CN114767575B - Fluffy shampoo composition - Google Patents
Fluffy shampoo composition Download PDFInfo
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- CN114767575B CN114767575B CN202210467197.4A CN202210467197A CN114767575B CN 114767575 B CN114767575 B CN 114767575B CN 202210467197 A CN202210467197 A CN 202210467197A CN 114767575 B CN114767575 B CN 114767575B
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- polyurethane
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000002453 shampoo Substances 0.000 title claims abstract description 43
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 230000000694 effects Effects 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 18
- 239000004814 polyurethane Substances 0.000 claims abstract description 18
- 244000068988 Glycine max Species 0.000 claims abstract description 17
- 235000010469 Glycine max Nutrition 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 230000003750 conditioning effect Effects 0.000 claims abstract description 11
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 6
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 239000002562 thickening agent Substances 0.000 claims abstract description 5
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 4
- 239000003205 fragrance Substances 0.000 claims abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- -1 glycerol glucoside Chemical class 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 4
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 4
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 108700004121 sarkosyl Proteins 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 3
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 3
- 229960004025 sodium salicylate Drugs 0.000 claims description 3
- 239000004475 Arginine Substances 0.000 claims description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 claims 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 claims 1
- 210000004209 hair Anatomy 0.000 abstract description 87
- 210000004761 scalp Anatomy 0.000 abstract description 30
- 230000000052 comparative effect Effects 0.000 description 32
- 238000012360 testing method Methods 0.000 description 26
- 239000004519 grease Substances 0.000 description 14
- 230000003741 hair volume Effects 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 230000001965 increasing effect Effects 0.000 description 9
- 210000003491 skin Anatomy 0.000 description 8
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- 230000001953 sensory effect Effects 0.000 description 7
- 208000001840 Dandruff Diseases 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 210000002374 sebum Anatomy 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000002390 adhesive tape Substances 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 230000028327 secretion Effects 0.000 description 5
- 150000001413 amino acids Chemical class 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 2
- 235000003880 Calendula Nutrition 0.000 description 2
- 240000001432 Calendula officinalis Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
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- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 210000001061 forehead Anatomy 0.000 description 2
- 210000003780 hair follicle Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 102000016942 Elastin Human genes 0.000 description 1
- 108010014258 Elastin Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 description 1
- 241000580938 Sapindus Species 0.000 description 1
- 240000003377 Shepherdia canadensis Species 0.000 description 1
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 230000003656 anti-hair-loss Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229920002549 elastin Polymers 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 150000002333 glycines Chemical class 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000019622 heart disease Diseases 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229940094541 polyglycerin-10 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920003009 polyurethane dispersion Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000010938 white gold Substances 0.000 description 1
- 229910000832 white gold Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/008—Preparations for oily hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Biophysics (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a fluffy shampoo composition which comprises the following components in parts by weight: 0.05-10 parts of polyurethane, 0.05-10 parts of disilylated silica, and 0.05-10 parts of wild soybean seed extract; the composition comprises the following components in addition to the three components: anionic surfactants, nonionic surfactants, zwitterionic surfactants, conditioning agents, pearling agents, thickeners, preservatives, pH modifiers, fragrances and water. The fluffy shampoo composition disclosed by the invention is mild, does not irritate scalp, has strong oil control capability, and can endow hair with good fluffy effect.
Description
Technical Field
The invention belongs to the field of daily chemicals and relates to a fluffy shampoo composition.
Background
In recent years, a small amount of hair becomes a heart disease of more and more people, and the hair loss phenomenon shows a tendency to be younger. The effectiveness of a plurality of anti-hair loss and hair growth products on the market is doubtful; the investment of the hair implantation operation is high and has a certain risk. However, if the hair is sufficiently fluffy, the amount of hair can be visually significantly increased. Fluffy is that the hair looks like a very layered feeling with gaps instead of close fitting and collapse. According to 2021 scalp health white paper, the oil control and fluffiness effects become popular trends, and the proportion of people consuming the oil control and fluffiness washing and protecting products after 95 years is improved year by year; and the consumption level of the 95-th crowd is almost equal to that of the 80-th crowd. The oil-control fluffy product has huge market and wide prospect.
Healthy hair is very tough, but keratin in hair is easily damaged by excessive physicochemical treatments such as combing, blowing heat, dyeing, perming, etc., and the hair is roughened, losing luster, thereby reducing softness and flexibility, and the hair is difficult to finish due to increased friction, broken hair or forked ends occur, and the hair becomes thin, loses elasticity, and loses vitality and sags, thereby losing fluffiness. Shampoo is used for cleaning the grease, sweat scale, cell falling off scalp, foreign dust, microorganism, residue of shaping product and bad smell, etc. adhered on scalp and hair, keeping scalp and hair clean and hair beautiful. However, shampoos with various additional functions are also becoming popular due to the diversity of people's needs.
Currently, cationic conditioning agents are used in most shampoos to promote hair volume, generally by repelling the hair with a repulsive cationic charge. The cationic conditioning agent is adsorbed on the surface of hair through the action of charges, has stronger accumulation property than silicone oil, and is easy to adsorb more dust particles when the hair is contacted with the outside air, so that the scalp is continuously stimulated to secrete grease, and the grease is mixed with the dust to form grease so as to aggravate greasy hair. The more the use frequency is increased, the more cations are accumulated, the pores are tightly wrapped by the accumulated matters, the hair follicle respiration is blocked, the oxygen permeation is insufficient, the hair papilla is gradually atrophic, and then the alopecia occurs. The hair care effects such as softness and the like can be achieved in a short period, but the cleaning force, the poor oil control and fluffy effects of the shampoo can be reduced after long-term use, and the oil output of the scalp is increased.
Chinese patent application CN 109419643A discloses a shampoo composition comprising an aqueous polyurethane, a detersive surfactant, a conditioning agent and a carrier; the shampoo composition has the characteristics of good film forming elasticity, high glossiness, good toughness and non-sticky hand feeling through the unique design of polyurethane molecules in the aqueous polyurethane dispersion, and brings brand new natural plumping effect to hair after washing. However, the composition improves the hair bulk through the film formation of the aqueous polyurethane, is easy to deposit on the hair in the continuous multiple use process, so that the hair is heavier and the bulking effect is affected. And has no effect on hair flattening and collapse caused by hair peel oil production, and has no lasting fluffing effect.
Chinese patent application CN 109620754A discloses a low-irritation hair-volume shampoo composition comprising the following components in mass percent: 0.5-1.5% of nonionic surfactant, 9-25% of anionic surfactant, 0.5-5% of zwitterionic surfactant, 0.05-5% of cationic conditioning agent, 0.05-11.5% of grease, 0.01-10% of suspending agent, 0.01-5% of higher fatty alcohol and the balance of pure water. The invention adopts mild surfactant and reasonable conditioner collocation, and has the effects of small irritation and capability of remarkably increasing the hair after washing. However, the shampoo composition mainly reduces electrostatic adsorption of hair through flocculating deposition of cationic guar gum, polyquaternium-10, silicone oil conditioning agent and the like, so that the effects of plumping and fluffing hair are achieved. Has no effect on hair flattening and collapse caused by scalp oil extraction, and has no lasting fluffing effect.
Therefore, it is necessary to explore a shampoo composition which is strong in cleaning power and oil control and good in bulking effect.
Disclosure of Invention
Aiming at the common problem of general fluffy effect of the fluffy shampoos in the market, the invention provides a shampoo composition capable of enhancing the fluffy effect. The composition has low irritation and high oil control effect, and can reduce hair static electricity and dandruff.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
first, a composition is provided, the composition comprising the following components: polyurethane, silica disilylate, wild soybean seed extract.
Further, the composition comprises the following components in parts by weight: 0.05-10 parts of polyurethane, 0.05-10 parts of disilylated silica and 0.05-10 parts of wild soybean seed extract.
Further, the weight ratio of polyurethane, silica disilylate and wild soybean seed extract in the composition is 1-5:0.1-5:0.1-3.
Further, the polyurethane is 1-5% by weight of the composition, the silica disilylate is 0.1-5% by weight of the composition, and the wild soybean seed extract is 0.1-3% by weight of the composition.
The polyurethane can form a soft film on the surface of hair, so that stronger toughness is brought to the hair, and the soft collapse of the hair is reduced. The film can permanently ensure the fluffy effect of hair, has good shape-keeping effect under the high humidity condition, and has good anti-dandruff property. The polyurethane can protect hair at high temperature (such as a hair dryer), reduce thermal damage of hair, have a certain anti-frizziness effect, and reduce bifurcation.
The disilylated silica is one of fumed silica and has good effect on improving the fullness and the carding property of hairline; can continuously control oil, reduce greasiness and prevent the greasy and flat collapse of hair.
The wild soybean seed extract is an oil-in-water emulsifier with HLB of up to 14.9 and has stronger emulsifying property; has higher charge density, can reduce the interfacial tension between particles and a dispersion medium, wraps tiny particles, preventing flocculation/coagulation caused by steric hindrance and static electricity can enhance the stability of the product, and is also beneficial to reducing the sticky feeling of the system. The wild soybean seed extract also has excellent moisturizing performance, can obviously reduce skin percutaneous water loss, increase ceramide generation while moisturizing, and has promotion effect on collagen and elastin synthesis; this property allows the addition of the hair conditioning composition to provide sufficient nutrition to the skin of the head while providing good moisturization to the hair, thereby reducing scalp oil and enhancing the oil control ability of the shampoo.
The chemical structural formula of the wild soybean extract is as follows:
further, the composition also comprises the following components: anionic surfactants, nonionic surfactants, zwitterionic surfactants, conditioning agents, pearling agents, thickeners, preservatives, pH modifiers, fragrances and water.
Further, the anionic surfactant comprises one or two of sodium cocoyl hydroxyethyl sulfonate and sodium lauroyl sarcosinate.
Further, the nonionic surfactant comprises one or more of cocamide MEA, cocamidomethyl MEA and lauric acid monoglyceride.
Further, the zwitterionic surfactant comprises cocamidopropyl betaine, the conditioning agent comprises guar hydroxypropyl trimethyl ammonium chloride, and the thickener comprises PEG-120 glycerol glucoside trioleate.
Further, the preservative comprises one or more of benzyl alcohol, sodium benzoate and sodium salicylate, and the pH regulator comprises one or two of citric acid and arginine.
Further, the application of the composition in preparing the fluffy shampoo.
In some specific embodiments, the preparation method of the fluffy shampoo composition comprises the following steps (the components are added according to the formula amount):
(1) Adding guar gum hydroxypropyl trimethyl ammonium chloride into cold water under stirring, stirring and dispersing, adding citric acid, and stirring and dissolving uniformly;
(2) Sequentially adding cocamidopropyl betaine, sodium cocoyl hydroxyethyl sulfonate, sodium lauroyl sarcosinate, cocamidomethyl MEA, glycerol laurate and PEG-120 glycerol glucoside trioleate, stirring and heating to 80-85 ℃, uniformly dissolving, preserving heat for 5min, and starting to cool;
(3) Cooling to 45deg.C, sequentially adding benzyl alcohol, sodium salicylate, sodium benzoate, essence, citric acid, polyurethane, semen glycines Indici extract, and disilylated silica, and stirring to obtain shampoo.
Compared with the prior art, the invention has the following beneficial effects:
(1) The fluffy shampoo composition disclosed by the invention belongs to a nonionic composition, has no strong accumulation and sedimentation, and can not adsorb negatively charged dust particles like cations;
(2) The fluffy shampoo composition disclosed by the invention is mild, does not irritate scalp, and is strong in oil control capability;
(3) The fluffy shampoo composition disclosed by the invention can remove and continuously control oil, keep a hairstyle and endow hair with a good fluffy effect.
Detailed Description
It is to be noted that the raw materials used in the present invention are all common commercial products, and the sources thereof are not particularly limited.
The following reagent sources are exemplary illustrations: wild soybean seed extract (Singapore Biotech, lysoft), polyurethane @C1010 Kogyo Polymer (China Co., ltd.), disilylated silica (AEROSIL R972 win the company of specialty Chemie (Shanghai Co., ltd.), polyglycerol-10 oleate from Longsha (China) investment Co., ltd.), kashi white gold activated plump amino acid shampoo (3474636612475) of comparative example 10, plant amino acid calendula oil shampoo (6970197302031) of comparative example 11, and Sapindus mukurossi oil light shampoo (6944750437713) of comparative example 12.
1. Shampoo formula composition
Examples 1 to 3
Table 1 shows the compositions of the shampoo formulations of examples 1-3.
TABLE 1
Note that: in the above table, to 100 represents the sum of the parts by weight of water added and the parts by weight of the other components To be 100 parts.
Comparative examples 1 to 9
Table 2 shows the compositions of the shampoo formulations of comparative examples 1-9.
TABLE 2
Note that: in the above table, to 100 represents the sum of the parts by weight of water added and the parts by weight of the other components To be 100 parts.
Comparative examples 10 to 12
Comparative example 10 is Kashi platinum activated plump amino acid shampoo, comparative example 11 is plant-observing amino acid calendula oil control shampoo, and comparative example 12 is Ziyuan soapberry oil control light shampoo.
The preparation method of the shampoo comprises the following steps:
(1) Adding guar gum hydroxypropyl trimethyl ammonium chloride into cold water under stirring, stirring and dispersing, adding citric acid, and stirring and dissolving uniformly;
(2) Adding the phase B raw materials one by one according to the sequence in tables 1 and 2, stirring and heating to 80-85 ℃, uniformly dissolving, preserving heat for 5min, and starting to cool;
(3) Cooling to 45deg.C, adding phase C materials one by one in the order shown in tables 1 and 2, and stirring to obtain shampoo.
The physicochemical index and the sanitation index of the shampoos prepared in examples 1-3 and comparative examples 1-9 are within the requirements of GB/T29679-2013.
2. Testing
1. Hair volume change before and after shampoo application
The volume of hair is related to the total combined volume of hair fibers on the head rather than the volume of individual fibers. Depending on the style and length of the hair, individual fibers of the hair contact and help support other fibers, thereby maintaining the structure of the hair as a whole. All hair fibers of the hair strand are fixed at one end, not thousands of points on the scalp, respectively, and the hair fibers in the hair strand cannot be regarded as a space-filling structure as the actual hair, but rather the hairs should be mutually supported to generate a volume. The human model volume measurement method is used, which is closer to the human hair and the test is more reliable.
The manikin head used in the volume experiments was purchased from amazon, RYHAIR Store, USA, and was rinsed with a detergent solution containing 20% sodium laureth sulfate and 5% cocamidopropyl betaine prior to the experimental treatment. To reduce entanglement, the hair is rinsed with running water at 38 ℃ with a ventilation brush (vent brush) to clean and clear the hair. The model head was washed twice with 5mL of detergent solution each time, followed by 2.5mL of solution, after which the hair was combed through with a brush. The hair is then allowed to dry overnight and must be combed as flat as possible to give a measured intrinsic volume V (front) The influence of the hair style is minimal.
In the volume experiment, first moistened with 38 ℃ water, then 3mL of shampoo was rubbed into the hair for 30 seconds, then rinsed with 38 ℃ water for more than 60 seconds until the rinse water was clear and transparent. Volume measurements were made after one application and were run in duplicate. The apparent change on the mannequin head was measured using a Zeiss Kontron image analyzer with a Sony XC-77CE miniature camera (with a 60mm Nikon AF Micro-Nikkor lens) attached. The human body model image is taken by camera and is processed by computer to obtain the hair volume V of human body model head (rear) 。
Volume change rate V% = 100% × [ V (rear) -V (front) ]/V (front)
A statistical p-value was used to verify whether the data was reliable, a p-value greater than 0.05 indicated that the data was not statistically significant at the 95% confidence level. Note that the data is the average of at least 5 evaluations.
TABLE 3 Hair volume change after different shampoos
The volume increase reported in table 3 is all statistically significant p <0.05, the magnitude of the volume increase being 7.7-39.5%, indicating that the compositions of the present invention are very effective in significantly increasing hair volume, comparing examples 1-3 to comparative example 1, a significant increase in hair volume was observed with the treatment with the compositions containing fluffy composition (referred to herein as polyurethane, silica disilylate, wild soybean seed extract three components), confirming that the fluffy effect is from a fluffy composition; comparing examples 1-3 with comparative examples 2-8, the result is a fluffy composition in which the polyurethane, silica disilylate, and wild soybean seed extract are used in combination in a certain ratio, and the hair volume increasing effect is most pronounced, and the effect is deteriorated when either or both of them are absent; comparative example 9 the comparative example 9 was slightly less effective than example 1 in that polyglycerol-10 oleate was used instead of the wild soybean seed extract on the basis of example 1, and the volume change rate of the hair of example 1 was almost twice that of comparative example 9; comparing examples 1-3 with comparative examples 10-12, the hair volume increasing effect of the resulting leave-on shampoo compositions of the invention is superior to the commercial products.
2. Oil control human body test evaluation
Equipment and equipment are used: grease strip (CK, germany), meibomeMB560 scalp grease tester (CK, germany), skin pen, rubber band, stopwatch timer, blower.
According to the principle of a grease testing photometer, the adhesive tape strip used in the skin grease testing method, namely the Sebumeter method, is bent into a circular ring to be contacted with the scalp, the transparency of the testing adhesive tape is changed by lipid compounds (grease) in the scalp, and then the testing adhesive tape strip is flattened and then is put into a sliding block of an instrument, and the sliding block is pushed into the instrument. The light transmittance distribution curve on the adhesive tape can be obtained through testing by a photoelectric tube in the instrument, the peak value of the light transmittance distribution curve represents the content of lipid compounds, namely grease, in the scalp, and the annular top end of the adhesive tape is just the part which is in full contact with the scalp during testing.
90 volunteers with vigorous scalp grease secretion are recruited, the age is 20-30 years, the hair is not washed at night before the test, the grease secreted by scalp sebaceous glands is more easily adhered to hair roots in a spreading manner under the condition of comb hair combing, and the volunteers are required to not comb hair as much as possible in a test area. Examples 1-3 and comparative examples 1-12, 15 shampoos total, each of which was randomly drawn out for trial by 6 volunteers.
The volunteers were allowed to sit still in a room at a temperature of 20-22 c and a humidity of 40-65% for 30min before testing, during which time they were unable to drink water and beverages. The test part is exposed, placed in a test state and kept relaxed. The test time points are immediately before, immediately after, 6 hours after and 8 hours after the sample. The test site was taken as a forehead-top 5cm area and a 1cm x 1cm square was drawn on the test area with a skin pen. And (3) during sample application, testing the grease content at the test part for three times respectively for analysis. The same method is adopted by the same person to wash the hair of the volunteer when the hair is washed, and the hair of the volunteer is dried by using medium-grade hot air of a blower.
Because scalp oil secretion is a dynamic continuous process, scalp oil content varies at different times after shampooing. Whereas the evaluation of the oil control efficacy of the washing and care product is actually to determine the temporary sebum level of the scalp, i.e. the amount of oil spilled out of the hair follicle after sebum secretion. If the skin surface is degreased, sebum will be excreted at a rapid rate, taking about 4 hours to recover to a temporary level, entering the sebum secretion phase. If after 3-4 hours after shampooing the sample, only sebum excretion is measured, not sebum secretion. Thus, the oil content measurement time point of the scalp oil control test should be greater than 4 hours.
SPSS19.0 statistical software is adopted for data analysis, T-test or rank sum test is adopted for comparing data distinction before, immediately after, 6 hours after and 8 hours after the sample, and significance analysis is carried out.
TABLE 4 sample forehead skin oil content
Formulation of | Scalp fat content before application (μg/cm) 2 ) (mean.+ -. Standard deviation) |
Example 1 | 450.7±125.1 |
Example 2 | 473.4±108.1 |
Example 3 | 455.6±123.6 |
Comparative example 1 | 453.3±127.6 |
Comparative example 2 | 490.3±129.6 |
Comparative example 3 | 469.3±138.9 |
Comparative example 4 | 468.3±113.7 |
Comparative example 5 | 444.9±126.9 |
Comparative example 6 | 479.6±119.6 |
Comparative example 7 | 465.3±126.4 |
Comparative example 8 | 461.7±130.4 |
Comparative example 9 | 477.9±109.6 |
Comparative example 10 | 459.6±117.5 |
Comparative example 11 | 478.3±123.6 |
The data in table 4 show that there was no significant difference in scalp fat content of the test group as the basis value of the study prior to sampling, which also ensured the scientificity and rigor of the subsequent test.
TABLE 5 forehead skin oil content at various time periods after the sample
The scalp fat content was measured for 90 volunteers over a test period, and the experimental results are shown in table 5. Comparing the scalp fat content data of examples 1-3 and comparative examples 1-12 at 6 and 8 hours after sampling, three components of polyurethane, disilylated silica and wild soybean seed extract in the fluffy composition can be obtained, when the composition is used together, the scalp fat content is lower, any one or two components are absent, or one component is replaced, the scalp fat content is increased, and the effect is better when the composition is arranged in a certain proportion range; at the same time, the scalp fat content of the present invention's leave-on shampoo compositions (i.e., examples 1-3) was lower than that of the commercial products.
3. Human sensory evaluation
150 volunteers with few and thin and soft hair are selected, and the volunteers have the phenomena of flat hair, lack of fluffiness and the like with different degrees at ordinary times, and simultaneously have the symptoms of head oil and dandruff, and the scalp of the patient is subjected to sensory and hair image evaluation before the product is tried out, so that the volunteers are ensured to meet the requirements of the test.
Examples 1-3 and comparative examples 1-12, 15 shampoos total, each of which was randomly drawn from 10 volunteers for trial use.
Volunteers used samples once a day for two weeks. During the trial, the degree of hair collapse and the hair volume were recorded separately, and after two weeks, comprehensive scoring was performed, see table below.
The volunteers scored before and after use, with higher scores being better.
1-2: the hair conditioner is ineffective, the hair fluffiness condition is evaluated after each hair washing, and the hair collapse state and the hair crumbs fluffiness condition are the same as those before use;
2-3: effectively, the hair bulk is evaluated after each hair washing, and the flat state of the hair and the fluffy condition of the dandruff are improved;
3-5: the hair conditioner is powerful, and after each shampooing, the hair bulk is evaluated, the flat state of the hair and the fluffy condition of the dandruff are improved, the hair becomes relatively dense and fluffy, the hair can last for 24 hours, the hair oil is obviously reduced, and the dandruff is also reduced.
The volunteers were subjected to sensory evaluation after using the inventive examples, comparative example products, and the results are shown in table 6.
TABLE 6
As can be seen from the data in Table 6, the number of volunteers experiencing the high sensory effect was higher and the number of sensory nulls was lower in examples 1-3, and comparative examples 2-8, which lacked either or both components, had the polyglycerin-10 oleate instead of the wild soybean seed extract, had the lower number of volunteers experiencing the high sensory effect, and had the higher sensory nulls, and had the better effect at the given ratio.
Finally, it should be noted that the above description is only for illustrating the technical solution of the present invention, and not for limiting the scope of the present invention, and that the simple modification and equivalent substitution of the technical solution of the present invention can be made by those skilled in the art without departing from the spirit and scope of the technical solution of the present invention.
Claims (8)
1. A composition for enhancing the hair-relaxing effect, said composition comprising the following components: polyurethane, silica disilylate, wild soybean seed extract; the weight ratio of polyurethane to disilylated silica to wild soybean seed extract in the composition is 1-5:0.1-5:0.1-3.
2. The composition of claim 1, wherein the polyurethane is present in the composition in an amount of 1 to 5% by weight, the silica disilylate is present in the composition in an amount of 0.1 to 5% by weight, and the wild soybean seed extract is present in the composition in an amount of 0.1 to 3% by weight.
3. The composition according to any one of claims 1-2, wherein the composition further comprises the following components: anionic surfactants, nonionic surfactants, zwitterionic surfactants, conditioning agents, pearling agents, thickeners, preservatives, pH modifiers, fragrances and water.
4. A composition according to claim 3, wherein the anionic surfactant is selected from one or both of sodium cocoyl isethionate, sodium lauroyl sarcosinate.
5. A composition according to claim 3, wherein the nonionic surfactant is selected from one or more of cocamide MEA, cocamidomethyl MEA, lauric acid monoglyceride.
6. A composition according to claim 3, wherein the zwitterionic surfactant is selected from cocamidopropyl betaine, the conditioning agent is selected from guar hydroxypropyl trimonium chloride, and the thickener is selected from PEG-120 glycerol glucoside trioleate.
7. A composition according to claim 3, wherein the preservative is selected from one or more of benzyl alcohol, sodium benzoate, sodium salicylate, and the pH adjuster is selected from one or both of citric acid and arginine.
8. Use of a composition according to any one of claims 1 to 7 for the preparation of a puffy shampoo.
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KR20110092971A (en) * | 2010-02-11 | 2011-08-18 | 웅진코웨이주식회사 | Mixture extracts having anti-oxidation activity and anti-inflammatory activity and cosmetic composition comprising the same |
CN104207950A (en) * | 2013-06-05 | 2014-12-17 | 上海家化联合股份有限公司 | Application of gas silicon dioxide in increasing amount of hair |
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