CN114790413A - 一种高效除油的表面活性剂组合物 - Google Patents
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- 239000004094 surface-active agent Substances 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000003921 oil Substances 0.000 claims abstract description 29
- 235000019198 oils Nutrition 0.000 claims abstract description 29
- 230000001954 sterilising effect Effects 0.000 claims abstract description 12
- 239000003619 algicide Substances 0.000 claims abstract description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 238000006073 displacement reaction Methods 0.000 claims abstract description 9
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 7
- 239000003240 coconut oil Substances 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
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- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 239000002216 antistatic agent Substances 0.000 claims abstract description 6
- 239000011259 mixed solution Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 150000002978 peroxides Chemical class 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical group CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 7
- 239000012459 cleaning agent Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000004976 Lyotropic liquid crystal Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
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Abstract
本发明提供了一种高效除油的表面活性剂组合物，包括以下重量份的组分：椰子油脂肪酸二乙醇酰胺20～40份、脂肪醇聚氧乙烯醚10～20份、碱性驱油组分4～7份、破乳剂0.3～0.5份、抗静电剂0.1～0.5份、灭菌灭藻剂0.1～0.3份。本发明的表面活性剂组合物，能够高效快速地清除大型机械设备表面的油污。
Description
技术领域
本发明涉及表面活性剂技术领域，具体涉及一种高效除油的表面活性剂组合物。
背景技术
表面活性剂是一类在添加量很少时就能显著降低界面张力的物质，其分子具有独特结构：一端为亲水性的极性基团，另一端为亲油性的非极性基团，也称为两亲分子。在溶液中可自发形成胶束、溶致液晶、微乳液、囊泡、蠕虫状胶束、微乳液凝胶等稳定、有序排列的缔合结构。普遍的表面活性剂存在去油性不足问题，尤其是大型机械设备表面的油类的去除效果较差。因此，亟需一种去油能力强的表面活性剂组合物，能够高效快速地清除大型机械设备表面的油污。
发明内容
针对以上问题，本发明提供一种高效除油的表面活性剂组合物，能够高效快速地清除大型机械设备表面的油污。
为实现上述目的，本发明通过以下技术方案来解决：
一种高效除油的表面活性剂组合物，包括以下重量份的组分：椰子油脂肪酸二乙醇酰胺20～40份、脂肪醇聚氧乙烯醚10～20份、碱性驱油组分4～7份、破乳剂0.3～0.5份、抗静电剂0.1～0.5份、灭菌灭藻剂0.1～0.3份。
具体的，所述表面活性剂组合物的pH值为8～9.5。
具体的，所述碱性驱油组分是由聚丙烯酰胺与碱剂按重量份比为10:1～5组成的混合液。
具体的，所述碱剂选自氢氧化钠、碳酸钠、氢氧化铵、磷酸钠、硅酸钠中的一种。
具体的，所述破乳剂选自聚氧乙烯聚氧丙烯十八醇醚、聚氧乙烯聚氧丙烯聚醚中的一种。
具体的，所述抗静电剂为十二胺聚氧乙烯醚。
具体的，所述灭菌灭藻剂由戊二醛、过氧化物按重量份比为1～3:1组成的混合液。
具体的，所述过氧化物选自双氧水、过氧化钠、过氧乙酸中的一种。
本发明的有益效果是：
1.本发明提供的表面活性剂组合物，含有椰子油脂肪酸二乙醇酰胺与脂肪醇聚氧乙烯醚，通过非离子表面活性剂与阴离子表面活性剂组合使用，能够高效快速地清除大型机械设备表面的油污；
2.增加了碱性驱油组分，碱性驱油组分是由聚丙烯酰胺与碱剂组成的混合液，聚丙烯酰胺具有优异的驱油特性，能够将附着在大型机械设备表面的油污驱除，并且通过碱剂与原油中酸性成分反应生成的表面活性物质，降低界面张力，使得油污更容易驱除；
3.增加了抗静电剂，在大型机械设备表面清洗过程中能防止静电产生，从而降低设备的漏电风险；
4.通常清洗后废水会直接流道河道中，本发明通过增加灭菌灭藻剂，使得清洗废液中含有灭菌灭藻剂，灭菌灭藻剂内含戊二醛、过氧化物，具有灭菌灭藻速度快、效果强力的特点，起到预防河道藻类滋生的效果。
具体实施方式
为了能进一步了解本发明的特征、技术手段以及所达到的具体目的、功能，下面结合具体实施方式对本发明作进一步的详细描述。
实施例1
将0.7g戊二醛和0.3g过氧化钠加入烧杯中，搅拌均匀后制得灭菌灭藻剂备用；
将20g聚丙烯酰胺和10g磷酸钠加入烧杯中，搅拌均匀后制得碱性驱油组分备用；
将300g椰子油脂肪酸二乙醇酰胺和150g脂肪醇聚氧乙烯醚置于反应釜中，搅拌均匀，然后缓慢加入3g聚氧乙烯聚氧丙烯十八醇醚、1g十二胺聚氧乙烯醚、40g碱性驱油组分和1g灭菌灭藻剂，搅拌均匀，并加入少量磷酸钠将混合液的pH值调整至8～9.5，得到表面活性剂组合物作为清洗剂。
对比例1
采用椰子油脂肪酸二乙醇酰胺作为清洗剂。
对比例2
采用脂肪醇聚氧乙烯醚作为清洗剂。
对比例3
采用椰子油脂肪酸二乙醇酰胺与脂肪醇聚氧乙烯醚按重量比1:1组成的混合液作为清洗剂。
测试：
参照中国石油化工集团公司企业标准Q/SHCG11-2011中规定的方法，对实施例1、对比例1、对比例2、对比例3分别制备的清洗剂进行静态洗油率评价，实验结果在下表1中列出。
表1
上述结果证实，采用本发明的表面活性剂组合物作为清洗剂，能够有效提高对油的洗脱能力。
以上所述实施例仅表达了本发明的1种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。
Claims (8)
1.一种高效除油的表面活性剂组合物，其特征在于，包括以下重量份的组分：椰子油脂肪酸二乙醇酰胺20～40份、脂肪醇聚氧乙烯醚10～20份、碱性驱油组分4～7份、破乳剂0.3～0.5份、抗静电剂0.1～0.5份、灭菌灭藻剂0.1～0.3份。
2.根据权利要求1所述的一种高效除油的表面活性剂组合物，其特征在于，所述表面活性剂组合物的pH值为8～9.5。
3.根据权利要求1所述的一种高效除油的表面活性剂组合物，其特征在于，所述碱性驱油组分是由聚丙烯酰胺与碱剂按重量份比为10:1～5组成的混合液。
4.根据权利要求3所述的一种高效除油的表面活性剂组合物，其特征在于，所述碱剂选自氢氧化钠、碳酸钠、氢氧化铵、磷酸钠、硅酸钠中的一种。
5.根据权利要求1所述的一种高效除油的表面活性剂组合物，其特征在于，所述破乳剂选自聚氧乙烯聚氧丙烯十八醇醚、聚氧乙烯聚氧丙烯聚醚中的一种。
6.根据权利要求1所述的一种高效除油的表面活性剂组合物，其特征在于，所述抗静电剂为十二胺聚氧乙烯醚。
7.根据权利要求1所述的一种高效除油的表面活性剂组合物，其特征在于，所述灭菌灭藻剂由戊二醛、过氧化物按重量份比为1～3:1组成的混合液。
8.根据权利要求7所述的一种高效除油的表面活性剂组合物，其特征在于，所述过氧化物选自双氧水、过氧化钠、过氧乙酸中的一种。
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| CN109208016A (zh) * | 2018-09-29 | 2019-01-15 | 黑龙江大学 | 一种无磷防锈金属清洗剂及其制备方法 |
| CN111171975A (zh) * | 2020-01-16 | 2020-05-19 | 广东丽臣奥威实业有限公司 | 一种高效去污的表面活性剂组合物 |
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