CN115109195B - 一种生物基光与热双固化镜片、镜头填充胶及其应用 - Google Patents
一种生物基光与热双固化镜片、镜头填充胶及其应用 Download PDFInfo
- Publication number
- CN115109195B CN115109195B CN202210365046.8A CN202210365046A CN115109195B CN 115109195 B CN115109195 B CN 115109195B CN 202210365046 A CN202210365046 A CN 202210365046A CN 115109195 B CN115109195 B CN 115109195B
- Authority
- CN
- China
- Prior art keywords
- lens
- curing
- bio
- dual
- photo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000011049 filling Methods 0.000 title claims abstract description 50
- 239000000853 adhesive Substances 0.000 title claims abstract description 28
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 28
- 230000003287 optical effect Effects 0.000 claims abstract description 7
- 238000001723 curing Methods 0.000 claims description 41
- 238000000016 photochemical curing Methods 0.000 claims description 26
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 13
- 239000011265 semifinished product Substances 0.000 claims description 12
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 125000004386 diacrylate group Chemical group 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 8
- 238000013007 heat curing Methods 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 5
- -1 hydroxyl modified epoxy acrylate Chemical class 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- KFUSXMDYOPXKKT-UHFFFAOYSA-N 2-[(2-methylphenoxy)methyl]oxirane Chemical compound CC1=CC=CC=C1OCC1OC1 KFUSXMDYOPXKKT-UHFFFAOYSA-N 0.000 claims description 4
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 4
- 239000004519 grease Substances 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 claims description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 230000009977 dual effect Effects 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 2
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
- QNYBOILAKBSWFG-UHFFFAOYSA-N 2-(phenylmethoxymethyl)oxirane Chemical compound C1OC1COCC1=CC=CC=C1 QNYBOILAKBSWFG-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 2
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 2
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229940119545 isobornyl methacrylate Drugs 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 241001655736 Catalpa bignonioides Species 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 208000001491 myopia Diseases 0.000 description 1
- 230000004379 myopia Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
- C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
- C08F283/105—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule on to unsaturated polymers containing more than one epoxy radical per molecule
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明公开了一种生物基光与热双固化镜片、镜头填充胶及其应用，本发明利用光与热烘固化两类树脂、反应单体以及生物基碳树脂为原料，结合固化剂和催化剂制成一种生物基光与热双固化镜片、镜头填充胶。利用本发明的填充胶制成镜片或镜头，具有节能环保且光学性能优良的特点。
Description
技术领域
本发明具体涉及一种生物基光与热双固化镜片、镜头填充胶及其应用。
背景技术
化工原料的加工以及使用过程会不可避免产生大量的温室气体排放，因此造成碳排放量的增加。树脂材料加工领域中需要使用大量的石油碳材料，因此并不能适应环保的要求。
本发明提供了一种生物基光与热双固化镜片、镜头填充胶，旨在引入生物碳树脂，取代部分石油碳材料，从而达到减少碳排放的目的。
发明内容
基于此，本发明提供了一种生物基光与热双固化镜片、镜头填充胶，其具体原料质量百分数如下：
光固化树脂30-83％；热固化树脂3-8％，所述热固化树脂为环氧树脂；反应性单体12-60％，光固化剂2％，反应催化剂0.01-0.02％，染料0-0.01％，
所述光固化树脂是由生物基光固化树脂、羟基的改性环氧丙烯酸酯、聚酯丙烯酸酯以及聚氨酯丙烯酸酯混合而成，其中所述生物基光固化树脂为油脂改性的丙烯酸酯树脂，所述油脂为亚麻油、桐油、豆油、蓖麻油、梓油或松香中的任意一种或几种。
优选的，所述反应单体为带反应性双键或含环氧基、羟基光学级的改性丙烯酸酯系列反应性单体。
优选的，所述反应单体是由2-甲基丙烯酸羟乙酯(2-HEMA)、甲基丙烯酸缩水甘油酯(GMA)、季戊四醇三丙烯酯(PET3A)、三羟甲基丙烷三丙烯酸酯(TMPTA)、三羟甲基丙烷三甲基丙烯酸酯(TMPTMA)、三丙二醇二丙烯酯(TPGDA)、丙烯酸异冰片酯(IBOA)、甲基丙烯酸异冰片酯(IBOMA)、2-苯氧基乙基丙烯酸酯(2-PEA)、双酚A聚氧乙烯醚二丙烯酸酯、苯基缩水甘油醚、脂肪缩水甘油醚、苄基缩水甘油醚、邻甲苯基醚、邻甲苯基缩水甘油醚、新戊二醇二缩水甘油醚中的一种或几种构成。
优选的，所述反应催化剂为有机银或有机钒。
本发明还提供了所述生物基光与热双固化镜片、镜头填充胶的制备方法，具体是将所述原料按比例混合，搅拌1-3小时，搅拌速度为60-100转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，所述过滤网的网孔为0.5-1微米。
本发明还提供了所述生物基光与热双固化镜片、镜头填充胶的应用，具体是利用所述生物基光与热双固化镜片、镜头填充胶制备镜片或镜头，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长305-405nm，照射3秒到十分钟完成第一阶段光固化，制得半成品；
将所述半成品在70-150℃的烘箱内烘烤20-90分钟，完成热固化，制得所述镜片、镜头。
与现有技术相比，本发明具有以下有益效果：
本发明利用光与热烘固化两类树脂、反应单体以及生物基碳光固化树脂为原料，结合固化剂和催化剂制成一种生物基光与热双固化镜片、镜头填充胶。利用本发明的填充胶制成镜片或镜头，具有节能环保且光学性能优良的特点。
具体实施方式
下面结合具体实施例对本发明作进一步说明。
实施例1
一种生物基光与热双固化镜片、镜头填充胶，其原料质量百分数如下：
环氧树脂(宏昌电子材料股份有限公司GESR904H)2.5％，
三羟甲基丙烷三丙烯酸酯(TMPTA)4.99％
双酚A聚氧乙烯醚二丙烯酸酯10％
新戊二醇二缩水甘油醚1％
2-甲基丙烯酸羟乙酯(2-HEMA)1％
光固化剂2％，
有机银0.01％，
光固化带羟基的改性环氧丙烯酸酯(新力美科技股份有限公司，1010)3.8％，
光固化聚酯丙烯酸酯(新力美科技股份有限公司，708)3.8％，
光固化聚氨酯丙烯酸酯(新力美科技股份有限公司，670A2)0.38％，
大豆油改性丙烯酸树脂(三木化工，6103)70.52％。
本发明所述生物基光与热双固化镜片、镜头填充胶的制备方法是将上述原料按比例混合搅拌2小时，搅拌速度为80转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，其中过滤网的网孔为0.5微米。
利用所述生物基光与热双固化镜片、镜头填充胶制备镜片，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长400nm，照射5分钟完成第一阶段光固化，制得半成品；
将所述半成品在100℃的烘箱内烘烤60分钟，完成热固化，制得所述镜片。
实施例2
一种生物基光与热双固化镜片、镜头填充胶，其原料质量百分数如下：
环氧树脂(宏昌电子材料股份有限公司GESR904H)6.6％，
2-甲基丙烯酸羟乙酯(2-HEMA)8.5％
季戊四醇三丙烯酯(PET3A)16.5％
双酚A聚氧乙烯醚二丙烯酸酯29.99％
邻甲苯基缩水甘油醚5％
光固化剂2％，
有机银0.01％，
光固化带羟基的改性环氧丙烯酸酯(新力美科技股份有限公司，1010)5％，
光固化聚酯丙烯酸酯(新力美科技股份有限公司，708)3.3％，
光固化聚氨脂丙烯酸酯(新力美科技股份有限公司，670A2)1.7％，
大豆油改性丙烯酸树脂(三木化工，6103)21.4％。
本发明所述生物基光与热双固化镜片、镜头填充胶的制备方法是将上述原料按比例混合搅拌2小时，搅拌速度为100转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，其中过滤网的网孔为0.5微米。
利用所述生物基光与热双固化镜片、镜头填充胶制成600度防蓝光近视镜片，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长405nm，照射1分钟完成第一阶段光固化，制得半成品；
将所述半成品在100℃的烘箱内烘烤50分钟，完成热固化，制得所述镜片。
对照组
一种镜片、镜头填充胶，其原料质量百分数如下：
环氧树脂(宏昌电子材料股份有限公司GESR904H)6.6％，
2-甲基丙烯酸羟乙酯(2-HEMA)11.5％
季戊四醇三丙烯酯(PET3A)13.5％
双酚A聚氧乙烯醚二丙烯酸酯29.99％
邻甲苯基缩水甘油醚5％
光固化剂2％，
有机银0.01％，
光固化带羟基的改性环氧丙烯酸酯(新力美科技股份有限公司，1010)25％，
光固化聚酯丙烯酸酯(新力美科技股份有限公司，708)4.7％，
光固化聚氨脂丙烯酸酯(新力美科技股份有限公司，670A2)1.7％
同时利用对照组制备的填充胶按照实施例2的方法制成一种对照组镜片，将对照组镜片与本发明实施例制备的镜片进行性能检测，具体如下所示。
实施例3
一种生物基光与热双固化镜片、镜头填充胶，其原料质量百分数如下：
环氧树脂(宏昌电子材料股份有限公司GESR904H)7％，
季戊四醇三丙烯酯(PET3A)6％
2-苯氧基乙基丙烯酸酯(2-PEA)4.99％
双酚A聚氧乙烯醚二丙烯酸酯20％
苄基缩水甘油醚3％
2-甲基丙烯酸羟乙酯(2-HEMA)8％
光固化剂2％，
有机钒0.02％，
光固化带羟基的改性环氧丙烯酸酯(新力美科技股份有限公司，1010)7.3％，
光固化聚酯丙烯酸酯(新力美科技股份有限公司，708)3.7％，
光固化聚氨脂丙烯酸酯(新力美科技股份有限公司，670A2)1％
松香改性聚酯丙烯酸酯(江门市恒之光环保新材料有限公司5335)9％
大豆油改性丙烯酸树脂(三木化工，6103)18％
本发明所述生物基光与热双固化镜片、镜头填充胶的制备方法是将上述原料按比例混合搅拌2小时，搅拌速度为100转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，其中过滤网的网孔为0.5微米。
利用所述生物基光与热双固化镜片、镜头填充胶制成100度老光镜片，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长405nm，照射3分钟完成第一阶段光固化，制得半成品；
将所述半成品在150℃的烘箱内烘烤30分钟，完成热固化，制得所述镜片。
实施例4
一种生物基光与热双固化镜片、镜头填充胶，其原料质量百分数如下：
环氧树脂(宏昌电子材料股份有限公司GESR904H)5％，
季戊四醇三丙烯酯(PET3A)2％
双酚A聚氧乙烯醚二丙烯酸酯13％
苄基缩水甘油醚2％
2-甲基丙烯酸羟乙酯(2-HEMA)6.98％
光固化剂2％，
有机钒0.02％，
光固化带羟基的改性环氧丙烯酸酯(新力美科技股份有限公司，1010)7.3％，
光固化聚酯丙烯酸酯(新力美科技股份有限公司，708)3.7％，
光固化聚氨脂丙烯酸酯(新力美科技股份有限公司，670A2)1％
松香改性聚酯丙烯酸酯(江门市恒之光环保新材料有限公司5335)15％
大豆油改性丙烯酸树脂(三木化工，6103)42％
本发明所述生物基光与热双固化镜片、镜头填充胶的制备方法是将上述原料按比例混合搅拌2小时，搅拌速度为100转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，其中过滤网的网孔为0.5微米。
利用所述生物基光与热双固化镜片、镜头填充胶制成太阳镜镜片，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长305nm，照射10分钟完成第一阶段光固化，制得半成品；
将所述半成品在70℃的烘箱内烘烤90分钟，完成热固化，制得所述太阳镜镜片。
需要说明的是，以上列举的仅是本发明的若干个具体实施例，显然本发明不仅仅限于以上实施例，还可以有其他变形。本领域的技术人员从本发明公开内容直接导出或间接引申的所有变形，均应认为是本发明的保护范围。
Claims (5)
1.一种生物基光与热双固化镜片、镜头填充胶，其特征在于，由以下质量百分数的原料制备而成：
光固化树脂30-83％；热固化树脂3-8％，所述热固化树脂为环氧树脂；
反应性单体12-60％，光固化剂2％，反应催化剂0.01-0.02％，染料0-0.01％，所述光固化树脂是由生物基光固化树脂、羟基的改性环氧丙烯酸酯、聚酯丙烯酸酯以及聚氨酯丙烯酸酯混合而成，其中所述生物基光固化树脂为油脂改性的丙烯酸酯树脂，所述油脂为豆油。
2.根据权利要求1所述生物基光与热双固化镜片、镜头填充胶，其特征在于，所述反应单体是由三羟甲基丙烷三丙烯酸酯、双酚A聚氧乙烯醚二丙烯酸酯、新戊二醇二缩水甘油醚、2-甲基丙烯酸羟乙酯混合而成，或，
所述反应单体是由2-甲基丙烯酸羟乙酯、季戊四醇三丙烯酯、双酚A聚氧乙烯醚二丙烯酸酯、邻甲苯基缩水甘油醚混合而成。
3.根据权利要求1所述生物基光与热双固化镜片、镜头填充胶，其特征在于，所述反应催化剂为有机银。
4.根据权利要求1-3任意一项所述生物基光与热双固化镜片、镜头填充胶的制备方法，其特征在于，将所述原料按比例混合，搅拌1-3小时，搅拌速度为60-100转/分钟，然后过滤后得到生物基光与热双固化镜片、镜头填充胶，所述过滤网的网孔为0.5-1微米。
5.根据权利要求1-3任意一项所述生物基光与热双固化镜片、镜头填充胶的应用，其特征在于，利用所述生物基光与热双固化镜片、镜头填充胶制备镜片或镜头，具体制备步骤如下：
将所述光与热双固化镜片、镜头填充胶充填进玻璃模具内，放进LED-UV光固化机，设定光波段范围为LED-UV波长305-405nm，照射3秒到十分钟完成第一阶段光固化，制得半成品；
将所述半成品在70-150℃的烘箱内烘烤20-90分钟，完成热固化，制得所述镜片、镜头。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210365046.8A CN115109195B (zh) | 2022-04-07 | 2022-04-07 | 一种生物基光与热双固化镜片、镜头填充胶及其应用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210365046.8A CN115109195B (zh) | 2022-04-07 | 2022-04-07 | 一种生物基光与热双固化镜片、镜头填充胶及其应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115109195A CN115109195A (zh) | 2022-09-27 |
| CN115109195B true CN115109195B (zh) | 2024-02-09 |
Family
ID=83324464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210365046.8A Active CN115109195B (zh) | 2022-04-07 | 2022-04-07 | 一种生物基光与热双固化镜片、镜头填充胶及其应用 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115109195B (zh) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010027041A1 (ja) * | 2008-09-05 | 2010-03-11 | 協立化学産業株式会社 | 光学機能材料を貼り合わせるための光硬化型樹脂組成物 |
| KR20100072566A (ko) * | 2008-12-22 | 2010-07-01 | 이피캠텍 주식회사 | 아크릴레이티드에스테르 모노머를 포함하는 조성물 및 이를이용한 코팅제 |
| CN105820723A (zh) * | 2016-05-30 | 2016-08-03 | 成都纳硕科技有限公司 | 一种耐磨光固化镜片 |
| CN106554364A (zh) * | 2016-10-12 | 2017-04-05 | 中国林业科学研究院林产化学工业研究所 | 一种油脂基双固化树脂单体的制备方法 |
| CN108715752A (zh) * | 2018-06-22 | 2018-10-30 | 瑞洲树脂（东莞）有限公司 | 一种光与热双固化镜片、镜头填充胶 |
| CN111978784A (zh) * | 2020-09-15 | 2020-11-24 | 中山市富日印刷材料有限公司 | 一种生物质基环保uv光固化油墨的制备方法 |
-
2022
- 2022-04-07 CN CN202210365046.8A patent/CN115109195B/zh active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010027041A1 (ja) * | 2008-09-05 | 2010-03-11 | 協立化学産業株式会社 | 光学機能材料を貼り合わせるための光硬化型樹脂組成物 |
| KR20100072566A (ko) * | 2008-12-22 | 2010-07-01 | 이피캠텍 주식회사 | 아크릴레이티드에스테르 모노머를 포함하는 조성물 및 이를이용한 코팅제 |
| CN105820723A (zh) * | 2016-05-30 | 2016-08-03 | 成都纳硕科技有限公司 | 一种耐磨光固化镜片 |
| CN106554364A (zh) * | 2016-10-12 | 2017-04-05 | 中国林业科学研究院林产化学工业研究所 | 一种油脂基双固化树脂单体的制备方法 |
| CN108715752A (zh) * | 2018-06-22 | 2018-10-30 | 瑞洲树脂（东莞）有限公司 | 一种光与热双固化镜片、镜头填充胶 |
| CN111978784A (zh) * | 2020-09-15 | 2020-11-24 | 中山市富日印刷材料有限公司 | 一种生物质基环保uv光固化油墨的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115109195A (zh) | 2022-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100588690C (zh) | 用于金属的阻燃型紫外光固化涂料 | |
| CN104726052B (zh) | 一种uv/底涂双重固化液态光学胶及其制备方法 | |
| CN100376637C (zh) | 双重固化的涂料 | |
| CN110467890A (zh) | 压敏胶带及其制备方法、用于制备压敏胶带的树脂组合物 | |
| CN108084952A (zh) | 一种uv压敏/湿气双固化聚氨酯热熔胶的制备方法 | |
| Aung et al. | A comparative study of acrylate oligomer on Jatropha and Palm oil-based UV-curable surface coating | |
| CN107189032B (zh) | 一种多官能uv固化聚氨酯植物油酸酯预聚物及其制法和应用 | |
| CN101942277A (zh) | 一种紫外光固化转印胶 | |
| CN105086916A (zh) | 一种高透光uv-湿气双固化胶黏剂 | |
| CN108003802B (zh) | 一种基于逐步聚合机理热致自愈合紫外光固化胶黏剂 | |
| CN106519182A (zh) | 一种机硅改性聚氨酯丙烯酸酯低聚物及制备方法 | |
| CN104447325A (zh) | 一种可紫外光固化耐黄变环氧丙烯酸酯及其制备方法 | |
| CN107129788B (zh) | 一种uv固化型压敏胶粘剂 | |
| CN113429889A (zh) | 一种紫外光固化压敏胶的制备方法 | |
| CN104592903A (zh) | 一种uv固化丙烯酸酯压敏胶及其制备方法 | |
| CN115109195B (zh) | 一种生物基光与热双固化镜片、镜头填充胶及其应用 | |
| CN101701143A (zh) | 一种紫外光固化粘合剂及其制备方法 | |
| CN106147587B (zh) | 一种含有蓖麻油基的抗菌uv涂料及其制备方法和应用 | |
| CN105837214B (zh) | 一种石墨烯制品的制备方法 | |
| CN109438631A (zh) | 一种高精度和高热变形温度立体光刻3d打印光敏树脂及其制备方法 | |
| CN110183885B (zh) | 一种电子束固化生物基涂料组合物及其制备方法 | |
| CN109735224A (zh) | 一种uv/湿气双重固化的眼镜框涂料及其制备方法 | |
| CN111056943B (zh) | 一种多官能亚麻油基uv固化预聚物及其制备方法和应用 | |
| CN110591632A (zh) | 一种黑色紫外光固化胶及其制备方法 | |
| CN115746690B (zh) | 一种水性uv玻璃透明光油 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 40076880 Country of ref document: HK |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |