CN115233016B - Al-50Sn alloy based aluminum melt iron removal method - Google Patents
Al-50Sn alloy based aluminum melt iron removal method Download PDFInfo
- Publication number
- CN115233016B CN115233016B CN202210920819.4A CN202210920819A CN115233016B CN 115233016 B CN115233016 B CN 115233016B CN 202210920819 A CN202210920819 A CN 202210920819A CN 115233016 B CN115233016 B CN 115233016B
- Authority
- CN
- China
- Prior art keywords
- alloy
- iron
- iron removal
- aluminum
- aluminum melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/003—Alloys based on aluminium containing at least 2.6% of one or more of the elements: tin, lead, antimony, bismuth, cadmium, and titanium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses an Al-50Sn alloy-based aluminum melt iron removal method, which takes Al-50Sn alloy as an iron removal agent, the aluminum melt is aluminum with high iron content, the iron removal method is a flux method, and the basic principle is that by introducing Sn element, sn phase is formed and attached to beta-Fe phase, so that the Fe-rich phase is promoted to be settled, and the Fe-rich phase in the alloy is mainly gathered at the bottom; the iron removal rate is 31.0-43.0%. The method comprises the following steps: 1, preparing raw materials; and 2, iron removal operation of the aluminum melt. The invention has the following advantages: 1. by introducing Sn element, the Sn phase only acts with the Fe-rich phase and is attached to the Fe-rich phase, so that the Fe-rich phase is promoted to be settled, and the iron content at the top is reduced; 2. the introduced Sn is attached to the Fe-rich phase, is stable at high temperature and cannot be decomposed; 3. the iron removing effect is stable and efficient for the aluminum alloy with high Fe content; 4. the process is simple. Therefore, the iron removal method used by the invention has an iron removal effect on the aluminum melt.
Description
Technical Field
The invention relates to the technical field of alloy iron removal, in particular to an Al-50Sn alloy based aluminum melt iron removal method.
Background
The impurity iron in aluminum has a complex source and has three main aspects: firstly, the mined aluminum ore contains a certain amount of iron element; secondly, in the actual aluminum processing process, an iron tool cannot be separated, so that iron elements in the workpiece permeate into aluminum alloy; thirdly, the recycled aluminum continuously accumulates impurity iron in aluminum and aluminum alloy in the recycling production process to reach higher content.
In the conventional iron removal method for the aluminum alloy, the gravity settling method consumes long time, and the centrifugal separation method is inconvenient to operate; the cold speed method is improved and lacks of practical production operability; the electromagnetic separation method has high cost and is difficult to popularize; the overheating of the melt and the heat treatment process cause losses in the melting of the casting. The method for adding the iron removing agent into the aluminum melt has simple experimental process, does not need high cost, and does not cause loss of castings.
The method for adding the iron remover mainly comprises 2 methods.
One method is a modification treatment method, which is to add Mn, co, mo, cr, ti and Be elements into an aluminum melt, and convert the existence form of the Fe element into an alpha-AlFeSi phase with less influence on the performance of the aluminum alloy by inhibiting the generation of the beta-AlFeSi phase, thereby reducing the harm of impurity iron and realizing the iron removal effect. As shown in prior art document 1, (Morphological students on β -FeSiAl5 phase in Al-7-Si-0.3 Mg alloy with trace additions of Be, mn, cr, and Co [ J ]. Materials purification, 1994,33 (2): 99-112), murali et Al indicate that the Be, mn, cr and Co elements can change the needle-like or flake-like β -AlFeSi phase to α -AlFeSi phase with less influence on the properties of the aluminum alloy in various degrees. Although this technique can suppress the formation of β -AlFeSi phase and reduce the harmful effect of iron impurity on the aluminum alloy, the iron element remains in the aluminum alloy, and therefore the harmful effect of Fe cannot be completely eliminated.
The other method is a flux method of adding an iron removing agent, and the purpose of removing iron is achieved by adding a flux into an aluminum melt, reacting with Fe in the alloy, and capturing slagging or generating precipitation. The flux method has short time consumption, convenient operation, no damage to the casting and low cost, and can be produced in large batch. At present, the flux method is a method for introducing B element as an iron remover, and no report is provided for introducing other elements as the iron remover.
The basic principle of introducing B element for removing iron is that Fe is formed by B element and iron element 2 And B, further forming slag by sinking in a precipitation mode, thereby reducing the content of Fe element. Such as prior document 2 (purifying effect and mechanism of boride on impurity iron in aluminum melt [ D)]The Shanghai university of transportation, 2010) Gao Jianwei iron was removed from commercial purity aluminum by the combined addition of sodium chloride, potassium chloride and borax, achieving iron content reduction from the initial 0.14wt.%, 0.66wt.%, and 1.08wt.% to 0.08wt.%, 0.45wt.%, and 0.84wt.%, with iron removal rates of 42.9%, 31.8%, and 22.2%, respectively. However, iron removal by introduction of B element represented by this technique is all as followsOne technical problem is that: under the condition of low iron content, the iron removal rate basically meets the requirement, but when the iron is removed from the aluminum alloy with high iron content, the iron removal rate is obviously reduced.
In order to improve the iron removal effect on the aluminum alloy, the current technology is to add an additive such as a refining agent and a fluxing agent at the same time of adding a flux containing an element B. The principle is that the B element and impurity iron are fully reacted, so that the iron removal rate is improved. For example, in the existing document 3 (chinese patent CN104831103B, an aluminum alloy iron-removing flux and its preparation method [ P ]), an aluminum alloy iron-removing flux and its preparation method are disclosed, in which, in addition to boron carbide, industrial sodium chloride, industrial potassium chloride, manganese tetraborate, manganese chloride and a refining agent are added, so that the technical effect of reducing the iron content in the aluminum alloy from 0.30wt.% to 0.17wt.% is achieved, and the iron-removing rate is 43.3%. Although the technology can fully react the B element with impurity iron to improve the iron removal rate, the mixed flux used by the technology needs to be subjected to the processes of dehydration, heat preservation drying, ball milling and the like, the preparation is complex, and the iron removal rate of the low-iron-content aluminum alloy is only improved.
In addition, according to the present research, it is shown that B element reacts with impurity Fe to generate Fe 2 B is unstable at high temperature and is easy to decompose, so that the iron removal effect is reduced. Such as prior document 4 (technical study for removing impurities in cast Al-Si alloy iron phase [ D ]]Zhejiang industrial university, 2019), pang Shipeng indicate that Fe is produced when the heat is preserved for a long time above 780 ℃ 2 B is unstable and will be decomposed into Fe element again, so that the iron content in the melt is increased. Therefore, fe exists in the method for removing iron by introducing the B element 2 B is unstable and easy to decompose, and the iron content in the melt after decomposition is increased, so that the iron removal effect is reduced.
It is obvious that the flux method using the B element cannot solve the above problems from the root, and as described above, no other element has been reported for the flux method in the current studies on the flux method. Based on the basic principle of the flux method, the new iron remover needs to meet the following technical characteristics: the iron removal element has stable iron removal effect, and the iron-containing compound is settled to the bottom of the melt and is not decomposed; the method is suitable for the aluminum alloy with high iron content, namely, the aluminum alloy with the iron content higher than 1.0wt.% still has higher iron removal rate; on the basis, the problem of complex preparation of the iron removing agent is solved, processes such as dehydration, ball milling and the like are not needed, and the iron removing agent is not needed to be mixed with various fluxing agents for use.
Disclosure of Invention
The invention aims to provide an Al-50Sn alloy-based aluminum melt iron removal method, which still has higher iron removal rate when matrix aluminum alloy has higher iron content, is simple to operate, has low iron removal flux viscosity and is pollution-free.
In order to achieve the above-mentioned object, the basic principle involved in the present invention is: by introducing new elements, the iron-containing compound can be generated by reaction with Fe in a temperature range of 700-800 ℃, and the generated phase density of the iron-containing compound is greater than that of aluminum liquid, so that the iron-containing compound is precipitated and enriched to the bottom of the melt, the iron content at the bottom of the melt is increased, the iron content at the upper part of the melt is reduced, and finally, the enriched bottom of the iron element is cut off, so that the iron removal effect of the aluminum alloy can be realized. In addition, the introduced elements should be sufficient to react only with the iron element and not react with other elements in the aluminum alloy to form phases, i.e., not to cause damage to the matrix.
In light of the above requirements, the applicant has found that Sn element reacts with Fe only in the temperature range of 700-800 ℃ to form Fe 3 Sn 2 、Fe 5 Sn 3 And the like, do not react with Al.
In order to achieve the purpose of the invention, the invention adopts the technical scheme that:
an Al-50Sn alloy-based aluminum melt iron removal method is characterized in that Al-50Sn alloy is used as an iron removal agent, the aluminum melt is aluminum with high iron content, the iron removal method is a flux method, and the basic principle is that Sn phase is formed by introducing Sn element and attached to beta-Fe phase, so that Fe-rich phase is promoted to be precipitated, and the Fe-rich phase in the aluminum is mainly gathered at the bottom;
the content of Fe in the aluminum melt is 0.9-1.1wt.%;
the iron removal rate of the iron removal method is 31.0-43.0%.
An Al-50Sn alloy-based aluminum melt iron removal method comprises the following steps:
step 1, preparing raw materials, namely respectively weighing Al-50Sn alloy and aluminum alloy according to a certain proportion of the addition amount of the Al-50Sn alloy, then preheating the Al-50Sn alloy to obtain preheated Al-50Sn alloy, and simultaneously heating and melting the aluminum alloy to obtain an aluminum melt;
in the step 1, the addition amount of the Al-50Sn alloy is 1.0-3.0wt.%;
in the step 1, the Al-50Sn alloy is preheated under the condition that the Al-50Sn alloy is wrapped by an aluminum foil, and the preheating temperature is 150-200 ℃;
step 2, performing iron removal operation on the aluminum melt, namely adding preheated Al-50Sn alloy into the aluminum melt to perform iron removal operation under a certain condition, cooling the aluminum melt to room temperature in the air after the iron removal operation is finished to obtain the aluminum melt after the iron removal operation, and finally cutting the aluminum melt from a position 1/6 away from the bottom of the alloy in the embodiment 1 to complete the iron removal of the aluminum melt;
in the step 2, the iron removal operation conditions are that the iron removal temperature is 720-840 ℃ and the iron removal time is 30-90min.
The invention uses ICP detection means to prove that the addition of the Al-50Sn alloy enables the Fe-rich phase to settle to the bottom of the melt, and the Fe removing effect is achieved, and the Fe removing rate is 31.0-43.0%.
The invention uses OM detection means to prove that the addition of the Al-50Sn alloy enables the Fe-rich phase to settle to the bottom of the melt, thereby obtaining the iron removal effect.
Compared with the prior art, the invention has the following advantages:
1. according to the invention, by introducing Sn element, the Sn phase only acts with the Fe-rich phase and attaches to the Fe-rich phase, so that the Fe-rich phase is promoted to be settled, and the technical effect of reducing the iron content at the top is achieved;
2. the invention introduces Sn element which is attached to the Fe-rich phase, is stable at high temperature and can not be decomposed, and introduces Fe generated by B element 2 Substantial differences exist in B-phase pyrolysis, and a remarkable technical effect is obtained;
3. the iron removal method has stable and efficient iron removal effect on the aluminum melt with high Fe content;
4. the method has simple process, only needs Al-50Sn alloy, does not need dehydration, ball milling and other processes, and does not need to be mixed with various fluxing agents for use, so the method for removing the iron has convenient operation and meets the application requirement and the production requirement.
Drawings
FIG. 1 is a schematic height diagram of the selection of alloys in comparative example 1, example 2, example 3 and comparative example 2;
FIG. 2 is a graph showing the variation of the iron content of the alloys in comparative example 1, example 2, example 3 and comparative example 2 with the height;
FIG. 3 is a metallographic structure chart of the alloy of example 1, wherein 3a is a metallographic structure at 4.5cm, and 3b is a metallographic structure at 1.0 cm;
FIG. 4 is a metallographic structure diagram of a matrix alloy of comparative example 1 at a position of 4.5 cm;
FIG. 5 is a metallographic structure chart of the alloy of example 2, wherein 5a is a metallographic structure at a position of 4.5cm, and 5b is a metallographic structure at a position of 1.0 cm;
FIG. 6 is the metallographic structure of the alloy of example 3, where 6a is a metallographic phase at 4.5cm and 6b is a metallographic phase at 1.0 cm;
FIG. 7 is a metallographic structure of an alloy of comparative example 2, in which 7a is a metallographic structure at a position of 4.5cm and 7b is a metallographic structure at a position of 1.0 cm;
Detailed Description
The present invention will be described in further detail by way of examples, but the present invention is not limited thereto, with reference to the accompanying drawings.
Description 1: in order to facilitate the evaluation of the iron removal rate, the aluminum alloy with the Fe content of 1.0wt.% is uniformly adopted in the aluminum melt, which is referred to in the invention, and is referred to as Al-1Fe alloy for short.
Description 2: since Sn element can form Fe with Fe element 3 Sn 2 And Fe 5 Sn 3 Therefore, in an ideal state, sn element completely reacts with Al-1Fe alloy, the iron remover is determined to be Al-50Sn, and the range of investigation of the addition amount is limited to 1.0-3.0wt.%.
Example 1
An aluminum melt iron removal method based on an Al-50Sn alloy comprises the following specific steps when the addition amount of the Al-50Sn alloy is 3 wt.%:
step 1, preparing raw materials, namely respectively weighing 23.4g of Al-50Sn alloy and 600g of Al-1Fe alloy with the addition of the Al-50Sn alloy being 3wt.%, wrapping the Al-50Sn alloy with aluminum foil, preheating at the preheating temperature of 150 ℃ to obtain preheated Al-50Sn alloy, and simultaneously heating and melting the Al-1Fe alloy to obtain Al-1Fe alloy melt;
and 2, performing iron removal operation on the aluminum melt, namely adding preheated Al-50Sn alloy into the Al-1Fe melt at the iron removal temperature of 780 ℃, performing iron removal operation under the condition that the iron removal time is 60min, cooling the aluminum alloy to room temperature in the air after the iron removal operation is finished, thus obtaining the aluminum alloy after the iron removal operation, namely the alloy of the embodiment 1, and finally cutting the aluminum alloy from the position 1/6 away from the bottom of the alloy of the embodiment 1, thus finishing the iron removal of the aluminum melt.
Description 3: in the invention, all the aluminum alloys obtained in the examples and the comparative examples after iron removal operation are cylinders with the height of 6.0cm and the diameter of 6.0cm, so that the aluminum alloy after iron removal operation in the step 2 is cut from a position 1.0cm away from the bottom, and after cutting, the remaining 5/6 of the alloy in the example 1 is the aluminum alloy after iron removal of 3wt.% of Al-50Sn alloy.
Description 4: for the subsequent tests, the aluminum alloys obtained in all the examples of the present invention and the comparative examples after iron removal operation were sampled as follows. The specific sampling method is shown in fig. 1, and the aluminum alloy after iron removal is cut at the positions 1.0cm, 2.5cm and 4.5cm away from the bottom to obtain 3 sections, wherein the 3 sections are named as the positions 1.0cm, 2.5cm and 4.5cm respectively.
In order to demonstrate the iron removal effect of the iron removal method of the present invention, ICP tests were performed at 1.0cm, 2.5cm and 4.5cm, respectively, of the alloy of example 1. The results of the tests are shown in table 1 and fig. 2, with example 1 alloy having an iron content of 1.19wt.% at 1.0cm, an iron content of 0.77wt.% at 2.5cm and an iron content of 0.56wt.% at 4.5 cm. Experimental results show that the iron content of the Al-1Fe alloy at the positions of 4.5cm and 2.5cm is reduced, the iron content of the Al-1Fe alloy at the position of 1.0cm is increased, the effect that the Fe-rich phase is settled to the bottom of the alloy is realized by adding the Al-50Sn alloy, and the iron removal effect is obtained. In order to quantify the iron removal effect, the change in iron content was calculated. The iron content at the position of 4.5cm is reduced from 0.96wt.% to 0.56wt.%, and the iron removal rate can reach 41.7% by calculation.
TABLE 1 iron content at different heights for the alloys of the examples and the base alloy of the comparative example
To further demonstrate the iron removal effect of the iron removal method of the present invention, metallographic structure tests were conducted at 1.0cm and 4.5cm, respectively, of the alloy of example 1. The test results are shown in FIG. 3, in which FIG. 3a shows the metallographic structure of the alloy of example 1 at 4.5cm, with a small amount of Fe-rich phases; FIG. 3b shows the metallographic structure at 1.0cm of the alloy of example 1, showing a large number of Fe-rich phases and a large size. Experimental results show that the Fe-rich phase is settled, the Fe-rich phase at the position of 4.5cm is less, the Fe-rich phase at the position of 1.0cm is more, namely the Al-50Sn alloy is added with the iron removal effect, and the Fe-rich phase is settled to the bottom of the alloy. The metallographic structure experiment result and the ICP test result are combined, so that the effect that the Fe-rich phase is settled to the bottom of the alloy can be further realized by adding the Al-50Sn alloy, and the iron removal effect is obtained.
To demonstrate the iron removal effect of the iron removal method of the present invention, i.e., the technical effect of Al-50Sn alloy as an iron remover, comparative example 1, which is an aluminum melt iron removal method without adding Al-50Sn alloy, is provided.
Comparative example 1
A method of treating an aluminum melt without adding an Al-50Sn alloy, the steps not particularly described being the same as those in example 1 except that: the step 1 does not carry out weighing and preheating of the Al-50Sn alloy, and the step 2 does not add the Al-50Sn alloy, so that the Al-1Fe alloy without the Al-50Sn alloy, which is called matrix alloy for short, can be obtained.
To demonstrate the effect of the addition of Al-50Sn alloy on the iron removal effect, ICP measurements were performed at 1.0cm, 2.5cm and 4.5cm for the base alloy of comparative example 1. The test results are shown in table 1 and fig. 2, with an iron content of 1.03wt.% at 1.0cm, an iron content of 1.02wt.% at 2.5cm and an iron content of 0.96wt.% at 4.5 cm. The experimental result shows that the iron content in the matrix alloy has no obvious change along with the height change. As can be seen from the comparison of the test results with the alloy of example 1, the addition of the Al-50Sn alloy realizes the precipitation of the Fe-rich phase, i.e., the Al-50Sn alloy has the effects of precipitation and iron removal.
To demonstrate the effect of the addition of Al-50Sn alloy on the metallographic structure, metallographic structure tests were carried out at 4.5cm for the base alloy of comparative example 1. As shown in FIG. 4, the Fe-rich phase at 4.5cm of the base alloy was large in number and large in size. The comparison of the test result with the alloy of example 1 shows that the addition of the Al-50Sn alloy realizes the sedimentation of the Fe-rich phase and obtains the iron removal effect.
To demonstrate the effect of Al-50Sn alloy addition on iron removal, example 2, an aluminum melt iron removal process with an Al-50Sn alloy addition of 2wt.%, was provided.
Example 2
An iron removal method for an aluminum melt in which an Al-50Sn alloy was added in an amount of 2wt.%, and the steps not specifically described were the same as in example 1, except that: in the step 1, the addition amount of the Al-50Sn alloy is 2wt.%, namely 15.6g of the Al-50Sn alloy is weighed, and the aluminum alloy of the Al-50Sn alloy of 2wt.% after iron removal is obtained.
In order to demonstrate the iron removal effect of the iron removal method of the present invention, ICP tests were performed at 1.0cm, 2.5cm and 4.5cm, respectively, of the alloy of example 2. The results of the tests are shown in table 1 and fig. 2, with example 2 alloy having an iron content of 1.15wt.% at 1.0cm, an iron content of 0.79wt.% at 2.5cm and an iron content of 0.61wt.% at 4.5 cm. In order to quantify the iron removal effect, the change in iron content was calculated. The iron content at 4.5cm was reduced from 0.96wt.% to 0.61wt.%, and the iron removal rate was calculated to be 36.5%.
In order to further prove the iron removal effect of the iron removal method of the present invention, metallographic structure tests were carried out at 1.0cm and 4.5cm, respectively, of the alloy of example 2. The test results are shown in FIG. 5, in which FIG. 5a shows the metallographic structure of the alloy of example 2 at 4.5cm, with a small amount of Fe-rich phases; FIG. 5b shows the metallographic structure at 1.0cm of the alloy of example 2, showing a large number of Fe-rich phases and a large size.
To demonstrate the difference between the Sn element iron remover and the B element iron remover, example 2 and comparative example 2 were provided. In example 3, an Sn element iron remover, i.e., an Al-50Sn alloy, was added to the Al alloy; comparative example 2 is an Al-3B alloy with the addition of a B element iron remover to the Al alloy.
Example 3
An iron removal method for an aluminum melt in which an Al-50Sn alloy was added in an amount of 1wt.%, and the steps not specifically described were the same as in example 1, except that: the addition amount of the Al-50Sn alloy in the step 1 is 1wt.%, namely 7.8g of the Al-50Sn alloy is weighed, and the aluminum alloy with the 1wt.% of the Al-50Sn alloy subjected to iron removal can be obtained.
In order to demonstrate the iron removal effect of the iron removal method of the present invention, ICP tests were performed at 1.0cm, 2.5cm and 4.5cm, respectively, of the alloy of example 3. The results of the tests are shown in table 1 and fig. 2, with example 3 alloy having an iron content of 1.12wt.% at 1.0cm, an iron content of 0.79wt.% at 2.5cm and an iron content of 0.66wt.% at 4.5 cm. In order to quantify the iron removal effect, the change in iron content was calculated. The iron content at 4.5cm was reduced from 0.96wt.% to 0.66wt.%, and the iron removal rate was calculated to be 31.3%.
To further demonstrate the iron removal effect of the iron removal method of the present invention, metallographic structure tests were carried out at 1.0cm and 4.5cm, respectively, of the alloy of example 3. The test results are shown in FIG. 6, in which FIG. 6a shows the metallographic structure of the alloy of example 3 at 4.5cm, with a small amount of Fe-rich phases; FIG. 6b is a metallographic structure of the alloy of example 3 at 1.0cm showing a large number of Fe-rich phases and a large size.
Comparative example 2
A method for removing iron from an aluminum melt based on an Al-3B alloy, wherein when the Al-3B alloy is added in an amount of 1wt.%, the steps not specifically described are the same as in example 1, except that: the adding amount of the Al-3B alloy in the step 1 is 1wt.%, namely 7.8g of the Al-3B alloy is weighed, and the aluminum alloy with the 1wt.% of the Al-3B alloy subjected to iron removal can be obtained.
To compare the iron removal effect of Al-3B, ICP measurements were performed at 1.0cm, 2.5cm and 4.5cm, respectively, for the comparative example 2 alloy. The results of the tests are shown in table 1 and fig. 2, with the comparative example 2 alloy having an iron content of 1.06wt.% at 1.0cm, an iron content of 0.86wt.% at 2.5cm and an iron content of 0.79wt.% at 4.5 cm. In order to quantify the iron removal effect, the change in iron content was calculated. The iron content at the position of 4.5cm is reduced from 0.96wt.% to 0.79wt.%, and the iron removal rate can reach 17.7% by calculation.
In order to compare the iron removal effect of Al-3B, metallographic structure tests were performed at 1.0cm and 4.5cm, respectively, for the alloy of comparative example 2. The test result is shown in FIG. 7, in which FIG. 7a shows that the metallographic structure of the alloy of comparative example 2 at 4.5cm has a small amount of Fe-rich phases, but the amount of Fe-rich phases is greater than that of the alloy of example 3 at the same position; FIG. 7b shows the metallographic structure at 1.0cm of the alloy of comparative example 2, with a large number of Fe-rich phases.
As can be seen from the above example 3 and comparative example 2, the iron removal effect of the Al-50Sn alloy is better than that of the Al-3B alloy when the addition amount is the same, and the iron removal of the Al-50Sn alloy makes the sedimentation effect of the Fe-rich phase more remarkable.
The test results of the embodiment 1, the embodiment 2 and the embodiment 3 are combined to know that the addition of the Al-50Sn alloy realizes the sedimentation of the Fe-rich phase, namely, the Al-50Sn alloy has the sedimentation iron removal effect and has the iron removal effect on the aluminum melt.
Claims (2)
1. An aluminum melt iron removal method based on Al-50Sn alloy is characterized by comprising the following steps: al-50Sn alloy is used as an iron remover, the aluminum melt is aluminum with high iron content, the iron removal method is a flux method, and the Fe content in the aluminum melt is 0.9-1.1 wt%;
the method specifically comprises the following steps:
step 1, preparing raw materials, namely respectively weighing Al-50Sn alloy and aluminum alloy with the addition of the Al-50Sn alloy of 1.0-3.0 wt%, then wrapping the Al-50Sn alloy with aluminum foil, preheating the Al-50Sn alloy under the condition that the preheating temperature is 150-200 ℃ to obtain preheated Al-50Sn alloy, and simultaneously heating and melting the aluminum alloy to obtain an aluminum melt;
and 2, performing iron removal operation on the aluminum melt, namely adding preheated Al-50Sn alloy into the aluminum melt for iron removal operation under the conditions that the iron removal temperature is 720-840 ℃ and the iron removal time is 30-90min, cooling the aluminum melt to room temperature in the air after the iron removal operation is finished to obtain the aluminum alloy subjected to the iron removal operation, and finally cutting the aluminum alloy from a position 1/6 away from the bottom of the aluminum alloy to finish the iron removal of the aluminum melt.
2. The method for removing iron from the aluminum melt according to claim 1, wherein the method comprises the following steps: the iron removal rate of the iron removal method is 31.0-43.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210920819.4A CN115233016B (en) | 2022-08-02 | 2022-08-02 | Al-50Sn alloy based aluminum melt iron removal method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210920819.4A CN115233016B (en) | 2022-08-02 | 2022-08-02 | Al-50Sn alloy based aluminum melt iron removal method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115233016A CN115233016A (en) | 2022-10-25 |
| CN115233016B true CN115233016B (en) | 2023-02-03 |
Family
ID=83677305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210920819.4A Active CN115233016B (en) | 2022-08-02 | 2022-08-02 | Al-50Sn alloy based aluminum melt iron removal method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115233016B (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6132532A (en) * | 1997-01-13 | 2000-10-17 | Advanced Metal Technologies, Ltd. | Aluminum alloys and method for their production |
| JP2009108409A (en) * | 2007-10-12 | 2009-05-21 | Hitachi Metals Ltd | Al-Mg TYPE ALUMINUM ALLOY FOR FORGING, WITH EXCELLENT TOUGHNESS, AND CAST MEMBER COMPOSED THEREOF |
| CN101985714A (en) * | 2010-12-07 | 2011-03-16 | 吉林大学 | High-plasticity magnesium alloy and preparation method thereof |
| CN109207773A (en) * | 2018-10-24 | 2019-01-15 | 广西大学 | A kind of composite fluxing agent and a kind of method for refining rich ferroaluminium using composite fluxing agent |
| CA3070909A1 (en) * | 2017-08-16 | 2019-02-21 | Alcoa Usa Corp. | Methods of recycling aluminum alloys and purification thereof |
| CN110358950A (en) * | 2019-07-12 | 2019-10-22 | 上海大学 | Hypoeutectic cast aluminium-silicon alloy Modification Manners |
| CN111809086A (en) * | 2019-04-12 | 2020-10-23 | 比亚迪股份有限公司 | Die-casting aluminum alloy and preparation method and application thereof |
| CN113278832A (en) * | 2021-05-12 | 2021-08-20 | 南昌大学 | Method for preparing secondary aluminum alloy from scrap aluminum alloy |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102021370B (en) * | 2009-09-09 | 2013-03-27 | 贵州华科铝材料工程技术研究有限公司 | Be-Ni-RE high-strength heatproof aluminum alloy material and preparation method thereof |
| CN101805857B (en) * | 2009-09-23 | 2011-06-29 | 贵州华科铝材料工程技术研究有限公司 | Be-RE high-strength heat-resisting aluminum alloy material and production method thereof |
| CN112795811A (en) * | 2019-11-13 | 2021-05-14 | 新疆大学 | Polycrystalline multiphase reinforced heat-resistant titanium alloy and preparation method thereof |
| CN113774259B (en) * | 2021-08-20 | 2022-03-04 | 烟台南山学院 | Al-Cu-Mg alloy and method for eliminating harmful iron-containing phase |
-
2022
- 2022-08-02 CN CN202210920819.4A patent/CN115233016B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6132532A (en) * | 1997-01-13 | 2000-10-17 | Advanced Metal Technologies, Ltd. | Aluminum alloys and method for their production |
| JP2009108409A (en) * | 2007-10-12 | 2009-05-21 | Hitachi Metals Ltd | Al-Mg TYPE ALUMINUM ALLOY FOR FORGING, WITH EXCELLENT TOUGHNESS, AND CAST MEMBER COMPOSED THEREOF |
| CN101985714A (en) * | 2010-12-07 | 2011-03-16 | 吉林大学 | High-plasticity magnesium alloy and preparation method thereof |
| CA3070909A1 (en) * | 2017-08-16 | 2019-02-21 | Alcoa Usa Corp. | Methods of recycling aluminum alloys and purification thereof |
| CN111032890A (en) * | 2017-08-16 | 2020-04-17 | 美铝美国公司 | Method for recycling aluminum alloy and purification method thereof |
| CN109207773A (en) * | 2018-10-24 | 2019-01-15 | 广西大学 | A kind of composite fluxing agent and a kind of method for refining rich ferroaluminium using composite fluxing agent |
| CN111809086A (en) * | 2019-04-12 | 2020-10-23 | 比亚迪股份有限公司 | Die-casting aluminum alloy and preparation method and application thereof |
| CN110358950A (en) * | 2019-07-12 | 2019-10-22 | 上海大学 | Hypoeutectic cast aluminium-silicon alloy Modification Manners |
| CN113278832A (en) * | 2021-05-12 | 2021-08-20 | 南昌大学 | Method for preparing secondary aluminum alloy from scrap aluminum alloy |
Non-Patent Citations (2)
| Title |
|---|
| Revisiting selective nucleation at heterophase interfaces in Fe–Al solid-liquid reaction;罗群;《Journal of Materials Research and Technology》;20220111;第17卷;452-458 * |
| 再生铝合金中含Fe杂质的控制技术现状;何学峰;《化工进展》;20210526;第40卷(第10期);5251-5269 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115233016A (en) | 2022-10-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111378848B (en) | Pre-melted slag for electroslag remelting for improving purity of GH4169 alloy return and preparation method thereof | |
| EP2479304B1 (en) | Preparation method for aluminum-zirconium-titanium-carbon intermediate alloy | |
| JP5170975B2 (en) | Manufacturing method of iron-based amorphous material | |
| LU500368B1 (en) | Preparation method for copper or copper alloy material, and refining agent for refining | |
| CN1818109A (en) | Copper alloy materials with high-strength and conducting performances and production thereof | |
| CN106756149A (en) | A kind of aluminium titanium boron carbon zirconium rare earth fining agent, its preparation method and its application | |
| CN113444960A (en) | Unequal atomic ratio CoCrFeNiMoxHigh-entropy alloy and preparation method thereof | |
| CN105525117A (en) | Aluminum alloy material capable of being used for manufacturing cylinder cover and preparation method for aluminum alloy material | |
| CN115233016B (en) | Al-50Sn alloy based aluminum melt iron removal method | |
| CN102094125B (en) | Process method for preparing magnesium alloy through electro-slag remelting | |
| CN115233004B (en) | Al-Si alloy iron removal method based on Al-50Sn alloy | |
| CN102672148B (en) | New process for purifying magnesium alloy | |
| CN109762959B (en) | Smelting method of special steel and special steel | |
| EP2476764B1 (en) | Preparation method of al-zr-c master alloy | |
| CN109161708B (en) | High-purity high-concentration aluminum-boron intermediate alloy and preparation method thereof | |
| KR101234053B1 (en) | Manufacturing method of low nickel recycling magnesium alloy using magnesium scrap | |
| Al-khazraji et al. | Application of slag refining technique to metallurgical grade silicon purification process: A review | |
| CN105018800A (en) | Aluminum alloy material with good high-temperature resistance for cylinder head and preparation method of aluminum alloy material | |
| CN104313360A (en) | Method for purifying magnesium melt by adding zirconium | |
| CN112981102B (en) | Preparation of TiAl3Method for alloying and purifying Fe-containing waste aluminum alloy | |
| CN102304636A (en) | Method for preparing iron removing agent and removing iron from renewable aluminum alloy | |
| CN117363920A (en) | Preparation method for removing transition group metal from regenerated aluminum alloy | |
| JP2002097528A (en) | Purification method of aluminum | |
| CN1477218A (en) | Mangnesium alloy zirconium compound silicon-removing flux and its production method | |
| CN117403077A (en) | Pure magnesium and purifying method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |