CN114368245A - Method for making stainless steel porcelain picture - Google Patents

Method for making stainless steel porcelain picture Download PDF

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Publication number
CN114368245A
CN114368245A CN202111586661.3A CN202111586661A CN114368245A CN 114368245 A CN114368245 A CN 114368245A CN 202111586661 A CN202111586661 A CN 202111586661A CN 114368245 A CN114368245 A CN 114368245A
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China
Prior art keywords
base material
stainless steel
firing
parts
glaze
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Pending
Application number
CN202111586661.3A
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Chinese (zh)
Inventor
张柳松
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Individual
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Individual
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Priority to CN202111586661.3A priority Critical patent/CN114368245A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0415Ornamental plaques, e.g. decorative panels, decorative veneers containing metallic elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44DPAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D2/00Special techniques in artistic painting or drawing, e.g. oil painting, water painting, pastel painting, relief painting
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D11/00Continuous processes; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/06Coating with enamels or vitreous layers producing designs or letters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention relates to a method for manufacturing stainless steel porcelain paintings, which comprises the steps of selecting a base material, carrying out surface heat treatment on the base material, carrying out roughening surface treatment, applying ground coat on the surface of the base material, primarily firing the base material, applying white glaze on the surface of the base material, printing patterns on the surface of the base material, finally firing the base material and the like. The method has the advantages of ingenious design, stable base material, low manufacturing cost, hard texture, difficult rusting, customizable size, autonomously selectable patterns, attractive and elegant product, firmness and durability, and long-term storage, solves the technical problems of high manufacturing cost, difficult popularization, soft texture, easy collision and scratch, easy rusting, porcelain falling, short service cycle and the like of the existing metal plate paintings in the transportation process, and has good market prospect and development space for the prior art.

Description

Method for making stainless steel porcelain picture
Technical Field
The invention relates to the technical field of metal plate ceramic paintings, in particular to a method for manufacturing a stainless steel ceramic painting.
Background
Along with the improvement of people's standard of living, people are more and more high to the attention degree of indoor decoration pattern, for example the interior decoration is drawn mostly and is used rice paper to draw the mounting, and the yellowing oxidation problem appears in the long time easily, though the problem of yellowing oxidation is solved in the glass board drawing, but heavy, the transportation is inconvenient, and some metal sheet paintings get into people's demand scope gradually. The metal decorative painting at the present stage is mainly common, titanium plate painting is hard in texture and not easy to rust, but the manufacturing cost is high and cannot be popularized; the aluminum plate picture is low in manufacturing cost and simple and convenient to manufacture, but is soft in texture and very easy to collide and scratch in the transportation process; although the iron plate picture is low in manufacturing cost and hard in texture, the iron plate picture still has the following problems of easiness in rusting, porcelain falling and short service cycle. The technical problem that the ground coat layer and the base material can not be smoothly combined and fall off frequently occurs in the existing stainless steel plate painting manufacturing process.
How to design a manufacturing method of stainless steel porcelain painting which has the advantages of ingenious design, stable base material, low manufacturing cost, hard texture, difficult rustiness, customizable size, independent pattern selection, beautiful and elegant product, firmness and durability and long-term storage is the problem to be solved at present.
Disclosure of Invention
The invention provides a method for manufacturing a stainless steel porcelain picture, which aims to solve the technical problems that the existing metal plate picture is high in manufacturing cost, cannot be popularized, is soft in texture, is very easy to collide and scratch in the transportation process, is easy to rust and fall off porcelain, is short in service cycle and the like.
The technical scheme adopted by the invention for solving the technical problems is as follows: a manufacturing method of a stainless steel porcelain picture comprises the following steps:
selecting a base material, namely selecting a stainless steel plate as the base material of the ceramic picture;
secondly, performing surface heat treatment on the base material, namely horizontally placing the stainless steel base material into a tempering furnace for heat treatment to remove surface oil stains, controlling the temperature in the tempering furnace to be 500-600 ℃, and heating for 1-5 min;
thirdly, performing surface roughening treatment on the surface of the base material, performing sand blasting and surface roughening treatment on the surface of the stainless steel base material by using a sand blasting machine, then putting the stainless steel base material into a cleaning machine, cleaning by using alkaline water, drying after cleaning, and cooling to room temperature, so as to facilitate subsequent base glaze application;
step four, applying base coat on the surface of the substrate, and mixing the stainless steel powder and the base coat glaze material according to the proportion of 1: 3, fully stirring the mixture according to the proportion, and then glazing the surface of the base material;
step five, primarily firing the base material, namely placing the base material applied with the ground coat into a tempering furnace for heating and firing, controlling the temperature in the tempering furnace to be 700-1000 ℃, firing for 5-8min, and blowing air to cool to room temperature after firing;
step six, applying white glaze on the surface of the base material;
seventhly, printing patterns on the surface of the base material, and performing high-definition pattern printing on the surface of the base material treated in the sixth step by using a high-definition ceramic printer;
and step eight, finally firing the base material, namely placing the stainless steel plate printed in the step seven into a tempering furnace for high-temperature firing, controlling the temperature in the tempering furnace to be 700-1000 ℃, firing for 5-8min, and blowing air to cool to room temperature after firing.
The material of the stainless steel plate used in the first step is 201 or 304 stainless steel.
The ground glaze in the fourth step comprises the following components in parts by weight: 20-50 parts of agate powder, 10-20 parts of low-temperature frit powder, 10-30 parts of potassium oxide, 10-30 parts of calcium oxide, 5-20 parts of aluminum oxide and 70-90 parts of water.
The stainless steel powder used in the fourth step is nano-scale stainless steel powder.
The white glaze used in the sixth step is a commercially available ceramic white glaze.
The printing of the pattern in the seventh step can also use manual drawing of the pattern.
Compared with the prior art, the invention has the beneficial effects that:
1) the invention creatively provides a metal plate painting manufacturing process which has the advantages of ingenious design, stable base material, low manufacturing cost, hard texture, difficult rusting, customizable size, autonomously selectable pattern, attractive and elegant product, firmness and durability by integrating the defects of various existing metal plate paintings, and solves the existing problems;
2) the base material can be cut in advance according to the needs of customers, the size and the size of a good cutting plate are good, and the autonomy of a subsequent pattern selection user is better;
3) and (2) placing the stainless steel plate printed in the seven high-definition printing steps into a tempering furnace for high-temperature firing, cooling the plate by utilizing the upper and lower double-layer air grids after firing to obtain the stainless steel ceramic painting, firing the stainless steel ceramic painting by adopting the tempering furnace, wherein the firing temperature and the firing time are easy to control, and the fired product is attractive and elegant, firm and durable, saves the labor cost and improves the enterprise benefit.
Detailed Description
The following describes embodiments of the present invention in further detail.
In the first embodiment, the first step is,
a manufacturing method of a stainless steel porcelain picture comprises the following steps:
selecting a base material, namely selecting a stainless steel plate as the base material of the ceramic picture;
secondly, performing surface heat treatment on the base material, namely horizontally placing the stainless steel base material into a toughening furnace for heat treatment to remove surface oil stains, controlling the temperature in the toughening furnace at 500 ℃, and heating for 1 min;
thirdly, performing surface roughening treatment on the surface of the base material, performing sand blasting and surface roughening treatment on the surface of the stainless steel base material by using a sand blasting machine, then putting the stainless steel base material into a cleaning machine, cleaning by using alkaline water, drying after cleaning, and cooling to room temperature, so as to facilitate subsequent base glaze application;
step four, applying base coat on the surface of the substrate, and mixing the stainless steel powder and the base coat glaze material according to the proportion of 1: 3, fully stirring the mixture according to the proportion, and then glazing the surface of the base material;
fifthly, primarily firing the base material, namely placing the base material with the bottom glaze in a tempering furnace for heating and firing, controlling the temperature in the tempering furnace to be 700 ℃, firing for 5min, and blowing air to cool to room temperature after firing;
step six, applying white glaze on the surface of the substrate, wherein the white glaze is commercially available ceramic white glaze;
seventhly, printing patterns on the surface of the base material, and performing high-definition pattern printing on the surface of the base material treated in the step six by using a high-definition ceramic printer, wherein the patterns in the step seven can also be printed by using manual hand-drawing patterns;
and step eight, finally firing the base material, namely placing the stainless steel plate subjected to high-definition printing in the step seven into a toughening furnace for high-temperature firing, controlling the temperature in the toughening furnace at 700 ℃, firing for 5-8min, and blowing air to cool to room temperature after firing.
The stainless steel plate used in the first step is made of 201 stainless steel.
The ground glaze in the fourth step comprises the following components in parts by weight: 20-50 parts of agate powder, 10 parts of low-temperature frit powder, 10 parts of potassium oxide, 10 parts of calcium oxide, 5 parts of aluminum oxide and 70 parts of water.
In the second embodiment, the first embodiment of the method,
a manufacturing method of a stainless steel porcelain picture comprises the following steps:
selecting a base material, namely selecting a stainless steel plate as the base material of the ceramic picture;
secondly, performing surface heat treatment on the base material, namely horizontally placing the stainless steel base material into a toughening furnace for heat treatment to remove surface oil stains, controlling the temperature in the toughening furnace to be 550 ℃, and heating for 3 min;
thirdly, performing surface roughening treatment on the surface of the base material, performing sand blasting and surface roughening treatment on the surface of the stainless steel base material by using a sand blasting machine, then putting the stainless steel base material into a cleaning machine, cleaning by using alkaline water, drying after cleaning, and cooling to room temperature, so as to facilitate subsequent base glaze application;
step four, applying base coat on the surface of the substrate, and mixing the stainless steel powder and the base coat glaze material according to the proportion of 1: 3, fully stirring the mixture according to the proportion, and then glazing the surface of the base material;
fifthly, primarily firing the base material, namely placing the base material with the bottom glaze in a toughening furnace for heating and firing, controlling the temperature in the toughening furnace to be 800 ℃, firing for 7min, and blowing air to cool to room temperature after firing;
step six, applying white glaze on the surface of the substrate, wherein the white glaze is commercially available ceramic white glaze;
seventhly, printing patterns on the surface of the base material, and performing high-definition pattern printing on the surface of the base material treated in the step six by using a high-definition ceramic printer, wherein the patterns in the step seven can also be printed by using manual hand-drawing patterns;
and step eight, finally firing the base material, namely placing the stainless steel plate subjected to high-definition printing in the step seven into a tempering furnace for high-temperature firing, controlling the temperature in the tempering furnace at 900 ℃, firing for 7min, and blowing air to cool to room temperature after firing.
The material of the stainless steel plate used in the first step is 304 stainless steel.
The ground glaze in the fourth step comprises the following components in parts by weight: 35 parts of agate powder, 15 parts of low-temperature frit powder, 20 parts of potassium oxide, 20 parts of calcium oxide, 15 parts of aluminum oxide and 80 parts of water
In the third embodiment, the first step is that,
a manufacturing method of a stainless steel porcelain picture comprises the following steps:
selecting a base material, namely selecting a stainless steel plate as the base material of the ceramic picture;
secondly, performing surface heat treatment on the base material, namely horizontally placing the stainless steel base material into a toughening furnace for heat treatment to remove surface oil stains, controlling the temperature in the toughening furnace to be 600 ℃, and heating for 5 min;
thirdly, performing surface roughening treatment on the surface of the base material, performing sand blasting and surface roughening treatment on the surface of the stainless steel base material by using a sand blasting machine, then putting the stainless steel base material into a cleaning machine, cleaning by using alkaline water, drying after cleaning, and cooling to room temperature, so as to facilitate subsequent base glaze application;
step four, applying base coat on the surface of the substrate, and mixing the stainless steel powder and the base coat glaze material according to the proportion of 1: 3, fully stirring the mixture according to the proportion, and then glazing the surface of the base material;
fifthly, primarily firing the base material, namely placing the base material with the bottom glaze in a toughening furnace for heating and firing, controlling the temperature in the toughening furnace to be 1000 ℃, firing for 8min, and blowing air to cool to room temperature after firing;
step six, applying white glaze on the surface of the substrate, wherein the white glaze is commercially available ceramic white glaze;
seventhly, printing patterns on the surface of the base material, and performing high-definition pattern printing on the surface of the base material treated in the step six by using a high-definition ceramic printer, wherein the patterns in the step seven can also be printed by using manual hand-drawing patterns;
and step eight, finally firing the base material, namely placing the stainless steel plate subjected to high-definition printing in the step seven into a toughening furnace for high-temperature firing, controlling the temperature in the toughening furnace at 1000 ℃, firing for 8min, and blowing air to cool to room temperature after firing.
The material of the stainless steel plate used in the first step is 304 stainless steel.
The ground glaze in the fourth step comprises the following components in parts by weight: 20-50 parts of agate powder, 20 parts of low-temperature frit powder, 30 parts of potassium oxide, 30 parts of calcium oxide, 20 parts of aluminum oxide and 90 parts of water
In practice, in step one, the thickness of the selected stainless steel substrate is generally between 0.5 and 3mm, and in step five and step eight, the firing temperature and the firing time are determined by the thickness of the selected plate, the thinner the plate, the shorter the firing time, the thicker the plate, and the longer the firing time.
The invention mainly solves the technical problems of various existing metal plate paintings, in particular the technical defects of easy rusting, porcelain falling, short service cycle and the like in the iron enamel plate painting similar to the base material of the metal plate painting, and the glazing on the stainless steel is a technical problem which troubles the development of the industry for many years and has no breakthrough. The inventor creatively proposes that the nano-scale stainless steel powder is used as the bonding intermediate layer between the ground coat and the base material in the fourth step, the stainless steel powder and the ground coat glaze material are fully stirred, the expansion coefficients of the glaze layer and the stainless steel base material are approximate, and the combination of the glaze layer and the stainless steel base material is more favorable during high-temperature firing.
The method has the advantages of ingenious design, stable base material, low manufacturing cost, hard texture, difficult rusting, customizable size, autonomously selectable patterns, attractive and elegant product, firmness and durability, and long-term storage, solves the technical problems of high manufacturing cost, difficult popularization, soft texture, easy collision and scratch, easy rusting, porcelain falling, short service cycle and the like of the existing metal plate paintings in the transportation process, and has good market prospect and development space for the prior art.
While the preferred embodiments and examples of the present invention have been described in detail, the present invention is not limited to the embodiments and examples, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art.

Claims (6)

1. A manufacturing method of a stainless steel porcelain picture is characterized by comprising the following steps: the method comprises the following steps:
selecting a base material, namely selecting a stainless steel plate as the base material of the ceramic picture;
secondly, performing surface heat treatment on the base material, namely horizontally placing the stainless steel base material into a tempering furnace for heat treatment to remove surface oil stains, controlling the temperature in the tempering furnace to be 500-600 ℃, and heating for 1-5 min;
thirdly, performing surface roughening treatment on the surface of the base material, performing sand blasting and surface roughening treatment on the surface of the stainless steel base material by using a sand blasting machine, then putting the stainless steel base material into a cleaning machine, cleaning by using alkaline water, drying after cleaning, and cooling to room temperature, so as to facilitate subsequent base glaze application;
step four, applying base coat on the surface of the substrate, and mixing the stainless steel powder and the base coat glaze material according to the proportion of 1: 3, fully stirring the mixture according to the proportion, and then glazing the surface of the base material;
step five, primarily firing the base material, namely placing the base material applied with the ground coat into a tempering furnace for heating and firing, controlling the temperature in the tempering furnace to be 700-1000 ℃, firing for 5-8min, and blowing air to cool to room temperature after firing;
step six, applying white glaze on the surface of the base material;
seventhly, printing patterns on the surface of the base material, and performing high-definition pattern printing on the surface of the base material treated in the sixth step by using a high-definition ceramic printer;
and step eight, finally firing the base material, namely placing the stainless steel plate printed in the step seven into a tempering furnace for high-temperature firing, controlling the temperature in the tempering furnace to be 700-1000 ℃, firing for 5-8min, and blowing air to cool to room temperature after firing.
2. The method for making the stainless steel porcelain picture according to claim 1, wherein the method comprises the following steps: the material of the stainless steel plate used in the first step is 201 or 304 stainless steel.
3. The method for making the stainless steel porcelain picture according to claim 1, wherein the method comprises the following steps: the ground glaze in the fourth step comprises the following components in parts by weight: 20-50 parts of agate powder, 10-20 parts of low-temperature frit powder, 10-30 parts of potassium oxide, 10-30 parts of calcium oxide, 5-20 parts of aluminum oxide and 70-90 parts of water.
4. The method for making the stainless steel porcelain picture according to claim 1, wherein the method comprises the following steps: the stainless steel powder used in the fourth step is nano-scale stainless steel powder.
5. The method for making the stainless steel porcelain picture according to claim 1, wherein the method comprises the following steps: the white glaze used in the sixth step is a commercially available ceramic white glaze.
6. The method for making the stainless steel porcelain picture according to claim 1, wherein the method comprises the following steps: the printing of the pattern in the seventh step can also use manual drawing of the pattern.
CN202111586661.3A 2021-12-23 2021-12-23 Method for making stainless steel porcelain picture Pending CN114368245A (en)

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CN202111586661.3A CN114368245A (en) 2021-12-23 2021-12-23 Method for making stainless steel porcelain picture

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Application Number Priority Date Filing Date Title
CN202111586661.3A CN114368245A (en) 2021-12-23 2021-12-23 Method for making stainless steel porcelain picture

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3922458A (en) * 1972-11-24 1975-11-25 Curran Oils Ltd Vitreous enamelling
CN102083621A (en) * 2008-07-29 2011-06-01 Seb公司 Article with a ceramic coating and method for producing such an article using a laser
CN102976614A (en) * 2012-12-14 2013-03-20 中国科学院金属研究所 Low-cost glass enamel powder for stainless steel
CN103826514A (en) * 2011-06-17 2014-05-28 朱利亚股份公司 Heat exchanger, shower tray and method for producing a shower tray
CN108264232A (en) * 2018-01-24 2018-07-10 东北大学 Anti-oxidant, corrosion-resistant, shock proof high-temperature tubring coating and preparation method thereof
CN108972352A (en) * 2018-08-31 2018-12-11 张柳松 A kind of production method that iron plate enamel decorative is drawn
CN109130678A (en) * 2018-08-31 2019-01-04 张柳松 A kind of production method of aluminium sheet decoration painting
CN111349935A (en) * 2018-12-21 2020-06-30 武义威特厨房用具有限公司 Manufacturing process of stainless steel enamel cup
CN112062469A (en) * 2020-08-28 2020-12-11 浙江开尔新材料股份有限公司 Bottom glaze material of stainless steel enamel plate and preparation method and application thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3922458A (en) * 1972-11-24 1975-11-25 Curran Oils Ltd Vitreous enamelling
CN102083621A (en) * 2008-07-29 2011-06-01 Seb公司 Article with a ceramic coating and method for producing such an article using a laser
CN103826514A (en) * 2011-06-17 2014-05-28 朱利亚股份公司 Heat exchanger, shower tray and method for producing a shower tray
CN102976614A (en) * 2012-12-14 2013-03-20 中国科学院金属研究所 Low-cost glass enamel powder for stainless steel
CN108264232A (en) * 2018-01-24 2018-07-10 东北大学 Anti-oxidant, corrosion-resistant, shock proof high-temperature tubring coating and preparation method thereof
CN108972352A (en) * 2018-08-31 2018-12-11 张柳松 A kind of production method that iron plate enamel decorative is drawn
CN109130678A (en) * 2018-08-31 2019-01-04 张柳松 A kind of production method of aluminium sheet decoration painting
CN111349935A (en) * 2018-12-21 2020-06-30 武义威特厨房用具有限公司 Manufacturing process of stainless steel enamel cup
CN112062469A (en) * 2020-08-28 2020-12-11 浙江开尔新材料股份有限公司 Bottom glaze material of stainless steel enamel plate and preparation method and application thereof

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