CN114395931A - Cheese dyeing method capable of reducing internal and external color difference - Google Patents
Cheese dyeing method capable of reducing internal and external color difference Download PDFInfo
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- CN114395931A CN114395931A CN202210065502.7A CN202210065502A CN114395931A CN 114395931 A CN114395931 A CN 114395931A CN 202210065502 A CN202210065502 A CN 202210065502A CN 114395931 A CN114395931 A CN 114395931A
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- yarn
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- 235000013351 cheese Nutrition 0.000 title claims abstract description 97
- 238000004043 dyeing Methods 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 113
- 239000002699 waste material Substances 0.000 claims abstract description 53
- 238000004061 bleaching Methods 0.000 claims abstract description 22
- 239000002270 dispersing agent Substances 0.000 claims abstract description 21
- 238000004804 winding Methods 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims description 31
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 14
- 102220490391 Regucalcin_C40S_mutation Human genes 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 239000012224 working solution Substances 0.000 claims description 7
- 102220210373 rs1057521599 Human genes 0.000 claims description 3
- 102220527615 Transmembrane protein with metallophosphoesterase domain_C21S_mutation Human genes 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 230000004075 alteration Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 27
- 239000000975 dye Substances 0.000 description 16
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- 239000004902 Softening Agent Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 102220529569 ATP synthase subunit a_C21S_mutation Human genes 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- -1 sodium alkyl benzene Chemical class 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- UXYAJXBVMZFRMS-UHFFFAOYSA-N 2-hydroxy-1,3,2$l^{5}-dioxaphosphepane 2-oxide Chemical compound OP1(=O)OCCCCO1 UXYAJXBVMZFRMS-UHFFFAOYSA-N 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102220502409 Phosphoribosylformylglycinamidine synthase_C10S_mutation Human genes 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WMKBLOXVQBXSQM-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;2-hydroxy-1,3,2$l^{5}-dioxaphosphocane 2-oxide Chemical compound NCCNCCN.OP1(=O)OCCCCCO1 WMKBLOXVQBXSQM-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
- D06B3/09—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments as packages, e.g. cheeses
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention belongs to the technical field of cheese dyeing, and particularly relates to a cheese dyeing method for reducing internal and external chromatic aberration. The method comprises the following steps: adopting waste cheese and adding chelating dispersant to filter raw water; the raw water is underground water and/or reuse water; bleaching and/or dyeing the cheese base yarn by adopting the filtered water to obtain a cheese product with small inner and outer color difference; the winding density of the waste cheese is greater than that of the raw cheese. When the water quality can not meet the cheese dyeing requirement, the method can reduce the inner heterodynia of cheese dyeing, improve the level difference by 0.5-1, reduce the cost of water treatment, reasonably utilize waste yarns to purify the water quality, and is beneficial to popularization and application.
Description
Technical Field
The invention belongs to the technical field of cheese dyeing, and particularly relates to a cheese dyeing method for reducing internal and external chromatic aberration.
Background
Cheese dyeing is achieved by winding the yarn around a perforated bobbin and then loading a number of bobbins into a dye vat to color the yarn to achieve a unique color shade. The basic operation flow of the cheese dyeing machine is generally as follows: loosening, caging, dyeing, drying and rewinding. The cheese dyeing has the characteristics of small bath ratio, short process flow, small dye input amount and the like, and can reduce the production cost.
However, cheese dyeing has the problems of easy dye-impermeability and uneven dye. The color difference between the inner layer and the outer layer of the cheese dyed by the cheese generally has two conditions, namely the color depth of the middle layer yarn and the color depth of the inner layer yarn are different, the color light of the middle layer yarn is different, and the color depth of the inner layer yarn and the color depth of the outer layer yarn are different. In recent years, although dyeing equipment is continuously improved, the method is complex and high in cost, and the problem of color difference between the inner layer and the outer layer of cheese dyeing still needs to be solved.
Disclosure of Invention
In view of the above, the present invention provides a method for dyeing cheese, which can reduce the internal heterodyne of cheese dyeing and reduce the cost.
The invention provides a cheese dyeing method for reducing internal and external color difference, which comprises the following steps:
adopting waste cheese and adding chelating dispersant to filter raw water; the raw water is underground water and/or reuse water;
bleaching and/or dyeing the cheese base yarn by adopting the filtered water to obtain a cheese product with small inner and outer color difference; the winding density of the waste cheese is greater than that of the raw cheese.
In the embodiment of the invention, the winding density of the waste cheese is kept between 0.37 and 0.41g/cm3The average weight was 250-350 g.
In the embodiment of the invention, the hardness of the raw water is 250ppm-310ppm, and 1-2g/L of chelating dispersant is added.
In an embodiment of the present invention, the filtering process specifically includes: after raw water is put into the dye vat, adding a chelating dispersant, hanging the waste cheese into the dye vat, circulating for 50-70min, hanging the waste yarn out, and filtering the raw water.
In the embodiment of the invention, hydrogen peroxide working solution is adopted in the bleaching process, and the concentration of hydrogen peroxide is 4-15 g/L.
In the embodiment of the invention, the hydrogen peroxide working solution of the bleaching process also comprises 1-1.5g/L of penetrant and 2-2.5g/L of sodium hydroxide, and the hydrogen peroxide working solution is bleached at the temperature of 110 ℃.
In an embodiment of the invention, after the bleaching process is carried out by water washing and acid washing, the method for dyeing the cheese further comprises soft finishing.
In the embodiment of the invention, the specification of the waste cheese is C40S, and the specification of the raw cheese is C40S, C21S or C8S/2.
The color difference of cheese dyeing is caused by a plurality of factors, wherein a key factor is the water quality factor. The cheese dyeing water quality requires that the hardness is less than 25 ppm. The general requirements of cheese dyeing on water quality are as follows: free chlorine content is less than 0.05 mg/L; hardness <25 mg/L; chroma <3 degrees; iron content is less than or equal to 0.1 mg/L. If the chlorine content is higher, the reactive dye sensitive to chlorine can generate color change, and different colors are formed on the outer surface layer and the inner layer of the cheese. The water with high chroma always contains some suspended matters and other particles, and during dyeing, the cheese is like a filter to continuously filter the water, and unclean matters in the water are absorbed in the inner and outer layers of the cheese, so that the cheese cannot be normally circulated and used, and the color difference of the inner and outer layers of the cheese is often caused.
At present, the hardness of underground water raw water is 150-250 ppm, the underground water raw water does not meet the dyeing requirement, and after a chelating dispersant is added in dyeing, impurities in water are deposited on the inner layer of cheese to cause large difference between the inner layer and the outer layer after bleaching or dyeing. Similar inner layer deposition occurs with suspended impurities in the reuse water. Therefore, under the conditions that the current water treatment cost is high, the environmental protection requirement increases the use amount of reuse water, the waste yarn and the raw water reuse water are reasonably utilized, the color difference inside and outside the cheese is reduced, and the dyeing quality of the cheese is ensured.
The invention relates to a method for reducing the internal heterodyne of cheese dyeing when the water quality can not meet the cheese dyeing requirement, which mainly utilizes the daily produced waste cheese to purify the water quality, combines a chelating dispersant, can well filter underground water or reuse water, and then carries out normal cheese dyeing or bleaching procedures on the raw yarn with the bobbin winding density lower than that of the waste cheese. When the water quality can not meet the cheese dyeing requirement, the method can reduce the inner heterodynia of cheese dyeing, improve the level difference by 0.5-1, reduce the cost of water treatment, reasonably utilize waste yarns to purify the water quality, and is beneficial to popularization and application.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a cheese dyeing method for reducing internal and external color difference, which comprises the following steps:
adopting waste cheese and adding chelating dispersant to filter raw water; the raw water is underground water and/or reuse water;
bleaching and/or dyeing the cheese base yarn by adopting the filtered water to obtain a cheese product with reduced internal and external color difference; the winding density of the waste cheese is greater than that of the raw cheese.
The method for dyeing the cheese can reduce the inner heterodyning of the cheese dyeing, reduce the cost and is beneficial to popularization and application.
Mainly for solving the technical problem of the difference between the inner layer and the outer layer of the dyed cheese, the technical scheme adopted by the embodiment of the invention is as follows:
(1) building a raw water filtering system;
(2) the use of a raw water filtration system;
(3) and (5) carrying out a cheese dyeing process.
The raw water filtration system built by the embodiment of the invention mainly adopts bobbin waste yarn, and the structure of the raw water filtration system is similar to a membrane filtration structure; the invention integrates and innovates resources across the boundary, and utilizes waste yarn to filter and purify water, thereby not only reducing the cost, but also effectively purifying the water. The waste cheese is obtained by loosening waste yarns produced in daily production, and the density is kept between 0.37 and 0.41g/cm3The average weight was 250-350 g. According to the embodiment of the invention, the waste yarn barrel prepared according to the standard parameters is arranged on the steel frame to form a raw water filtering system, and the steel frame is hung beside the dye vat for standby.
In the embodiment of the invention, the built water filtering system is used for filtering raw water. The invention treats the water quality before cheese dyeing, utilizes underground water or reuse water, saves the water treatment cost, and improves the quality of uniform color inside and outside the cheese, which can be obtained by cross-boundary creative labor.
The invention relates to a dyeing and finishing method for reducing the heterodyne in the cheese dyeing when the water quality can not meet the cheese dyeing requirement, wherein the hardness of raw water is generally 250ppm-310ppm, such as 285-305 ppm.
Preferably, the filtering process performed by using the filtering system in the embodiment of the present invention specifically includes: and (3) putting raw water into the dye vat, adding a chelating dispersant, hanging the waste cheese into the dye vat, setting a program, performing single external circulation for 50-70min, then hanging the waste cheese out, and filtering the raw water.
The waste yarn is used for filtering water quality, and the yarn count and the winding density of the waste water are comprehensively selected according to the dyed good yarn and the like. For example: the dyed good yarn was 40s, and the package density was 0.35g/cm3. The density of the waste yarn is 0.35g/cm3Large, at least 0.38-0.40g/cm3Otherwise, the filtering effect cannot be achieved. In some embodiments of the invention, the size of the waste yarn on the bobbin is C40S, and the size of the raw yarn on the bobbin (good yarn for dyeing) is C40S, C21S or C8S/2. The bulk density of each yarn count has a fixed value, C21S is 0.33g/cm3(ii) a 0.32g/cm below C10S3. The invention has no special limit requirement on the material of the cheese, and the cotton yarn, the ramie yarn, the chemical fiber and the blended yarn can be selected and are not limited to the cotton yarn.
Moreover, the invention preferably adds 1-2g/L of chelating dispersant; the chelating dispersant is usually organic phosphate, such as sodium Ethylene Diamine Tetra Methylene Phosphate (EDTMPS), diethylenetriamine penta methylene phosphate (DETPMS) and the like. In the embodiment of the invention, the filtering effect of the waste cheese on water mainly aims at suspended impurities in raw water; also comprises the filtration of calcium and magnesium ions after the chelating agent is added. According to the local water quality condition, a proper amount of chelating dispersant is required to be added into the water to chelate calcium and magnesium ions in the water, and the part of impurities is filtered out by utilizing the filtering action of waste yarns, thereby realizing the purification of the water quality. If the water hardness can not meet the requirement without adding chelating dispersant, the subsequent process is difficult to carry out.
After the waste yarn is filtered, the embodiment of the invention carries out conventional cheese dyeing and/or bleaching procedures and the like.
In some embodiments of the present invention, the bleaching process is an alkaline oxygen bleaching process, and specifically bleaching is performed with hydrogen peroxide working solution. Illustratively, the concentration of hydrogen peroxide in the hydrogen peroxide working solution is 4-15 g/L; also comprises 1-1.5g/L of penetrating agent and 2-2.5g/L of sodium hydroxide. The penetrant comprises anionic or nonionic and compound penetrant, including alkyl sodium sulfonate, sodium alkyl benzene sulfonate, sodium alkyl sulfate, secondary alkyl sodium sulfonate, etc. The bleaching process conditions comprise: 110-120 ℃ heat preservation for 30-40 min; and then washing with water, pickling and the like to obtain a bleached cheese product. In addition, a soft finish can be applied, for example, of the polyethylene wax emulsion type, polyethers, fatty amide-based soft tablets.
In some embodiments of the present invention, the dyeing is a reactive dye one bath process, using dyeing operations conventional in the art.
By the method, the cheese is dyed uniformly inside and outside, the layer difference can be improved by 0.5-1 level, and the method is simple, convenient and feasible and has low cost.
For further understanding of the present application, the method for dyeing cheese provided by the present application is specifically described below with reference to the examples. It should be understood, however, that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention, which is defined by the following examples. The examples, where specific techniques or conditions are not indicated, are to be construed according to the techniques or conditions described in the literature in the art or according to the product specifications. The reagents or instruments used are not indicated by manufacturers, and are all conventional products available on the market.
In the following examples, chelating dispersants: powerful metal ion scavenger TX-908 Nicotiana yuanming textile science and technology Limited; penetrating agent DT-J01 Shandong yellow river Delta textile science and technology Co., Ltd; softener 600D Suzhou Lisheng chemical Co., Ltd. The bath ratio was controlled at 1: 10.
Example 1
(1) Building a water quality filtering system: the waste C40S yarn was fluffed to an average density of 0.4g/cm3And the average weight is 310g, waste yarn cylinders prepared according to standard parameters are arranged on a steel frame, and the steel frame is hung beside a dye vat for standby.
(2) Putting the built water filtration system into raw water (the hardness is about 285ppm), adding 1.7g/L of chelating dispersant, hanging the waste yarn steel frame into a dye vat, setting the program as single external circulation for 60min, then hanging out the waste yarn, and completing the raw water filtration (the water hardness is close to 0).
(3) The C21s yarn was bleached in filtered water as follows:
10g/L of hydrogen peroxide;
2.4g/L of sodium hydroxide;
1.2g/L of penetrant;
the process conditions are as follows: keeping the temperature at 110 ℃ for 40min, and performing single-flow;
washing with water at 90 deg.C for 10min, and acid washing (0.5g/L) at room temperature for 10 min;
after treatment, softener 5g/L is added at 45 ℃ for 30 min.
Bleaching product results: a whiteness degree 74.74; the difference between the inner layer and the middle layer is 3.5 grades, and the qualified standard is achieved.
Example 2
(1) Building a water quality filtering system: the waste C40S yarn was fluffed to an average density of 0.4g/cm3And the average weight is 323g, waste yarn barrels prepared according to standard parameters are arranged on a steel frame, and the steel frame is hung beside a dye vat for standby.
(2) And (3) putting the built water filtration system into raw water (the hardness is about 300ppm), adding a chelating dispersant in an amount of 2.0g/L, hoisting the waste yarn steel frame into a dye vat, setting the program as single external circulation for 60min, then hoisting the waste yarn out, and finishing the filtration of the raw water.
(3) The C21s yarn was bleached in filtered water as follows:
15g/L of hydrogen peroxide;
2.5g/L of sodium hydroxide;
1.5g/L of penetrant;
the process conditions are as follows: keeping the temperature at 110 ℃ for 40min, and performing single-flow;
washing with water at 90 deg.C for 10min, and acid washing (0.5g/L) at room temperature for 10 min;
after treatment, 4g/L of softening agent is added, and the temperature is 45 ℃ for 30 min.
Bleaching product results: a whiteness degree 76.23; the difference between the inner layer and the middle layer is 3.5 grades, and the qualified standard is achieved.
Example 3
(1) Building a water quality filtering system: the waste C40S yarn was fluffed to an average density of 0.4g/cm3And the average weight is 323g, waste yarn barrels prepared according to standard parameters are arranged on a steel frame, and the steel frame is hung beside a dye vat for standby.
(2) And (3) putting the built water filtration system into raw water (the hardness is about 298ppm), adding a chelating dispersant of 2.0g/L, hoisting the waste yarn steel frame into a dye vat, setting the program as single external circulation for 60min, then hoisting the waste yarn out, and finishing the filtration of the raw water.
(3) The C8s/2 yarn was bleached in filtered water as follows:
5g/L of hydrogen peroxide
Sodium hydroxide 2g/L
1.5g/L of penetrant;
the process conditions are as follows: keeping the temperature at 110 ℃ for 40min, and performing single-flow;
washing with water at 90 deg.C for 10min, and acid washing (0.5g/L) at room temperature for 10 min;
after treatment, 4g/L of softening agent is added, and the temperature is 45 ℃ for 30 min.
Bleaching product results: the whiteness is 75.54; the difference between the inner layer and the middle layer is 4 grades, and the qualified standard is achieved.
Example 4
(1) Building a water quality filtering system: the waste C40S yarn was fluffed to an average density of 0.4g/cm3And the average weight is 323g, waste yarn barrels prepared according to standard parameters are arranged on a steel frame, and the steel frame is hung beside a dye vat for standby.
(2) And (3) putting the built water filtration system into raw water (the hardness is about 223ppm), adding 1.5g/L of chelating dispersant, hoisting the waste yarn steel frame into a dye vat, setting the program as single external circulation for 60min, then hoisting the waste yarn out, and finishing the filtration of the raw water.
(3) The C20s yarn was bleached in filtered water as follows:
hydrogen peroxide 12g/L
Sodium hydroxide 2g/L
1.5g/L of penetrant;
the process conditions are as follows: keeping the temperature at 110 ℃ for 40min at a bath ratio of 1:10, and performing single-flow;
washing with water at 90 deg.C for 10min, and acid washing (0.5g/L) at room temperature for 10 min;
after treatment, 4g/L of softening agent is added, and the temperature is 45 ℃ for 30 min.
Dyeing the bleached cheese according to the following formula:
the process conditions are as follows: keeping the temperature at 60 ℃ for 60min, keeping the bath ratio at 1:10, and performing single-flow;
washing with water at 90 deg.C for 10min, and acid washing (0.5g/L) at room temperature for 10 min;
after treatment, 4g/L of softening agent is added, and the temperature is 45 ℃ for 30 min.
Dyeing product results: orange yarn, which is of grade 4 for the standard sample, and the difference between the inner layer and the middle layer is grade 4, thus reaching the qualified standard.
From the above examples, it can be seen that when the water quality can not meet the cheese dyeing requirements, the present invention mainly utilizes the daily produced waste cheese to purify the water quality, and the chelating dispersant is combined to well filter the underground water or the reuse water, and then the normal cheese dyeing or bleaching process is carried out on the raw yarn with the winding density lower than that of the waste cheese. When the water quality can not meet the cheese dyeing requirement, the method can reduce the inner heterodynia of cheese dyeing, improve the level difference by 0.5-1, reduce the cost of water treatment, reasonably utilize waste yarns to purify the water quality, and is beneficial to popularization and application.
The above description is only a preferred embodiment of the present invention, and it should be noted that various modifications to these embodiments can be implemented by those skilled in the art without departing from the technical principle of the present invention, and these modifications should be construed as the scope of the present invention.
Claims (8)
1. A method for dyeing cheese with reduced color difference between inside and outside is characterized by comprising the following steps:
adopting waste cheese and adding chelating dispersant to filter raw water; the raw water is underground water and/or reuse water;
bleaching and/or dyeing the cheese base yarn by adopting the filtered water to obtain a cheese product with small inner and outer color difference; the winding density of the waste cheese is greater than that of the raw cheese.
2. The method for dyeing cheese according to claim 1, characterized in that the cone density of the cone waste yarn is maintained between 0.37 and 0.41g/cm3The average weight was 250-350 g.
3. The method for dyeing cheese according to claim 1, characterized in that the raw water has a hardness of 250ppm to 310ppm and 1 to 2g/L of chelating dispersant is added.
4. The method for dyeing cheese according to any of claims 1 to 3, characterized in that the filtration treatment is in particular: after raw water is put into the dye vat, adding a chelating dispersant, hanging the waste cheese into the dye vat, circulating for 50-70min, hanging the waste yarn out, and filtering the raw water.
5. The method for dyeing the cheese according to any one of claims 1 to 3, wherein the bleaching process adopts hydrogen peroxide working solution, and the concentration of the hydrogen peroxide is 4 to 15 g/L.
6. The method for dyeing cheese according to claim 5, wherein the hydrogen peroxide working solution of the bleaching process further comprises 1-1.5g/L of penetrant and 2-2.5g/L of sodium hydroxide, and the bleaching is performed at 110-120 ℃.
7. The method for dyeing cheese according to claim 6, wherein the bleaching step further comprises a soft finish after washing with water and acid.
8. The method for dyeing cheese according to any of claims 1 to 3, characterized in that the cheese waste has a size of C40S and the cheese base has a size of C40S, C21S or C8S/2.
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