump; during the stirring process, the ozone generator is started, and ozone is introduced into the solution.
7. The method of claim 6, wherein the ozone is applied for 1-5min.
CN202210917540.0A 2022-08-02 2022-08-02 Biological agent for deodorizing pigsty and preparation method thereof Active CN115301072B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001316277A (en) * 2000-05-02 2001-11-13 Maruzen Pharmaceut Co Ltd Antimicrobial agent and deodorizer
CN104171690A (en) * 2014-08-06 2014-12-03 广州市信农生物科技有限公司 Feed additive used for repelling mosquitoes and removing odor of pigsty
CN104289091A (en) * 2014-08-29 2015-01-21 湖北省生物农药工程研究中心 Bacillus production tail gas treatment process
CN106539787A (en) * 2016-11-01 2017-03-29 侯建生 Application of the ozonized surfactant in pig cultivation
CN109497103A (en) * 2018-11-28 2019-03-22 广东省农业科学院动物科学研究所 A kind of complex lipid reduces livestock and poultry feces stink foul smell discharge complex lipid spray and its preparation method and application
CN111053937A (en) * 2019-11-21 2020-04-24 吴杨 Plant-extracted household deodorizing and deodorizing disinfection composition and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001316277A (en) * 2000-05-02 2001-11-13 Maruzen Pharmaceut Co Ltd Antimicrobial agent and deodorizer
CN104171690A (en) * 2014-08-06 2014-12-03 广州市信农生物科技有限公司 Feed additive used for repelling mosquitoes and removing odor of pigsty
CN104289091A (en) * 2014-08-29 2015-01-21 湖北省生物农药工程研究中心 Bacillus production tail gas treatment process
CN106539787A (en) * 2016-11-01 2017-03-29 侯建生 Application of the ozonized surfactant in pig cultivation
CN109497103A (en) * 2018-11-28 2019-03-22 广东省农业科学院动物科学研究所 A kind of complex lipid reduces livestock and poultry feces stink foul smell discharge complex lipid spray and its preparation method and application
CN111053937A (en) * 2019-11-21 2020-04-24 吴杨 Plant-extracted household deodorizing and deodorizing disinfection composition and preparation method thereof

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