CN114673019A - Method for preparing jacquard-like fabric through anhydrous modification and jacquard-like fabric - Google Patents
Method for preparing jacquard-like fabric through anhydrous modification and jacquard-like fabric Download PDFInfo
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- CN114673019A CN114673019A CN202210395144.6A CN202210395144A CN114673019A CN 114673019 A CN114673019 A CN 114673019A CN 202210395144 A CN202210395144 A CN 202210395144A CN 114673019 A CN114673019 A CN 114673019A
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- 239000004744 fabric Substances 0.000 title claims abstract description 168
- 238000000034 method Methods 0.000 title claims abstract description 53
- 230000004048 modification Effects 0.000 title claims abstract description 31
- 238000012986 modification Methods 0.000 title claims abstract description 31
- 238000004043 dyeing Methods 0.000 claims abstract description 45
- 229920000728 polyester Polymers 0.000 claims abstract description 42
- 239000000986 disperse dye Substances 0.000 claims abstract description 41
- 230000009467 reduction Effects 0.000 claims abstract description 20
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 3
- 239000000975 dye Substances 0.000 claims description 75
- 238000004140 cleaning Methods 0.000 claims description 69
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 51
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 51
- 230000008569 process Effects 0.000 claims description 23
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 14
- 125000002091 cationic group Chemical group 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000004321 preservation Methods 0.000 claims description 10
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 7
- MCSXGCZMEPXKIW-UHFFFAOYSA-N 3-hydroxy-4-[(4-methyl-2-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound Cc1ccc(N=Nc2c(O)c(cc3ccccc23)C(=O)Nc2cccc(c2)[N+]([O-])=O)c(c1)[N+]([O-])=O MCSXGCZMEPXKIW-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 230000000149 penetrating effect Effects 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 7
- 229940005550 sodium alginate Drugs 0.000 claims description 7
- 239000000661 sodium alginate Substances 0.000 claims description 7
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 5
- 239000012943 hotmelt Substances 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 238000009980 pad dyeing Methods 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 229920004934 Dacron® Polymers 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 12
- 238000009941 weaving Methods 0.000 abstract description 11
- 239000004753 textile Substances 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 7
- 229920004933 Terylene® Polymers 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 23
- 239000011159 matrix material Substances 0.000 description 14
- 230000008859 change Effects 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2005—Treatments with alpha, beta, gamma or other rays, e.g. stimulated rays
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/228—Indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/523—Polyesters using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a method for preparing an imitation jacquard fabric through anhydrous modification, which comprises the steps of controlling a modification area through a computer, selectively modifying a polyester fabric by using a laser net making machine, and generating dark patterns on the modified part through subsequent dyeing; or the dyed terylene fabric is selectively modified by a laser net making machine, and the modified part also generates dark patterns. The surface of the polyester fiber has stereoscopic impression by modification treatment, the porosity of the fabric is increased, the weave structure of the similar fabric is changed, and the jacquard-like effect is achieved. Compared with the dyeing depth value of the disperse dye of the untreated part, the dyeing depth value of the modified treated part of the polyester fabric is improved by 67.06 percent to the maximum, and the dyeing depth value of the fabric dyed by the plant indigo non-reduction method is improved by 125.23 percent to the maximum. The laser net making machine treatment belongs to anhydrous modification, is green and safe, and has no noise pollution of weaving processing; compared with the traditional textile mill, the method for preparing the jacquard fabric has the advantages of low cost, convenient processing, flexible batch, rich jacquard-like patterns, and capability of obtaining jacquard-like effects of same-color-system jacquard-like, white-bottom color, continuous gradient and the like.
Description
Technical Field
The invention relates to the technical field of jacquard-like fabrics, in particular to a method for preparing a jacquard-like fabric through anhydrous modification and the jacquard-like fabric.
Background
The jacquard is a concave-convex pattern formed by interlacing warp and weft of a textile fabric, and is a pattern formed by changing warp and weft textures during weaving of the fabric, the yarn count is fine, the requirement on raw materials is extremely high, and yarns with inferior quality cannot be provided. The jacquard fabric has the disadvantages of complex weaving process, high cost and weaving noise pollution. The jacquard is finished by a textile mill, the jacquard fabric is formed by the change of the weave structure during weaving, and the jacquard pattern can not be selected after the fabric is formed.
Laser screen making is a method for preparing a rotary screen pattern plate in the process of printing cloth of printing and dyeing enterprises at present, coating glue on a rotary screen is gasified through computer control, meshes are exposed, and color paste is printed on a fabric through the meshes during printing.
Disclosure of Invention
The invention aims to provide a method for preparing an imitation jacquard fabric through anhydrous modification and the imitation jacquard fabric, which solve the problems of complex process, high cost, weaving noise pollution and the like of the traditional weaving method for preparing the jacquard fabric.
On one hand, the invention provides a method for preparing an imitation jacquard fabric through anhydrous modification, which comprises the following steps:
according to a graphic file in a computer, carrying out 1-time scanning modification on the polyester fabric by a laser net making machine, and then dyeing the polyester fabric;
or dyeing the polyester fabric firstly, and then carrying out 1-time scanning modification on the polyester fabric by a laser net making machine according to a graphic file in a computer;
wherein, the power of the laser net making machine is 5-14W, the scanning speed is 100-150mm/s, and the scanning precision is 0.2-0.4 mm.
In some embodiments, the dyeing process is one of a disperse dye high temperature and high pressure dip dyeing process, a plant indigo high temperature and high pressure dip dyeing process, a cationic dye dip dyeing process, or a disperse dye pad dyeing hot melt dyeing process.
In some embodiments, the disperse dye high-temperature high-pressure dip dyeing process comprises the following steps:
preparing a dye solution, wherein the dye solution comprises 1% o.w.f of disperse dye and acetic acid, the acetic acid adjusts the pH value of the dye solution to 4.5-5, and the bath ratio is 1: 20;
heating the dye solution to 130 ℃, carrying out heat preservation dyeing for 30min, and then cooling to 75 ℃;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
In some embodiments, the disperse dye hot melt dyeing process comprises the steps of:
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-dipping;
drying at the temperature of 80 ℃ for 3 min;
baking at 170 ℃ for 3 min;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
In some embodiments, the disperse dye is one of a low temperature disperse dye comprising disperse blue 56, disperse red 60, and disperse yellow 211, or a high temperature disperse dye comprising disperse navy SFN, disperse deep red SFN, and disperse yellow-brown SFN.
In some embodiments, the plant indigo high-temperature high-pressure dip dyeing process comprises the following steps:
preparing a dye solution, wherein the dye solution comprises 0.5-2% o.w.f of plant indigo and acetic acid, the pH value of the dye solution is adjusted to 4.5-5 by the acetic acid, and the bath ratio is 1: 20;
heating the dye liquor to 120 ℃, carrying out heat preservation and dyeing for 30min, and then cooling to 75 ℃;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
In some embodiments, the cationic dye dip dyeing process comprises the steps of:
preparing a dye solution, wherein the dye solution comprises 2.5% o.w.f of cationic dye blue X-B, 2.5% o.w.f of acetic acid, 1% o.w.f of sodium acetate and 0.5% o.w.f of a leveling agent, and the bath ratio is 1: 50;
heating the dye solution to 98 ℃, and carrying out heat preservation and dyeing for 30 min;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
In some embodiments, the method comprises the following steps:
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-padding;
drying at the temperature of 80 ℃ for 3 min;
then according to a graphic file in a computer, a laser net making machine is used for carrying out 1-time scanning modification on the dyed and dried polyester fabric, wherein the power of the laser net making machine is 5-14W, the scanning speed is 100-150mm/s, and the scanning precision is 0.2-0.4 mm;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
On the other hand, the invention provides the jacquard-like fabric prepared by the method through anhydrous modification.
The invention has the beneficial effects that:
1. compared with the polyester fabric dyeing depth value of the untreated part, the dyeing depth value of the polyester fabric treated by the laser net making machine is improved by 67.06% to the maximum extent, and the dyeing depth value of the fabric dyed by the plant indigo non-reduction method is improved by 125.23%. The laser net making machine treatment belongs to anhydrous modification, is green and safe, and has no weaving noise pollution when jacquard fabrics are processed in a textile mill.
2. Controlling the modification area through a computer, selectively modifying the polyester fabric by using a laser net making machine, and generating dark patterns on the modified part through subsequent dyeing; or the dyed terylene fabric is selectively modified by a laser net making machine, and the modified part also generates dark patterns. The surface of the polyester fiber has stereoscopic impression due to the modification treatment of the laser net making machine, the porosity of the fabric is increased, the weave structure of the similar fabric is changed, and the jacquard-like effect of the same color system is achieved.
3. The modified area is controlled by a computer, the traditional baking is replaced by the treatment of a laser net making machine, so that the disperse dye in the modified area on the fabric is subjected to color fixing, the disperse dye in the untreated area is not fixed with the fiber and is washed away in the subsequent reduction cleaning, and the jacquard-like effect of the locally-fixed white-base pattern is achieved.
4. The modified area is controlled by a computer, the polyester fabric is selectively modified by a laser net making machine, the cationic dye can dye modified polyester fibers, and the cationic dye of the unmodified part cannot dye, so that the jacquard-like effect of white-bottom flower color is generated.
5. The laser screen making equipment is the existing rotary screen making equipment of a printing and dyeing mill, has multiple functions, and does not need to add extra special equipment; compared with the traditional jacquard fabric prepared by textile factories, the cost is much lower, the processing is convenient, the batch is flexible, the jacquard-like pattern is more abundant than the traditional jacquard, and especially, the continuous gradual change jacquard pattern effect which can not be achieved by the traditional weaving jacquard can be realized by controlling the processing process parameters. So that the printing and dyeing mill can also produce the jacquard-like fabric.
Drawings
FIG. 1 is a schematic representation of a jacquard-like fabric prepared in example 1;
FIG. 2 is a schematic representation of a jacquard-like fabric prepared in example 2;
FIG. 3 is a schematic representation of a jacquard-like fabric prepared in example 3;
FIG. 4 is a schematic representation of a jacquard-like fabric prepared in example 7;
FIG. 5 is a schematic representation of a jacquard-like fabric prepared in example 8;
FIG. 6 is a schematic representation of a jacquard-like fabric prepared in example 9;
FIG. 7 is a schematic representation of a jacquard-like fabric prepared in example 40;
FIG. 8 is a schematic representation of a jacquard-like fabric prepared in example 16;
FIG. 9 is a schematic representation of a jacquard-like fabric prepared in example 20;
FIG. 10 is a schematic representation of a jacquard-like fabric prepared in example 24;
FIG. 11 is a schematic representation of a jacquard-like fabric prepared in example 28;
FIG. 12 is a schematic representation of a jacquard-like fabric produced in example 32;
FIG. 13 is a schematic representation of a jacquard-like fabric produced in example 36;
FIG. 14 is a schematic representation of a jacquard-like fabric produced in example 41;
FIG. 15 is a schematic representation of a jacquard fabric produced in example 42;
FIG. 16 is a schematic representation of a jacquard-like fabric produced in example 43;
FIG. 17 is a histogram of K/S values at the wavelength of maximum absorption for the jacquard-like fabrics prepared in examples 1-3;
FIG. 18 is a histogram of K/S values at the wavelength of maximum absorption for the jacquard-like fabrics prepared in examples 4-6;
FIG. 19 is a histogram of K/S values at the maximum absorption wavelength for the jacquard-like fabrics prepared in examples 7-9;
FIG. 20 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 10-12;
FIG. 21 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 13-15;
FIG. 22 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 16-19;
FIG. 23 is a histogram of K/S values at the wavelength of maximum absorption for the jacquard fabrics prepared in examples 20-23;
FIG. 24 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 24-27;
FIG. 25 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 28-31;
FIG. 26 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 32-35;
FIG. 27 is a bar graph of K/S values at the wavelengths of maximum absorption for the jacquard fabrics prepared in examples 36-39;
FIG. 28 is a surface structure of an unmodified polyester fabric;
FIG. 29 is the surface structure of a polyester fabric modified by a 12W laser net making machine;
FIG. 30 shows the surface structure of the modified polyester fabric of the 14W laser net-making machine.
Detailed Description
The present invention will be further described with reference to the following examples. The following examples are only for illustrating the performance of the present invention more clearly and are not limited to the following examples.
Examples 1 to 6:
a method for preparing a jacquard-like fabric through anhydrous modification comprises the following steps:
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan undyed polyester fabrics, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 12W, the scanning speed is 150mm/s, and the scanning precision is 0.2 mm;
preparing a dye solution, wherein the dye solution comprises 1% o.w.f of disperse dye and acetic acid, the acetic acid adjusts the pH value of the dye solution to 4.5-5, and the bath ratio is 1: 20;
heating the dye solution to 130 ℃, performing heat preservation dyeing on undyed polyester fabrics for 30min, and then cooling to 75 ℃;
reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
and (5) drying.
Examples 1-6 differ in that: the disperse dyes selected are different, namely disperse blue 56, disperse red 60, disperse yellow 211, disperse azure SFN, disperse deep red SFN and disperse yellow-brown SFN.
The jacquard-like fabrics prepared in examples 1 to 3 are shown in fig. 1 to 3, respectively.
Examples 7 to 12:
a method for preparing a jacquard-like fabric through anhydrous modification comprises the following steps:
preparing a dye solution, wherein the dye solution comprises 1% o.w.f of disperse dye and acetic acid, the acetic acid adjusts the pH value of the dye solution to 4.5-5, and the bath ratio is 1: 20;
heating the dye liquor to 130 ℃, carrying out heat preservation dyeing on the polyester fabric for 30min, and then cooling to 75 ℃;
reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
drying;
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
and acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan the dyed polyester fabric, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 5W, the scanning speed is 150mm/s, and the scanning precision is 0.2 mm.
Examples 7 to 12 differ in that: the disperse dyes selected are different, namely disperse blue 56, disperse red 60, disperse yellow 211, disperse azure SFN, disperse deep red SFN and disperse yellow-brown SFN.
The jacquard-like fabrics prepared in examples 7 to 9 are shown in fig. 4 to 6, respectively.
Examples 13 to 15:
a method for preparing a jacquard-like fabric through anhydrous modification comprises the following steps:
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan undyed polyester fabrics, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 8W, the scanning speed is 100mm/s, and the scanning precision is 0.3 mm;
preparing a dye solution, wherein the dye solution comprises 0.5-2% o.w.f of plant indigo and acetic acid, the acetic acid adjusts the pH value of the dye solution to 4.5-5, and the bath ratio is 1: 20;
heating the dye solution to 120 ℃, performing heat preservation dyeing on undyed polyester fabrics for 30min, and then cooling to 75 ℃;
reducing and cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
and (5) drying.
Examples 13 to 15 differ in that: the indigo was used at different concentrations, 0.5o.w.f, 1o.w.f and 1.5 o.w.f.
Examples 16 to 27:
a method for preparing a jacquard-like fabric through anhydrous modification comprises the following steps:
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan undyed polyester fabrics, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 10W, the scanning speed is 150mm/s, and the scanning precision is 0.3 mm;
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-dipping;
drying at the temperature of 80 ℃ for 3 min;
baking at the temperature of 170 ℃ for 3 min;
reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
and (5) drying.
Examples 16 to 19 differ in that: the dispersed azure SFN is selected, and the concentrations of the used dispersed azure SFN are respectively 5g/L, 10g/L, 20g/L and 30 g/L.
The jacquard-like fabrics prepared in example 16 are shown in fig. 8.
Examples 20 to 23 differ in that: the concentration of the disperse deep red SFN is 5g/L, 10g/L, 20g/L and 30g/L respectively.
The jacquard-like fabrics prepared in example 20 are shown in fig. 9.
Examples 24 to 27 differ in that: the concentration of the disperse yellow-brown SFN is 5g/L, 10g/L, 20g/L and 30g/L respectively.
The jacquard-like fabrics prepared in example 24 are shown in fig. 10.
Examples 28 to 39:
a method for preparing a jacquard-like fabric through anhydrous modification comprises the following steps:
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-dipping;
drying at the temperature of 80 ℃ for 3 min;
baking at 170 ℃ for 3 min;
reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
drying;
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
and acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan the dyed polyester fabric, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 14W, the scanning speed is 100mm/s, and the scanning precision is 0.2 mm.
Examples 28 to 31 differ in that: the dispersed azure SFN is selected, and the concentrations of the used dispersed azure SFN are respectively 5g/L, 10g/L, 20g/L and 30 g/L.
The jacquard-like fabrics prepared in example 28 are shown in fig. 11.
Examples 32-35 differ in that: the concentration of the disperse deep red SFN is 5g/L, 10g/L, 20g/L and 30g/L respectively.
The jacquard-like fabrics prepared in example 32 are shown in fig. 12.
Examples 36 to 39 differ in that: the concentration of the disperse yellow-brown SFN is 5g/L, 10g/L, 20g/L and 30g/L respectively.
The jacquard-like fabrics prepared in example 36 are shown in fig. 13.
Example 40:
a method for preparing an imitation jacquard fabric through anhydrous modification comprises the following steps:
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan undyed polyester fabrics, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 10W, the scanning speed is 150mm/s, and the scanning precision is 0.3 mm;
preparing a dye solution, wherein the dye solution comprises 2.5% o.w.f of cationic dye blue X-B, 2.5% o.w.f of acetic acid, 1% o.w.f of sodium acetate and 0.5% o.w.f of leveling agent, and the bath ratio is 1: 50;
heating the dye solution to 98 ℃, and dyeing the undyed polyester fabric for 30min in a heat preservation way;
reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
and (5) drying.
The cationic dye can dye modified polyester fibers, and the non-modified cationic dye can not dye, so that the jacquard-like effect of white-bottom pattern is generated.
The jacquard-like fabrics prepared in example 40 are shown in fig. 7.
Examples 41 to 43:
a method for preparing an imitation jacquard fabric through anhydrous modification comprises the following steps:
padding a dye solution, wherein the dye solution comprises 5g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-dipping;
drying at the temperature of 80 ℃ for 3 min;
obtaining a target pattern for processing by the graphic processing software by using the graphic input equipment, and obtaining dot matrix information of the target pattern;
and acquiring dot matrix information of a target pattern by using a computer control system, further controlling a laser net making machine to scan the dyed (not baked) polyester fabric, and forming a complete pattern through 1-time scanning, wherein the power of the laser net making machine is 14W, the scanning speed is 100mm/s, and the scanning precision is 0.2 mm.
Reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30;
and (5) drying.
At the moment, the scanning treatment of the laser net making machine replaces the traditional baking, so that the dye in the modified treatment area on the fabric is subjected to color fixing, the dye in the untreated area is not fixed with the fiber and is washed away in subsequent reduction washing, and the jacquard-like effect of the locally-fixed white background color is achieved.
The differences between the embodiments 41 to 43 are: the disperse dyes selected are different and respectively are disperse navy blue SFN, disperse dark red SFN and disperse yellow brown SFN.
The jacquard-like fabrics prepared in examples 41 to 43 are shown in fig. 14 to 16, respectively.
The test method comprises the following steps:
testing the K/S value of the sample under the maximum absorption wavelength on a 600-type color measuring and matching instrument under the test condition of D65Light source, 10 ° viewing angle, cloth sample folded 4 layers.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 1-3 are shown in FIG. 17.
From FIG. 17, it can be seen that the K/S values of the low temperature disperse dyes disperse blue 56, disperse red 60, and disperse yellow 211 dyed fabrics were increased by 53.34%, 56.56%, and 39.46%, respectively, relative to the K/S value of the unmodified fabric, after the pretreatment by the laser screen machine.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 4-6 are shown in FIG. 18.
As can be seen from FIG. 18, the K/S values of the high temperature disperse dye disperse navy blue SFN, disperse deep red SFN and disperse yellow-brown SFN dyed fabrics are respectively improved by 67.06%, 54.39% and 51.83% compared with the K/S value of the unmodified fabrics after the pretreatment of the laser net making machine.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 7-9 are shown in FIG. 19.
From FIG. 19, it can be seen that the K/S values of the low-temperature disperse dye disperse blue 56, disperse red 60 and disperse yellow 211 dyed fabrics were respectively improved by 14.58%, 7.00% and 16.76% compared with the K/S values of the unmodified fabrics after the post-treatment of the laser net-making machine.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 10-12 are shown in FIG. 20.
From FIG. 20, it can be seen that the K/S values of the high temperature disperse dye disperse navy blue, disperse dark red and disperse yellow-brown dyed fabrics after the post-treatment by the laser net-making machine are respectively increased by 44.33%, 21.41% and 24.86% compared with the K/S values of the unmodified fabrics.
After the high-temperature disperse dye dyed fabric is subjected to post-treatment by a laser screen machine, the K/S value is improved more, which is probably because the sublimation fastness of the low-temperature disperse dye is poor, and the dye on the surface of the fabric is sublimated due to the post-treatment.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 13-15 are shown in FIG. 21.
Under the same concentration of the plant indigo dye, the K/S value of the subsequent plant indigo dyed fabric is increased relative to the K/S value of the unmodified fabric through the pretreatment of the laser net making machine, the K/S value of the subsequent dyed fabric is increased by 30.17-125.23% through the pretreatment of the laser net making machine according to different usage amounts of the plant indigo, and the increase of the color depth K/S value of the light color fabric is particularly obvious.
The data for the K/S values at the maximum absorption wavelengths of the jacquard-like fabrics prepared in examples 16-19 are shown in FIG. 22.
After the pretreatment of a laser net making machine, the K/S value of the subsequent 10g/L dispersed navy blue SFN dyed fabric reaches 12.48, which is close to the color depth of the unmodified fabric dyed by 30g/L dye.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 20-23 are shown in FIG. 23.
After the pretreatment of a laser screen making machine, the K/S value of the subsequent 20g/L disperse dark red SFN dyed fabric reaches 22.69, and the color depth of the unmodified fabric dyed by the dye exceeds 30 g/L.
The data for the K/S values at the maximum absorption wavelengths of the jacquard-like fabrics prepared in examples 24-27 are shown in FIG. 24.
After the pretreatment of the laser net making machine, the K/S value of the subsequent 20g/L disperse yellow brown SFN dyed fabric reaches 21.06, which is close to the color depth of the unmodified fabric dyed by 30g/L dye.
The data in fig. 22-24 show that the amount of disperse dye required by the polyester fabric pretreated by the laser net making machine is approximately saved by 33%.
The data for the K/S values at the wavelengths of maximum absorption of the jacquard-like fabrics prepared in examples 28-31 are shown in FIG. 25.
For 20g/L disperse navy blue SFN dyed fabric, after the fabric is subjected to post-treatment by a laser net making machine, the K/S value of the dyed fabric reaches 11.44, and is close to the color depth of the unmodified fabric dyed by 30g/L dye.
The data for the K/S values at the wavelengths of maximum absorption for the jacquard-like fabrics prepared in examples 32-35 are shown in FIG. 26.
After the 20g/L disperse dark red SFN dyed fabric is subjected to post-treatment by a laser net making machine, the K/S value of the dyed fabric reaches 18.60, and the color depth of the unmodified fabric dyed by 30g/L dye is approximate.
The data for the K/S values at the wavelengths of maximum absorption for the jacquard-like fabrics prepared in examples 36-39 are shown in FIG. 27.
After the 20g/L disperse yellow-brown SFN dyed fabric is subjected to post-treatment by a laser net making machine, the K/S value of the dyed fabric reaches 18.16, and the color depth of the fabric dyed with unmodified dye approaches to 30 g/L.
From the data in fig. 25-27, it can be seen that the amount of disperse dye required by the polyester fabric after the post-treatment by the laser net-making machine is approximately saved by 33.33%.
The unmodified polyester fabric, the polyester fabric modified by the 12W laser net making machine in example 1, and the polyester fabric modified by the 14W laser net making machine in example 28 were observed under a microscope, and the surface structures thereof are shown in fig. 28 to 30;
wherein, fig. 28 is the surface structure of the unmodified fabric, fig. 29 is the polyester fabric modified by the 12W laser net making machine, and fig. 30 is the polyester fabric modified by the 14W laser net making machine, another inventive point of the present application lies in that, after the modification treatment by the laser net making machine, the polyester fiber surface has stereoscopic impression, and the porosity of the fabric is increased, the weave structure of the similar fabric is changed, so that the jacquard-like effect can be achieved.
The embodiment provided by the invention utilizes the existing laser net making equipment for processing the rotary screen pattern plate in a factory in a printing and dyeing enterprise, and the laser net making equipment is used for general polyester textile fabrics, has multiple purposes and does not need to add extra special equipment. The laser net making machine treatment belongs to anhydrous modification, is green and safe, and has no noise pollution of weaving processing. The modified area is controlled by the computer, the white fabric, the printed fabric and the dyed fabric are modified in an anhydrous manner, the surface morphology and the color effect different from the non-modified part are generated by adjusting the modification parameters, the jacquard-like effect can be generated on the fabric, the pattern can be selectively modified by the digital file control of the computer, the pattern is more flexible and variable, the jacquard-like pattern is rich, the jacquard-like effects such as jacquard-like patterns of the same color system and white-bottom patterns, continuous gradient color and the like can be obtained, the pattern can be conveniently selected after weaving and forming, the processing is convenient, the process is simple, the batch is flexible, the method is suitable for the modern individual requirements of small batches and multiple varieties, the cost is lower than that of jacquard-like fabrics prepared by the traditional textile mill, and the printing and dyeing mill can also produce the jacquard-like fabric which can be prepared by the traditional textile mill.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various changes and modifications can be made without departing from the inventive concept of the present invention, and these should also be construed as being within the scope of the present invention.
Claims (9)
1. A method for preparing a jacquard-like fabric through anhydrous modification is characterized by comprising the following steps:
according to a graphic file in a computer, carrying out 1-time scanning modification on the polyester fabric by using a laser net making machine, and then dyeing the polyester fabric;
or dyeing the polyester fabric firstly, and then carrying out 1-time scanning modification on the polyester fabric by a laser net making machine according to a graphic file in a computer;
wherein, the power of the laser net making machine is 5-14W, the scanning speed is 100-150mm/s, and the scanning precision is 0.2-0.4 mm.
2. The method according to claim 1, wherein the dyeing process is one of a disperse dye high-temperature high-pressure dip dyeing process, a plant indigo high-temperature high-pressure dip dyeing process, a cationic dye dip dyeing process or a disperse dye pad dyeing hot melt dyeing process.
3. The method as claimed in claim 2, wherein the disperse dye high-temperature high-pressure dip dyeing process comprises the following steps:
preparing a dye solution, wherein the dye solution comprises 1% o.w.f of disperse dye and acetic acid, the acetic acid adjusts the pH value of the dye solution to 4.5-5, and the bath ratio is 1: 20;
heating the dye solution to 130 ℃, carrying out heat preservation dyeing for 30min, and then cooling to 75 ℃;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
4. The method according to claim 2, wherein the disperse dye pad dyeing hot melt dyeing process comprises the steps of:
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-dipping;
drying at the temperature of 80 ℃ for 3 min;
baking at 170 ℃ for 3 min;
and (3) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
5. The method of claim 3 or 4, wherein the disperse dye is one of a low temperature disperse dye or a high temperature disperse dye, the low temperature disperse dye comprises disperse blue 56, disperse red 60, and disperse yellow 211, and the high temperature disperse dye comprises disperse navy SFN, disperse deep red SFN, and disperse yellow-brown SFN.
6. The method as claimed in claim 2, wherein the plant indigo high-temperature high-pressure dip dyeing process comprises the following steps:
preparing a dye solution, wherein the dye solution comprises 0.5-2% o.w.f of plant indigo and acetic acid, the pH value of the dye solution is adjusted to 4.5-5 by the acetic acid, and the bath ratio is 1: 20;
heating the dye liquor to 120 ℃, carrying out heat preservation and dyeing for 30min, and then cooling to 75 ℃;
and (3) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
7. The method as claimed in claim 2, wherein the cationic dye dip dyeing process comprises the steps of:
preparing a dye solution, wherein the dye solution comprises 2.5% o.w.f of cationic dye blue X-B, 2.5% o.w.f of acetic acid, 1% o.w.f of sodium acetate and 0.5% o.w.f of a leveling agent, and the bath ratio is 1: 50;
heating the dye solution to 98 ℃, and carrying out heat preservation and dyeing for 30 min;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 75 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
8. The method of claim 1, comprising the steps of:
padding a dye solution, wherein the dye solution comprises 5-30g/L of disperse dye, 2g/L of sodium alginate and 2g/L of penetrating agent JFC, and the padding mode is three-padding and three-padding;
drying at the temperature of 80 ℃ for 3 min;
then, according to a graphic file in a computer, a laser net making machine is used for carrying out scanning modification on the dacron for 1 time, wherein the power of the laser net making machine is 5-14W, the scanning speed is 100-150mm/s, and the scanning precision is 0.2-0.4 mm;
and (2) reduction cleaning, wherein the cleaning solution comprises 2g/L sodium hydrosulfite and 2g/L NaOH, the temperature of the cleaning solution is 80 ℃, the cleaning time is 10min, and the bath ratio is 1: 30.
9. The jacquard-like fabric produced by the method according to any one of claims 1 to 8.
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