CN114763422A - Impact-resistant building material and preparation method thereof - Google Patents

Impact-resistant building material and preparation method thereof Download PDF

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Publication number
CN114763422A
CN114763422A CN202110492860.1A CN202110492860A CN114763422A CN 114763422 A CN114763422 A CN 114763422A CN 202110492860 A CN202110492860 A CN 202110492860A CN 114763422 A CN114763422 A CN 114763422A
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building material
impact
resistant building
parts
fiber
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CN114763422B (en
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彭娟
李雯
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Shanghai Weicheng Architectural Planning And Design Co ltd
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Shanghai Weicheng Architectural Planning And Design Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

Abstract

The invention relates to the technical field of buildings, in particular to an impact-resistant building material and a preparation method thereof. The raw materials comprise, by weight, 15-45 parts of natural fibers, 15-50 parts of plastics, 0.5-4 parts of a compatilizer and 10-25 parts of water. The impact-resistant building material provided by the invention has the advantages of high tensile strength, good impact resistance, excellent mechanical property and better water resistance.

Description

Impact-resistant building material and preparation method thereof
Technical Field
The invention relates to the technical field of buildings, in particular to an impact-resistant building material and a preparation method thereof.
Background
The wood fiber resource is a renewable biological resource, the wood-plastic composite material becomes a hot research spot at present, particularly, China is a big agricultural country, and the developed agriculture means that China can generate a large amount of agricultural wastes every year, but the agricultural wastes are poor to recycle, and are treated by adopting a direct incineration mode, so that not only can the environment be polluted, but also the resource is greatly wasted. The plate prepared by utilizing the agricultural wastes is a better recycling mode, but the building material prepared by directly adopting the agricultural wastes has poor mechanical property and durability, and is particularly not suitable for the building material.
In view of the above, the invention particularly provides an impact-resistant building material and a preparation method thereof, which not only can effectively utilize wood resources to prepare the building material, but also the prepared building material has extremely excellent mechanical properties.
Disclosure of Invention
In order to solve the technical problem, the invention provides an impact-resistant building material in a first aspect, which comprises, by weight, 15-45 parts of natural fibers, 15-50 parts of plastics, 0.5-4 parts of a compatilizer and 10-25 parts of water.
Preferably, the natural fiber comprises one or more of corn straw, cotton straw, wheat straw, rice straw, bamboo fiber, poplar fiber, birch fiber and larch fiber.
Preferably, the rice straw is pretreated rice straw, and the weight ratio of the pretreating agent to the rice straw in the pretreatment process is (3-8): (1-2).
Preferably, the plastic comprises one or more of PU, ABS, PP, PVC and PE.
Preferably, the compatibilizer includes at least one of a maleic anhydride graft-type compatibilizer and an acrylic copolymer compatibilizer.
Preferably, the maleic anhydride grafting compatilizer comprises one or more of ABS-g-MAH, PE-g-MAH, PP-g-MAH, SMA, SAN-g-MAH and EVA-g-MAH.
Preferably, the raw materials also comprise 0.5-1.5 parts of coupling agent, 0.5-1 part of lubricant, 5-10 parts of filler and 15-25 parts of glass fiber.
Preferably, the coupling agent includes at least one of a titanate coupling agent and a silane coupling agent.
Preferably, the filler includes at least one of silicates and calcium carbonates.
The second aspect of the present invention provides a method for preparing an impact-resistant building material, comprising the steps of: drying natural fiber, stripping fiber with screw fiber stripper, chopping, sieving, mixing natural fiber, plastic, compatilizer, lubricant, filler and glass fiber, and molding under 8-15 MPa.
Has the advantages that:
1) the impact-resistant building material provided by the invention has the advantages of high tensile strength, good impact resistance and excellent mechanical property.
2) The impact-resistant building material provided by the invention also has good water resistance and phase change performance, and excellent creep resistance and thermodynamic performance.
3) The invention utilizes agricultural wastes to prepare the building material, has low cost, accords with the sustainable development strategy and is suitable for large-scale production.
Detailed Description
In order to solve the technical problems, the first aspect of the invention provides an impact-resistant building material, which comprises, by weight, 15-45 parts of natural fibers, 15-50 parts of plastics, 0.5-4 parts of a compatilizer and 10-25 parts of water.
Natural fiber
The natural fiber is obtained from plants, contains cellulose and lignin, is filled into plastics as a reinforcing phase, and can effectively improve the mechanical property of the plastics.
Preferably, the natural fiber comprises one or more of corn straw, cotton straw, wheat straw, rice straw, bamboo fiber, poplar fiber, birch fiber and larch fiber.
Preferably, the natural fibers include rice straw, bamboo fibers and poplar fibers. The weight ratio of the rice straw, the bamboo fiber and the poplar fiber is (2-7): (3-5): (5-10).
Preferably, the rice straw is pretreated rice straw, and the weight ratio of the pretreating agent to the rice straw in the pretreatment process is (3-8): (1-2).
Preferably, the pretreating agent is a water glass and acrylic emulsion composite pretreating agent. The weight ratio of the water glass to the acrylic emulsion is (3-8): (1-2).
The agricultural wastes are low in price and low in use cost as raw materials, meanwhile, the recycling of the agricultural wastes has important significance on sustainable development, but the agricultural wastes are poor in strength and cannot effectively transmit external force to fibers when used for preparing building materials. The research of the invention finds that the agricultural waste is pretreated, so that the water resistance of the building material is effectively improved, and the building material has extremely excellent phase change performance and mechanical property. It is presumed that the agricultural waste absorbs water glass to increase the rigidity of the agricultural waste, but the water glass and the agricultural waste have high water absorption, so that the water resistance of the produced building board is liable to be poor.
The preparation method of the pretreating agent rice straw comprises the following steps: mixing water glass and acrylic emulsion, adding rice straw, and mixing.
Plastic material
The plastic is an important organic synthetic polymer material, and most plastics are light in weight, stable in chemical property and excellent in performances.
Preferably, the plastic comprises one or more of PU, ABS, PP, PVC and PE.
Preferably, the plastic is PE.
Further preferably, the PE is ultra high molecular weight polyethylene.
Preferably, the ultra-high molecular weight polyethylene has a viscosity average molecular weight of 3.0 x 106-4.0*106
More preferably, the ultra-high molecular weight polyethylene has a viscosity average molecular weight of 4.3 x 106-4.8*106
Compatilizer
The compatibilizer can facilitate the compatibility of the natural fibers with the plastic, thereby helping to improve the performance of the building material.
Preferably, the content of the compatilizer is 0.8-3 parts.
Preferably, the compatibilizer includes at least one of a maleic anhydride graft-type compatibilizer and an acrylic copolymer compatibilizer.
Preferably, the maleic anhydride grafting compatilizer comprises one or more of ABS-g-MAH, PE-g-MAH, PP-g-MAH, SMA, SAN-g-MAH and EVA-g-MAH.
More preferably, the maleic anhydride grafting compatilizer is PE-g-MAH.
Preferably, the PE-g-MAH has a grafting degree of 0.9 to 1.5%.
In order to further improve the performance of the building material, the raw material preferably further comprises 0.5-1.5 parts of coupling agent, 0.5-1 part of lubricant, 5-10 parts of filler and 15-25 parts of glass fiber.
Coupling agent
The coupling agent can promote the filler in the system to be combined with natural fibers, plastics and the like, thereby helping to improve the performance of the building material.
Preferably, the coupling agent includes at least one of a titanate coupling agent and a silane coupling agent.
The silane coupling agent comprises one or two of vinyltriethoxysilane, gamma-aminopropyltriethoxysilane, gamma-glycidoxypropyltrimethoxysilane and gamma- (methacryloyloxy) propyltrimethoxysilane.
Lubricant agent
The lubricant can promote the dispersion of the raw materials in the system, improve the friction force among the raw materials and help the raw materials in the system to be mixed more easily.
Preferably, the lubricant comprises one or more of stearic acid and salts thereof, fatty acid and esters thereof, fatty acid amide, polyethylene wax and paraffin.
Filler material
The filler can help improve the performance of the building material and reduce the cost of the building material.
Preferably, the filler includes at least one of silicates and calcium carbonates.
Preferably, the specific surface area of the silicate filler is 330-380m2/kg。
The invention discovers that the building board prepared by selecting the specific natural fiber has extremely excellent mechanical property and high tensile strength. The speculated that the specific natural fiber has high cellulose and lignin content, the added specific natural fiber has good compatibility with the ultra-high molecular weight polyethylene, the combination of the specific natural fiber and the ultra-high molecular weight polyethylene increases the movement resistance, improves the rigidity of the building material, enhances the deformation resistance, and improves the mechanical property of the building material, particularly when the weight ratio of the rice straw, the bamboo fiber and the poplar fiber is (2-7): (3-5): (5-10) the building material has the best comprehensive performance.
The second aspect of the present invention provides a method for preparing an impact-resistant building material, comprising the steps of: drying natural fiber, stripping fiber with screw fiber stripper, chopping, sieving, mixing natural fiber, plastic, compatilizer, lubricant, filler and glass fiber, and molding under 8-15 MPa.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Examples
Example 1
An impact-resistant building material comprises, by weight, 30 parts of natural fibers, 40 parts of plastics, 1.2 parts of a compatilizer, 0.8 part of a lubricant, 7 parts of a filler, 20 parts of glass fibers and 17 parts of water.
The biological fiber comprises rice straw, bamboo fiber and poplar fiber. The weight ratio of the rice straw, the bamboo fiber and the poplar fiber is 5: 4: 8.
the rice straw is pretreated rice straw, and the weight ratio of the pretreating agent to the rice straw in the pretreatment process is 5: 1.5.
the pretreating agent is a water glass and acrylic emulsion composite pretreating agent. The weight ratio of the water glass to the acrylic emulsion is 5: 1. the acrylic emulsion is purchased from Wuhan, a co-creation science and technology company Limited.
The preparation method of the pretreated rice straw comprises the following steps: mixing water glass and acrylic emulsion, adding rice straw, and mixing.
The plastic is ultra-high molecular weight polyethylene. The viscosity average molecular weight of the ultra-high molecular weight polyethylene is 4.5 x 106. The ultra-high molecular weight polyethylene was purchased from Beijing Accelerator II.
The compatilizer is PE-g-MAH. The grafting ratio of the PE-g-MAH is 1-1.4%, and the compatilizer is purchased from Nanjing Jietansi New Material Co.
The coupling agent is vinyl triethoxysilane (CAS number: 78-08-0).
The lubricant is ethylene bis stearamide.
The filler is silicate. The specific surface area of the silicate filler is 330-380m2The filler is Portland cement, and the filler is purchased from Gansu Kelianshan cement group GmbH and has a brand number of P.O52.5.
A preparation method of an impact-resistant building material comprises the following steps: drying natural fiber, stripping the fiber by a screw fiber stripper, then chopping and sieving, uniformly mixing the natural fiber, plastic, compatilizer, lubricant, filler and glass fiber, and then molding by compression under the pressure of 10 MPa.
Example 2
The specific implementation mode of the impact-resistant building material is the same as that of example 1, except that the weight ratio of the rice straws, the bamboo fibers and the poplar fibers is 7: 5: 10.
example 3
The specific implementation mode of the impact-resistant building material is the same as that in example 1, except that the weight ratio of the water glass to the acrylic emulsion is 3: 1.
example 4
An impact-resistant building material is as defined in example 1, except that the compatibilizer is 4 parts.
Example 5
An impact resistant building material, according to the same embodiment as in example 1, except that the ultra high molecular weight polyethylene has a viscosity average molecular weight of 3.5 x 106. The ultra-high molecular weight polyethylene was purchased from Beijing Accelerator II.
Comparative example 1
The specific implementation mode of the impact-resistant building material is the same as that of example 1, except that the weight ratio of the rice straw, the bamboo fiber and the poplar fiber is 10: 4: 8.
comparative example 2
An impact-resistant building material, the specific embodiment is the same as example 1, except that the pretreating agent is an acrylic emulsion.
Comparative example 3
The specific implementation mode of the impact-resistant building material is the same as that in example 1, except that the pretreating agent is water glass.
Comparative example 4
An impact-resistant building material, the specific embodiment being the same as example 1, except that the compatibilizer is ABS-g-MAH.
Performance testing
1. And (3) testing tensile property: the tensile strength and elongation at break were tested with reference to GB/T1040-70, with a tensile speed of 50 mm/min.
2. And (3) testing the impact resistance: the test was carried out with reference to GB/T1043.1-2008.
3. And (3) testing the water resistance: the sheets prepared in examples and comparative examples were immersed in boiling water at 100 ℃ for 12 hours, dried, and tested for the mass loss rate of (mass before immersion-mass after immersion)/mass before immersion) x 100%.
Table 1 results of performance testing
Figure BDA0003053089500000071
While the invention has been described with reference to the preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention.

Claims (10)

1. An impact-resistant building material is characterized in that the raw materials comprise, by weight, 15-45 parts of natural fibers, 15-50 parts of plastics, 0.5-4 parts of a compatilizer and 10-25 parts of water.
2. The impact-resistant building material of claim 1, wherein the natural fibers comprise one or more of corn stover, cotton stover, wheat straw, rice straw, bamboo fibers, poplar fibers, birch fibers, and larch fibers.
3. The impact-resistant building material of claim 2, wherein the rice straw is pretreated rice straw, and the weight ratio of the pretreating agent to the rice straw in the pretreatment process is (3-8): (1-2).
4. An impact-resistant building material according to claim 1, wherein said plastic comprises one or more of PU, ABS, PP, PVC, PE.
5. The impact-resistant building material of claim 1, wherein the compatibilizer comprises at least one of a maleic anhydride grafted compatibilizer, and an acrylic copolymer compatibilizer.
6. The impact-resistant building material of claim 5, wherein the maleic anhydride grafted compatibilizer comprises one or more of ABS-g-MAH, PE-g-MAH, PP-g-MAH, SMA, SAN-g-MAH, EVA-g-MAH.
7. The impact-resistant building material of claim 1, wherein the raw materials further comprise 0.5-1.5 parts of a coupling agent, 0.5-1 part of a lubricant, 5-10 parts of a filler, and 15-25 parts of glass fiber.
8. The impact-resistant building material of claim 7, wherein the coupling agent comprises at least one of a titanate coupling agent and a silane coupling agent.
9. The impact-resistant building material of claim 7, wherein the filler comprises at least one of silicates and calcium carbonates.
10. A method for preparing an impact-resistant building material according to any one of claims 7 to 9, comprising the steps of: drying natural fiber, stripping fiber with screw fiber stripper, chopping, sieving, mixing natural fiber, plastic, compatilizer, lubricant, filler and glass fiber, and molding under 8-15 MPa.
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Citations (7)

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JPH08116803A (en) * 1994-10-27 1996-05-14 Mitsui Toatsu Chem Inc Flame-retardant mulching material
US20040072924A1 (en) * 2002-10-09 2004-04-15 Crompton Corporation Natural fiber-filled polyolefin composites
CN102977460A (en) * 2012-12-12 2013-03-20 奇瑞汽车股份有限公司 Injecting molding grade natural fiber composite material and preparation method thereof
CN103102586A (en) * 2011-11-15 2013-05-15 上海杰事杰新材料(集团)股份有限公司 Fibrilia/polypropylene wear-resistant wood-plastic composite material and preparation method thereof
WO2014086971A1 (en) * 2012-12-07 2014-06-12 Lothar Rauer Building material comprising bamboo fibers and method for producing such a material
CN109705453A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 Polypropylene base wood-plastic composite material and its preparation method and application
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Patent Citations (7)

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Publication number Priority date Publication date Assignee Title
JPH08116803A (en) * 1994-10-27 1996-05-14 Mitsui Toatsu Chem Inc Flame-retardant mulching material
US20040072924A1 (en) * 2002-10-09 2004-04-15 Crompton Corporation Natural fiber-filled polyolefin composites
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WO2014086971A1 (en) * 2012-12-07 2014-06-12 Lothar Rauer Building material comprising bamboo fibers and method for producing such a material
CN102977460A (en) * 2012-12-12 2013-03-20 奇瑞汽车股份有限公司 Injecting molding grade natural fiber composite material and preparation method thereof
CN109705453A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 Polypropylene base wood-plastic composite material and its preparation method and application
CN111440465A (en) * 2020-04-16 2020-07-24 上海工程技术大学 Organic-inorganic hybrid coating and preparation method thereof

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Title
欧阳慧: "绿色品牌包装创新研究", vol. 1, 吉林大学出版社, pages: 76 *

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