CN115247096A - 一种高安全无害的切削液及其制备方法 - Google Patents
一种高安全无害的切削液及其制备方法 Download PDFInfo
- Publication number
- CN115247096A CN115247096A CN202111238661.4A CN202111238661A CN115247096A CN 115247096 A CN115247096 A CN 115247096A CN 202111238661 A CN202111238661 A CN 202111238661A CN 115247096 A CN115247096 A CN 115247096A
- Authority
- CN
- China
- Prior art keywords
- parts
- cutting fluid
- agent
- safety
- harmlessness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 39
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 19
- 230000007797 corrosion Effects 0.000 claims abstract description 16
- 238000005260 corrosion Methods 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000013556 antirust agent Substances 0.000 claims abstract description 14
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 14
- 239000006184 cosolvent Substances 0.000 claims abstract description 13
- 239000003112 inhibitor Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004327 boric acid Substances 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims abstract description 11
- 229930195729 fatty acid Natural products 0.000 claims abstract description 11
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 11
- 229940075507 glyceryl monostearate Drugs 0.000 claims abstract description 11
- 239000002480 mineral oil Substances 0.000 claims abstract description 11
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 11
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims abstract description 11
- 239000012188 paraffin wax Substances 0.000 claims abstract description 11
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 6
- 235000010338 boric acid Nutrition 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 2
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical group CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 claims description 2
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 2
- LDTRLQFRPHFLGA-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;decanedioic acid Chemical compound OCCN(CCO)CCO.OC(=O)CCCCCCCCC(O)=O LDTRLQFRPHFLGA-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000011684 sodium molybdate Substances 0.000 claims description 2
- 235000015393 sodium molybdate Nutrition 0.000 claims description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 230000001050 lubricating effect Effects 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000035943 smell Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000003754 machining Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明提供一种高安全无害的切削液及其制备方法，涉及切削液技术领域。该高安全无害的切削液及其制备方法，包括如下重量份的原料组成：石蜡基矿物油4‑8份、脂肪酸4‑8份、硼酸2‑5份、甘油10‑15份、单硬脂酸甘油酯6‑10份、聚异丁烯2‑5份、聚丙烯酰胺1‑4份、二甘醇二丁醚3‑6份，表面活性剂1‑3份，抗氧化剂0.5‑1.5份，抑菌剂0.5‑1.5份，消泡剂2‑4份，缓蚀剂2‑4份，复合防锈剂0.5‑2.0份，助溶剂10‑15份，去离子水200‑300份。本发明提供一种高安全无害的切削液及其制备方法，该切削液的清洗性好，还具有良好的润滑性能，还克服了乳化型切削液易变质发臭、使用寿命短的缺点，大大提高了机械设备和切削液的使用寿命，配方中不含有污染环境的物质，对环境污染小，绿色环保，安全无害。
Description
技术领域
本发明涉及切削液技术领域，具体为一种高安全无害的切削液及其制备方法。
背景技术
切削液是一种用在金属切削、磨加工过程中，用来冷却和润滑刀具和加工件的工业用液体，切削液由多种超强功能助剂经科学复合配合而成，同时具备良好的冷却性能、润滑性能、防锈性能、除油清洗功能、防腐功能、易稀释特点。
机床加工设计到各种刀具和工件，对切削液的要求较高，现有的切削液，从基质上可以分为两类：水基切削液和非水基切削液，水基切削液的优点是流动性较好，冷却性能较好，缺点是粘性较低，润滑作用不如非水基切削液；非水基切削液，即一般为溶剂型切削液，优点是粘度适中，润滑效果较为理想，缺点是流动性差，冷却效果不佳。
现有切削液普遍存在防锈效果差，无法避免工件与环境介质及切削液组分分解或氧化变质而产生的油泥等腐蚀性介质接触而腐蚀的问题，并且现有的油基切削液大多存在一定的污染问题，使用后会对环境造成一定的有害影响。
水基切削液具有冷却效果好、可节约能源、操作环境清洁等优点而日渐广泛应用于金属机械加工工艺中，并且有逐步替代油基切削液的趋势，一些水溶性切削液虽然冷却性能较好，但是存在润滑性和防锈效果较差的问题，因此开发兼具润滑性、冷却性、防锈性、易清洗、无毒、无味、对人体无侵蚀、对设备不腐蚀、对环境不污染的切削液就显得尤为重要。
发明内容
(一)解决的技术问题
针对现有技术的不足，本发明提供了一种高安全无害的切削液及其制备方法，解决了现有切削液普遍存在防锈效果差，无法避免工件与环境介质及切削液组分分解或氧化变质而产生的油泥等腐蚀性介质接触而腐蚀，并且现有的油基切削液大多存在一定的污染问题，使用后会对环境造成一定有害影响的问题。
(二)技术方案
为实现以上目的，本发明通过以下技术方案予以实现：一种高安全无害的切削液，包括如下重量份的原料组成：石蜡基矿物油4-8份、脂肪酸4-8份、硼酸2-5份、甘油10-15份、单硬脂酸甘油酯6-10份、聚异丁烯2-5份、聚丙烯酰胺1-4份、二甘醇二丁醚3-6份，表面活性剂1-3份，抗氧化剂0.5-1.5份，抑菌剂0.5-1.5份，消泡剂2-4份，缓蚀剂2-4份，复合防锈剂0.5-2.0份，助溶剂10-15份，去离子水200-300份。
优选的，所述表面活性剂采用阴离子型表面活性剂和非离子型表面活性剂调配而成，且阴离子型表面活性剂和非离子型表面活性剂的质量之比为1：2，所述阴离子型表面活性剂为石油磺酸钠，所述非离子型表面活性剂为异构十三醇醚。
优选的，所述抑菌剂为均三嗪和异噻啉酮中的至少一种。
优选的，所述消泡剂为有机硅消泡剂和聚醚消泡剂中的一种或两种。
优选的，所述消泡剂为水溶性有机硅消泡剂。
优选的，所述缓蚀剂为硼砂、钼酸钠、苯并三氮唑中的一种或几种的混合物。
优选的，所述复合防锈剂为十二烯基丁二酸三乙醇胺、癸二酸三乙醇胺、均三嗪环羧酸衍生物三乙醇胺、油酸三乙醇胺中的两种或几种的混合物。
优选的，所述助溶剂为丙三醇、丙二醇、聚乙二醇中的一种或几种的混合物。
优选的，一种高安全无害的切削液的制备方法，包括以下步骤：
S1.按照各个组分的重量份数依次称取各个组分；
S2.将石蜡基矿物油、脂肪酸、硼酸、甘油、单硬脂酸甘油酯、聚异丁烯、聚丙烯酰胺、二甘醇二丁醚依次加入搅拌釜中，将反应釜加热至40-50℃，然后混合搅拌均匀；
S3.然后再加入复合防锈剂和助溶剂，继续加热至60-70℃，并继续搅拌；
S4.最后加入表面活性剂、抗氧化剂、抑菌剂、消泡剂、缓蚀剂和去离子水，并不断搅拌，直至搅拌到透明状态；
S5.将搅拌好的混合液放入容器中，放置在真空室温环境下静置8-15h；
S6.真空静置后，进行包装封装，即得到该高安全无害的切削液。
优选的，所述搅拌的速率为3000-4000r/min，搅拌的时间为10-30min。
(三)有益效果
本发明提供了一种高安全无害的切削液及其制备方法。具备以下有益效果：
1、本发明提供的高安全无害的切削液及其制备方法，该切削液的清洗性好，还具有良好的润滑性能，还克服了乳化型切削液易变质发臭、使用寿命短的缺点，大大提高了机械设备和切削液的使用寿命，而且其冷却性能好，适用于有色金属和黑色金属的加工，尤其适用于铝材的加工，能够有效防止铝材表面的腐蚀问题。
2、本发明提供的高安全无害的切削液及其制备方法，通过加入复合防锈剂、抑菌剂、抗氧化剂、表面活性剂等成分，使该切削液均有优异的防锈作用，并且能够抑制细菌、真菌的繁殖，延长切削液的使用周期，表面活性剂的使用可以显著降低切削液的表面张力，提高切削液的渗透性和清洗力，同时较之其它类别的表面活性剂能够产生较少的泡沫。
3、本发明提供的高安全无害的切削液及其制备方法，本发明切削液的配方中不含有污染环境的物质，对环境污染小，绿色环保，并且多种组分能够被生物降解，使该切削液对人体无伤害，对环境无污染，更加安全无害。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
本发明实施例提供一种高安全无害的切削液，包括如下重量份的原料组成：石蜡基矿物油4份、脂肪酸4份、硼酸2份、甘油10份、单硬脂酸甘油酯6份、聚异丁烯2份、聚丙烯酰胺1份、二甘醇二丁醚3份，表面活性剂1份，抗氧化剂0.5份，抑菌剂0.5份，消泡剂2份，缓蚀剂2份，复合防锈剂0.5份，助溶剂10份，去离子水200份。
一种高安全无害的切削液的制备方法，包括以下步骤：
S1.按照各个组分的重量份数依次称取各个组分；
S2.将石蜡基矿物油、脂肪酸、硼酸、甘油、单硬脂酸甘油酯、聚异丁烯、聚丙烯酰胺、二甘醇二丁醚依次加入搅拌釜中，将反应釜加热至40℃，然后混合搅拌均匀；
S3.然后再加入复合防锈剂和助溶剂，继续加热至60℃，并继续搅拌；
S4.最后加入表面活性剂、抗氧化剂、抑菌剂、消泡剂、缓蚀剂和去离子水，并不断搅拌，直至搅拌到透明状态；
S5.将搅拌好的混合液放入容器中，放置在真空室温环境下静置10h；
S6.真空静置后，进行包装封装，即得到该高安全无害的切削液。
实施例2：
本发明实施例提供一种高安全无害的切削液，包括如下重量份的原料组成：石蜡基矿物油6份、脂肪酸6份、硼酸3份、甘油12份、单硬脂酸甘油酯8份、聚异丁烯3份、聚丙烯酰胺2份、二甘醇二丁醚4份，表面活性剂2份，抗氧化剂1.0份，抑菌剂1.0份，消泡剂3份，缓蚀剂3份，复合防锈剂1.0份，助溶剂12份，去离子水250份。
一种高安全无害的切削液的制备方法，包括以下步骤：
S1.按照各个组分的重量份数依次称取各个组分；
S2.将石蜡基矿物油、脂肪酸、硼酸、甘油、单硬脂酸甘油酯、聚异丁烯、聚丙烯酰胺、二甘醇二丁醚依次加入搅拌釜中，将反应釜加热至45℃，然后混合搅拌均匀；
S3.然后再加入复合防锈剂和助溶剂，继续加热至65℃，并继续搅拌；
S4.最后加入表面活性剂、抗氧化剂、抑菌剂、消泡剂、缓蚀剂和去离子水，并不断搅拌，直至搅拌到透明状态；
S5.将搅拌好的混合液放入容器中，放置在真空室温环境下静置12h；
S6.真空静置后，进行包装封装，即得到该高安全无害的切削液。
实施例3：
本发明实施例提供一种高安全无害的切削液，包括如下重量份的原料组成：石蜡基矿物油8份、脂肪酸8份、硼酸5份、甘油15份、单硬脂酸甘油酯10份、聚异丁烯5份、聚丙烯酰胺4份、二甘醇二丁醚6份，表面活性剂3份，抗氧化剂1.5份，抑菌剂1.5份，消泡剂4份，缓蚀剂4份，复合防锈剂1.5份，助溶剂15份，去离子水300份。
一种高安全无害的切削液的制备方法，包括以下步骤：
S1.按照各个组分的重量份数依次称取各个组分；
S2.将石蜡基矿物油、脂肪酸、硼酸、甘油、单硬脂酸甘油酯、聚异丁烯、聚丙烯酰胺、二甘醇二丁醚依次加入搅拌釜中，将反应釜加热至50℃，然后混合搅拌均匀；
S3.然后再加入复合防锈剂和助溶剂，继续加热至70℃，并继续搅拌；
S4.最后加入表面活性剂、抗氧化剂、抑菌剂、消泡剂、缓蚀剂和去离子水，并不断搅拌，直至搅拌到透明状态；
S5.将搅拌好的混合液放入容器中，放置在真空室温环境下静置14h；
S6.真空静置后，进行包装封装，即得到该高安全无害的切削液。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (10)
1.一种高安全无害的切削液，其特征在于：包括如下重量份的原料组成：石蜡基矿物油4-8份、脂肪酸4-8份、硼酸2-5份、甘油10-15份、单硬脂酸甘油酯6-10份、聚异丁烯2-5份、聚丙烯酰胺1-4份、二甘醇二丁醚3-6份，表面活性剂1-3份，抗氧化剂0.5-1.5份，抑菌剂0.5-1.5份，消泡剂2-4份，缓蚀剂2-4份，复合防锈剂0.5-2.0份，助溶剂10-15份，去离子水200-300份。
2.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述表面活性剂采用阴离子型表面活性剂和非离子型表面活性剂调配而成，且阴离子型表面活性剂和非离子型表面活性剂的质量之比为1：2，所述阴离子型表面活性剂为石油磺酸钠，所述非离子型表面活性剂为异构十三醇醚。
3.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述抑菌剂为均三嗪和异噻啉酮中的至少一种。
4.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述消泡剂为有机硅消泡剂和聚醚消泡剂中的一种或两种。
5.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述消泡剂为水溶性有机硅消泡剂。
6.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述缓蚀剂为硼砂、钼酸钠、苯并三氮唑中的一种或几种的混合物。
7.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述复合防锈剂为十二烯基丁二酸三乙醇胺、癸二酸三乙醇胺、均三嗪环羧酸衍生物三乙醇胺、油酸三乙醇胺中的两种或几种的混合物。
8.根据权利要求1所述的一种高安全无害的切削液，其特征在于：所述助溶剂为丙三醇、丙二醇、聚乙二醇中的一种或几种的混合物。
9.一种高安全无害的切削液的制备方法，其特征在于，包括以下步骤：
S1.按照各个组分的重量份数依次称取各个组分；
S2.将石蜡基矿物油、脂肪酸、硼酸、甘油、单硬脂酸甘油酯、聚异丁烯、聚丙烯酰胺、二甘醇二丁醚依次加入搅拌釜中，将反应釜加热至40-50℃，然后混合搅拌均匀；
S3.然后再加入复合防锈剂和助溶剂，继续加热至60-70℃，并继续搅拌；
S4.最后加入表面活性剂、抗氧化剂、抑菌剂、消泡剂、缓蚀剂和去离子水，并不断搅拌，直至搅拌到透明状态；
S5.将搅拌好的混合液放入容器中，放置在真空室温环境下静置8-15h；
S6.真空静置后，进行包装封装，即得到该高安全无害的切削液。
10.根据权利要求9所述的一种高安全无害的切削液的制备方法，其特征在于：所述搅拌的速率为3000-4000r/min，搅拌的时间为10-30min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111238661.4A CN115247096A (zh) | 2021-10-25 | 2021-10-25 | 一种高安全无害的切削液及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111238661.4A CN115247096A (zh) | 2021-10-25 | 2021-10-25 | 一种高安全无害的切削液及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115247096A true CN115247096A (zh) | 2022-10-28 |
Family
ID=83697299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111238661.4A Pending CN115247096A (zh) | 2021-10-25 | 2021-10-25 | 一种高安全无害的切削液及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115247096A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746281A (zh) * | 2004-09-06 | 2006-03-15 | 大连广汇化学有限公司 | 环保型水基合成切削液 |
| CN101970621A (zh) * | 2007-12-10 | 2011-02-09 | 凯密特尔有限公司 | 金属加工流体配制剂 |
| CN103710131A (zh) * | 2013-12-07 | 2014-04-09 | 马鞍山市力鑫机械制造有限公司 | 一种水基铝合金切削液及其制备方法 |
| CN105602689A (zh) * | 2016-01-28 | 2016-05-25 | 陕西省石油化工研究设计院 | 一种环保可降解水基全合成切削液及其制备方法 |
| CN112940833A (zh) * | 2021-02-09 | 2021-06-11 | 上海应用技术大学 | 一种长寿环保切削液及其制备方法 |
-
2021
- 2021-10-25 CN CN202111238661.4A patent/CN115247096A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746281A (zh) * | 2004-09-06 | 2006-03-15 | 大连广汇化学有限公司 | 环保型水基合成切削液 |
| CN101970621A (zh) * | 2007-12-10 | 2011-02-09 | 凯密特尔有限公司 | 金属加工流体配制剂 |
| CN103710131A (zh) * | 2013-12-07 | 2014-04-09 | 马鞍山市力鑫机械制造有限公司 | 一种水基铝合金切削液及其制备方法 |
| CN105602689A (zh) * | 2016-01-28 | 2016-05-25 | 陕西省石油化工研究设计院 | 一种环保可降解水基全合成切削液及其制备方法 |
| CN112940833A (zh) * | 2021-02-09 | 2021-06-11 | 上海应用技术大学 | 一种长寿环保切削液及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101240422B (zh) | 一种水基金属防锈剂组合物 | |
| CN102311860B (zh) | 用于钕铁硼材料切片加工的水基切削液及其使用方法 | |
| CN103242946B (zh) | 一种机床工作液的配方及其配制工艺 | |
| CN105670738A (zh) | 一种防锈乳化型金属切削液 | |
| CN106281616A (zh) | 一种铝合金切削加工用长寿命低泡乳化液 | |
| CN104277902A (zh) | 一种重负荷金属加工全合成切削液及其制备方法与应用 | |
| CN102286302A (zh) | 水溶性切削液 | |
| CN111961522A (zh) | 一种通用性铝材加工微乳化切削液、其制备方法及用途 | |
| CN104450130A (zh) | 金属切削液及其制备方法 | |
| CN103351932A (zh) | 一种透明水溶性切削液及其制备方法 | |
| CN112745983A (zh) | 无磷型碱性水基喷淋清洗防锈剂及其制备方法 | |
| CN106893632A (zh) | 一种高速电火花线切割全合成液组合物及其制备工艺 | |
| CN102757853B (zh) | 一种抗极压性好的金属切削液 | |
| CN104560352A (zh) | 一种防锈效果显著分散性好的水基切削液及其制备方法 | |
| CN108265285B (zh) | 一种铜材中性钝化剂 | |
| CN108441310B (zh) | 一种金属加工用半合成切削液及其制备方法 | |
| CN104004578A (zh) | 一种铝合金专用切削液 | |
| CN103865623B (zh) | 一种多功能无毒水基防锈切割液 | |
| CN115247096A (zh) | 一种高安全无害的切削液及其制备方法 | |
| CN112481011A (zh) | 一种用于钕铁硼材料加工的多用途全合成切削液及其制备方法 | |
| CN104560336A (zh) | 一种长效环保型水基切削液及其制备方法 | |
| CN104451698A (zh) | 一种用于变压器的金属防锈剂及其制备方法 | |
| CN113897234A (zh) | 多效型防锈复合添加剂及其制备方法 | |
| CN113462456A (zh) | 一种电火花线切割液及其制备方法 | |
| CN108048198B (zh) | 一种环保型全合成切削液及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20221028 |
|
| WD01 | Invention patent application deemed withdrawn after publication |