CN114409376B - Preparation method of high-saturation amorphous photonic crystal structure colored glaze - Google Patents
Preparation method of high-saturation amorphous photonic crystal structure colored glaze Download PDFInfo
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- 239000004038 photonic crystal Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 15
- 239000010433 feldspar Substances 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010453 quartz Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000498 ball milling Methods 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 12
- 239000002893 slag Substances 0.000 claims abstract description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000032683 aging Effects 0.000 claims abstract description 6
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 6
- 239000004927 clay Substances 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 230000001590 oxidative effect Effects 0.000 claims abstract description 6
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 6
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 6
- 239000000454 talc Substances 0.000 claims abstract description 6
- 235000012222 talc Nutrition 0.000 claims abstract description 6
- 229910052623 talc Inorganic materials 0.000 claims abstract description 6
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 6
- 229940078499 tricalcium phosphate Drugs 0.000 claims abstract description 6
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019731 tricalcium phosphate Nutrition 0.000 claims abstract description 6
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 5
- 238000010304 firing Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 238000003825 pressing Methods 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000015895 biscuits Nutrition 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 13
- 238000005034 decoration Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 230000031700 light absorption Effects 0.000 description 6
- 239000000049 pigment Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910001428 transition metal ion Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
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Abstract
The invention discloses a preparation method of a colored glaze with a high-saturation amorphous photonic crystal structure, which comprises the steps of mixing clay with high iron content, feldspar, quartz and kaolin; or taking black tailings or slag, feldspar, quartz and kaolin for mixing; ball-milling the mixed blank, and drying, grinding, granulating, ageing, tabletting and the like to obtain a black blank; mixing feldspar, quartz, calcite, talc, kaolin, tricalcium phosphate and boron frit, sodium carboxymethylcellulose and sodium tripolyphosphate to obtain a mixed glaze; uniformly applying the mixed glaze material on the prepared blank after ball milling to obtain a glazed blank; and drying the glazing blank, and then putting the dried glazing blank into an electric furnace to be fired in an oxidizing atmosphere. The invention provides a new method for the application of the amorphous photonic crystal structure colored glaze in the traditional ceramic decoration, and can open up a new way for the efficient utilization of low-quality raw materials in ceramic blanks.
Description
Technical Field
The invention relates to the technical field of ceramic material manufacturing, in particular to a preparation method of a colored glaze with a high-saturation amorphous photonic crystal structure.
Background
According to different sources of the structural colors, the structural colored glaze can be divided into the amorphous photonic crystal structural colored glaze and the structural colored glaze formed by Rayleigh scattering and Mie scattering. As the amorphous photonic crystal structure has the characteristics of isotropic photonic band gap, non-iridescence effect, light localization and the like, the ceramic glaze is soft and bright and has a color rendering effect which is not changed along with the angle, and the ceramic glaze has a wider application space in the field of ceramic decoration (material report, 2017,31 (1): 43-55). However, in the amorphous photonic crystal structure colored glaze, the color saturation of the structural color formed by Bragg scattering is reduced under the influence of incoherent scattering (Advanced Materials,2018,30 (28): 1706654), the color visibility is not strong, and the wide application of the amorphous photonic crystal structure colored glaze in the traditional ceramic industry is limited.
In the field of new materials, researchers select nanoscale carbon black, magnetite, black TiO 2 Polypyrrole and the like absorb incoherent scattered light, and colored pigments and films of amorphous photonic crystal structure having high color development have been successfully prepared (Chemical Communications,2018,54 (39): 4905-4914 acs Applied Materials&Interfaces,2016,8 (25): 16289-16295). In addition, takeoka et al can also make amorphous photonic crystal structure color films and colorants exhibit latent structural color effects by using a black background instead of a black light absorber (ACS Applied Nano Materials,2020,3 (7): 7047-7056). For the amorphous photonic crystal structure colored glaze, if a high-temperature resistant black pigment is introduced into the formula of the porcelain glaze, the particle size of the pigment, the dispersity, the thermal stability and the distribution rule of pigment crystal grains in the phase-splitting glaze after firing are considered, the influence of the pigment on the amorphous photonic crystal structure color is also considered, and the experimental process is too complicated. Based on this, by using the method of absorbing stray light by the black background, a black light absorption layer can be formed at the bottom of the glaze layer, and the purpose of improving the color saturation of the colored glaze of the amorphous photonic crystal structure is achieved.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a preparation method of a high-saturation amorphous photonic crystal structure colored glaze, which takes clay or black tailings and slag with high iron content as raw materials of a ceramic blank body, and forms a black light absorption layer at the bottom of the amorphous photonic crystal structure colored glaze by diffusion of transition metal ions in the blank body in the glaze firing process. The black light absorption layer can absorb incoherent scattered light in the glaze layer, so that the aim of improving the color glaze saturation of the amorphous photonic crystal structure is fulfilled. The invention can provide a new method for the application of the amorphous photonic crystal structure colored glaze in the traditional ceramic decoration, and can open up a new way for the efficient utilization of low-quality raw materials in ceramic blanks.
In order to achieve the purpose, the invention adopts the technical scheme that:
a preparation method of high-saturation amorphous photonic crystal structure colored glaze comprises the following steps;
the method comprises the following steps: mixing 10-85% of clay (such as black crucible soil, purple golden soil, etc.), 2-20% of feldspar, 8-20% of quartz and 5-50% of kaolin according to mass ratio;
or taking 5-50% of black tailings, slag (such as iron tailings, manganese tailings, slag and the like), 5-20% of feldspar, 5-15% of quartz and 40-60% of kaolin according to the mass ratio for mixing;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank;
step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talc and 4% of kaolin are taken in mass ratio, and 2% of tricalcium phosphate (Ca) in total mass is added 3 (PO 4 ) 2 ) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and cooling the sample to prepare the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And the firing temperature of the fifth step is 1200-1350 ℃, and the temperature is kept for 10-50min.
At high temperature, the transition metal elements in the blank exist in an ion state, and due to the action of concentration gradient, the ions gradually diffuse to the bottom layer of the structural colored glaze and form a black light absorption layer. And after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
The invention has the beneficial effects that:
according to the invention, the clay or black metal tailings and slag with high iron content are used for preparing the ceramic body, and the diffusion of transition metal ions is utilized to form the black light absorption layer at the bottom of the glaze layer, so that the color saturation of the colored glaze with the amorphous photonic crystal structure is effectively improved, and the application range of the structural color in the traditional ceramic decoration is widened. In addition, the application of the low-quality raw materials greatly reduces the production cost of the product and has good environmental and social benefits. Therefore, the invention not only improves the innovation of ceramic enterprises in the preparation of the amorphous photonic crystal structure colored glaze, but also provides an effective solution for the energy-saving and environment-friendly production of ceramic industries.
Drawings
FIG. 1 is an optical micrograph of a cross section of a sample in a black crucible porcelain body.
FIG. 2 is a reflection spectrum of the surface of the colored glaze with amorphous photonic crystal structure in black crucible clay enamel.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1:
the method comprises the following steps: taking 85% of black crucible soil, 2% of feldspar, 8% of quartz and 5% of kaolin according to the mass ratio, and mixing;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added 3 (PO 4 ) 2 ) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and cooling the sample to prepare the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And the firing temperature in the fifth step is 1350 ℃, and the temperature is kept for 10min.
As shown in figure 1, the transition metal element in the matrix diffuses to the bottom of the glaze layer and forms a black light absorption layer with a certain thickness.
As shown in fig. 2, the formation of the black light absorbing layer effectively improves the color saturation of the amorphous photonic crystal structure colored glaze.
Example 2:
the method comprises the following steps: taking 50% of iron tailings, 5% of feldspar, 5% of quartz and 40% of kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin are taken according to the mass ratio, and tricalcium phosphate (Ca) with the total mass of 2% is added 3 (PO 4 ) 2 ) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and after the sample is cooled, preparing the amorphous photonic crystal structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And the firing temperature in the fifth step is 1200 ℃, and the temperature is kept for 50min.
Example 3:
the method comprises the following steps: taking 5% of manganese slag, 20% of feldspar, 15% of quartz and 60% of kaolin according to the mass ratio;
step two: grinding the mixed blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank.
Step three: taking 57% of feldspar, 16% of quartz and 12% of the formula according to the mass ratioLitholysis, 11% of talc, 4% of kaolin, and addition of tricalcium phosphate (Ca) in an amount of 2% by mass of the total 3 (PO 4 ) 2 ) Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and cooling the sample to prepare the amorphous photon structure colored glaze with high saturation.
In the second step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And in the second step, pressing the aged blank powder under the pressure of 25MPa by using a tablet press, taking out, biscuiting to 900 ℃, and preserving heat for 120min.
In the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the materials to the balls to the water is 1.
And the firing temperature in the fifth step is 1300 ℃, and the temperature is kept for 30min.
Claims (5)
1. A preparation method of a colored glaze with a high-saturation amorphous photonic crystal structure is characterized by comprising the following steps;
the method comprises the following steps: taking 10-85% of clay with high iron content, 2-20% of feldspar, 8-20% of quartz and 5-50% of kaolin according to the mass ratio for mixing;
or taking 5-50% of black tailings or slag, 5-20% of feldspar, 5-15% of quartz and 40-60% of kaolin according to the mass ratio for mixing;
step two: mixing the ingredients to serve as a blank, grinding the blank by a planetary ball mill, drying, grinding, granulating and ageing the obtained slurry, pressing the aged blank powder by a tablet press, taking out, biscuit firing, and preserving heat to obtain a black blank;
step three: taking 57% of feldspar, 16% of quartz, 12% of calcite, 11% of talcum and 4% of kaolin according to the mass ratio, and adding tricalcium phosphate Ca accounting for 2% of the total mass of the materials 3 (PO 4 ) 2 Mixing with 10% of boron frit, 0.8% of sodium carboxymethylcellulose and 0.3% of sodium polyphosphate to obtain mixed glaze;
step four: grinding the mixed glaze obtained in the third step by a planetary ball mill, uniformly applying the obtained glaze slurry on the prepared blank by adopting a glaze dipping method, and controlling the glazing thickness to be 5mm to obtain a glazed blank;
step five: and fourthly, drying the glazed blank, then placing the dried glazed blank into an electric furnace to be fired in an oxidizing atmosphere, and cooling the sample to prepare the amorphous photonic crystal structure colored glaze with high saturation.
2. The method for preparing the colored glaze with the high saturation amorphous photonic crystal structure according to claim 1, wherein in the second step, the rotating speed of a ball mill is 300r/min, the ball milling time is 40min, and the ratio of material to ball to water is 1.
3. The method for preparing high-saturation colored glaze with amorphous photonic crystal structure according to claim 1, wherein in the second step, a tablet press is used for pressing the aged blank powder under the pressure of 25MPa, the blank powder is bisque-fired to 900 ℃ after being taken out, and the temperature is kept for 120min.
4. The preparation method of the colored glaze with the high saturation amorphous photonic crystal structure according to claim 1, wherein in the fourth step, the rotating speed of the ball mill is 300r/min, the ball milling time is 40min, and the ratio of the material to the ball to the water is 1.
5. The method for preparing the colored glaze with the high-saturation amorphous photonic crystal structure according to claim 1, wherein the firing temperature in the fifth step is 1200-1350 ℃, and the temperature is kept for 10-50min.
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